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Test bank

Chapter 5,7,8,9 .

Dr.Laila Al-Harbi

Which is correct? 1. All gases are fluids. 2. All gases are diatomic.
a. Both statements are true. b. Both statements are false. c. Statement 1 is true, but statement 2 is false. d. Statement 1 is false, but statement 2 is true.
Dr.Laila Al-Harbi

As a helium-filled balloon rises, its volume increases. This is an example of:


a. b. c. d. Avogadro s Law. Boyle s Law. Charles Law. Gay-Lussac s Law.
Dr.Laila Al-Harbi

Hot air balloons rise. This is an example of:


a. b. c. d. Avogadro s Law. Boyle s Law. Charles Law. Gay-Lussac s Law.

Dr.Laila Al-Harbi

Avogadro s Law states that the volume of a gas is directly proportional to:
a. b. c. d. the number of gas particles. the mass of the gas. the pressure of the gas. the Kelvin temperature of the gas.
Dr.Laila Al-Harbi

Standard temperature and pressure (STP) for a gas is:


a. b. c. d. 0 atmospheres and 25 degrees C. 1 atmosphere and 0 degrees C. (273 K) 1 atmosphere and 25 degrees C. 0 atmospheres and 0 degrees C.

Dr.Laila Al-Harbi

The partial pressure of each gas in a mixture is proportional to:


a. the mass of the gas. b. the molecular weight of the gas. c. the square root of the molecular weight of the gas. d. the mole fraction of the gas.
Dr.Laila Al-Harbi

4. Under conditions of fixed temperature and amount of gas, Boyle's law requires that I. P1V1 = P2V2 II. PV = constant III. P1/P2 = V2/V1 (a) I only (b) II only (c) III only (d) I, II, and III (e) another combination
Dr.Laila Al-Harbi

A sample of two moles of nitrogen gas (N2) will occupy what volume at STP? PV=nRT = 2x0.082x273/1=
a. b. c. d. 11.2 liters 22.4 liters 44.8 liters 89.6 liters
Dr.Laila Al-Harbi

A sample of hydrogen gas was collected over water at 21rC and 0.9 atm. The volume of the container was 7.80 L. Calculate the mass of H2(g) collected. (Vapor pressure of water = 0.025 atm at 21rC.) (A) 0.283 g (B) 435 g (C) 0.571 g (D) 7.14 g

Dr.Laila Al-Harbi

If 250 mL of NO is placed in a flask with O2, what volume of O2 is needed for complete reaction? 2 NO (g) + O2 (g) 2 NO2 (g)
From the equation because all reactant are gases 250 x1 /2 = 125

100 mL 125 mL 200 mL 250 mL Cannot be determined from the given information.
Dr.Laila Al-Harbi

If an equal mass of each gas is put into a separate balloon, which will have the greatest volume?
Assume that they are all the same temperature and pressure.

He ( H2 ( N2 ( Ne ( O2 (

=2) =1) =28) =20) =32)

Assume that they are all the same temperature and pressure. PV =(m/ ) RT V 1/ Sine all other variables are constants
Dr.Laila Al-Harbi

If equal masses of CH4, C2H6, and C3H8 are placed in a flask, which of the following is true?

PCH4 = PC2H6 = PC3H8 PCH4 ~ PC2H6 ~ PC3H8 PCH4 > PC2H6 > PC3H8 PCH4 < PC2H6< PC3H8 None of the above
PV =(m/ ) RT

Dr.Laila Al-Harbi

Chapter 7

Dr.Laila Al-Harbi

The wavelength of electromagnetic energy multiplied by its frequency equals: = c/ =c


a. b. c. d. c, the speed of light h, Planck s constant Avogadro s number 4.184
Dr.Laila Al-Harbi

The energy of a photon of electromagnetic energy divided by its frequency equals: E =h E/ = h


a. b. c. d. c, the speed of light h, Planck s constant Avogadro s number 4.184
Dr.Laila Al-Harbi

Light that contains colors of all wavelengths is called:


a. b. c. d. a continuous spectrum. monochromatic. a line spectrum. a Balmer series.

Dr.Laila Al-Harbi

The lowest energy state of an atom is referred to as its:


a. b. c. d. bottom state. ground state. fundamental state. original state.

Dr.Laila Al-Harbi

All s orbitals are:


a. b. c. d. shaped like four-leaf clovers. dumbbell-shaped. spherical. triangular.

Dr.Laila Al-Harbi

The way electrons are distributed among the various orbitals of an atom is referred to as the atom s:
a. b. c. d. orbital diagram. electron configuration. electron distribution. electron spread.
Dr.Laila Al-Harbi

[He]2s22p2 is the electron configuration of which element?


a. b. c. d. beryllium boron carbon nitrogen

Dr.Laila Al-Harbi

Considering only the n = 1 to n = 5 states in the hydrogen atom, which transition will emit the longest wavelength?
n = 5 to n = 4 n = 5 to n = 2 n = 3 to n = 1 n = 3 to n = 2 n = 4 to n = 2
E & h are directly proportional E& are inversely proportional
Dr.Laila Al-Harbi

E =h E =hc/

What are the valence electrons of vanadium (V)?


4s2 3d3 4s23d3 3d5 4d5

Dr.Laila Al-Harbi

What are the valence electrons of gallium Ga?


4s2 4p1 4s23d104p1 4s23d10 4s24p1

Dr.Laila Al-Harbi

What is the maximum number of orbitals described by the quantum numbers:


1 3 5 8 9
n=3 l=2 the maximum number of orbitals = 2 +1=2x2+1=5

Dr.Laila Al-Harbi

What is the maximum number of electrons described by the quantum numbers:


n=4

7 14 16 32 48

the maximum number of electrons = 2n2 =2(4) 2 =32

Dr.Laila Al-Harbi

How many unpaired electrons does selenium Se have?


4s24p4 0 2 4 6 8

Dr.Laila Al-Harbi

How many unpaired electrons does chromium have?


0 2 4 6 8 4s13d5

Dr.Laila Al-Harbi

The electron configuration of a neutral atom is [Ne] 3s2 3p1. The four quantum numbers of the last electron are:

(A) (2, 1, -1, +1/2) (B) (3, 3, -1 , +1/2) (C) (3, 0, -1, +1/2) (D) (3, 1, -1, +1/2 )#

Dr.Laila Al-Harbi

Chapter 8

Dr.Laila Al-Harbi

- Selenium (34Se) element is: (a) a nonmetal (b) found in group 6A (c) both a and b

Dr.Laila Al-Harbi

The outer electron configuration of the noble gases is (a) ns2 np6 (b) ns2 nd10 (c) ns2 np4 Which of the following species is isoelectronic with Cl(a) F(b) O2(c) K+ (d) Na+
Dr.Laila Al-Harbi

-Which of the following sets of elements is expected to have similar chemical properties? a) Sulfur and phosphorous b) Sulfur and oxygen c) Sulfur and argon

Dr.Laila Al-Harbi

Gallium (Ga) element is found in the periodic table in (a) period 3, group 1B (b) period 3A, group 4 (c) period 4, group 1A (d) period 4, group 3A

Dr.Laila Al-Harbi

Titanium (Ti) element is found in the periodic table in


(a) (b) (c) (d) s-block P-block d-block f-block

Dr.Laila Al-Harbi

Choose the incorrect quantum numbers for electron in an atom. A) (3, 0, 0, +1/2). (B) (4, 3, 2, +1/2). (C) (1, 0, -1, -1/2). Correct (1,0,0,-1/2) (D) (3, 2, 0, +1/2)
(

Dr.Laila Al-Harbi

Write the electronic configuration for Co2+ (a) [Ar] 4s2 3d5 (b) [Ar] 3d7 (c) [Ar] 4s1 3d6

Select the correct order of radius of the two ions (A) A+ > A(B) A- < A (C) A2+ > A+ (D) A2+ < A+

Dr.Laila Al-Harbi

Which choice below correctly lists the elements in order of increasing atomic radii?
a. b. c. d. Na < Mg < K < Rb Mg < Na < K < Rb Rb < K < Na < Mg Rb < K < Mg < Na
Dr.Laila Al-Harbi

Two ions are referred to as isoelectronic if they have the same number of:
a. b. c. d. electrons. protons. atoms. neutrons.
Dr.Laila Al-Harbi

Which statement is false?


a. Fluoride ions are larger than rubidium ions. b. Bromide ions are larger than sodium ions. c. Iodide ions are larger than rubidium ions. d. Chloride ions are larger than potassium ions.
Dr.Laila Al-Harbi

The energy required to remove an electron from an atom in its ground state is known as the:
a. b. c. d. potential energy. activation energy. electron affinity. ionization energy.
Dr.Laila Al-Harbi

Which choice correctly lists the elements in order of increasing electron affinity (most negative to least negative)?
a. b. c. d. O, Cl, B, C O, Cl, C, B Cl, O, C, B Cl, O, B, C
Dr.Laila Al-Harbi

Which choice correctly lists the elements in order of increasing first ionization energy?
a. b. c. d. Na < Ca < Al < Sn Na < Al < Ca < Sn Na < Al < Sn < Ca Ca < Na < Sn < Al
Dr.Laila Al-Harbi

An unknown solid gives a green flame test. When it was dissolved in water and reacted with NaOCl, a purple color appeared. The unknown is:
a. b. c. d. barium bromide. calcium iodide. barium iodide. calcium bromide.
Dr.Laila Al-Harbi

Characteristics of noble gases include:


a. b. c. d. filled s and p subshells. monatomic gases. generally unreactive chemically. all of the above.

Dr.Laila Al-Harbi

In an germanium atom, which electron will experience the greatest effective nuclear charge? An electron in a
1. 2. 3. 4. 5. 2s orbital. 2p orbital. 3s orbital. 3p orbital. 3d orbital.

Dr.Laila Al-Harbi

Order the following according to increasing atomic/ionic radius.


1. 2.

N3 C < Li+ < O2 < N3 N3 < O2 < C < Li+ Li+ < C < N3 < O2 Li+ < C < N3 < O2 Li+ < C < O2 < N3

Li+ C O2

Dr.Laila Al-Harbi

Which will have the highest ionization energy?


C N O Al Si

Dr.Laila Al-Harbi

Which will be the largest?


I = ionization energy

I1 of Na I2 of Na I1 of Mg I2 of Mg I3 of Mg

Dr.Laila Al-Harbi

Chapter 9

Dr.Laila Al-Harbi

The two types of chemical bonds commonly found in compounds are:


a. b. c. d. doric and covalent. ionic and electrolytic. ionic and covalent. electrolytic and compound.
Dr.Laila Al-Harbi

The electrons used by atoms to form chemical bonds are the:


a. b. c. d. core electrons. valence electrons. lone pair electrons. unpaired electrons.

Dr.Laila Al-Harbi

Atoms tend to gain, lose, or share electrons until they are surrounded by eight valence electrons is a statement of:
a. b. c. d. the rule of octaves. the double quartet rule. the eight electron rule. the octet rule.
Dr.Laila Al-Harbi

When a transition metal atom becomes a +1 ion, the electron lost usually comes from what type of orbital?
a. b. c. d. p f d s
Dr.Laila Al-Harbi

A molecule of CS2 contains:


a. b. c. d. two single bonds. two double bonds. one single bond and one double bond. one single bond and one triple bond.

Dr.Laila Al-Harbi

An atom in the ground state has atomic number Z=5. Choose the correct electron-dot structure which represents this atom?
X X X X
Dr.Laila Al-Harbi

)C(

)D(

)B(

)A(

What is the formal charge on the nitrogen atom in the nitrate ion (NO3 1) ?
a. +2 b. +1 c. 0 d. 1
Dr.Laila Al-Harbi

Which compound below contains an atom that is surrounded by more than an octet of electrons?
a. b. c. d. PF5 CH4 NBr3 OF2
Dr.Laila Al-Harbi

Which choice below correctly lists the elements in order of increasing electronegativity?
a. b. c. d. C<N<O<F N<C<O<F N<C<F<O C<N<F<O
Dr.Laila Al-Harbi

As the number of bonds between two atoms increases, the distance between the atoms:
a. b. c. d. increases. decreases. remains unchanged. varies with the atoms involved.
Dr.Laila Al-Harbi

Which atom sometimes violates the octet rule?


1.C 2.N 3.O 4.F 5.S

Dr.Laila Al-Harbi

Order the following according to increasing atomic radius.


Ge Si Se Cl

1. 2. 3. 4. 5.

Ge < Si < Se < Cl Se < Si < Ge < Cl Si < Cl < Ge < Se Cl < Si < Se < Ge Si < Ge < Se < Cl

Dr.Laila Al-Harbi

What is the electronic configuration of Fe2+?


1. 2. 3. 4. 5. 4s23d4 4s13d5 3d5 3d6 4s23d8

Dr.Laila Al-Harbi

How many unpaired electrons are there in Cu+?


1. 2. 3. 4. 5. 0 1 2 3 4

Dr.Laila Al-Harbi

How many resonance structures can be drawn for NO3 ?


1.1 2.2 3.3 4.4 5.5

Dr.Laila Al-Harbi

An atom in the ground state has atomic number Z=5. Choose the correct electron-dot structure which represents this atom?

Considering formal charge, what is the preferred Lewis structure of NCO ?

Dr.Laila Al-Harbi

In Lewis structure of (SO4)-2structure the correct formal charge on sulfur (S) is: a) +2 b) -2 :O: +2 c) +1 6 4 _ d) 0

: : : _ _ : :
-

+2

:O: :

Dr.Laila Al-Harbi

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