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• SECTION OBJECTIVES:
• 1.Describe the formation and escape to the s
urface of volcanic gases.
• 2.Differentiate the different kinds of Hazardou
s volcanic gases.
• 3.Analyzes the effects of volcanic gases.
• 4.List the various volcanic gas mitigation mea
sures.
• In 1986,a sleepy settlement below lake
Nyos in Cameron (Central Africa), which
sits on top of an old one shot volcano (
mar),fell victim to a silent killer. One witn
ess recalled seeing nobody alive when
he went down to NGOs. Some of them
appeared to have fallen dead while slee
ping or cooking. They seem to Have suf
focated along with all their animal.
• All in all about 1700 people and 3,500 li
vestock died because of this strange ga
s. Some of those who survive smelled g
un powder and had strange marks (burn
s) all over their bodies. Word about the t
ragedy went around quickly. With the nu
mber of casualities, there was no way to
hide it from Everyday's attention. Scienti
es and the survivors at first had no idea
what befelled the dead.
•
• Another key witness narrated that the main cu
lprit was "white like cloth" which did not go up
in the air. From the trail that it had left, it was
soon realized that some kind of toxic gas from
the lake was to blame. What sort of gas could
this be that one cannot see, taste, or smell?
What could have forced such a deadly gas to
come out of the lake? Could something that c
ould be that quiet be so violent and fatal? Wh
at was the smelly, scalding gas that came wit
h it?
•
VOLCANIC GASES GENERATION OR FORM
ATION AND ESCAPE TO THE SURFACE
• Gas is what really makes volcanic eruption work. Ho
w violent an eruption would become depends on a nu
mber of factors discussed earlier in Section 5.1 Mag
ma is composed not only of melted minerals. It also h
as a volatile fraction-- substances that may become g
aseous or give off gases when heated. As magma ris
es toward the surface, these come out of solution in
much the same way as a bubbles of carbon dioxide g
as come out of carbonated drinks.
• The rapid expansion of the gases as magma
rises toward the surface can lead to explosive
eruption (figure 5.1-2). Volcanic gases expan
d enormously when magma rises to the earth'
s surface and erupts. One cubic meter of mag
ma under great pressure at depth can expand
670 times as mixture of water vapor and mag
ma at atmospheric pressure. This tremendou
s expansion of volcanic gases,mainly water, d
rives explosive eruption. Gas bubbles that sur
vive eruption form as vesicles in solidified lav
a. Example of this bubbles expect volcanic ro
cks are scoria and pumice.
• During eruptions, gases are forced out t
hrough the vent along with ash and aero
sol droplets. The gases spread from an
erupting vent primarily as acid rain, sulf
uric acid aerosols, compounds attached
to tephra particles, and microscopic salt
particles (figure 5.2-2). The prevailing wi
nds may blow the eruption cloud as far
ad thousands of kilometers away.
•
• Not only during eruptions are gases rele
ased from magma. Gases are also relea
sed from magma that remains below gr
ound as an intrusion or from magma lur
king just beneath an active volcano duri
ng periods of quiescence (Figure 5.2-3).
Gases may escape continuously into th
e atmosphere from the soil, volcanic ve
nts, fumaroles,and hydrothermal system
s.
• No eruption accompanied the released
of gas from Nyos, but a magma body lyi
ng beneath lake Nyos leaked CO² slowl
y into the water to form volcanic acid. T
he released of a large cloud of CO² on
August 21,1986 is believe to be the resu
lt of a landslide that agitated the lake. T
o prevent a represent of the disaster, tu
bes were installed to allow slow release
of safer quantities of CO².
•
• Other sources of volcanic gas are those
assimilated by the magma from the eart
hs crust on its way up. Crustal materials
may include older volcanic rocks with ga
ses trapped in cavities. Could you also i
magine how groundwater or water from
the atmosphere interacs with magmatic
body at depth or near the surface to for
m Part of volcanic gas?
•
• Figure 5.2.3. The movement of gas from
within the earth's to the surface through
faults in volcanic regions. Source;http://
www.indiana.edu/siera/papers/2007//ma
rks.htmt;Original source: Sorry,Michael
L., Christopher D. Farrar, et.al.invisible
CO2 Gas killing Tress at Mammoth Mou
ntain, California United states Geologica
l Survey fact sheet 172-96. version 2.0
Revised June 2000.
•
• But where do all the gases that volcano
es or volcanic areas give off come from
? Volcanoes related to trenches are sup
llied with gas from the water and the car
bon and sulfur compounds from organic
matter in the sediments that goes with t
he subducting oceanic plate. Melting of t
he subducting plates generates the mag
ma that brings the gases back to the sur
face.
• . A smaller portion of volcanic gas that c
omes out of spreading mid-oceanic ridg
es and intraplate volcanoes like those H
awaii, is believe to come from the deepe
r portions of the mantle. The volatiles in
the mantle formed as part of the ingredi
ents that made up the earth when it for
med about 4.5 billion years ago. Do you
recall what volatiles, other than hydroge
n, carbon, and sulfur were part of this or
iginal material?
DANGEROUS VOLCANIC GAS CO
MPONENTS AND THEIR EFFECTS
• The most abundant volcanic gas released int
o the atmosphere is water (H²O). Other volca
nic gases include CO², SO², and trace amoun
t of N, H, CO, S, Ar, Cl, and F. These gases c
ombine with hydrogen and water to produce t
oxic compounds, such as HCI, HF, H², SO², H
²S. These gases leave the emission sites as a
cid aerosols as compounds adsorbed on teph
ra, and as microscopic salt particles.
•
• The abundance of volcanic gases varies acco
rding to the tectonic setting of volcanoes. Tabl
e 5.2-1 indicates that convergent-plate volcan
oes or those associated with subduction zone
s tend to emit higher H²O and HCl and lower
CO² and SO² compared with divergent-plate v
olcanoes and hot-spot volcanoes. Why do yo
u think volcanoes located at convergent plate
boundaries emit more water vapor and chlori
ne than volcanoes at hot spot or divergent pla
te boundaries? Where do the extra water and
chlorine come from?
•
• Water vapor is harmless,as it is abunda
nt in the atmosphere. Health hazards ca
used by other volcanic gases can range
from minor to life threatening. Exposure
to acid gases such as sulfur dioxide,hyd
rogen sulfide, and hydrogen chloride ca
n damage eyes and mucous membrane
s along with the respiratory system and
under extreme condition,can lead to dea
th.
•
• Carbon dioxide is abundant in the atmospher
e and is a natural product of respiration Volca
nic CO² emissions over the entire globe amou
nt to less than 1 percent of human emissions.
Locally, CO² can be hazardous when the con
centration I'd high, in the next activity, we shal
l explore how Co² reached Nyos at high con
centrations. This inquiry-based activity, also s
hows how CO² gas from the reaction of vineg
ar and baking soda displaces oxygen and exti
nguished candles at different heights.
•
•
• Sulfur dioxide (SO²) is a colorless gas with a strong o
dor. It is the gas smells from lighting a kitchen match.
At 6-12 ppm, it can cause immediate imitation of the
nose and throat and at 20 ppm. It will irritate the eyes
. Because it forms an acid with water, moist skin will
be irritated within minutes at 10,000 ppm of SO². Its i
nhalation at very high concentrations should be avoid
ed as it is harmful to the upper respiratory tract and b
ronchi. Like SO² and H²S, hydrochloric acid [HCI] irrit
ates the mucous irritation of the throat. At >100 ppm,
HCI cause pulmonary edema and laryngeal spasm.
• The release of SO² gas during an eruption ca
n produce volcanic smog called VOC. Haze a
nd smog result when SO² oxygen, water, and
sunlight interact. The reaction produces tiny d
roplets of acidic water and sulphate mineral p
articles, which interfere with light rsys from th
e sun. Vog causes headaches and irritation of
the eyes and lungs.it causes shortness of bre
ath for people suffering from asthma and othe
r respiratory diseases.
•
• Hydrogen sulfide (H²S) is a colorless, fla
mmable gas which smells like a rotten e
gg. Like SO² it cause irritation of the eye
s at low concentration. A 30-minute exp
osure to 500 ppm of H²S will cause dizzi
ness, headache, and diarrhea. Sometim
es, these symptoms are followed by bro
nchitis or bronchopneumonia.
•
• Florine is a pale yellow gas that occurs i
n volcanic gas as hydrogen fluoride (HF
). Fluorine attaches to fine ash Particles
which diary grass that can be ingested b
y animals. Fluorine that exceeds 250 pp
m In dried grass causes flourosis, an af
fliction taht destroys the bones.
• Since it is known to have caused massi
ve death among livestock, it can also aff
ect humans in the same way. Aside fro
m FIuorosis, it can also caused conjunct
ivitis and skin irritation. Once in contact
with moisture in tissues, hydrogen fluori
de converts right away to a very toxic ac
id. Table 5.2-2 is a summary of the effec
ts of volcanic gases at a given threshold
limit.
•
• Apart from its effects on human and ani
mal health safety, volcanic gases have
huge impact on agriculture, property, an
d the environment. Volcanic gases can
severely damage vegetation. Direct exp
osure to concentrated volcanic gas or lo
ng-term exposure to diluted volcanic ga
s is lethal to most types of foliage.
• Sulfur dioxide (SO²) hydrogen fluoride (
HF), and HCI dissolve in water droplets
in the eruption cloud and fall as acid rai
n. Volcanic gases and acid rain can cau
se corrosion of metal objects such as ai
rcraft body parts and engines, utility line
s, communications equipment farm mac
hinery, and Vehicles. Persistent acid rai
n causes lead-bearing metals to deterior
ate and release toxic metals into drinkin
g eatere.
• In addition to the warming effect of carb
on dioxide released during eruptions, th
e aerosols that form from SO² and ash p
articles help in this warming processes
of stratosphere by absorbing heat radiat
ed up from the earth.
• Aerosol are formed when SO² reacts wi
th water to form sulfuric acid H²SO) vap
or which in turn condenses onto ash par
ticles (figure 5.3-5).the Earth's lower at
mosphere, on the other hand, cools whe
n the aerosols reflect radiation from sun
back into space rather than going straig
ht to the earth's surface. This leads to th
e ground being cooler than usual.
•
• The June 15,1991 eruption of Pinatubo i
njected about 2 million metric tons of S
O² into the stratosphere which caused t
he 20th centuryse largest aerosols dist
urbance of the stratosphere. As a result
the Earth's surface cooled by out 0. C in
the three years following the eruption. T
he sulfate aerosols also accelerated che
mical reactions that lead to the accelera
tion of the ozone layer's depletion.
• The particles themselves do not contribute to
ozone destruction, but they interact with chlori
ne- and bromine-bearing compounds from hu
man-made chemicals, allowing increased ozo
ne destruction. Fortunately, volcanic particles
remain in the stratosphere for only two or thre
e years. The direct contribution of some gase
s from volcanic eruptions to the destruction of
the ozone layer is not significant.
• Hydrogen chlorine, for instances, is an efficie
nt ozone destroyer but is readily dissolve in W
ater. Before it ever reaches the ozone layer, h
ydrogen chlorine is dissolved by rainwater. Th
rough bromine oxide is ten times more effecti
ve in depleting the ozone layer, its concentrati
on is 100. Times less than that of chlorine. Co
mpared with the 75-85% contribution of Hum
an activity, volcanoes contribute for less to oz
one damage (1-5%).
•
Table 5.2. Toxicology of volcanic gases
(Source:Sax,1993,1974; Wilcox,1959)