Incerteza Ânions Matriz Líquida

Planilha de Avaliao da Incerteza
1) Preparao da Soluo Padro

A) Pureza do Reagente - Incerteza Tipo B
Reagente
NaF
NaCl
NaNO2
Marca
Synth
JT Baker
JT Baker
Lote
99785
E35C51
E25585
Resultado
100
99.6
99.60
a
0
0.2
0.2
u
0
0.115470
0.1154701
K2HPO4
NaBr
KNO3
JT Baker
JT Baker
FMaia
X06C14
C11650
35223
100.3
99.9
100
0.15
0.05
0
0.0866025
0.0288675
0
K2SO4
FMaia
34882
99.42
0.29
0.1674316
u = a / Raiz(3)
a = incerteza fornecida no certificado de calibrao ou calculada conforme a pureza do reagente
u = incerteza padro combinada
B) Massa do Reagente - Incerteza Tipo B
Reagente
NaF
NaCl
NaNO2
m(terica)
221.0
164.9
492.6
m(real)
223.2
165.6
494.5
a
0.1
0.1
0.1
K2HPO4
NaBr
KNO3
562.1
128.8
606.8
560.1
128.9
728.2
0.1
0.1
0.1
K2SO4
massa ( mg )
181.4
183.2
0.1
C) Diluio
C.1) Certifica do Calibrao dos bales Volumtricos - Incerteza Tipo B
balo
100
250
500
n certif.
3
4
A 141
11645/08
A 134
A 135
A 334
A 335
A 131
A 137
A 337
a
0.07
0.07
0.06
0.031
0.14
0.14
0.14
0.14
0.27
0.27
0.27
u
0.04041452
0.04041452
0.03464102
0.01789786
0.08082904
0.08082904
0.08082904
0.08082904
0.15588457
0.15588457
0.15588457
uc
0.069188
u = a / Raiz(3)
uc = Raiz ( u2 )
0.161658
0.270000
C.2) Certifica do Calibrao das Pipetas Volumtricas e Graduada - Incerteza Tipo B

pipeta
1
2
4
5
10
20
25
1
n certif.
A 209
A 199
A 195
A 189
5577/08
3
A 178
A 202
a
0.0006
0.0012
0.0022
0.0029
0.02
0.011
0.014
0.0006
u
0.0003464
0.0006928
0.0012702
0.0016743
0.0115470
u = a / Raiz(3)
0.0063509
0.0080829
0.0003464 pipeta graduada
Enchimento dos Bales - Incerteza Tipo A
n
1
2
3
4
5
6
7
8
9
10
mdia
dvp
u
3
99.72
99.76
99.70
99.69
99.73
99.74
99.76
99.74
99.75
99.74
99.73
0.023594
0.007461
n balo de 100ml
4
A 141
99.57
99.66
99.66
99.79
99.60
99.58
99.58
99.69
99.57
99.66
99.49
99.58
99.57
99.58
99.48
99.61
99.56
99.57
99.49
99.53
99.56
99.63
0.056184
0.076194
0.017767
0.024095
11645/08
99.72
99.73
99.71
99.69
99.67
99.7
99.68
99.65
99.7
99.64
99.69
0.029231
0.009244
n
1
2
3
4
5
6
7
8
9
10
mdia
dvp
u
A 134
249.14
249.06
248.98
248.99
249.08
249.05
249.02
249.06
248.99
249.08
249.05
0.050387
0.015934
n balo de 250ml
A 135
A 334
248.98
249.11
249.00
248.96
248.94
248.94
248.88
248.89
248.86
248.96
248.88
248.98
249.01
248.85
249.06
248.97
248.96
249.01
248.98
248.96
248.96
248.96
0.064850
0.068969
0.020507
0.021810
A 335
249.19
248.95
249.04
248.87
248.9
248.89
248.93
248.88
248.81
248.79
248.93
0.116643
0.036886
n
1
2
3
4
5
6
7
8
9
10
mdia
dvp
u
n balo de 500ml
A 131
A 133
498.4
497.9
497.8
498.00
497.3
497.60
498.3
497.3
497.7
497.3
497.3
497.6
497.8
498.1
497.7
497.9
498.1
497.3
497.8
497.6
497.82
497.66
0.367575
0.302581
0.116237
0.095685
A 337
498.7
498.4
498.3
498.6
498.4
498.4
498.5
498.3
498.4
498.6
498.46
0.134990
0.042687
u = dvp / RAIZ(n)
uc = Raiz ( u2 )
uc
uc
0.032208
uc
0.050107
0.156489
C.3) Balana utilizada na Pesagem dos Bales - Incerteza Tipo B

Balana Gehaka BG 4400
u = 0,01g
Incerteza na Pesagem
Incerteza combinada no Enchimento
Balo
100 ml
250 ml
500 ml
u
0.00020070
0.00008033
0.00003478
Balo
100 ml
250 ml
500 ml
u = Raiz ( Somatria ( 0.01/ mdia de cada balo)^2 )
uc
0.03220828
0.05010662
0.15648927
uc = Raiz ( u2 )
C.4) Temperatura - Incerteza Tipo B

coeficiente de expanso da gua = 2.1 x 10E-04/C
Temperatura do laboratrio = 19C 2C
Balo
100 ml
250 ml
500 ml
u
0.0242487
0.0606218
0.1212436
u = (vol. Balo x Dt x coef.expanso) / RAIZ(3)
D) Clculo da Incerteza para o Volume

Balo de 100 ml
uc = Raiz ( u2 )
Incerteza do certificado :
0.06918815
Incerteza no enchimento : 0.03220828
Incerteza da Temperatura: 0.02424871
uc = 0.0800773
Balo de 250 ml
uc = Raiz ( u2 )
0.16165808
uc = 0.1797749
Balo de 500 ml
uc = Raiz ( u2 )
0.27000000
uc = 0.3347968
E) Clculo da Incerteza da Massa Corrigida pela Pureza

mc = (mterica x 100 ) / Pureza
Reagente
NaF
NaCl
NaNO2
m(terica)
221.0
164.9
492.6
Pureza
0.1000
0.9960
0.9960
a
0.1
0.1
0.1
u pureza
0.000000
0.115470
0.115470
uc
0.0004525
0.1159354
0.115934
K2HPO4
NaBr
KNO3
562.1
128.8
606.8
0.1003
0.9990
0.1000
1.1
2.1
3.1
0.086603
0.028868
0.000000
0.8634373
0.0331788
0.0051088
K2SO4
massa ( mg )
181.4
0.9942
4.1
0.167432
0.1699183
uc = Raiz ( ( a / m terica )^2 + ( u pureza / Pureza )^2 )

Contribuio molar dos ctions em seus respectivos reagentes:
Reagente
F
Cl
NO2
PO4
NaF
0.4524
NaCl
0.6066
NaNO2
(1)
K2HPO4
(2)
NaBr
KNO3
K2SO4
(1) N = 0,2030
(2) P = 0,2276
(3) N = 0,1386
(4) S = 0,1840
Br
NO3
SO4
0.7765
(3)
(4)
|
|
|
|
O = 0,4638
O = 0,4703
O = 0,4747
O = 0,3673

2) Preparao das Amostras para curva de calibrao
Tipo B
up = { [ Raiz ( (upipeta/vpipeta)^2 + (usoluo)^2 + (ubalo/vbalo) ) ] / 500} * conc.
Fluoreto
amostra
diluo
conc.
P1
1/100 ppm
0.20
P2
2,5/100ppm
0.50
P3
5/100ppm
1.00
P4
7,5/100ppm
1.50
P5
10/100ppm
2.00
P6
15/100ppm
3.00
P7
25/100ppm
5.00
P8
4/1000ppm
8.00
P9
5/1000ppm
10.00
P10
7,5/1000ppm
15.00
uamostras = 0.038981828
Nitrito
amostra
P1
P2
P3
P4
P5
P6
P7
P8
P9
P10
diluo
conc.
2/100 ppm
0.40
5/100ppm
1.00
10/100ppm
2.00
15/100ppm
3.00
20/100ppm
4.00
3/1000ppm
6.00
5/1000ppm
10.00
8/1000ppm
16.00
10/1000ppm
20.00
15/1000ppm
30.00
uamostras = 6.73649E-05
u
0.0001414
0.0003535
0.0007069
0.0010604
0.0014139
0.0021208
0.0035347
0.0157033
0.0196291
0.0294437
Cloreto
amostra
diluo
conc.
P1
1/100 ppm
0.20
P2
2,5/100ppm
0.50
P3
5/100ppm
1.00
P4
7,5/100ppm
1.50
P5
10/100ppm
2.00
P6
15/100ppm
3.00
P7
25/100ppm
5.00
P8
4/1000ppm
8.00
P9
5/1000ppm
10.00
P10
7,5/1000ppm
15.00
uamostras =
3.92579E-05
u
3.916E-07
8.947E-07
1.508E-06
2.684E-06
5.505E-06
4.446E-06
8.947E-06
1.206E-05
2.752E-05
2.231E-05
u
6.031E-07
1.659E-06
2.995E-06
5.368E-06
1.068E-05
1.651E-05
1.487E-05
2.371E-05
3.579E-05
4.523E-05
Fosfato
amostra
diluo
conc.
P1
1/100 ppm
0.20
P2
2,5/100ppm
0.50
P3
5/100ppm
1.00
P4
7,5/100ppm
1.50
P5
10/100ppm
2.00
P6
15/100ppm
3.00
P7
25/100ppm
5.00
P8
4/1000ppm
8.00
P9
5/1000ppm
10.00
P10
7,5/1000ppm
15.00
uamostras =
4.78424E-05
u
3.579E-07
7.539E-07
1.789E-06
2.489E-06
2.974E-06
4.446E-06
8.947E-06
1.206E-05
1.789E-05
4.128E-05
Brometo
amostra
diluo
conc.
P1
1/100 ppm
0.20
P2
2,5/100ppm
0.50
P3
5/100ppm
1.00
P4
7,5/100ppm
1.50
P5
10/100ppm
2.00
P6
15/100ppm
3.00
P7
25/100ppm
5.00
P8
4/1000ppm
8.00
P9
5/1000ppm
10.00
P10
7,5/1000ppm
15.00
u
3.016E-07
8.297E-07
1.497E-06
2.684E-06
5.339E-06
5.368E-06
1.376E-05
1.19E-05
1.958E-05
2.684E-05
Sulfato
amostra
diluo
conc.
P1
5/100 ppm
0.10
P2
15/100ppm
0.20
P3
25/100ppm
0.40
P4
4/1000ppm
0.80
P5
5/1000ppm
1.00
P6
7,5/1000ppm
1.50
P7
10/1000ppm
2.00
P8
12,5/1000ppm
3.00
P9
17,5/1000ppm
5.00
P10
25/1000ppm
8.00
u
1.508E-07
3.319E-07
5.989E-07
1.432E-06
2.67E-06
2.262E-06
5.505E-06
4.461E-06
8.947E-06
1.432E-05
Nitrato
amostra
P1
P2
P3
P4
P5
P6
P7
P8
P9
P10
diluo
conc.
3/100 ppm
0.60
7,5/100ppm
1.50
15/100ppm
3.00
22,5/100ppm
4.50
3/1000ppm
6.00
4,5/1000ppm
9.00
7,5/1000ppm
15.00
12/1000ppm
24.00
15/1000ppm
30.00
22,5/1000ppm
45.00
uamostras =
0.000104797
u
1.175E-06
2.684E-06
4.523E-06
8.052E-06
1.651E-05
1.338E-05
2.223E-05
4.295E-05
4.018E-05
8.052E-05
F
P1
P2
P3
P4
P5
P6
P7
P8
P9
P10
Cl
pipeta
0.00000012
0.00000024
1.12133E-07
3.52133E-07
1.33333E-06
1.44547E-06
1.04533E-07
1.00833E-07
1.12133E-07
3.52133E-07
soluo
0.124937
0.124937
0.124937
0.124937
0.124937
0.124937
0.124937
0.963253
0.963253
0.963253
balo
4.48356E-07
4.48356E-07
4.48356E-07
4.48356E-07
4.48356E-07
4.48356E-07
4.48356E-07
4.48356E-07
4.48356E-07
4.48356E-07
pipeta
0.00000012
0.00000024
1.12133E-07
3.52133E-07
1.33333E-06
1.44547E-06
1.04533E-07
1.00833E-07
3.52133E-07
0.00000012
soluo
balo
4.48356E-07
4.48356E-07
4.48356E-07
4.48356E-07
4.48356E-07
4.48356E-07
4.48356E-07
4.48356E-07
4.48356E-07
4.48356E-07
pipeta
0.00000012
0.00000024
1.12133E-07
3.52133E-07
1.33333E-06
3.52133E-07
1.44547E-06
1.04533E-07
0.00000051
3.52133E-07
soluo
pipeta
0.00000012
0.00000024
1.12133E-07
3.52133E-07
1.33333E-06
0.00000012
1.44547E-06
1.04533E-07
3.52133E-07
3.52133E-07
soluo
NO2
P1
P2
P3
P4
P5
P6
P7
P8
P9
P10
soluo
balo
4.48356E-07
4.48356E-07
4.48356E-07
4.48356E-07
4.48356E-07
4.48356E-07
4.48356E-07
4.48356E-07
4.48356E-07
4.48356E-07
P1
P2
P3
P4
P5
P6
P7
P8
P9
P10
pipeta
3.52133E-07
0.00000012
3.52133E-07
0.00000024
1.04533E-07
1.00833E-07
3.52133E-07
0.00000012
3.52133E-07
1.44547E-06
soluo
balo
4.48356E-07
4.48356E-07
4.48356E-07
4.48356E-07
4.48356E-07
4.48356E-07
4.48356E-07
4.48356E-07
4.48356E-07
4.48356E-07
pipeta
0.00000051
3.52133E-07
0.00000012
3.52133E-07
1.44547E-06
1.04533E-07
1.00833E-07
3.52133E-07
0
3.52133E-07
soluo
balo
4.48356E-07
4.48356E-07
4.48356E-07
4.48356E-07
4.48356E-07
4.48356E-07
4.48356E-07
4.48356E-07
4.48356E-07
4.48356E-07
NO3
balo
4.48356E-07
4.48356E-07
4.48356E-07
4.48356E-07
4.48356E-07
4.48356E-07
4.48356E-07
4.48356E-07
4.48356E-07
4.48356E-07
SO4
P1
P2
P3
P4
P5
P6
P7
P8
P9
P10
pipeta
0.00000051
3.52133E-07
0.00000012
3.52133E-07
1.44547E-06
1.00833E-07
3.52133E-07
0.00000012
1.44547E-06
1.04533E-07
PO4
Br
P1
P2
P3
P4
P5
P6
P7
P8
P9
P10
P1
P2
P3
P4
P5
P6
P7
P8
P9
P10
balo
4.48356E-07
4.48356E-07
4.48356E-07
4.48356E-07
4.48356E-07
4.48356E-07
4.48356E-07
4.48356E-07
4.48356E-07
4.48356E-07
P1
P2
P3
P4
P5
P6
P7
P8
P9
P10

3) Volume de Injeo - Tipo B
volume = 20l
Adotar incerteza mxima = 0,5% do volume
a = 0,02 x 0,5%
a = 0,0001
u = a / Raiz(3)
u=
5.77E-05 ml
4) Curva de Calibrao
Tipo A
Parmetro
Fluoreto
Cloreto
Nitrito
Fosfato
Brometo
Nitrato
Sulfato
b
6.2939
5.1695
11.461
6.9714
3.3843
4.3843
5.3843
sy/x
0.05385384
0.11645429
0.08438505
0.12952242
0.03121853
0.03121853
0.03121853
xo
15.00
15.00
30.00
15.00
15.00
0.00
0.00
x
4.62
4.62
9.24
4.62
4.62
4.60
5.06
Sxx
217.096
217.096
868.384
217.096
217.096
415002.6
5174
10
ucurva
0.009025
0.023825
0.007735
0.019576
0.009863
0.007468
0.006082
5) Incerteza associada a Repetitividade

Tipo A
u = dvp / RAIZ(n)
dvp = maior desvio entre a gua Desmi e gua Bruta.
Parmetro
Fluoreto
Cloreto
Nitrito
Fosfato
Brometo
Nitrato
Sulfato
dvp
0.0568859
0.0741100
0.0771165
0.0737606
0.0688494
0.0688494
0.0688494
urep
0.021501
0.028011
0.029147
0.027879
0.026023
#DIV/0!
#DIV/0!
6) Incerteza associada a Reprodutibilidade

Tipo A
u = dvp / RAIZ(n)
dvp = maior desvio entre a gua Desmi e gua Bruta.
Parmetro
Fluoreto
Cloreto
Nitrito
Fosfato
Brometo
Nitrato
Sulfato
dvp
urepro
0
0
0
0
0
#DIV/0!
#DIV/0!
7) Incerteza Padro Combinada para os Mtodos

u = Raiz ( ( uinjeo )^2 + ( ucurva )^2 + ( urep )^2 + ( urepro )^2 )
adotar k = 2
U=2*u
Parmetro
u
U
Fluoreto
0
0
Cloreto
0
0
Nitrito
0
0
Fosfato
#VALUE! #VALUE!
Brometo
#VALUE! #VALUE!
Nitrato
0.2
0.4
Sulfato
0.5
1
F
conc.
0.20
0.50
1.00
1.50
2.00
3.00
5.00
8.00
10.00
Cl
conc.
0.20
0.50
1.00
1.50
2.00
3.00
5.00
8.00
10.00
NO2
conc.
0.40
1.00
2.00
3.00
4.00
6.00
10.00
16.00
20.00
PO4
conc.
0.20
0.50
1.00
1.50
2.00
3.00
5.00
8.00
10.00
Br
conc.
0.20
0.50
1.00
1.50
2.00
3.00
5.00
8.00
10.00
NO3
conc.
0.60
1.50
3.00
4.50
6.00
9.00
15.00
24.00
30.00
SO4
conc.
1.00
3.00
5.00
8.00
10.00
15.00
20.00
25.00
35.00
15.00
15.00
30.00
15.00
15.00
45.00
50.00
217.096
217.096
868.384
217.096
217.096 415002.6
Syx/b
1/p
0.008557
0.022527
0.007363
0.018579
0.009225
0.007121
0.005798
1/n
1
1
1
1
1
1
1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
(x0 - x)^2
107.7444
107.7444
430.9776
107.7444
107.7444
21.15968
25.55869
(b^2)*Sxx
8599.862
5801.615
114066.2
10550.96
2486.506
7977216
149997.8
5174
Incerteza das Solues Padres

Clculo da Incerteza da Soluo Padro atravs do mtodo numrico de Kragten
Soluo Padro de Fluoreto - 1000ppm
CF = ( 1000 x mreal x 0.4524 ) / V
massa
volume
valor
223.2
incerteza 0.1159354
223.2
223.31594
100.0
100.0
100.0
0.08008
223.2
100.08008
CF
u(CF,x)
[u(CF,x)]2
1009.757 1010.2813
0.5245
0.2750915
1008.9489
0.8079
0.6527654
u(CFa)
0.963253
coef. Sensib.
u(CF) = 0.9632533
adotando k = 2
U = 2 * u(CF)
4.5240
10.0895
U=
1.9
mg/L

CF =[ ( 1000 x mreal x 0.4524 ) / V1 ] * (alquota / V2 )
massa
volume 1
alquota
volume 2
valor
223.2
incerteza 0.1159354
223.2
223.31594
100.0
100.0
25.0
25.0
250.0
250.0
CF
u(CF,x)
[u(CF,x)]2
100.976
u(CFa)
0.124937
coef. Sensib.
101.028
0.0524
0.0027509
100.0
25.0
250.0
0.08008
0.008083 0.17977
223.2
223.2
223.2
100.08008
100.0
100.0
25.0
25.008083
25.0
250.0
250.0
250.17977
100.895
101.008
100.903
-0.0808
0.0326
-0.0726
0.0065277 0.0010658 0.0052649
u(CF) = 0.124937
adotando k = 2
U = 2 * u(CF)
0.4524
1.0089
4.0390
0.4036
U=
0.25
mg/L

CF =[ ( 1000 x mreal x 0.4524 ) / V1 ] * (alquota / V2 )
massa
volume 1
alquota
volume 2
valor
223.2
incerteza 0.1159354
223.2
223.31594
100.0
100.0
1.0
1.0
100.0
100.0
CF
u(CF,x)
[u(CF,x)]2
10.0976
u(CFa)
0.01305
coef. Sensib.
10.1028
0.0052
0.0000275
100.0
0.08008
223.2
100.08008
1.0
100.0
1.0
100.0
0.000346 0.08008
223.2
223.2
100.0
100.0
1.000346
1.0
100.0
100.08008
10.0895
10.1011
10.0895
-0.0081
0.0035
-0.0081
0.0000653 0.0000122 0.0000653
u(CF) =
0.01305
adotando k = 2
U = 2 * u(CF)
0.0452
0.1009
10.0976
0.1009
U=
0.03
mg/L

Contribuio das Incertezas nas Solues Padro
CF
volume
massa
1.0000
0.1000
CF
volume 2
alquota
1.0000
0.1000
0.0100
0.0010
CF
volume 2
alquota
1.00000
0.10000
0.01000
0.00100
0.00010
0.00001

Soluo Padro de Cloreto - 1000ppm
CCl = ( 1000 x mreal x 0.6063 ) / V
massa
volume
valor
165.6
incerteza 0.0004525
165.6
165.60045
100.0
100.0
100.0
0.08008
165.6
100.08008
CCl
u(CCl,x)
[u(CCl,x)]2
1004.530 1004.5323
0.0027
0.0000075
1003.7258
-0.8038
0.6460246
u(CCl)
0.803761
coef. Sensib.
m real =
volume =
165.6 mg
100 ml
u(CCl) = 0.8037612
adotando k = 2
U = 2 * u(CCl)
6.0660
10.0373
U=
1.6
mg/L

CNH4 =[ ( 1000 x mreal x 0.6063 ) / V1 ] * (alquota / V2 )
massa
volume 1
alquota
volume 2
valor
165.6
incerteza 0.0004525
165.6
165.60045
100.0
100.0
25.0
25.0
250.0
250.0
CCl
u(CCl,x)
[u(CCl,x)]2
100.453
u(CCl)
0.112808
coef. Sensib.
100.453
0.0003
0.0000001
100.0
25.0
250.0
0.08008
0.008083 0.17977
165.6
165.6
165.6
100.08008
100.0
100.0
25.0
25.008083
25.0
250.0
250.0
250.17977
100.373
100.485
100.381
-0.0804
0.0325
-0.0722
0.0064602 0.0010548 0.0052105
u(CCl) = 0.112808
adotando k = 2
U = 2 * u(CCl)
0.6066
1.0037
4.0181
0.4015
U=
0.23
mg/L

CCl =[ ( 1000 x mreal x 0.6063 ) / V1 ] * (alquota / V2 )
massa
volume 1
alquota
volume 2
valor
165.6
incerteza 0.0004525
165.6
165.60045
100.0
100.0
1.0
1.0
100.0
100.0
CCl
u(CCl,x)
[u(CCl,x)]2
10.0453
u(CCl)
0.011888
coef. Sensib.
10.0453
0.0000
0.0000000
100.0
0.08008
165.6
100.08008
1.0
100.0
1.0
100.0
0.000346 0.08008
165.6
165.6
100.0
100.0
1.000346
1.0
100.0
100.08008
10.0373
10.0488
10.0373
-0.0080
0.0035
-0.0080
0.0000646 0.0000121 0.0000646
u(CCl) = 0.011888
adotando k = 2
U = 2 * u(CCl)
0.0607
0.1004
10.0453
0.1004
U=
0.02
mg/L

CCl
volume
massa
1.0000
0.1000
0.0100
0.0010
0.0001
0.0000
0.0000
CCl
volume 2
alquota
1.0000
0.1000
0.0100
0.0010
CCl
volume 2
alquota
1.00000
0.10000
0.01000
0.00100
0.00010
0.00001

Soluo Padro de Potssio - 1000ppm
CK = ( 1000 x mreal x 0,1914 ) / V
massa
volume
valor
494.5
incerteza 0.115934
494.5
494.61593
100.0
100.0
CK
u(CK,x)
[u(CK,x)]2
-4945.000 -4946.1593 -4941.0433

-1.1593
3.9567
1.3440685 15.6551108
u(CK)
4.123006
coef. Sensib.
100.0
0.08008
494.5
100.08008
u(CK) = 4.1230061
adotando k = 2
U = 2 * u(CNa)
-10.0000
49.4104
U=
8.2
mg/L

CK =[ ( 1000 x mreal x 0,1914 ) / V1 ] * (alquota / V2 )
valor
494.5
incerteza 0.115934
494.5
494.61593
100.0
100.0
25.0
25.0
250.0
250.0
100.0
25.0
250.0
0.08008
0.008083 0.17977
494.5
494.5
494.5
100.08008
100.0
100.0
25.0
25.008083
25.0
250.0
250.0
250.17977
CK
u(CK,x)
[u(CK,x)]2
-494.500
-494.104
-494.660 -494.145
0.3957
-0.1599
0.3553
0.1565511 0.0255616 0.1262659
u(CK)
0.567291
massa
volume 1
alquota
volume 2
coef. Sensib.
-494.616
-0.1159
0.0134407
u(CK) = 0.567291
adotando k = 2
U = 2 * u(CNa)
-1.0000
4.9410
-19.7800
1.9766
U=
1.13
mg/L

CK =[ ( 1000 x mreal x 0,1914 ) / V1 ] * (alquota / V2 )
valor
494.5
incerteza 0.115934
494.5
494.61593
100.0
100.0
1.0
1.0
100.0
100.0
100.0
0.08008
494.5
100.08008
1.0
100.0
CK
u(CK,x)
[u(CK,x)]2
-49.4500
-49.4104
-49.4671 -49.4104
0.0396
-0.0171
0.0396
0.0015655 0.0002934 0.0015655
u(CK)
0.059656
massa
volume 1
alquota
volume 2
coef. Sensib.
-49.4616
-0.0116
0.0001344
1.0
100.0
0.000346 0.08008
494.5
494.5
100.0
100.0
1.000346
1.0
100.0
100.08008
u(CK) = 0.059656
adotando k = 2
U = 2 * u(CNa)
-0.1000
0.4941
-49.4500
0.4941
U=
0.12
mg/L

CK
volume
massa
100.0000
10.0000
1.0000
CK
volume 2
alquota
1.0000
0.1000
0.0100
0.0010
CK
volume 2
alquota
1.00000
0.10000
0.01000
0.00100
0.00010

Soluo Padro de Clcio - 1000ppm
CCa = ( alquota x soluo ) / V
valor
10
incerteza 0.011547
alquota
10
10.011547
volume
100.0
100.0
soluo
100.3
100.3
CCa
10.030
10.0416
u(CCa,x)
0.0116
[u(CCa,x)]2
0.0001341
u(CCa)
0.016539
coef. Sensib.
1.0030
100.0
0.08008
10
100.08008
100.3
10.0220
-0.0080
0.0000644
100.3
0.086603
10
100.0
100.3866
10.03866
0.008660
0.000075
0.1002
0.1000
u(CCa) 0.0165391
adotando k = 2
U = 2 * u(CNa)
U=
0.0
mg/L

CCa =[ ( aliquota1 x soluo ) / V1 ] * (alquota2 / V2 )
valor
10
incerteza 0.011547
alquota1
10
10.011547
volume 1
100.0
100.0
alquota2
25.0
25.0
volume 2
250.0
250.0
Soluo
100.3
100.3
CCa
1.003
1.004
u(CCa,x)
0.0012
[u(CCa,x)]2
0.0000013
u(CCa)
0.001833
coef. Sensib.
0.1003
u(CCa) 0.001833
U = 2 * u(CNa)
100.0
25.0
250.0
100.3
0.08008
0.008083 0.17977 0.0866025
10
10
10
10
100.08008
100.0
100.0
100.0
25.0
25.008083
25.0
25.0
250.0
250.0
250.17977
250.0
100.3
100.3
100.3
100.3866
1.002
1.003
1.002
1.004
-0.0008
0.0003
-0.0007
0.000866
0.0000006 0.0000001 0.0000005 0.000001
0.0100
0.0401
0.0040
0.0100
adotando k = 2
U=
0.00
mg/L

CCa =[ ( aliquota1 x soluo ) / V1 ] * (alquota2 / V2 )
valor
10
incerteza 0.011547
alquota1
10
10.011547
volume 1
100.0
100.0
alquota2
1.0
1.0
volume 2
100.0
100.0
Soluo
100.3
100.3
CCa
0.1003
0.1004
u(CCa,x)
0.00012
[u(CCa,x)]2
0.0000000
u(CCa)
0.000166
coef. Sensib.
0.0100
u(CCa) 0.000166
U = 2 * u(CNa)
100.0
1.0
100.0
100.3
0.08008
0.000346 0.08008 0.0866025
10
10
10
10
100.08008
100.0
100.0
100.0
1.0
1.000346
1.0
1.0
100.0
100.0
100.08008
100.0
100.3
100.3
100.3
100.3866
0.1002
0.1003
0.1002
0.1004
-0.0001
0.0000
-0.0001
0.00009
0.0000000 0.0000000 0.0000000 0.000000
0.0010
0.1003
0.0010
0.0010
adotando k = 2
U=
0.00
mg/L

CCa
soluo
volume
alquota
1.0E+00
1.0E-01
1.0E-02
CCa
volume 2
alquota2
1.0000
0.1000
0.0100
0.0010
0.0001
0.0000
0.0000
0.0000
CCa
volume 2
alquota2
0.10000
0.00100
0.00001
0.00000
0.00000

Soluo Padro de Magnsio - 1000ppm
CMg = ( alquota x soluo ) / V
valor
10
incerteza 0.011547
alquota
10
10.011547
volume
100.0
100.0
soluo
100.3
100.3
CMg
10.030
10.0416
u(CMg,x)
0.0116
[u(CMg,x)]2
0.0001341
u(CMg)
0.014383
coef. Sensib.
1.0030
100.0
0.08008
10
100.08008
100.3
10.0220
-0.0080
0.0000644
100.3
0.028868
10
100.0
100.3289
10.03289
0.002887
0.000008
0.1002
0.1000
u(CMg) 0.0143831
adotando k = 2
U = 2 * u(CNa)
U=
0.0
mg/L

CMg =[ ( aliquota1 x soluo ) / V1 ] * (alquota2 / V2 )
valor
10
incerteza 0.011547
alquota1
10
10.011547
volume 1
100.0
100.0
alquota2
25.0
25.0
volume 2
250.0
250.0
Soluo
100.3
100.3
CMg
1.003
1.004
u(CMg,x)
0.0012
[u(CMg,x)]2
0.0000013
u(CMg)
0.001641
coef. Sensib.
0.1003
100.0
25.0
250.0
100.3
0.08008
0.008083 0.17977 0.0288675
10
10
10
10
100.08008
100.0
100.0
100.0
25.0
25.008083
25.0
25.0
250.0
250.0
250.17977
250.0
100.3
100.3
100.3
100.32887
1.002
1.003
1.002
1.003
-0.0008
0.0003
-0.0007
0.000289
0.0000006 0.0000001 0.0000005 0.000000
0.0100
u(CMg) 0.001641
U = 2 * u(CNa)
0.0401
0.0040
0.0100
adotando k = 2
U=
0.00
mg/L

CMg =[ ( aliquota1 x soluo ) / V1 ] * (alquota2 / V2 )
valor
10
incerteza 0.011547
alquota1
10
10.011547
volume 1
100.0
100.0
alquota2
1.0
1.0
volume 2
100.0
100.0
Soluo
100.3
100.3
CMg
0.1003
0.1004
u(CMg,x)
0.00012
[u(CMg,x)]2
0.0000000
u(CMg)
0.000166
coef. Sensib.
0.0100
u(CMg) 0.000166
U = 2 * u(CNa)
100.0
1.0
100.0
100.3
0.08008
0.000346 0.08008 0.0288675
10
10
10
10
100.08008
100.0
100.0
100.0
1.0
1.000346
1.0
1.0
100.0
100.0
100.08008
100.0
100.3
100.3
100.3
100.32887
0.1002
0.1003
0.1002
0.1003
-0.0001
0.0000
-0.0001
0.00003
0.0000000 0.0000000 0.0000000 0.000000
0.0010
0.1003
0.0010
0.0010
adotando k = 2
U=
0.00
mg/L

CMg
CMg
soluo
soluo
volume
volume
alquota
alquota
1.0E+00
1.0E-01
1.0E-02 1.0E-01 1.0E-03
1.0E-04
1.0E-05
1.0E-02
CMg
CMg
volume 2
alquota2
1.0000
0.1000
0.0100
0.0010
0.0001
0.0000
0.0000
0.0000
CMg
volume 2
alquota2
0.10000
0.00100
0.00001
0.00000
0.00000

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Planilha de Avaliao da Incerteza

1) Preparao da Soluo Padro

C.2) Certifica do Calibrao das Pipetas Volumtricas e Graduada - Incerteza Tipo B

Enchimento dos Bales - Incerteza Tipo A

C.3) Balana utilizada na Pesagem dos Bales - Incerteza Tipo B

Incerteza combinada no Enchimento

u = Raiz ( Somatria ( 0.01/ mdia de cada balo)^2 )

C.4) Temperatura - Incerteza Tipo B

u = (vol. Balo x Dt x coef.expanso) / RAIZ(3)

D) Clculo da Incerteza para o Volume

E) Clculo da Incerteza da Massa Corrigida pela Pureza

uc = Raiz ( ( a / m terica )^2 + ( u pureza / Pureza )^2 )

Planilha de Avaliao da Incerteza

Planilha de Avaliao da Incerteza

5) Incerteza associada a Repetitividade

6) Incerteza associada a Reprodutibilidade

7) Incerteza Padro Combinada para os Mtodos

Incerteza das Solues Padres

Soluo Padro de Fluoreto - 100ppm

Soluo Padro de Fluoreto - 10ppm

Incerteza das Solues Padres

Soluo Padro de Fluoreto - 100ppm

Soluo Padro de Fluoreto - 10ppm

Incerteza das Solues Padres

Soluo Padro de Cloreto - 100ppm

Soluo Padro de Cloreto - 10ppm

Incerteza das Solues Padres

Soluo Padro de Cloreto - 100ppm

Soluo Padro de Cloreto - 10ppm

Incerteza das Solues Padres

-4945.000 -4946.1593 -4941.0433

Soluo Padro de Potssio - 100ppm

Soluo Padro de Potssio - 10ppm

Incerteza das Solues Padres

Soluo Padro de Potssio - 100ppm

Soluo Padro de Potssio - 10ppm

Incerteza das Solues Padres

Soluo Padro de Clcio - 100ppm

Soluo Padro de Clcio - 10ppm

Incerteza das Solues Padres

Soluo Padro de Clcio - 100ppm

Soluo Padro de Clcio - 10ppm

Incerteza das Solues Padres

Soluo Padro de Magnsio - 100ppm

Soluo Padro de Magnsio - 10ppm

Incerteza das Solues Padres

1.0E-02 1.0E-01 1.0E-03

Soluo Padro de Magnsio - 100ppm

Soluo Padro de Magnsio - 10ppm

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