BALANÇO DE MASSA - SHALE GAS

Composição Shale Gas (mol%) n=m/MM

Comp Shale Gas %mol MM M %massa Conversão Etano/Etileno
CH4 85.45% 16.042 13.707889 73.74% 90%
C2H6 6.58% 30.07 1.978606 10.64%
C3H8 1.92% 44.1 0.84672 4.56% Produção em t/ano
i-C4H10 0.56% 58.124 0.3254944 1.75% 415000
n-C4H10 0.59% 58.124 0.3429316 1.84%
i-C5H12 0.17% 72.15 0.122655 0.66% Produção em t/dia
n-C5H12 0.13% 72.15 0.093795 0.50% 1202.90
CO2 1.66% 44.01 0.730566 3.93%
N2 2.78% 14 0.3892 2.09% Produção em t/h
H2O 0.02% 18 0.004392 0.02% 50.12
H2S 0.14% 34.082 0.0461129 0.25%
Total 100% 18.58836 100% MM Média
19.13
12.123217527
Corrente 1 2 3 4 5 6
CH4 385.82 385.82 385.82 - -
C2H6 55.69 55.69 55.69 - -
C3H8 23.83 23.83 23.83 - -
C4H10 13.10 13.10 13.10 - -
C5H12 6.09 6.09 - 6.09 6.09
CO2 20.56 20.56 - 20.56 -
N2 10.95 10.95 10.95 - -
H2O 0.12 0.12 0.12 - -
H2S 1.30 1.30 - 1.30 -
H2O
H2 - - - - - -
CO2
CO - - - - - -
Metano
Etino - - - - - -
Eteno - - - - - -
Ar - - - - - -
NaOH - - - - - -
Na2CO3 - - - - - -
Total 517.48 517.48 489.53 27.95 - 6.09
DE MASSA - SHALE GAS

nversão Etano/Etileno Forno de pirólise

90% Componentes Entrada Saída
Ar - - Nos maçaricos
Produção em t/ano CO2 - -
415000 Etano 75% 12.50% Nas serpentinas
H2O 25% 10.00%
Produção em t/dia Metano - 2.00% 0.5 for the H2S/CO2 molar ratio.
1202.90 Etileno - 67.50% Vapor: 0.25 a 0.4 em massa.
Etino - 2.00%
Produção em t/h H2 - 5.00%
50.12 CO2 - 0.45%
CO - 0.05%
Total 100% 100%
92.63

7 8 9 10 11 12 13 14
- 385.82 385.82 - - - -
- 55.69 55.69 55.69 - 55.69 9.28
- 23.83 23.83 - 23.83 - -
- 13.10 13.10 - 13.10 - -
- - - - - - -
20.56 - - - - - -
- 10.95 10.95 - - - - -
- - - - - - -
1.30 - - - - - -
- 18.56 7.43
- - - - - - - 3.71
- 0.33
- - - - - - - 0.04
1.49
- - - - - - - 1.49
- - - - - - - 50.12
- - - - - -
- - - - - - -
- - - - - - -
21.86 489.40 396.78 55.69 36.94 74.25 73.88
 Carga de Etano t/h
55.69

Carga Gas de Xisto t/h

523.19

15 16 17 18 19 20 21 22 23
- - - - - - - - -
- - - - - 9.28 - - 9.28
- - - - - - - - -
- - - - - - - - -
- - - - - - - - -
- - - - - - - - -
- - - - - - - - -
- - - - - - - - -
- - - - - - - - -
- - - - - 7.43 - - 7.43
- - - - - 3.71 - - 3.71
- - - - - - 0.33 - -
- - - - - 0.04 - - 0.04
1.49 - 1.49
- - - - - 1.49 - - 1.49
- - - - - 50.12 - - 50.12
- - - - - - - - -
- - - - - - - - -
- - - - - - - - -
- - - - - 73.55 0.33 - 73.55
24 25 26 27 28 29 30
- - - - - - -
- 9.28 9.28 - 9.28 - -
- - - - - - -
- - - - - - -
- - - - - - -
- - - - - - -
- - - - - - -
- - - - - - -
- - - - - - -
- 7.43 - 7.43 7.43 -
3.71 - - - - - -
- - - - - - -
0.04 - - - - - -
1.49 - - - - - -
- - - - - - -
- 50.12 - 50.12 - 50.12 50.12
- - - - - - -
- - - - - - -
- - - - - - -
5.23 66.83 9.28 57.55 9.28 57.55 50.12
 Bombas Separação da carga de Etano
Properties Unidade P-101 P-102 P-103 P-104 P-105
Fase -
Corrente 4 DEA 10 11 11
Vazão mássica kg/h 27950 10621 92630 18526 92630
Psucção kgf/cm2 14 14 15 16.5 16.5
Pfsucção kgf/cm2 167.16
ρsucção kg/m3 838.8 1063 670.8 628.3 430.4
Pdescarga kgf/cm2 18 18 18 18 18
Pfdescarga kgf/cm2 214.79
ρdescarga kg/m3 839 1063 671 628.2 426.2

BOMBAS (10)
Entrada
Tag P-101 P-102 P-103 P-104 P-105 P-106
P vaso (kgf/cm2) 14.00 14.00 14.00 16.50 16.50 38.00
ro (kg/m3) 838.80 1063.00 670.80 628.30 430.40 338.30
Delta P/100 (kg/cm2) 0.09 0.09 0.09 0.09 0.09 0.09
L (m) 2 2 3 1 15 3
Delta P Linha (kgf/cm2) 0.0018 0.0018 0.0027 0.0009 0.0135 0.0027
PO (kgf/cm2) 0.25 0.25 0.25 0.25 0.25 0.25
VC (kgf/cm2) 0.15 0.15 0.15 0.15 0.15 0.15
H (m) 12 12 3 4 7 2
P coluna (kgf/cm2) 0.98 1.24 0.18 0.23 0.29 0.06
P suc (kgf/cm2) 14.00 14.00 15.00 16.50 16.50 37.26
Head suc (m) 166.91 131.70 223.61 262.61 383.36 1101.36
Saída
P-101 P-102 P-103 P-104 P-105 P-106
P vaso (kgf/cm2) 18.00 18.00 18.00 16.50 16.50 38.00
ro (kg/m3) 839.00 1063 671.00 628.20 426.20 341.10
Delta P/100 (kg/cm2) 0.5 0.5 0.5 0.5 0.5 0.5
L (m) 900 500 100 200 100 10
Delta P Linha (kgf/cm2) 4.5 2.5 0.5 1 0.5 0.05
ta P Trocador (kgf/cm2) 0.5 0.5 0.5 0.5 0 0
H (m) 17.5 12.5 8 3 17.5 17.5
P coluna (kgf/cm2) 1.42 1.26 0.50 0.15 0.72 0.58
P desc (kgf/cm2) 18.00 18.00 18.00 18.00 18.00 40.00
Head desc (m) 214.59 169.33 268.34 286.49 418.22 1182.38
H bomba (m) 47.69 37.63 44.72 23.87 34.85 81.02
m (kg/h) 27950.00 10621.00 92630.00 18526.00 92630.00 55690.00
Q (m3/s) 0.0093 0.0028 0.0384 0.0082 0.0598 0.0454
Q (ft3/min) 19.61224236 5.8808 81.27602796 17.35475396 126.6727685 96.094683214
ro (kg/m3) 838.8 1063 670.80 628.30 430.40 341.10
 Ef 0.7 0.7 0.7 0.7 0.7 0.7
Pot (hp) 7.05 2.115 21.92 2.340 17.081 23.9
Fm 1 2 1 1 1 1
Fp 1 1 1 1 1 1
Pvapor (kgf/cm2) 0.043 0.0045 7.48 5.84 1.3 0.3169
NPSHd (m) 11.60 11.60 2.602 3.603 6.591 1.602
Preco (USD) $ 9,662.53 $ 4,981.85 $ 18,028.68 $ 5,267.42 $ 15,717.87 $ 18,895.69

33.32141154 9.991533396 138.0888491 29.48591437 215.2184015 163.26590443

Custo de bomba centrífuga (US$ FOB EUA, 2013) = 3300*Pot^0,55

 Deethanizer Sistema de Neutralização
P-106 P-201 P-202 P-301 P-302

- 27 27 -
55690 11510 57550 330 330
38 16.5 16.5 1 6

338.3 628.3 430.4 904.9 904.9

40 18 18 11 8

341.1 628.2 426.2 904.9 904.9

BAS (10)
trada
P-201 P-202 P-301 P-302
16.50 16.50 1.00 6.00
628.30 430.40 904.00 904.90
0.09 0.09 0.09 0.09
3 3 2 3
0.0027 0.0027 0.0018 0.0027
0.25 0.25 0.25 0.25
0.15 0.15 0.15 0.15
1 7 3 7
0.04 0.29 0.24 0.61
15.74 15.99 0.84 5.80
250.54 371.41 9.32 64.14
aída
P-201 P-202 P-301 P-302
18.00 18.00 11.00 8.00
778.92 426.2 904.90 904.9
0.5 0.5 0.5 0.5
10 250 250 250
0.05 1.25 1.25 1.25
0 0.5 0.5 0.5
14.5 12 12 12
1.08 0.49 1.03 1.03
19.13 19.81 6.04 11.04
304.52 460.17 66.84 122.03
53.98 88.76 57.52 57.90
11510.00 57550.00 660.00 660.00
0.0041 0.0375 0.0002 0.0002
8.6973724488 79.4759528651 0.4292864773 0.4292864773
778.92 426.20 904.90 904.90
 0.7 0.7 0.7 0.7
3.287 27.026 0.2009 0.202
1 1 1 1
1 1 1 1
0.822 1.72 0.5097 1.72
0.597 6.597 2.598 6.597
$ 6,349.93 $ 20,229.91 $ 1,364.90 $ 1,369.88

14.776929706 135.0305021117 0.7293623605 0.7293623605

 E-101 E-102 E-103 E-104

Função AGR Integração AGR AGR

Tipo Casco-e-Tubos Casco-e-Tubos Casco-e-Tubos Casco-e-Tubos

T1 (°C) 45 78 200 150
T2 (°C) 36 45 60 56
t1 (°C) 31 31 31 31
t2 (°C) 41 41 45 45
m (kg/h) 489525.46 27952.56 10621 21860.4
m (kg/s) 135.98 7.76 2.95 6.07
h1 (kJ/kg) -4153 -4689 -4373 -8344
h1 (J/kg) -4153000 -4689000 -4373000 -8344000
h2 (kJ/kg) -4176 -4624 -4659 -8436
h2 (J/kg) -4176000 -4624000 -4659000 -8436000
ft 0.85 0.85 0.85 0.85
U (W/m2*K) 730 750 750 250
ΔTML (K) 4.48 23.67 75.17 55.75
A (m2) 1124.72 33.45 17.61 47.16
A(ft2) 12101.95 359.95 189.45 507.44
Fp 1.05 1 1 1
Fm 1 1 1 1
q (kJ/s) 3127.52 504.70 843.78 558.65
Preço (US$) $ 154,253.36 $ 21,586.02 $ 9,511.63 $ 28,903.08

COLD BOX (1)

Função
CB-101
T1 (°C) 45
T2 (°C) -160
t1 (°C) -200
t2 (°C) -180
m (kg/h) 1015415
m (kg/s) 282.060
h1 (kJ/kg) -4639
h1 (J/kg) -4639000.000
h2 (kJ/kg) -5450
h2 (J/kg) -5450000.000
ft 0.85
U (W/m2*K) 850
ΔTML (K) 107.1084739937
 A (m2) 2955.9719861589
A(ft2) 31806.2585710696
Fp 1
Fm 1
q (kJ/h) 228.75
Preço (US$) $ 3,163,771.86

Para uma área de troca térmica na faixa de 500 a 3000 m², a

equação de custo da cold box é a seguinte:

$ FOB EUA, 2015 = 10.030*A^0,72, A em m².

 TROCADORES D
E-105 E-106 E-107 E-108 E-109 E-110

Sistema de Fluido AGR

Reboiler Fluido Refrigerante Fluido Refrigerante
Frigoria Refrigerante

Casco-e-Tubos Casco-e-Tubos Casco-e-Tubos Casco-e-Tubos Casco-e-Tubos

150 150 80 31 105
115 115 -14 45 65
78 -10 -20 -10 31
90 80 10 20 45
6090.0 36936 55690 55690 36936.1
1.69 322.65 15.47 15.47 10.26
8293 -2240 -3267 -3267 -3115
8293000 Preço incluso -2240000 -3267000 -3267000 -3115000
no sistema da
8415 Cold Box -2560 -3282 -3282 -3220
8415000 -2560000 -3282000 -3282000 -3220000
0.85 0.85 0.85 0.85 0.85
750 1000 750 750 750
47.58 94.86 26.05 27.34 45.78
6.80 1280.56 13.97 13.3139024528 36.92
73.22 13778.78 150.34 143.26 397.22
1 1.05 1 1 1
1 1 1 1 1
206.38 103249.54 232.04 232.04 1077.30
$ 2,635.45 $ 161,211.29 $ 6,961.19 $ 6,522.16 $ 23,471.78
TROCADORES DE CALOR (22)
E-201 E-202 E-203 E-204 E-205
Pré-Aquecedor Pré-Aquecedor Pré-Aquecedor AGR AGR

Casco-e-Tubos Casco-e-Tubos Casco-e-Tubos Casco-e-Tubos Casco-e-Tubos

200 200 200 900 900
150 150 150 200 200
20 58.3 116.6 31 31
58.3 116.6 175 45 45
55689.7 55689.7 55689.7 27844.9 27844.9
15.47 15.47 15.47 7.73 7.73
-2845 -2773 -2650 61.32 61.32
-2845000 -2773000 -2650000 61320 61320
-2773 -2650 -2517 -2451 -2451
-2773000 -2650000 -2517000 -2451000 -2451000
0.85 0.85 0.85 0.85 0.85
750 750 750 750 750
135.77 87.48 29.00 423.14 423.14
12.87 34.12 111.30 72.04 72.04
138.47 367.10 1197.56 775.11 775.11
1 1 1 1 1
1 1 1 1 1
1113.79 1902.73 2057.43 19432.01 19432.01
$ 6,229.46 $ 21,949.80 $ 59,967.98 $ 41,431.11 $ 41,431.11
 E-206 E-207 E-208 E-209 E-210 E-211
Fluido
AGR AGR AGR Reboiler
AGR Refrigerante

Casco-e-Tubos Casco-e-Tubos Casco-e-Tubos Casco-e-Tubos Casco-e-Tubos Casco-e-Tubos

200 148 96 56 150 80
148 96 44 48 115 -14
31 31 31 31 -10 -20
36 36 36 45 80 10
73881.73 73881.73 73881.73 668.28 9281.62 57546.07
20.52 20.52 20.52 0.19 2.58 15.99
-49.55 -160.4 -363.8 -6270 -2240 -3267
-49550 -160400 -363800 -6270000 -2240000 -3267000
-160.4 -363.8 -608.7 -6308 -2560 -3282
-160400 -363800 -608700 -6308000 -2560000 -3282000
0.85 0.85 0.85 0.85 0.85 0.85
750 750 750 750 750 750
139.18 86.38 30.73 13.78 94.86 26.05
25.64 75.80 256.55 0.80 13.64 14.44
275.88 815.66 2760.43 8.64 146.80 155.35
1 1 1 1 1 1
1 1 1 1 1 1
2274.94 4174.32 5026.01 7.05 825.03 239.78
$ 15,798.38 $ 43,266.28 $ 88,880.55 $ 12,512.13 $ 6,740.96 $ 7,276.25
 E-212
Fluido
Refrigerante

Casco-e-Tubos
10
30
-10
-1
50121
13.92
1810
1810000
1844
1844000
0.85
750
22.46
33.05
355.67
1
1
473.36
$ 21,367.80
 Fator de tecnologia do forno reator: 1,85.

FORNOS
H-201 H-202
m (kg/h) 37126.50 37126.50 Tr (h)
Tin 175 175 m (kg/h)
Tout 900 900 roh mix (kg/m3)
h1 (kJ/kg) 3680.00 3680.00 V (m3)
h2 (kJ/kg) 5326.00 5326.00 Espessura (m)
q (kJ/h) 61110216.4966899 61110216.4966899 D (m)
q(BTU/h) 58054705.67 58054705.67 H (m)
q(MMBTU/h) 58.05 58.05 E aço
Preco (USD) $ 3,862,502.00 $ 3,862,502.00 S aço (kgf/cm2 g)
C (m)
roh aço (kg/m3)
V aço (m3)
m aço (kg)
L/D
P op (kgf/cm2)
P proj (kgf/cm2)
Preco (USD)
 REATOR
R-201A R-201B R-202
0.00833 0.00833 0.00833
36773.80 36773.80 66827.70
0.70 0.70 0.90
437.6081812489 437.6081812489 618.3213575436
0.082 0.082 0.092
11.87 11.87 13.32
35.6035680467 35.6035680467 39.9518101973
0.7500 0.7500 0.7500
1000 1000 1000
0.003 0.003 0.003
7833 7833 7833
109.430 109.430 154.008
857165.83 857165.83 1206341.08
3.00 3.00 3.00
8.00 8.00 8.00
10.00 10.00 10.00
$ 3,267,808.71 $ 3,267,808.71 $ 4,222,411.71
 V-101 V-102A V-102B V-103
m (kg/h) 517478 258739 258739 258739
Q (m3/h) 868.25 821.39 821.39 845.55
ro (kg/m3) 596 315 315 306
L/D 3 3 3 3
tr (h) 0.083 0.083 0.083 0.083
V (m3) 72.354 68.449 68.449 70.463
D (m) 3.131 3.074 3.074 3.104
L (m) 9.394 9.222 9.222 9.312
Pproj bar
Pproj kgf/cm2 30 17 17 14.5
S 1000 1000 1000 1000
E 0.85 0.85 0.85 0.85
C (m) 0.003 0.003 0.003 0.003
t (m) 0.03 0.03 0.03 0.03
ro ac carb (kg/m3) 7833 7834 7834 7834
V aco (m3) 2.7726468578 2.6719707446 2.6719707446 2.724108807
m aco c (kg) 21718.1428370588 20932.218813226 20932.218813226 21340.6683940091
Preco (USD) $ 187,804.84 $ 182,751.64 $ 182,751.64 $ 185,383.86

COLUNAS DE DESTILAÇÃO (4)

Tag Novo V-106 V-107 V-205 V-206
N pratos 12 34 15 32
L (m) 13.5 24.5 15 23.5
L/D 3 3 3 3
D (m) 4.5 8.2 5.0 7.8
V (m3) 214.7 1283.4 294.5 1132.5
Pproj kgf/cm2 15 17.5 15 17
S 1000 1000 1000 1000
E 0.85 0.85 0.85 0.85
C (m) 0.003 0.003 0.003 0.003
t (m) 0.092 0.094 0.092 0.093
ro ac carb (kg/m3) 7833 7833 7833 7833
V aco (m3) 17.56 59.09 21.68 53.78
m aco c (kg) 137534.64 462824.95 169795.86 421284.44
Preco (USD) $ 527,261.41 $ 1,294,223.95 $ 616,236.01 $ 1,207,221.14
 VASOS DE PROCESSO (13)
V-104 V-105A V-105B V-108 V-201 V-204
27953 244763 244763 55690 73882 73882
33.32 728.46 728.46 88.64 671.65 223.88
839 336 336 628 110 330
3 3 3 3 3 3
0.083 0.083 0.083 0.083 0.083 0.083
2.776 60.705 60.705 7.386 55.971 18.657
1.056 2.954 2.954 1.464 2.875 1.993
3.169 8.861 8.861 4.391 8.624 5.979

17 17 17.5 17.5 1.5 11

1000 1000 1000 1000 1000 1000
0.85 0.85 0.85 0.85 0.85 0.85
0.003 0.003 0.003 0.003 0.003 0.003
0.03 0.03 0.03 0.03 0.03 0.03
7834 7834 7834 7834 7834 7834
0.315430632 2.4664262542 2.4664262542 0.6056237824 2.3364709328 1.1232580663
2471.0835710296 19321.98327555 19321.98327555 4744.456711042 18303.9132879 8799.60369149
$ 37,600.59 $ 172,240.89 $ 172,240.89 $ 60,930.68 $ 165,478.09 $ 96,241.13
 V-207 V-208A V-208B
57546 57546 57546
73.88 76.12 76.12
779 756 756
3 3 3
0.083 0.083 0.083
6.157 6.343 6.343
1.377 1.391 1.391
4.132 4.173 4.173

17 16.5 16.5
1000 1000 1000
0.85 0.85 0.85
0.003 0.003 0.003
0.03 0.03 0.03
7834 7834 7834
0.5363883668 0.5471756008 0.5471756008
4202.0664658 4286.5736567 4286.5736567
$ 55,695.56 $ 56,522.27 $ 56,522.27
 COMPRESSORES (3)
C-101 C-102 C-103
m (kg/h) 489525.46 396775.98
Z 1.0 1.00
R (J/kmol.K) 8314.5 8314.5
T (K) 576.2 113.15
MM (kg/kmol) 19.1 12.12
roh (kg/m3) 11.6 23.48
Incluso no custo da
Ef 0.7 Cold Box 0.74
k 1.4 1.4
n 1.27 1.2700
P1 (kgf/cm2) 14.0 14.5
P2 (kgf/cm2) 15.0 17
Pot (J/h) 8517647932.9 4982757149.3
Pot (hp) 3172.9 1856.1
Preco (USD) $ 1,265,296.86 $ 823,972.01
 ESFERAS (3)
V-109 V-110 V-211
Roh medio (kg/m3) 430.40 476.60 430.4
m (kg/h) 55689.75 36936.12 50120.77
m (kg/dia) 2320.41 1539.00 2088.37
tr (dia) 10 10 10
m (kg) 23204.06 15390.05 20883.66
V vaso (m3) 53.91 32.29 48.52
E aço 0.85 0.85 0.85
S aço (kgf/cm2 g) 1000 1000 1000
C (m) 0.003 0.003 0.003
P op (kgf/cm2) 38.60 17 17
P projeto (kgf/cm2) 44.46 20.70 20.70
r (m) 3.588 2.777 3.403
espessura (m) 0.193 0.071 0.086
Roh do aço (kg/m3) 7833 7833 7833
vol. aço (m3) 31.1565 6.8729 12.5608
maço (kg) 244049.03 53835.61 98388.84
Preco (USD) $ 805,998.18 $ 101,872.48 $ 125,809.54
 TANQUE (1)
V-301
m (kg/hr) 668.28
Q (m3/hr) 0.74
ro (kg/m3) 904
H (m) 15
tr (hr) 24
V (m3) 17.74
D (m) 1.23
Preco (USD) $ 22,542.03