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Appendix E Tables for Prediction of Transport Properties SE. Intermolecular force parameters and critical properties §E.2_ Functions for prediction of transport properties of gases at low densities 863 = rd ssc see ws] 9 We fos ares atu = 8 ‘00z ow gee] 4 ee (teOF ovr “HD = ee ISL esr ose] 9 Sz UF 80% = SHO=HO'HD = = = — swe) Pt ere 90 0F e02 o1z “aH wer roo} 9 9 zez SREY woe = siz vel ous we] 9 9Ie (Bae sos = “ee eat ig) cere a) cies i +097 ‘8S ‘si £86 ss rit] @ HSL ORE wot ssuogreo1p AH, = = = — os) » sg caer ai - = vel wor fa] wes 89t 0% “ck ¥2L vs wie) & use SUI = = = Se cr ere 9°86 our wi 22) cosy | eo, oor, “et zee £96 cu coe] ™ weve ON zeit 86 us 7 ost] 7 6h ON wl ere 16 sz che] » 61 966 ‘oo soe ‘061 re6 sve ez] % Ol ose oO sor “ose ve ey yeu ei cre i} s99 ‘ost 106 see ci] 49 86 Love N 806 61 998 we er] 9» 0%6 ase av ssose8 opuuoyedjod aydunng zor ‘06h sil oss sosc] 4 Leet OOF oeter 2x vor ‘96€ 7% ers veo] 4 ou save oes » ou 9¢ zee ose cou] 4 ret cere shoe wv wee 9s1 ce 6% st | o cse eae e802 oN ssase8 a1q0n, = WS sus vz 9s | OL oust 00% oH = cee 089 oszt eee | # oge si6z 07 H ssyuawiay 14817 (OL A-8-w9/Te) (OL x §-W/3) | (ejow-8/.u>) (Une) OH) oD w Ww aoueysqng, of "” dL | pao? 2 aM se 1N29}0, (pSenuadoud [eRUD ‘sippourered sau0f-pacuLy soppadoag [RUD Pur SIBpPUTEIEG TERUAIOA (ZI-9) SUOFPOUUT] TA IAEL 864 “US6L) 191-P90 pmuinol 3HDTY ’SOpOL, “5 pu suaMG “[-g wy axe KAnoMpUOD euLaXN £8 °4 “UHL MOA MAN “KOHIM TOA HMioUL SsIDO4Y [O}MOY) “WOSIEAL > PUL UBBMOH “YC UHOUS axe KpsO>sIA. -Ayso3sta wody paureygo s1ayeurese% “Aysoosta wiouy poureqo sioyoures unded ap e6e 626) TOA “SRL HED oyymaya uy; uan se ay Aap jo wopsodwion afezane ax wtoy paynduoo Uaog aney soxuadosd weopyDopnasd ayy pue jy WSlom 1H99fOU aM HT 304 UD 24 JO SINIE Ag 24 J0 Sone “9611961 9661) wopLOT ‘SOMUBHING‘e-1 SOA "4OHPS) 1g 49509 fo suoruny suena puE (e961) SDL, “woREIS ABO ‘ASAT WRY SEXO, IUD YAS SOTUTCUAPOLLIILL "FF lod HPUEAP, uy wanajoaog OU {(9B) 9EC-LUL ZS "A Wo) “af "UAT "A "Y PUR OROY “V “Y LOIS PorD9}9 axe saDUEASANS aand ayp 405 sAUEySLOD [EHUD 94 JO SONA, -sopuodosd yodsuen pareqnozes pue sapped eay ‘suaourered sauof-preuur] jo sage} aarsuayxa sopyaod yodas sjyy “Aysonsta wroxy paureygo ssayauresed (7961) ZET-Y HOdIY YAL VSVN ‘EMPAS "VU » nol SHOIV"SOPOUL,"D PUE WAALS Mp (C961) 696-296 2691-9091 'S6 "shyg ‘way | 'WOSePY "Y “ PUE>PEDUO "T , ‘uorte|9220- way payndiuoo aze saowesqns s94710 40} NTE AHL ‘soutersqns yet wo eep AypsoDstA utods axe auaztiog 405 SanqeA HLL (9961) E9E-9SES ‘S]HUIUUNPUN -uOH_ Fug ‘PU “HEMAY "A “NY PUE “HOOD "S22," T g “G961) HOA MON ’K2qENA “PAPpE saOU YEN BuAULA p}>2110> ‘spynbry pu S2s05 Jo Auda, sNMD2,OW “PAE “AA PUP 'SSIUND "4 “D “YOPIMPSHT OL « = — ‘ale Co alee a z60zt SEDO = tor “et 8 Pr9d, ic = = = 19 se] 2 eee OTe 2009 $09 _ _ _ “6S ‘oor | 2 ‘Ore We zs "ND = lh 4 oop pegs] 9 eee HBS zest "20 - ‘Ole oF. ys 99g] 9 ore oes set "OHO ome ae ae 09 ‘ois | 2 “86E Beeb 698 HD = see mL os9 cow) 2 sce IST or 0s. D'HD 8st “6s £86 sop rit] 9 ysl ome OSL "HO sspunoduzos spuefz0 3410 = ze ‘09% ger ozs) 9 use eS 18 auazueg a ‘W8Z "BOE oF fess) cle! ero ores auexayop A, = ‘997 ‘8S om ores) 9 Ise eorL ore Hu = 687 zor sw Leg) 4 ‘We = sme evo SE = 4 zh ow vos) 9 ese 999 ozo0t HH = ‘807 we ze eos) 9 we f8eO 8098 "yD = = “eve ore ser) 9 we sce Ut *CHOID = = ‘90€ ce ror) a me ues ste BHO — 4 ue wee ser] 9 ze Ones srt : = 68Z 92, ove sur) 9 sez ees zrss 865 Table E.2_ Collision Integrals for Use with the Lennard-Jones (6-12) Potential for the Prediction of Transport Properties of Gases at Low Densities" = 9, a, = 9% KT/e (for viscosity KT/e (for viscosity e or and thermal or and thermal (for KT/eqy conductivity) diffusivity) | KT/e4s conductivity) diffusivity) 030 2.840 2.619 27 1.0691 0.9782 038 2.676 2.468 28 1.0583 0.9682 040 2531 2314 29 1.0482 0.9588 045 2401 2182 30 1.0388 0.9500 050 2.284 2.066 31 1.0300 ooais 055 2178 1.965 32 10217 0.9340 060 2.084 187 33 10138 0.9267 0.65 4.999 1798 34 1.0066 0.9197 070 1922 178 33 0.9996 osi3t 075 1853 11667 36 0.9931 0.9068 080 1790 1612 37 0.9868 0.9008 085 1734 1562 38 0.9808 0.8952 0.90 1682 1317 39 0.9753 0.8897 0.95 1.636 1477 40 0.9698 0.8885 1.00 1.593 1.440 41 0.9687 0.8756 1.08 1554 1406 42 0.9598 0.8748 110 1518 1375 43 0.9551 0.8703 115 1485 1347 44 0.9506 0.8659 120 1455 1320 45 0.9462 08617 1235 1427 1296 46 0.9820 08576 130 1401 1274 a7 0.9380 08537 135 137 1.253 438 0.9341 0.8199 140 1355 1234 49 0.9304 0.8163, 145 1334 1216 50 0.9268 0.8428 1315 1198 60 0.8962 08129 1297 1183 70 08727 0.7898 1280 1168 80 0.8538 ov 1.264 1s 90 08380 0.7555 1249 1a 100 08244 07422 1235 1128 120 0.8018 0702 122 7 40 0.7836 0.7025 1.208 1.105 160 0.7683, 0.6878 1198 1.095 180 0.7552 0.6751 1186 1.088 200 0.7436 0.6640 1176 1075 25.0 07198 6nd 1.156 1.058 30.0 07010 06235, 1.138 101 35.0 0.6854 0.6088 230 1 1027 400 06723 05864 240 1107 1013 50.0 0.6510 05763 250 1.0933 1.0006 750 06140 0585 260 1.0807 0.9890 100.0 0.5887 05180 © The values inthis table, applicable forthe Lennard-Jones (6-12) potential are interpolated from the results of L Monchick and E. A. Mason, J. Chem. Ps, 35, 1676-1697 (196), The Monchick-Mason table is believed tobe slightly ‘etter than the eavler table by J.O. Hirschfelder, RB. Bird and EL. Spot, J Chem. Ps, 16, 968-981 (1948) This table has been extended to lower temperatures by C.F. Curtis, J Chem. Phys, 97, 7679-7686 (192), Curtiss showed that a low temperatures, the Boltzmann equation needs to be modified to take into account “orbiting pales” fof molecules Only by making this modification ist possible to get a smooth transition from quantum to classical behavior. The deviations ate appreciable below dimensionless temperatures of 030. ‘Tre cllsion integrals have been curve-fted by P. D. Neufeld, A.R. Jansen, and R.A. Aziz, J. Chon. Plys, 87 1109-1102 1972), a5 follows: osaus7 26178 BpOTEROT * expesare7T) , 01830 1osss7 1.7074 See * epOATAST * expLSRET) * expOSHHLIT) 24) a0 22) where T= KT 866

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