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removal of hardness
Hardness is?...
primarily Ca, Mg, plus Fe, Mn, St, Al
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Classifying Water Hardness
Description of water Hardness expressed as mg/L of CaCO3
Hard 150–300
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Why bother?
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Formation of Hardness
Precipitation
Topsoil
Subsoil
CO2 + H2O H2CO3
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Hardness
Non-Carbonate Hardness
» Called permanent hardness because it is not
removed when the water is heated. It is much
more expensive to remove non-carbonate
hardness than carbonate hardness.
» Ca2+, Mg2+ associated with other ions, Cl-,
NO3-, SO42-
» NCH = TH - CH
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Hardness Units
milligrams per liter (mg/L) as calcium
carbonate (most common)
parts per million (ppm) as calcium carbonate
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What is “lime”?
• Limestone, mainly
calcium carbonate,
CaCO3
• Quicklime, calcium
oxide, CaO
• Slaked lime,
calcium hydroxide,
Ca(OH)2
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Lime Conversions
• Limestone can be converted to quick lime:
CaCO3 CaO + CO2 (1800F)
• Quick lime is slaked with water:
CaO + H2O Ca(OH)2
• Slaked lime slowly reacts with CO2 in air:
…Ca(OH)2 + CO2 CaCO3 + H2O
• Dissolved lime (hardness) can precipitate:
Ca(HCO3)2 CaCO3 + H2O + CO2
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LIME - SODA ASH SOFTENING
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Stoichiometry
CO2 + Ca(OH)2 --> CaCO3 + H2O
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Typical lime softening process…
Ca(OH)2
Lime
Lime sludge
…presented as a complete
drinking water treatment process
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Precipitation occurs in a settling tank
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Solubilities
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Removal by precipitation
Is complete removal possible?...
No, lime-soda ash softening
cannot remove all hardness
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Effectiveness
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BASE EXCHANGE PROCESS
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BASE EXCAHNGE/ZEOLITE
ROCESS
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Applications of ion exchange in water & wastewater
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• Natural: Proteins, Soils, Lignin, Coal,
Metal oxides, Aluminosilicates
(zeolites) (NaOAl2O3.4SiO2).
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:
FOLLOWING ARE OTHER WAYS OF REMOVING ODORS IN WATER TREATMENTPLANTS
Oxidation
Oxidation is the best method for controlling taste and odor problems.
Aeration
Aeration is a practical solution for taste and odor control when the problem is caused by
volatile compounds, such as hydrogen sulfide. It is generally not the best method for
controlling taste and odors that are caused by algae.
Adsorption
Adding powdered activated carbon to water or using /granular activated carbon (GAC)
in the water filter can remove taste and odor. Powdered activated carbon (PAC) is the
preferred method when the taste and odor is moderate and infrequent.
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1. Water Treatments Aeration
Aeration is the process of bringing water in intimate contact with
air.
During the process, water absorbs oxygen from the air. Aeration
removes iron, manganese, CO,. H2S and oxidize certain organic
impurities present in the water.
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ii) Water Treatments with Activated carbon.
Activated carbon is obtained by charring wood or saw dust at
500°C in a closed vessels, thereby hydrocarbons, which usually
interfere with the absorption of organic matters, are expelled.
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Water Treatments with Copper Sulphate.
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