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Function of Cells
Carbohydrates
HO 1 2 3 H HO H
HO 1 2 3 4 H
Longer polymer
(a) Dehydration reaction in the synthesis of a polymer
HO 1 2 3 4 H
HO 1 2 3 H HO H
(b) Hydrolysis of a polymer
H O H O H O H O
C C C C
H C OH H C OH H C OH H C OH
Aldoses
H C OH H C OH HO C H HO C H
H H C OH H C OH HO C H
H C OH H C OH H C OH
Glyceraldehyde
H H C OH H C OH
Ribose H H
Glucose Galactose
H H H
H C OH H C OH H C OH
C O C O C O
H C OH H C OH HO C H
Ketoses
H H C OH H C OH
Dihydroxyacetone H C OH H C OH
H H C OH
Ribulose H
Fructose
(a) Linear and ring forms. Chemical equilibrium between the linear and ring
structures greatly favors the formation of rings. To form the glucose ring,
carbon 1 bonds to the oxygen attached to carbon 5.
CH2OH CH2OH
CH2OH CH2OH
O O O O
H H H H H 1–2 H
H H glycosidic 2
1
H linkage
(b) OH H HO OH H H HO
OH HO
Dehydration reaction HO CH2OH HO O CH2OH
in the synthesis of
sucrose. Sucrose is
a disaccharide formed H OH OH H H OH OH H
from glucose and fructose.
Notice that fructose,
H2O
though a hexose like
Glucose Fructose Sucrose
glucose, forms a
five-sided ring.
1µ m
Amylose Amylopectin
0.5 µ m
Glycogen
H O
CH2O C CH2O
H H
O H C OH H O OH
H H
H H
4
OH H HO C H 4 1
OH H
HO OH HO H
H C OH
H OH C H OH
H OH
α glucose H C OH β glucose
OH OH OH OH
About 80 cellulose
Cellulose microfibrils molecules associate
in a plant cell wall Microfibril to form a microfibril, the
Cell walls main architectural unit
of the plant cell wall.
∩
0.5 µ m
Plant cells
CH2OH OH CH2OH OH
O O O O
OH OH OH OH
O O O O O
OH CH2OH OH CH2OH Cellulose
CH2OH OH CH2OH OH molecules
O O O
OH O OH OH OH
Parallel cellulose molecules are O O O O O
OH CH2OH OH CH2OH
held together by hydrogen
bonds between hydroxyl CH2OH OH CH2OH OH
O O O O
groups attached to carbon OH OH
O OH O O
OH O
atoms 3 and 6. O A cellulose molecule
OH CH2OH OH CH2OH
is an unbranched β
β Glucose glucose polymer.
Prepared by Raajeswari Rajendran
monomer
Cellulose is difficult to digest
Cows have microbes in their stomachs
to facilitate this process
(a) The structure of the (b) Chitin forms the exoskeleton (c) Chitin is used to make a
chitin monomer. of arthropods. This cicada strong and flexible surgical
is molting, shedding its old thread that decomposes after
exoskeleton and emerging the wound or incision heals.
in adult form.