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LDPE
PRODUCT
PRODUCT GRADE PLANT TECHNOLOGY PLANT CAPACITY COMMISSIONING YEAR DETAIL ENGINEERING TYPE OF POLYMERISATION NATURE OF REACTION
UNIQUE FEATURES OF LDPE Tubular reactor Operating pressure is very high (2000-2400 bars). Operating Temp. is very high (300-310 0C). Conversion is 20 23 %. High power consumption. Reaction control needs skill . Control room panel equipped with DCS. DM Water based cooling tower.
Top injection
Hyper Comp.
Tubular reactor
LP steam
Oxygen
LPG/Propylene OFF GAS
Side injection
LP Separator
MP Separator
Industries generate tremendous amount of Heat This Waste Heat is to be taken by cooling water in various heat exchangers. From cooling water the heat is dissipated into the atmosphere and water is chemically treated and recirculated.
There are two industrial method for disposing heat. Cooling of water on surface of a pond by Spray ponds .
By a Cooling Tower.
PRINCIPLES
The heat transfer process involves
Latent Heat Transfer by vaporization of a small portion of the water. Sensible Heat Transfer by the difference in temperature of water and air. About 80% of heat transfer is due to latent heat and 20% to sensible heat.
Cooling tower Theory The Merkel Equation is KaV/L = integral of (dT/h1-h2) under limits of T1 and T2 which is entering and leaving water temperature.
K=mass transfer constant A = contact area V = active cooling volume L = water rate T1 and T2 = entering and leaving water temperatures. h1 and h2 = entering and leaving water enthalpy.
The integral part of this equation is called as L/G ratio which is said as Tower characteristics .
L/G= h2-h1/T1-T2
Where L/G =liquid to gas mass flow ratio h2= enthalpy of air-vapor mixture at outlet wet bulb temperature h1= enthalpy of air-vapor mixture at inlet wet bulb temperature T1= hot water temperature T2=cold water temperature
Cross flow Cooling tower Water and air flows perpendicularly.Fill material is at sides. * Ultimately, the economic choice between counter flow and cross flow is determined by the effectiveness of fill,design conditions and the cost of tower manufacture.
Air Flow
Drift Eliminators
Longitudinal Partition
Fan blades
Cycles of Concentration
Blowdown is for discarding a portion of concentrated circulating water due to the evaporation process in order to lower the systems solid concentration. Cycles of concentration (COC) is the ratio of dissolved solids in recirculated water to dissolved solids in make up water. COC = (We+Wb)/Wb So Wb= We/(COC-1) Normally COC is in range of 5-7 cycles.
At LDPE we have Induced Draft Cross Current flow type cooling tower.
Construction details
Multi-Blade Distribution Area1.Fan Splash Bar Grid And Supports Air Flow End Wall Casing
Air Flow
Louvers
Air Flow
Drift Eliminators
Longitudinal Partition
Water circulation
Volume of cooling tower sump 780 m3 Volume of pump sump 355 m3 Volume of connecting channel 35 m3 Volume of distributed lines 500 m3 Total hold up 2000 m3 LDPEs water consumption is 2700 m3/hr
Two pumps of 2285 m3/hr each ( GA 165/166/167) = 4570 m3/hr One pump of 350 m3/hr (GA 333/334) = 350 m3/hr Total = 4920 m3/hr assuming 80% pump efficiency total discharge is 4000 m3/hr
Water Treatment
Water treatment is done by Chembond Drewtreat Ltd. Chemicals added.. Orthophosphate For maintaining ph of water. 7.2-7.8 and corrosion inhibition
Biocide
For microbiological control Methyle Base Thiocynide.(MBT) Quartarnary Amonium Compound (* Temp. inside the cooling tower supports the bacteria which generates HNO3 and other acids.)
A Dispersant is also added to not settle down the phosphate in sump or heat exchangers. Candy Filter is used to remove turbidity from water. Its a column of sand gravels,pebbles and water passes from it. 30% of total flow passes from it.
Candy Filter