Tabela de Propriedades Residuais

HR/RT

Equao

van der
Waals
(1873)
RedlichKwong
(1949)

Z 1
P

RT
a
2,
V b V

P
a

SoaveRedlichKwong
(1972)

2,5
c

0,42748R T
Pc

27 R 2Tc2
RT
, b c
64 Pc
8Pc

,b

RT
aT

V b V V b

0,42748R 2Tc2
0,08664 RTc
,b
Pc
Pc

RT
a

V b V V b bV b

0,45724 RTc
0,07780 RTc
,b
Pc
Pc

1 1 Tr

1 / V ; Tr T / Tc

Z 1

3a
Z B
ln

1, 5
2bRT
Z
bP
B
RT

ln Z B

RTc
da
0,42748
dT
Pc
TcT
2

da
T
a
Z 1 2 B
dT

Z 1
ln
RT 2 2b Z 1 2 B
bP
B
RT
2

da
RTc

0,45724

dT
Pc
TcT

P dB
R dT

V b
ln Z ln

a
RT V

da
a
Z B
Z 1 dT
ln
, sendo
RT b
Z

; 0,37464 1,54226 0,26992

0,48508 1,55171 0,17613 2

Z 1

0,08664 RTc
Pc

B dB
1 C dC 2
ln Z T

2 T dT
T dT

P B dB

R T dT

BP
RT

RT
a
1/ 2
V b T V V b

1 1 Tr

PengRobinson
(1976)

B dB
C 1 dC 2
T


T 2 dT
T dT

Z 1 B C 2

Virial
Truncada

SR/R

ln Z B

a
Z B
ln

1, 5
2bRT
Z

1 da Z B
ln
, sendo
R b dT Z
bP
B
RT

da

Z 1 2 B
dT

ln Z B
ln
R 2 2b Z 1 2 B