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Introduction Results
Nanoscale titanium dioxide (TiO2) films were successfully 110
deposited on the surface of PET and PA6.6 fabrics and films by a) 100 a)
110
b)
100
90
T (%)
T (%)
80
70
ATR) and energy x-ray analysis (EDX). Thermal properties were 110
c)
80
80
70
T (% )
60
T (%)
60
40
50
Untreated PET film Untreated PA6.6 film
PET film treated with 15 min TiO2 40 PA6.6 film treated with 15 min TiO2
20
PET film treated with 30 min TiO2 30 PA6.6 film treated with 30 min TiO2
PET film treated with 45 min TiO2 PA6.6 film treated with 45 min TiO2
0 20
Experimental Conditions
Samples: Figure 3. FTIR-ATR spectra of TiO2 deposition: a) PET fabric; b) PA6.6 fabric; c) PET film;
Fabrics: and d) PA6.6 film
• PET woven fabric with a density of 240 g/m2 and a thickness of 80 10 200 10
W/mK)
m 2K/W)
W/mK)
60
m 2K/W)
150
Untreated fabric Untreated film
of 0.35 mm; 45 min and films treated with 15 min. 15 min TiO2 deposition
-3
15 min TiO2 deposition
-3
50
-3
-3
Thermal Conductivity (10
6
6
Films:
30 4 15 min TiO2 deposition
35 min TiO2 deposition
96 min TiO2 deposition 30 min TiO2 deposition
20 45 min TiO2 deposition
• PET film with a thickness of 1.08 mm; 2
50
2
10
ns)
2,00
Time (s)
• Ti target, connected to a dc power unit (100 A/m2); 1,50
• Gas mixture composed of Ar (60 sccm) and O2 (9 sccm). Figure 2. EDX spectra of TiO2 deposition: a) PET fabric; b) 1,00
PA6.6 fabric; c) PET film and d) PA6.6 film. Fabrics treated with
0,50
Films: 15, 30 and 45 minutes Figure 4. Thermal properties for fabrics and films untreated and treated with TiO 2: a)
thermal conductivity for fabrics; b) thermal conductivity for films and c) Hot Rod test for
fabrics
Conclusion
• TiO2 films were successfully deposited on PET and PA6.6 fabrics and films by reactive magnetron sputtering.
• SEM analysis showed that TiO2 sputtered particles covered completely the fibre surface, in the case of the fabrics, and the surface of PET and PA6.6 films.
Acknowledgments The TiO2 film exhibit a columnar morphology growth, through particles grains with smaller diameters, aligned and piled together, forming smoothness uniform
The authors gratefully acknowledge funding by FCT, Fundação TiO2 films, except in the case of PA6.6 films that present some pinholes in their structure with a not so uniform film formation.
para a Ciência e Tecnologia, under the reference • EDX and FTIR-ATR spectra confirm the presence of TiO2 film.
SFRH/BDE/15622/2006
• Only PA6.6 exhibited a slightly improve of thermal properties.
Engenharia para a Qualidade de Vida: MOBILIDADE E ENERGIA – Semana da Escola de Engenharia -11 a 16 de Outubro de 2010