8.1. A Txy phase diagram displays the bubble point and dew point over the entire range of liquid and vapor mole fractions. By assuming ideal solution and ideal gas behavior of the mixture, we can use the following relationships P= xP +(1-x,)Ps" ‘We can calculate the saruration pressures using Antoine’s Equation. ‘Ihe temperature that satisfies the first equation is the bubble point. The temperature that satisfies the second equation is the dew point. The following spreadsheet was created with these two expressions (the temperatures were found using a “Solver” function): x Tre) | ys Tap (K) Se o1 325 | 01 3429 02 as | 02 3442 03 34a6 | 033455 o4 = as7 | 04 3468 os 469 | 05 480 06 = as | 06 © 349.2 o7 394 | 07 3503 os 3507 | 08 3514 o9 3520 | 09 = 3524 1 334 | 353.4 ‘The data were plotted to obtain the following graph: ‘Try Diagram for Cyclohexane and n-Hexane 3540 as20 | 350.0 348.0 348.0 3440 342.0 3400 0.00 0.20 0.40 0.60 080 1.00 Temperature (K)82 The vapor mole fractions of n-pentane (1) and n-hexane (2) are y= 033 y= 0.67 We can solve this problem by finding the temperature at which the following relationship is true 2 ae je ‘The saturation pressures can be found using Antoine's Equation, From Appendix A, Species a B c nepentane (I) | 9.2131 2477.07 39.94 n-hexane (2) | 9.2164 2697.55 48.78 ‘Therefore, we must solve the following equation for T: (0.33) bar) (0.67) bar) i exo{92131- ze ) exp| 9.2164 - 2697.55 T-39.94, T 48.78, ‘We obtain 7 =334K