C+0,5O2=CO

C+O2=CO2
C+CO2=2CO
T C
1000
1050
1100
1150
1200
1250
1300
1350
1400
1450
1500
1550
1600

TK
1273.15
1323.15
1373.15
1423.15
1473.15
1523.15
1573.15
1623.15
1673.15
1723.15
1773.15
1823.15
1873.15

C+0,5O2=CO
C+O2=CO2
Mn+0,5O2=MnO

T C
1000
1050
1100
1150
1200
1250
1300
1350
1400
1450
1500
1550
1600

G
"-26840-20,85T"
"-94074-0,49T"
"40394-41,21T"
G cal
-12072.5115
-14133.0115
-16193.5115
-18254.0115
-20314.5115
-22375.0115
-24435.5115
-26496.0115
-28556.5115
-30617.0115
-32677.5115
-34738.0115
-36798.5115

K cte. equ.
118.1809626
216.0716651
378.0630508
636.0016047
1032.804472
1624.628366
2483.042166
3697.123866
5375.406437
7647.605273
10666.07102
14606.9246
19670.84488

1/T
0.0007855
0.0007558
0.0007283
0.0007027
0.0006788
0.0006565
0.0006357
0.0006161
0.0005977
0.0005803
0.000564
0.0005485
0.0005339

pCO
0.991678638
0.995414255
0.997368839
0.998432602
0.999033633
0.999385231
0.999597592
0.999729666
0.999814037
0.999869274
0.999906262
0.999931549
0.999949169

G
"-26840-20,85T"
"-94074-0,49T"
"-91980+17,48T"

MnO+CO=Mn+CO2

"24746+2,88T"

TK
1273.15
1323.15
1373.15
1423.15
1473.15
1523.15
1573.15
1623.15
1673.15
1723.15
1773.15
1823.15
1873.15

G cal
28412.672
28556.672
28700.672
28844.672
28988.672
29132.672
29276.672
29420.672
29564.672
29708.672
29852.672
29996.672
30140.672

24746 A
2.88 B
K cte. equ.
1.32512E-05
1.91775E-05
2.7017E-05
3.71556E-05
5.00053E-05
6.59994E-05
8.55859E-05
0.000109222
0.000137369
0.000170487
0.000209026
0.000253429
0.00030412

1/T
log pCO2/pCO
0.0007855
-4.877743374
0.0007558
-4.717207239
0.0007283
-4.56836219
0.0007027
-4.429975985
0.0006788
-4.300983678
0.0006565
-4.180460157
0.0006357
-4.067597921
0.0006161
-3.96168897
0.0005977
-3.862109933
0.0005803
-3.768309791
0.000564
-3.679799678
0.0005485
-3.596144355
0.0005339
-3.516955056

grficos justapostos:
Temperatura termodinmica mnima para reduo do xido

log (pCO2 / pCO)

-2.5

-3
-3.5
-4

-4.5
-5
5.0E-04

6.0E-04

pCO2
0.008321362
0.004585745
0.002631161
0.001567398
0.000966367
0.000614769
0.000402408
0.000270334
0.000185963
0.000130726
0.00009374
6.84513E-05
5.08315E-05

log(PCO2/pCO)
-2.076176565
-2.336593963
-2.578708439
-2.804139458
-3.014438001
-3.211021105
-3.395158893
-3.567981422
-3.730492078
-3.883582241
-4.028045185
-4.164588516
-4.293845095

log (pCO2 / pCO)

-2.3
y = 8817.9x

-2.8

-3.3

-3.8

-4.3
5.0E-04

5.5E-04

6.0E-04

6.5E-04

1/T (K-1)

-3.4

pCO
0.999986749
0.999980823
0.999972984
0.999962846
0.999949997
0.999934005
0.999914421
0.99989079
0.999862649
0.999829542
0.999791018
0.999746636
0.999695972

pCO2
0.00001325107
0.00001917717
0.00002701631
0.00003715420
0.00005000283
0.00006599502
0.00008557855
0.00010921030
0.00013735055
0.00017045752
0.00020898232
0.00025336440
0.00030402751

log (pCO2 / pCO)

-3.6
-3.8
-4
-4.2

-4.4
-4.6
-4.8
-5
5.0E-04

5.5E-04

6.0E-04

1/T (K

1/T (K

ra termodinmica mnima para reduo do xido:

1426,3 C

reduo de MnO

Boudouard

7.0E-04

1/T (K-1)

8.0E-04

y = 8817.9x - 9.0008

6.5E-04

1/T

7.0E-04

7.5E-04

8.0E-04

(K-1)

y = -5408.7x - 0.6295

6.5E-04

1/T

(K-1)

7.0E-04

7.5E-04

8.0E-04

1/T (K-1)