LIQUID-LIQUID EQUILIBRIA OF TERNARY SYSTEM EUGENOL + ISOPROPANOL + WATER AT 303.15, 313.15, and 323.

15 K

Zuhriyyah Ratih Ardyani NRP. 2311.201.907

Thermodynamic Laboratory Chemical Engineering Department Institut Teknologi Sepuluh Nopember Surabaya

BACKGROUND

Liquid-Liquid Equilibria Data

Improvement of Separation Process

Essential Oil Industry

BACKGR OUND

OBJEC TIVE

OBJECTIVE

Correlated the experimental data by NRTL an UNUQUAC models Obtain the equilibria data for liquid-liquid system of eugenol + isopropanol + water at 303.15, 313.15 and 323.15 K

BACKGR OUND

OBJEC TIVE

LIQUID-LIQUID EQUILIBRIA (LLE)

Hence,

so :

Generat function

RESEARCH METHODOLOGY

Correlated Experiment Data and UNIQUAC

Gas Chromatografy (GC) Analysis

Experiment

MATERIAL & VARIABLE MATERIAL : 1. Eugenol (Indesso Aroma, p.a.) 2. Isopropanol (MERCK, p.a.) 3. Aquabidestilata Temperature Variable: 303,15 K 313,15 K 323,15 K

APPARATUS

Detail: 1. Thermometer 3. Pipe 5. Equilibrium cell 7. Fuse waterbath 9. Display

2. Condensor 4. Stirrer 6. Pump 8. Waterbath 10. Thermocouple

GC ANALYSIS

Gas Chromatography (GC Shimadzu 2010 , TCD, Rtx-5 Column)

GC ANALYSIS

Sample Analysis Calibration Curve Area Ratio for Quantitative Prepare Method for The System

CORRELATION MODEL

UNIQUAC Model NRTL Model

NRTL MODEL
START
Input R , T, xiexp

Trial aij, aji,

Print aij dan aji

END

NRTL

UNIQU AC

COMPO SITION

UNIQUAC MODEL
START
Input R , T, xiexp

Trial aij, aji

N Y Print aij dan aji

NRTL
END

UNIQU AC

COMPO SITION

EQUILIBRIUM COMPOSITION
START
Input aij,aji,R,T,ri,qi,zi Trial ia, ib,

iabaru, ibbaru dengan model NRTL atau UNIQUAC

iabaru ia = 0 ibbaru ib = 0 baru = 0 Y Print , xia, xib

END

NRTL

UNIQU AC

COMPO SITION

EXPERIMENT RESULT

Experiment Data

Parameter

PARAMETER RESULT

Experiment Data

Parameter

CORRELATION RESULT

LLE of eugenol(1) + isopropanol(2) + water(3) system at 303.15 K, ( ) experimental tie line, (----) UNIQUAC tie line

LLE of eugenol(1) + isopropanol(2) + water(3) system at 303.15 K, ( ) experimental tie line, (----) NRTL tie line

303.15 K

313.15 K

323.15 K

CORRELATION RESULT

LLE of eugenol(1) + isopropanol(2) + water(3) system at 313.15 K, ( ) experimental tie line, (----) UNIQUAC tie line

LLE of eugenol(1) + isopropanol(2) + water(3) system at 313.15 K, ( ) experimental tie line, (----) NRTL tie line

303.15 K

313.15 K

323.15 K

CORRELATION RESULT

LLE of eugenol(1) + isopropanol(2) + water(3) system at 323.15 K, ( ) experimental tie line, (----) UNIQUAC tie line

LLE of eugenol(1) + isopropanol(2) + water(3) system at 323.15 K, ( ) experimental tie line, (----) NRTL tie line

303.15 K

313.15 K

323.15 K

CONCLUSION

Correlation with UNIQUAC gives slightl better results than the NRTL equation

The equations of NRTL & UNIQUAC fit the experimental data satisfactorily (RMSD is less than 10%) LLE of the eugenol + isopropanol + water system at 303.15, 313.15, & 323.15 K has been measured

CONCL USION

SUGGE STION

SUGGESTION

Use GC Column which is more suitable for analysing the system

Use mathematical program such as Matlab or Fortran for improvin accuracy of data correlation

CONCL USION

SUGGE STION

THANK YOU..