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Section #3
Acids & pH
Acids occur in many foods, drinks and even within our stomachs
Acids & pH
Classification of Acids
Acids are classified as being either Strong Acids or Weak Acids. This is based upon the nature of the equilibrium system that they establish when they are dissolved in water. HA H+ + A-
i. Strong Acids
Shows very high levels of dissociation into ions.
Equilibrium favors Forward Reaction
HA
100% dissociation in solution
H+
A-
HA
low% dissociation in solution
H+
A-
Acids & pH
Strong Acids
There are several acids that are classified as strong acids, however the most commonly encountered strong acids in the HSC are
i. Hydrochloric Acid
HCl - Molecular Weight = 36.46 g.mol-1 Also known as Muriatic Acid. Small amounts of hydrochloric acid are secreted by cells in the lining of the stomach to aid in food digestion. Ionizes in solution according to the equation
H - Cl
HCl
H+
Cl-
Acids & pH
ii. Sulfuric Acid O HO S O OH
H2SO4 - Molecular Weight =
H2SO4 HSO4-
H+ H+
+ +
HSO4SO42-
diprotic acid
Acids & pH
iii. Nitric Acid
HNO3 - Molecular Weight =
HNO3
H+
NO3-
Acids & pH
Weak Acids
There are several acids that are classified as weak acids, however the most commonly encountered weak acids in the HSC are
i. Methanoic Acid
O H C OH
HCOOH
H+
Acids & pH
ii. Ethanoic Acid
CH3COOH - Molecular Weight
O
H H C H C OH
CH3COOH
H+
Acids & pH
iii. Citric Acid
2-hydroxypropane-1,2,3-tricarboxylic
OH
H2 C
CO OH
CO OH
CH2 CO OH
H+(aq)
Acids & pH
Ions in Water
Ions do not simply float around in liquid water. Remember from the preliminary course, when NaCl crystals dissolve in water, the ions become surrounded by water molecules
Acids & pH
It is precisely due to this fact we use the subscript (aq) to indicate dissolved ions in solution
NaCl(s)
Na+(aq)
OH-(aq)
Similarly, the ions produced by the dissociation of acids are not simply floating around.
In fact the H+ ions piggy back upon water molecules, forming Hydronium Ions H3O+.
+
Acids & pH
The H+ ion bonds to the water molecule through a special type of covalent bonding called a Coordinate Bond (more on this in the Chemistry of Art). Hence, H+(aq) and H3O+(aq) can be used interchangeably. Therefore the equations for the ionisation of acids can be written form) as
(in a more correct
i. Hydrochloric Acid
HCl(g) + H2O(l) H3O+(aq) + Cl-(aq)
Acids & pH
iii. Nitric Acid
HNO3(l) + H2O(l) H3O+(aq) + NO3-(aq)
v. Ethanoic Acid
CH3COOH(l) + H2O(l) H3O+(aq) + CH3COO-(aq)
C3H5O(COOH)(COO)22-(aq)
H2O(l)
H3O+(aq)
C3H5O(COO)33-(aq)
Acids & pH
Example 100% of the HCl molecules in Hydrochloric Acid will dissociate in solution
Acids & pH
Weak acids exhibit a very small degree of dissociation in solution
Acids & pH
Concentration =
Therefore, a concentrated solution can be created when a large amount of material is dissolved in a relatively small amount of solvent. Likewise, a dilute solution can be created when a small amount of material is dissolved in a relatively large amount of solvent.
Acids & pH
Example
Concentrated HCl
(a strong acid)
(a strong acid)
Diluted HCl
Acids & pH
Example
Concentrated CH3COOH
(a weak acid)
Diluted CH3COOH
(a weak acid)
Acids & pH
Acid Equilibria
When an acid dissolves in water an Acid Equilibrium is setup HX H+ + X-
The Acid Dissociation Constant for this system is [H+] [X-] [HX]
Ka =
The stronger an acid is, the more it dissociates producing more H+ and XHence the stronger acid is the larger its Ka value will be. Strong acids completely dissociate in solution so their Ka values approach infinity!
Acids & pH
Therefore
Ka = [H+] [OH-]
[H2O]
Exactly how chemists get around this is not on your course however using mathematical processes we gain a special constant called the Ion Product Constant of Water, Kw. Kw = [H+] [OH-] at 25C Kw = 1.0 10-14
Hence the [H+] of pure water is 1.0 10-7, this is important when we consider
Acids & pH
pH
pH is a measure of the strength of an acidic solution. pH = -log10[H+] Hence the pH of pure water is pH = -log10[1.0 10-7] pH = 7 Calculation steps
1. Enter the concentration using the EXP button
making sure you push equals at the end.
[H+]
< 1.0
10-7
g pH > 7
Acids & pH
pOH
pOH is a measure of the strength of an alkaline solution.
pOH = -log10[OH-]
pH & pOH are related by
pH + pOH = 14
Hence the pH of 0.1M NaOH is NaOH Na+(aq) [OH-] = 0.1 + OH-(aq) pOH = -log10[0.1] pOH = 1 pH = 13
Acids & pH
The pH Scale
So, the pH scale is as follows
pOH
It is very important to note that if a solution changes its pH by one unit on the pH scale, there is a ten fold change in the H+ concentration.
Acids & pH
HCl 0.1M
CH3COOH 0.1M