Fe(+3a) + H2O(l) = FeO(+a) + 2H(+a)

1/T T deltaH deltaS deltaG K Log(K)

K K kcal cal/K kcal
0.00359518 278.150 20.219 42.145 8.496 2.107E-007 -6.676
0.0035317 283.150 19.932 41.123 8.288 4.002E-007 -6.398
0.00347041 288.150 19.662 40.179 8.085 7.370E-007 -6.133
0.00341122 293.150 19.408 39.302 7.886 1.319E-006 -5.880
0.00335402 298.150 19.165 38.482 7.692 2.298E-006 -5.639
0.0032987 303.150 18.933 37.710 7.501 3.905E-006 -5.408
0.00324517 308.150 18.710 36.980 7.315 6.484E-006 -5.188
0.00319336 313.150 18.495 36.288 7.131 1.053E-005 -4.977
0.00314317 318.150 18.287 35.630 6.952 1.676E-005 -4.776
0.00309454 323.150 18.086 35.003 6.775 2.616E-005 -4.582
0.00304739 328.150 17.892 34.406 6.602 4.008E-005 -4.397
0.00300165 333.150 17.704 33.839 6.431 6.038E-005 -4.219
0.00295727 338.150 17.523 33.297 6.263 8.948E-005 -4.048
0.00291418 343.150 17.346 32.780 6.098 1.306E-004 -3.884
0.00287233 348.150 17.176 32.287 5.935 1.879E-004 -3.726
0.00283166 353.150 17.011 31.818 5.775 2.666E-004 -3.574
0.00279213 358.150 16.853 31.371 5.617 3.733E-004 -3.428
0.00275368 363.150 16.699 30.946 5.461 5.165E-004 -3.287
0.00271628 368.150 16.552 30.544 5.308 7.062E-004 -3.151

Formula FM Conc. Amount Amount Volume

g/mol wt-% mol g l or ml
Fe(+3a) 55.847 75.610 1.000 55.847 0.000 ml
H2O(l) 18.015 24.390 1.000 18.015 18.069 ml
g/mol wt-% mol g l or ml
FeO(+a) 71.846 97.271 1.000 71.846 0.000 ml
H(+a) 1.008 2.729 2.000 2.016 0.000 ml

-3999.4129 7.76260285
26.2485986 0.08211669
0.99926827 0.03048619
23215.6175 17
21.5767697 0.01579993

A
Fe(+3a) + H2O(l) = FeO(+a) + 2H(+a) Para k1 Logk1 = A' + B'*(1/T) 7.76260285
FeO(+a) + H2O(l) = Fe(OH)O(a) + H(+a) Para k2 Logk1 = A' + B'*(1/T) 2.99617537
Fe(OH)O(a) = FeO2(-a) + H(+a) Para k3 Logk1 = A' + B'*(1/T) -2.3167538
 FeO(+a) + H2O(l) = Fe(OH)O(a) + H(+a)
1/T T deltaH deltaS deltaG K Log(K)
K K kcal cal/K kcal
0.00359518 278.150 9.995 19.989 4.435 3.272E-004 -3.485
0.0035317 283.150 9.729 19.039 4.338 4.484E-004 -3.348
0.00347041 288.150 9.479 18.163 4.245 6.029E-004 -3.220
0.00341122 293.150 9.241 17.348 4.156 7.968E-004 -3.099
0.00335402 298.150 9.015 16.582 4.071 1.036E-003 -2.985
0.0032987 303.150 8.797 15.857 3.990 1.328E-003 -2.877
0.00324517 308.150 8.586 15.167 3.913 1.678E-003 -2.775
0.00319336 313.150 8.381 14.507 3.838 2.094E-003 -2.679
0.00314317 318.150 8.181 13.874 3.767 2.581E-003 -2.588
0.00309454 323.150 7.986 13.265 3.700 3.145E-003 -2.502
0.00304739 328.150 7.795 12.679 3.635 3.793E-003 -2.421
0.00300165 333.150 7.609 12.115 3.573 4.529E-003 -2.344
0.00295727 338.150 7.426 11.571 3.514 5.357E-003 -2.271
0.00291418 343.150 7.247 11.044 3.457 6.281E-003 -2.202
0.00287233 348.150 7.071 10.534 3.403 7.303E-003 -2.136
0.00283166 353.150 6.897 10.040 3.352 8.425E-003 -2.074
0.00279213 358.150 6.727 9.562 3.303 9.648E-003 -2.016
0.00275368 363.150 6.560 9.099 3.256 1.097E-002 -1.960
0.00271628 368.150 6.396 8.650 3.212 1.239E-002 -1.907

Formula FM Conc. Amount Amount Volume

g/mol wt-% mol g l or ml
FeO(+a) 71.846 79.952 1.000 71.846 0.000 ml
H2O(l) 18.015 20.048 1.000 18.015 18.069 ml
g/mol wt-% mol g l or ml
Fe(OH)O(a) 88.854 98.878 1.000 88.854 0.000 ml
H(+a) 1.008 1.122 1.000 1.008 0.000 ml

-1786.715 2.99617537
25.5417964 0.07990552
0.99653794 0.02966528
4893.36575 17
4.30630215 0.01496049

pH aprox
T T T T T T
B 278 298 368 278 298 368
-3999.4129 -6.6237744 -5.6582457 -3.1053669 3.31188721 2.82912287 1.55268347
-1786.715 -3.4308569 -2.9995125 -1.8590284 3.43085691 2.99951246 1.85902836
-2161.9407 -10.093519 -9.5715884 -8.1915927 10.0935189 9.57158839 8.19159268
 Fe(OH)O(a) = FeO2(-a) + H(+a)
1/T T deltaH deltaS deltaG K Log(K)
K K kcal cal/K kcal
0.00359518 278.150 9.168 -13.104 12.813 8.551E-011 -10.068
0.0035317 283.150 9.290 -12.667 12.877 1.148E-010 -9.940
0.00347041 288.150 9.402 -12.275 12.939 1.532E-010 -9.815
0.00341122 293.150 9.505 -11.921 13.000 2.030E-010 -9.692
0.00335402 298.150 9.600 -11.600 13.059 2.673E-010 -9.573
0.0032987 303.150 9.688 -11.307 13.116 3.497E-010 -9.456
0.00324517 308.150 9.770 -11.039 13.172 4.544E-010 -9.343
0.00319336 313.150 9.847 -10.792 13.226 5.869E-010 -9.231
0.00314317 318.150 9.918 -10.566 13.280 7.533E-010 -9.123
0.00309454 323.150 9.985 -10.357 13.332 9.610E-010 -9.017
0.00304739 328.150 10.047 -10.167 13.383 1.219E-009 -8.914
0.00300165 333.150 10.104 -9.994 13.434 1.537E-009 -8.813
0.00295727 338.150 10.157 -9.836 13.483 1.927E-009 -8.715
0.00291418 343.150 10.206 -9.693 13.532 2.404E-009 -8.619
0.00287233 348.150 10.250 -9.564 13.580 2.981E-009 -8.526
0.00283166 353.150 10.290 -9.450 13.628 3.679E-009 -8.434
0.00279213 358.150 10.326 -9.349 13.675 4.516E-009 -8.345
0.00275368 363.150 10.358 -9.262 13.721 5.517E-009 -8.258
0.00271628 368.150 10.384 -9.189 13.767 6.706E-009 -8.174

Formula FM Conc. Amount Amount Volume

g/mol wt-% mol g l or ml
Fe(OH)O(a) 88.854 100.000 1.000 88.854 0.000 ml
g/mol wt-% mol g l or ml
FeO2(-a) 87.846 98.866 1.000 87.846 0.000 ml
H(+a) 1.008 1.134 1.000 1.008 0.000 ml

-2161.9407 -2.3167538
8.82236693 0.02760009
0.99971699 0.01024665
60050.596 17
6.30494787 0.0017849
 Fe(+2a) + H2O(l) = FeOH(+a) + H(+a)
1/T T deltaH deltaS deltaG K Log(K)
1/K K kcal cal/K kcal
0.00359518 278.150 12.112 -2.023 12.675 1.097E-010 -9.960
0.0035317 283.150 12.174 -1.801 12.684 1.618E-010 -9.791
0.00347041 288.150 12.222 -1.635 12.693 2.357E-010 -9.628
0.00341122 293.150 12.258 -1.511 12.701 3.393E-010 -9.469
0.00335402 298.150 12.285 -1.418 12.708 4.831E-010 -9.316
0.0032987 303.150 12.306 -1.349 12.715 6.804E-010 -9.167
0.00324517 308.150 12.322 -1.295 12.721 9.480E-010 -9.023
0.00319336 313.150 12.336 -1.252 12.728 1.307E-009 -8.884
0.00314317 318.150 12.347 -1.217 12.734 1.786E-009 -8.748
0.00309454 323.150 12.356 -1.189 12.740 2.416E-009 -8.617
0.00304739 328.150 12.364 -1.165 12.746 3.240E-009 -8.490
0.00300165 333.150 12.369 -1.147 12.752 4.306E-009 -8.366
0.00295727 338.150 12.375 -1.132 12.757 5.677E-009 -8.246
0.00291418 343.150 12.379 -1.118 12.763 7.425E-009 -8.129
0.00287233 348.150 12.384 -1.103 12.769 9.637E-009 -8.016
0.00283166 353.150 12.389 -1.089 12.774 1.242E-008 -7.906
0.00279213 358.150 12.395 -1.073 12.779 1.589E-008 -7.799
0.00275368 363.150 12.401 -1.056 12.785 2.020E-008 -7.695
0.00271628 368.150 12.408 -1.037 12.790 2.551E-008 -7.593

Formula FM Conc. Amount Amount Volume

g/mol wt-% mol g l or ml
Fe(+2a) 55.847 75.610 1.000 55.847 0.000 ml
H2O(l) 18.015 24.390 1.000 18.015 18.069 ml
g/mol wt-% mol g l or ml
FeOH(+a) 72.854 98.635 1.000 72.854 0.000 ml
H(+a) 1.008 1.365 1.000 1.008 0.000 ml

-2694.9961 -0.27546514
1.68050824 0.005257339
0.99999339 0.00195181
2571786.98 17
9.79738621 6.47626E-05

A
Fe(+2a) + H2O(l) = FeOH(+a) + H(+a) Para k4 Logk1 = A' + B'*(1/T) -0.2754651
FeOH(+a) + H2O(l) = HFeO2(-a) + 2H(+a)Para k5 Logk1 = A' + B'*(1/T) -4.9597768
 FeOH(+a) + H2O(l) = HFeO2(-a) + 2H(+a)
1/T T deltaH deltaS deltaG K Log(K)
1/K K kcal cal/K kcal
0.00359518 278.150 20.887 -21.054 26.743 9.675E-022 -21.014
0.0035317 283.150 20.844 -21.205 26.849 1.884E-021 -20.725
0.00347041 288.150 20.798 -21.367 26.955 3.582E-021 -20.446
0.00341122 293.150 20.748 -21.538 27.062 6.650E-021 -20.177
0.00335402 298.150 20.695 -21.718 27.170 1.208E-020 -19.918
0.0032987 303.150 20.639 -21.906 27.279 2.147E-020 -19.668
0.00324517 308.150 20.579 -22.101 27.389 3.740E-020 -19.427
0.00319336 313.150 20.517 -22.302 27.500 6.392E-020 -19.194
0.00314317 318.150 20.451 -22.508 27.612 1.072E-019 -18.970
0.00309454 323.150 20.383 -22.721 27.726 1.768E-019 -18.753
0.00304739 328.150 20.312 -22.939 27.840 2.865E-019 -18.543
0.00300165 333.150 20.238 -23.162 27.955 4.568E-019 -18.340
0.00295727 338.150 20.162 -23.390 28.071 7.173E-019 -18.144
0.00291418 343.150 20.083 -23.622 28.189 1.110E-018 -17.955
0.00287233 348.150 20.001 -23.860 28.308 1.693E-018 -17.771
0.00283166 353.150 19.916 -24.103 28.427 2.547E-018 -17.594
0.00279213 358.150 19.827 -24.351 28.549 3.782E-018 -17.422
0.00275368 363.150 19.736 -24.605 28.671 5.545E-018 -17.256
0.00271628 368.150 19.641 -24.864 28.795 8.032E-018 -17.095

Formula FM Conc. Amount Amount Volume

g/mol wt-% mol g l or ml
FeOH(+a) 72.854 80.175 1.000 72.854 0.000 ml
H2O(l) 18.015 19.825 1.000 18.015 18.069 ml
g/mol wt-% mol g l or ml
HFeO2(-a) 88.854 97.782 1.000 88.854 0.000 ml
H(+a) 1.008 2.218 2.000 2.016 0.000 ml

-4460.6513 -4.9597768
8.78357363 0.02747872
0.99993409 0.0102016
257901.607 17
26.8404928 0.00176923
pH aprox
T T T T T T
B 278 298 368 278 298 368
-2694.9961 -9.9696957 -9.3190762 -7.5988241 9.96969573 9.31907623 7.59882412
-4460.6513 -21.005285 -19.928405 -17.081112 10.5026424 9.96420256 8.54055584
 Fe(+3a) + e- = Fe(+2a)
1/T T deltaH deltaS deltaG K E vs. SHE logK
1/K K kcal cal/K kcal V
0.00359518 278.150 -10.377 24.767 -17.266 3.694E+013 0.749 13.567
0.0035317 283.150 -10.324 24.957 -17.390 2.654E+013 0.755 13.424
0.00347041 288.150 -10.278 25.118 -17.516 1.932E+013 0.760 13.286
0.00341122 293.150 -10.237 25.258 -17.641 1.423E+013 0.766 13.153
0.00335402 298.150 -10.200 25.384 -17.768 1.060E+013 0.771 13.025
0.0032987 303.150 -10.165 25.499 -17.895 7.986E+012 0.777 12.902
0.00324517 308.150 -10.132 25.609 -18.023 6.076E+012 0.782 12.784
0.00319336 313.150 -10.098 25.716 -18.151 4.667E+012 0.788 12.669
0.00314317 318.150 -10.065 25.822 -18.280 3.618E+012 0.793 12.558
0.00309454 323.150 -10.031 25.928 -18.410 2.829E+012 0.799 12.452
0.00304739 328.150 -9.996 26.034 -18.540 2.231E+012 0.804 12.348
0.00300165 333.150 -9.961 26.140 -18.670 1.773E+012 0.810 12.249
0.00295727 338.150 -9.925 26.248 -18.801 1.420E+012 0.816 12.152
0.00291418 343.150 -9.887 26.359 -18.932 1.145E+012 0.822 12.059
0.00287233 348.150 -9.848 26.473 -19.064 9.304E+011 0.827 11.969
0.00283166 353.150 -9.807 26.590 -19.197 7.609E+011 0.833 11.881
0.00279213 358.150 -9.763 26.712 -19.330 6.263E+011 0.839 11.797
0.00275368 363.150 -9.718 26.839 -19.464 5.187E+011 0.845 11.715
0.00271628 368.150 -9.670 26.970 -19.599 4.322E+011 0.850 11.636

Formula FM Conc. Amount Amount Volume

g/mol wt-% mol g l or ml
Fe(+3a) 55.847 99.999 1.000 55.847 0.000 ml
e- 0.001 0.001 1.000 0.001 0.000 ml
g/mol wt-% mol g l or ml
Fe(+2a) 55.847 100.000 1.000 55.847 0.000 ml

2197.40356 5.657233537
4.640919549 0.014518755
0.999924176 0.005390152
224187.5895 17
6.513487621 0.000493914

Fe(+3a) + e- = Fe(+2a) Para k6 Logk1 = A' + B'*(1/T)

FeO(+a) + 2H(+a) + e- = Fe(+2a) + H2O(l) Para k7 Logk1 = A' + B'*(1/T)
Fe(OH)O(a) + 3H(+a) + e- = Fe(+2a) + 2H2O(l) Para k8 Logk1 = A' + B'*(1/T)
Fe(OH)O(a) + 2H(+a) + e- = FeOH(+a) + H2O(l) Para k9 Logk1 = A' + B'*(1/T)
FeO2(-a) + 3H(+a) + e- = FeOH(+a) + H2O(l) Para k10 Logk1 = A' + B'*(1/T)
FeO2(-a) + H(+a) + e- = HFeO2(-a) Para k11 Logk1 = A' + B'*(1/T)
 FeO(+a) + 2H(+a) + e- = Fe(+2a) + H2O(l)
1/T T deltaH deltaS deltaG K E vs. SHE
1/K K kcal cal/K kcal V
0.00359518 278.150 -30.596 -17.379 -25.762 1.753E+020 1.118
0.0035317 283.150 -30.256 -16.166 -25.678 6.631E+019 1.114
0.00347041 288.150 -29.940 -15.061 -25.600 2.621E+019 1.111
0.00341122 293.150 -29.645 -14.044 -25.528 1.079E+019 1.108
0.00335402 298.150 -29.365 -13.098 -25.460 4.614E+018 1.105
0.0032987 303.150 -29.098 -12.211 -25.397 2.045E+018 1.102
0.00324517 308.150 -28.842 -11.371 -25.338 9.370E+017 1.099
0.00319336 313.150 -28.593 -10.572 -25.283 4.431E+017 1.097
0.00314317 318.150 -28.352 -9.808 -25.232 2.159E+017 1.095
0.00309454 323.150 -28.117 -9.075 -25.185 1.082E+017 1.093
0.00304739 328.150 -27.888 -8.372 -25.141 5.565E+016 1.091
0.00300165 333.150 -27.666 -7.699 -25.101 2.936E+016 1.089
0.00295727 338.150 -27.448 -7.049 -25.064 1.587E+016 1.088
0.00291418 343.150 -27.234 -6.422 -25.030 8.770E+015 1.086
0.00287233 348.150 -27.024 -5.815 -25.000 4.952E+015 1.085
0.00283166 353.150 -26.818 -5.227 -24.972 2.854E+015 1.084
0.00279213 358.150 -26.616 -4.659 -24.947 1.678E+015 1.083
0.00275368 363.150 -26.417 -4.108 -24.926 1.004E+015 1.082
0.00271628 368.150 -26.222 -3.574 -24.906 6.120E+014 1.081

Formula FM Conc. Amount Amount Volume

g/mol wt-% mol g l or ml
FeO(+a) 71.846 97.270 1.000 71.846 0.000
H(+a) 1.008 2.729 2.000 2.016 0.000
e- 0.001 0.001 1.000 0.001 0.000
g/mol wt-% mol g l or ml
Fe(+2a) 55.847 75.610 1.000 55.847 0.000
H2O(l) 18.015 24.390 1.000 18.015 18.069

6196.81644
30.88027157
0.999578021
40269.38914
51.80017278
log K
T T T
A B 278 298 368
5.65723354 2197.40356 13.5615629 13.031071 11.6284389
-2.1053693 6196.81644 20.1853373 18.6893167 14.7338058
-5.1015447 7983.53141 23.6161942 21.6888292 16.5928342
-5.3770098 5288.53531 13.6464985 12.369753 8.99401004
 -3.060256 7450.47601 23.7400174 21.9413414 17.1856027
-8.0200328 2989.82475 2.73473255 2.01293622 0.10449104
 Fe(OH)O(a) + 3H(+a) + e- = Fe(+2a) + 2H2O(l)
logK 1/T T deltaH deltaS deltaG K
1/K K kcal cal/K kcal
20.244 0.00359518 278.150 -40.591 -37.367 -30.198 5.357E+023
19.822 0.0035317 283.150 -39.984 -35.205 -30.016 1.479E+023
19.418 0.00347041 288.150 -39.419 -33.224 -29.845 4.347E+022
19.033 0.00341122 293.150 -38.886 -31.391 -29.684 1.354E+022
18.664 0.00335402 298.150 -38.380 -29.680 -29.531 4.453E+021
18.311 0.0032987 303.150 -37.895 -28.068 -29.387 1.540E+021
17.972 0.00324517 308.150 -37.428 -26.538 -29.250 5.584E+020
17.647 0.00319336 313.150 -36.975 -25.079 -29.121 2.116E+020
17.334 0.00314317 318.150 -36.534 -23.682 -28.999 8.364E+019
17.034 0.00309454 323.150 -36.103 -22.340 -28.884 3.439E+019
16.745 0.00304739 328.150 -35.684 -21.051 -28.776 1.467E+019
16.468 0.00300165 333.150 -35.275 -19.814 -28.674 6.483E+018
16.200 0.00295727 338.150 -34.874 -18.620 -28.578 2.962E+018
15.943 0.00291418 343.150 -34.481 -17.466 -28.487 1.396E+018
15.695 0.00287233 348.150 -34.095 -16.349 -28.403 6.781E+017
15.456 0.00283166 353.150 -33.716 -15.268 -28.324 3.388E+017
15.225 0.00279213 358.150 -33.343 -14.221 -28.250 1.739E+017
15.002 0.00275368 363.150 -32.977 -13.206 -28.182 9.154E+016
14.787 0.00271628 368.150 -32.618 -12.223 -28.118 4.937E+016

Formula FM Conc. Amount Amount

g/mol wt-% mol g
ml Fe(OH)O(a) 88.854 96.708 1.000 88.854
ml H(+a) 1.008 3.291 3.000 3.024
ml e- 0.001 0.001 1.000 0.001
g/mol wt-% mol g
ml Fe(+2a) 55.847 60.784 1.000 55.847
ml H2O(l) 18.015 39.216 2.000 36.030

-2.10536931
0.09660652
0.035865599
17
0.0218678
 Fe(OH)O(a) + 2H(+a) + e- = FeOH(+a) + H2O(l)
E vs. SHE logK 1/T T deltaH deltaS deltaG
V 1/K K kcal cal/K kcal
1.310 23.729 0.00359518 278.150 -28.479 -39.391 -17.523
1.303 23.170 0.0035317 283.150 -27.810 -37.006 -17.332
1.295 22.638 0.00347041 288.150 -27.197 -34.859 -17.152
1.288 22.132 0.00341122 293.150 -26.628 -32.902 -16.983
1.281 21.649 0.00335402 298.150 -26.095 -31.098 -16.823
1.275 21.188 0.0032987 303.150 -25.589 -29.416 -16.672
1.269 20.747 0.00324517 308.150 -25.106 -27.833 -16.529
1.264 20.326 0.00319336 313.150 -24.639 -26.332 -16.393
1.258 19.922 0.00314317 318.150 -24.187 -24.899 -16.265
1.253 19.536 0.00309454 323.150 -23.748 -23.529 -16.144
1.249 19.166 0.00304739 328.150 -23.320 -22.216 -16.030
1.244 18.812 0.00300165 333.150 -22.905 -20.961 -15.922
1.240 18.472 0.00295727 338.150 -22.499 -19.752 -15.820
1.236 18.145 0.00291418 343.150 -22.101 -18.583 -15.724
1.232 17.831 0.00287233 348.150 -21.710 -17.452 -15.634
1.229 17.530 0.00283166 353.150 -21.326 -16.356 -15.550
1.226 17.240 0.00279213 358.150 -20.948 -15.294 -15.471
1.223 16.962 0.00275368 363.150 -20.576 -14.262 -15.397
1.220 16.693 0.00271628 368.150 -20.210 -13.260 -15.328

Volume Formula FM Conc. Amount

l or ml g/mol wt-% mol
0.000 ml Fe(OH)O(a) 88.854 97.781 1.000
0.000 ml H(+a) 1.008 2.218 2.000
0.000 ml e- 0.001 0.001 1.000
l or ml g/mol wt-% mol
0.000 ml FeOH(+a) 72.854 80.175 1.000
36.139 ml H2O(l) 18.015 19.825 1.000

7983.53141 -5.1015447
56.4217867 0.17651116
0.99915163 0.06553055
20021.4906 17
85.9773434 0.0730023
 FeO2(-a) + 3H(+a) + e- = FeOH(+a) + H2O(l)
K E vs. SHE logK 1/T T deltaH deltaS
V 1/K K kcal cal/K
5.879E+013 0.760 13.769 0.00359518 278.150 -37.647 -26.287
2.392E+013 0.752 13.379 0.0035317 283.150 -37.101 -24.339
1.024E+013 0.744 13.010 0.00347041 288.150 -36.599 -22.584
4.595E+012 0.737 12.662 0.00341122 293.150 -36.133 -20.981
2.151E+012 0.730 12.333 0.00335402 298.150 -35.695 -19.498
1.048E+012 0.723 12.020 0.0032987 303.150 -35.277 -18.109
5.293E+011 0.717 11.724 0.00324517 308.150 -34.876 -16.794
2.767E+011 0.711 11.442 0.00319336 313.150 -34.486 -15.539
1.494E+011 0.706 11.174 0.00314317 318.150 -34.105 -14.334
8.308E+010 0.701 10.919 0.00309454 323.150 -33.732 -13.171
4.753E+010 0.696 10.677 0.00304739 328.150 -33.367 -12.049
2.792E+010 0.691 10.446 0.00300165 333.150 -33.009 -10.967
1.681E+010 0.686 10.226 0.00295727 338.150 -32.657 -9.916
1.037E+010 0.682 10.016 0.00291418 343.150 -32.307 -8.890
6.535E+009 0.678 9.815 0.00287233 348.150 -31.961 -7.888
4.207E+009 0.675 9.624 0.00283166 353.150 -31.617 -6.907
2.763E+009 0.671 9.441 0.00279213 358.150 -31.275 -5.945
1.849E+009 0.668 9.267 0.00275368 363.150 -30.934 -5.000
1.259E+009 0.665 9.100 0.00271628 368.150 -30.594 -4.071

Amount Volume Formula FM Conc.

g l or ml g/mol wt-%
88.854 0.000 ml FeO2(-a) 87.846 96.672
2.016 0.000 ml H(+a) 1.008 3.327
0.001 0.000 ml e- 0.001 0.001
g l or ml g/mol wt-%
72.854 0.000 ml FeOH(+a) 72.854 80.175
18.015 18.069 ml H2O(l) 18.015 19.825

5288.53531 -5.3770098
58.0498013 0.18160427
0.99795595 0.06742139
8299.83275 17
37.728085 0.07727595
OH(+a) + H2O(l) FeO2(-a) + H(+a) + e- = HFeO2(-a)
deltaG K E vs. SHE logK 1/T T deltaH
kcal V 1/K K kcal
-30.335 6.875E+023 1.316 23.837 0.00359518 278.150 -16.760
-30.209 2.083E+023 1.311 23.319 0.0035317 283.150 -16.256
-30.092 6.686E+022 1.306 22.825 0.00347041 288.150 -15.801
-29.983 2.263E+022 1.301 22.355 0.00341122 293.150 -15.385
-29.882 8.048E+021 1.297 21.906 0.00335402 298.150 -15.000
-29.788 2.996E+021 1.293 21.477 0.0032987 303.150 -14.639
-29.700 1.165E+021 1.289 21.066 0.00324517 308.150 -14.297
-29.620 4.715E+020 1.285 20.673 0.00319336 313.150 -13.969
-29.545 1.983E+020 1.282 20.297 0.00314317 318.150 -13.654
-29.476 8.645E+019 1.279 19.937 0.00309454 323.150 -13.349
-29.413 3.899E+019 1.276 19.591 0.00304739 328.150 -13.055
-29.356 1.816E+019 1.274 19.259 0.00300165 333.150 -12.771
-29.303 8.724E+018 1.272 18.941 0.00295727 338.150 -12.494
-29.256 4.313E+018 1.270 18.635 0.00291418 343.150 -12.224
-29.215 2.192E+018 1.268 18.341 0.00287233 348.150 -11.960
-29.178 1.144E+018 1.266 18.058 0.00283166 353.150 -11.701
-29.145 6.117E+017 1.265 17.787 0.00279213 358.150 -11.447
-29.118 3.351E+017 1.264 17.525 0.00275368 363.150 -11.198
-29.095 1.878E+017 1.263 17.274 0.00271628 368.150 -10.953

Amount Amount Volume Formula FM

mol g l or ml g/mol
1.000 87.846 0.000 ml FeO2(-a) 87.846
3.000 3.024 0.000 ml H(+a) 1.008
1.000 0.001 0.000 ml e- 0.001
mol g l or ml g/mol
1.000 72.854 0.000 ml HFeO2(-a) 88.854
1.000 18.015 18.069 ml

7450.47601 -3.060256
49.250868 0.1540775
0.99925769 0.05720195
22884.4387 17
74.8793363 0.05562508
+a) + e- = HFeO2(-a)
deltaS deltaG K E vs. SHE logK
cal/K kcal V
-47.341 -3.592 6.652E+002 0.156 2.823
-45.545 -3.360 3.926E+002 0.146 2.594
-43.951 -3.137 2.395E+002 0.136 2.379
-42.520 -2.921 1.505E+002 0.127 2.178
-41.217 -2.711 9.719E+001 0.118 1.988
-40.015 -2.508 6.433E+001 0.109 1.808
-38.895 -2.311 4.357E+001 0.100 1.639
-37.841 -2.119 3.014E+001 0.092 1.479
-36.842 -1.933 2.126E+001 0.084 1.328
-35.892 -1.751 1.528E+001 0.076 1.184
-34.988 -1.574 1.117E+001 0.068 1.048
-34.129 -1.401 8.298E+000 0.061 0.919
-33.306 -1.232 6.258E+000 0.053 0.796
-32.513 -1.068 4.787E+000 0.046 0.680
-31.748 -0.907 3.710E+000 0.039 0.569
-31.010 -0.750 2.912E+000 0.033 0.464
-30.296 -0.597 2.313E+000 0.026 0.364
-29.605 -0.447 1.858E+000 0.019 0.269
-28.935 -0.301 1.509E+000 0.013 0.179

Conc. Amount Amount Volume

wt-% mol g l or ml
98.865 1.000 87.846 0.000 ml
1.134 1.000 1.008 0.000 ml
0.001 1.000 0.001 0.000 ml
wt-% mol g l or ml
100.000 1.000 88.854 0.000 ml

2989.82475 -8.0200328
40.528188 0.12678927
0.99688601 0.04707108
5442.2325 17
12.0582813 0.03766667
 log K
T T
reacciones 278 298
R1 Fe(+3a) + H2O(l) = FeO(+a) + 2H(+a) -6.6237744 -5.6582457
R2 FeO(+a) + H2O(l) = Fe(OH)O(a) + H(+a) -3.4308569 -2.9995125
R3 Fe(OH)O(a) = FeO2(-a) + H(+a) -10.093519 -9.5715884
R4 Fe(+2a) + H2O(l) = FeOH(+a) + H(+a) -9.9696957 -9.3190762
R5 FeOH(+a) + H2O(l) = HFeO2(-a) + 2H(+a) -21.005285 -19.928405
R6 Fe(+3a) + e- = Fe(+2a) 13.5615629 13.031071
R7 FeO(+a) + 2H(+a) + e- = Fe(+2a) + H2O(l) 20.1853373 18.6893167
R8 Fe(OH)O(a) + 3H(+a) + e- = Fe(+2a) + 2H2O(l) 23.6161942 21.6888292
R9 Fe(OH)O(a) + 2H(+a) + e- = FeOH(+a) + H2O(l) 13.6464985 12.369753
R 10 FeO2(-a) + 3H(+a) + e- = FeOH(+a) + H2O(l) 23.7400174 21.9413414
R 11 FeO2(-a) + H(+a) + e- = HFeO2(-a) 2.73473255 2.01293622

T= 5C
reacciones redox (pe)
pH R6 R7 R8 R9 R10
0 13.5615629 20.1853373 23.6161942 13.6464985 23.7400174
0.5 13.5615629 19.1853373 22.1161942 12.6464985 22.2400174
1 13.5615629 18.1853373 20.6161942 11.6464985 20.7400174
1.5 13.5615629 17.1853373 19.1161942 10.6464985 19.2400174
2 13.5615629 16.1853373 17.6161942 9.64649849 17.7400174
2.5 13.5615629 15.1853373 16.1161942 8.64649849 16.2400174
3 13.5615629 14.1853373 14.6161942 7.64649849 14.7400174
3.31 13.5615629 13.5653373 13.6861942 7.02649849 13.8100174
3.43 13.5615629 13.3253373 13.3261942 6.78649849 13.4500174
3.5 13.5615629 13.1853373 13.1161942 6.64649849 13.2400174
4 13.5615629 12.1853373 11.6161942 5.64649849 11.7400174
4.5 13.5615629 11.1853373 10.1161942 4.64649849 10.2400174
5 13.5615629 10.1853373 8.61619422 3.64649849 8.74001742
5.5 13.5615629 9.18533731 7.11619422 2.64649849 7.24001742
6 13.5615629 8.18533731 5.61619422 1.64649849 5.74001742
6.5 13.5615629 7.18533731 4.11619422 0.64649849 4.24001742
7 13.5615629 6.18533731 2.61619422 -0.3535015 2.74001742
7.5 13.5615629 5.18533731 1.11619422 -1.3535015 1.24001742
8 13.5615629 4.18533731 -0.3838058 -2.3535015 -0.2599826
8.5 13.5615629 3.18533731 -1.8838058 -3.3535015 -1.7599826
9 13.5615629 2.18533731 -3.3838058 -4.3535015 -3.2599826
9.5 13.5615629 1.18533731 -4.8838058 -5.3535015 -4.7599826
9.96 0.26533731 -6.2638058 -6.2735015 -6.1399826
10 13.5615629 0.18533731 -6.3838058 -6.3535015 -6.2599826
 10.5 13.5615629 -0.8146627 -7.8838058 -7.3535015 -7.7599826
11 13.5615629 -1.8146627 -9.3838058 -8.3535015 -9.2599826
11.5 13.5615629 -2.8146627 -10.883806 -9.3535015 -10.759983
12 13.5615629 -3.8146627 -12.383806 -10.353502 -12.259983
12.5 13.5615629 -4.8146627 -13.883806 -11.353502 -13.759983
13 13.5615629 -5.8146627 -15.383806 -12.353502 -15.259983
13.5 13.5615629 -6.8146627 -16.883806 -13.353502 -16.759983
14 13.5615629 -7.8146627 -18.383806 -14.353502 -18.259983
14.5 13.5615629 -8.8146627 -19.883806 -15.353502 -19.759983
15 13.5615629 -9.8146627 -21.383806 -16.353502 -21.259983
15.5 13.5615629 -10.814663 -22.883806 -17.353502 -22.759983
16 13.5615629 -11.814663 -24.383806 -18.353502 -24.259983
16.5 13.5615629 -12.814663 -25.883806 -19.353502 -25.759983
17 13.5615629 -13.814663 -27.383806 -20.353502 -27.259983
17.5 13.5615629 -14.814663 -28.883806 -21.353502 -28.759983
18 13.5615629 -15.814663 -30.383806 -22.353502 -30.259983
18.5 13.5615629 -16.814663 -31.883806 -23.353502 -31.759983
19 13.5615629 -17.814663 -33.383806 -24.353502 -33.259983
19.5 13.5615629 -18.814663 -34.883806 -25.353502 -34.759983
20 13.5615629 -19.814663 -36.383806 -26.353502 -36.259983

T= 95C
reacciones redox (pe)
pH R6 R7 R8 R9 R10
0 13.031071 18.6893167 21.6888292 12.369753 21.9413414
0.5 13.031071 17.6893167 20.1888292 11.369753 20.4413414
1 13.031071 16.6893167 18.6888292 10.369753 18.9413414
1.5 13.031071 15.6893167 17.1888292 9.36975296 17.4413414
2 13.031071 14.6893167 15.6888292 8.36975296 15.9413414
2.5 13.031071 13.6893167 14.1888292 7.36975296 14.4413414
2.82 13.031071 13.0493167 13.2288292 6.72975296 13.4813414
3 13.031071 12.6893167 12.6888292 6.36975296 12.9413414
3.5 13.031071 11.6893167 11.1888292 5.36975296 11.4413414
4 13.031071 10.6893167 9.68882919 4.36975296 9.94134135
4.5 13.031071 9.68931673 8.18882919 3.36975296 8.44134135
5 13.031071 8.68931673 6.68882919 2.36975296 6.94134135
5.5 13.031071 7.68931673 5.18882919 1.36975296 5.44134135
6 13.031071 6.68931673 3.68882919 0.36975296 3.94134135
6.5 13.031071 5.68931673 2.18882919 -0.630247 2.44134135
7 13.031071 4.68931673 0.68882919 -1.630247 0.94134135
7.5 13.031071 3.68931673 -0.8111708 -2.630247 -0.5586586
8 13.031071 2.68931673 -2.3111708 -3.630247 -2.0586586
 8.5 13.031071 1.68931673 -3.8111708 -4.630247 -3.5586586
9 13.031071 0.68931673 -5.3111708 -5.630247 -5.0586586
9.31 13.031071 0.06931673 -6.2411708 -6.250247 -5.9886586
9.5 13.031071 -0.3106833 -6.8111708 -6.630247 -6.5586586
9.57 13.031071 -0.4506833 -7.0211708 -6.770247 -6.7686586
9.96 13.031071 -1.2306833 -8.1911708 -7.550247 -7.9386586
10 13.031071 -1.3106833 -8.3111708 -7.630247 -8.0586586
10.5 13.031071 -2.3106833 -9.8111708 -8.630247 -9.5586586
11 13.031071 -3.3106833 -11.311171 -9.630247 -11.058659
11.5 13.031071 -4.3106833 -12.811171 -10.630247 -12.558659
12 13.031071 -5.3106833 -14.311171 -11.630247 -14.058659
12.5 13.031071 -6.3106833 -15.811171 -12.630247 -15.558659
13 13.031071 -7.3106833 -17.311171 -13.630247 -17.058659
13.5 13.031071 -8.3106833 -18.811171 -14.630247 -18.558659
14 13.031071 -9.3106833 -20.311171 -15.630247 -20.058659
14.5 13.031071 -10.310683 -21.811171 -16.630247 -21.558659
15 13.031071 -11.310683 -23.311171 -17.630247 -23.058659
15.5 13.031071 -12.310683 -24.811171 -18.630247 -24.558659
16 13.031071 -13.310683 -26.311171 -19.630247 -26.058659
16.5 13.031071 -14.310683 -27.811171 -20.630247 -27.558659
17 13.031071 -15.310683 -29.311171 -21.630247 -29.058659
17.5 13.031071 -16.310683 -30.811171 -22.630247 -30.558659
18 13.031071 -17.310683 -32.311171 -23.630247 -32.058659
18.5 13.031071 -18.310683 -33.811171 -24.630247 -33.558659
19 13.031071 -19.310683 -35.311171 -25.630247 -35.058659
19.5 13.031071 -20.310683 -36.811171 -26.630247 -36.558659
20 13.031071 -21.310683 -38.311171 -27.630247 -38.058659
log K
T T T T
368 278 298 368
-3.1053669 pH=-log(k1)/2 pH= 3.3118872103 pH= 2.8291228725 pH= 1.5526834685
-1.8590284 pH=-log(k2) pH= 3.4308569075 pH= 2.9995124591 pH= 1.8590283605
-8.1915927 pH=-log(k3) pH= 10.0935189345 pH= 9.5715883899 pH= 8.1915926838
-7.5988241 pH=-log(k4) pH= 9.9696957303 pH= 9.3190762277 pH= 7.5988241189
-17.081112 pH=-log(k5)/2 pH= 10.5026424347 pH= 9.9642025649 pH= 8.5405558441
11.6284389 pe=logk6 pe= 13.5615628875 pe= 13.0310709847 pe= 11.6284388614
14.7338058 pe=logk7-2pH pe= 20.185-2pH pe= 18.689-2pH pe= 14.733-2pH
16.5928342 pe=logk8-3pH pe= 23.616-3pH pe= 21.688-3pH pe= 16.592-3pH
8.99401004 pe=logk9-2pH pe= 13.646-2pH pe= 13.646-2pH pe= 13.646-2pH
17.1856027 pe=logk10-3pH pe= 23.740-3pH pe= 21.941-3pH pe= 17.185-3pH
0.10449104 pe=logk11-pH pe= 2.734-pH pe= 2.0129-pH pe= 0.104-pH

R11 pH
Chart Title
2.73473255 3.31 13.5615628875 20
2.23473255 3.31 20 15
1.73473255 3.43 13.325337308 10
1.23473255 3.43 20 5
0.73473255 9.96 -20 0
0.23473255 9.96 -6.2638057845 -5
-0.2652674 10 -6.2599825803 -10

-0.5752674 10 20 -15
-20
-0.6952674 10.5 -20 0 2 4 6 8 1
-0.7652674 10.5 -7.7652674497 Col umn E Col umn F Col umn G
-1.2652674 Col umn I Col umn J Col umn N
-1.7652674 Col umn N Col umn N Col umn N
-2.2652674
-2.7652674
-3.2652674
-3.7652674
-4.2652674
-4.7652674
-5.2652674
-5.7652674
-6.2652674
-6.7652674
-7.2252674
-7.2652674
 -7.7652674
-8.2652674
-8.7652674
-9.2652674
-9.7652674
-10.265267
-10.765267
-11.265267
-11.765267
-12.265267
-12.765267
-13.265267
-13.765267
-14.265267
-14.765267
-15.265267
-15.765267
-16.265267
-16.765267
-17.265267

Chart Title
R11 pH
20
2.01293622 2.82 13.0310709847
1.51293622 2.82 20 15

1.01293622 3 12.6893167297 10
0.51293622 3 20
5
0.01293622 9.31 -20
-0.4870638 9.31 -6.2411708112 0

-0.8070638 9.57 -6.7702470389 -5

-0.9870638 9.57 20 -10
-1.4870638 9.96 -7.9470637789
-15
-1.9870638 9.96 -20
-2.4870638 -20
0 2 4 6 8 10
-2.9870638
-3.4870638
-3.9870638
-4.4870638
-4.9870638
-5.4870638
-5.9870638
-6.4870638
-6.9870638
-7.2970638
-7.4870638
-7.5570638
-7.9470638
-7.9870638
-8.4870638
-8.9870638
-9.4870638
-9.9870638
-10.487064
-10.987064
-11.487064
-11.987064
-12.487064
-12.987064
-13.487064
-13.987064
-14.487064
-14.987064
-15.487064
-15.987064
-16.487064
-16.987064
-17.487064
-17.987064
 Chart Title

6 8 10 12 14
ol umn F Col umn G Col umn H
ol umn J Col umn N Col umn N
ol umn N Col umn N
Chart Title

6 8 10 12 14
 HSO4(-a) = SO4(-2a) + H(+a)
1/T T deltaH deltaS deltaG K Log(K)
1/K K kJ J/K kJ
0.00359518 278.150 -13.635 -82.799 9.396 1.720E-002 -1.765
0.0035317 283.150 -15.623 -89.884 9.828 1.538E-002 -1.813
0.00347041 288.150 -17.400 -96.105 10.293 1.361E-002 -1.866
0.00341122 293.150 -19.013 -101.656 10.788 1.196E-002 -1.922
0.00335402 298.150 -20.502 -106.692 11.309 1.044E-002 -1.981
0.0032987 303.150 -21.898 -111.336 11.854 9.064E-003 -2.043
0.00324517 308.150 -23.226 -115.683 12.422 7.839E-003 -2.106
0.00319336 313.150 -24.506 -119.803 13.010 6.755E-003 -2.170
0.00314317 318.150 -25.750 -123.743 13.619 5.805E-003 -2.236
0.00309454 323.150 -26.965 -127.533 14.247 4.975E-003 -2.303
0.00304739 328.150 -28.154 -131.184 14.894 4.255E-003 -2.371
0.00300165 333.150 -29.315 -134.696 15.559 3.633E-003 -2.440
0.00295727 338.150 -30.461 -138.110 16.241 3.097E-003 -2.509
0.00291418 343.150 -31.600 -141.454 16.940 2.637E-003 -2.579
0.00287233 348.150 -32.735 -144.738 17.656 2.243E-003 -2.649
0.00283166 353.150 -33.869 -147.972 18.387 1.906E-003 -2.720
0.00279213 358.150 -35.004 -151.165 19.135 1.618E-003 -2.791
0.00275368 363.150 -36.144 -154.326 19.899 1.373E-003 -2.862
0.00271628 368.150 -37.291 -157.463 20.678 1.164E-003 -2.934

1345.88698 -6.5142037
38.8631899 0.12158046
0.98602358 0.04513728
1199.33442 17
2.44349318 0.03463536

A'
HSO4(-a) = SO4(-2a) + H(+a) Para k1 Logk1 = A' + B'*(1/T) -6.5142037
H2S(a) = HS(-a) + H(+a) Para k2 Logk1 = A' + B'*(1/T) -3.9122871
HS(-a) = S(-2a) + H(+a) Para k3 Logk1 = A' + B'*(1/T) -4.6909319
Para k4 Logk1 = A' + B'*(1/T) -11.462539
Para k5 Logk1 = A' + B'*(1/T) -4.9483356
Para k6 Logk1 = A' + B'*(1/T) -8.8606227
Para k7 Logk1 = A' + B'*(1/T) -13.551555
 H2S(a) = HS(-a) + H(+a)
T T deltaH deltaS deltaG K Log(K)
1/K K kJ J/K kJ
0.00359518 278.150 30.091 -34.713 39.746 3.430E-008 -7.465
0.0035317 283.150 28.237 -41.320 39.937 4.286E-008 -7.368
0.00347041 288.150 26.564 -47.177 40.158 5.244E-008 -7.280
0.00341122 293.150 25.028 -52.461 40.407 6.301E-008 -7.201
0.00335402 298.150 23.598 -57.301 40.682 7.449E-008 -7.128
0.0032987 303.150 22.247 -61.794 40.980 8.676E-008 -7.062
0.00324517 308.150 20.955 -66.020 41.299 9.971E-008 -7.001
0.00319336 313.150 19.709 -70.032 41.640 1.132E-007 -6.946
0.00314317 318.150 18.497 -73.873 42.000 1.270E-007 -6.896
0.00309454 323.150 17.311 -77.570 42.378 1.410E-007 -6.851
0.00304739 328.150 16.148 -81.142 42.775 1.551E-007 -6.809
0.00300165 333.150 15.005 -84.598 43.189 1.690E-007 -6.772
0.00295727 338.150 13.876 -87.963 43.621 1.825E-007 -6.739
0.00291418 343.150 12.754 -91.259 44.069 1.955E-007 -6.709
0.00287233 348.150 11.635 -94.495 44.533 2.079E-007 -6.682
0.00283166 353.150 10.518 -97.681 45.014 2.195E-007 -6.659
0.00279213 358.150 9.399 -100.825 45.510 2.301E-007 -6.638
0.00275368 363.150 8.277 -103.937 46.022 2.397E-007 -6.620
0.00271628 368.150 7.149 -107.023 46.549 2.482E-007 -6.605

-964.09088 -3.9122871
37.8670111 0.11846399
0.97444406 0.04398028
648.207267 17
1.2538047 0.03288251

pH aprox
T T T T T T
B' 278 298 368 278 298 368
1345.88698 -1.6728836 -1.9978044 -2.8569021 0.8364418 0.9989022 1.42845105
-964.09088 -7.3802399 -7.1474914 -6.5320993 7.38023991 7.1474914 6.53209928
-2462.0669 -13.547288 -12.952901 -11.381331 13.5472877 12.9529014 11.3813311
14994.8371 42.4757236 38.855706 29.2843006 -42.475724 -38.855706 -29.284301
13648.9501 44.1486072 40.8535104 32.1412027 -44.148607 -40.85351 -32.141203
12684.8592 36.7683673 33.706019 25.6091034 -36.768367 -33.706019 -25.609103
10222.7923 23.2210796 20.7531176 14.2277723 -23.22108 -20.753118 -14.227772
 HS(-a) = S(-2a) + H(+a)
1/T T deltaH deltaS deltaG K Log(K)
1/K K kJ J/K kJ
0.00359518 278.150 49.081 -83.273 72.243 2.704E-014 -13.568
0.0035317 283.150 49.334 -82.371 72.657 3.938E-014 -13.405
0.00347041 288.150 49.421 -82.063 73.068 5.668E-014 -13.247
0.00341122 293.150 49.370 -82.238 73.479 8.057E-014 -13.094
0.00335402 298.150 49.204 -82.801 73.891 1.131E-013 -12.946
0.0032987 303.150 48.941 -83.675 74.307 1.568E-013 -12.805
0.00324517 308.150 48.598 -84.798 74.728 2.146E-013 -12.668
0.00319336 313.150 48.187 -86.120 75.155 2.902E-013 -12.537
0.00314317 318.150 47.719 -87.604 75.590 3.877E-013 -12.412
0.00309454 323.150 47.200 -89.221 76.032 5.117E-013 -12.291
0.00304739 328.150 46.636 -90.952 76.482 6.678E-013 -12.175
0.00300165 333.150 46.030 -92.786 76.941 8.617E-013 -12.065
0.00295727 338.150 45.389 -94.695 77.410 1.100E-012 -11.959
0.00291418 343.150 44.721 -96.656 77.888 1.389E-012 -11.857
0.00287233 348.150 44.030 -98.655 78.377 1.737E-012 -11.760
0.00283166 353.150 43.320 -100.681 78.875 2.151E-012 -11.667
0.00279213 358.150 42.594 -102.722 79.384 2.638E-012 -11.579
0.00275368 363.150 41.855 -104.769 79.902 3.207E-012 -11.494
0.00271628 368.150 41.109 -106.811 80.431 3.865E-012 -11.413

-2462.0669 -4.6909319
14.8828026 0.04655969
0.9993792 0.01728549
27367.1931 17
8.17699334 0.0050794
 HSO4(-a) + 9H(+a) + 8e- = H2S(a) + 4H2O
1/T T deltaH deltaS deltaG K E vs. SHE Log(K)
1/K K kJ J/K kJ V
0.00359518 278.150 -301.497 -269.253 -226.605 3.617E+042 0.294 42.558
0.0035317 283.150 -299.446 -261.943 -225.277 3.647E+041 0.292 41.562
0.00347041 288.150 -297.520 -255.199 -223.984 4.040E+040 0.290 40.606
0.00341122 293.150 -295.687 -248.893 -222.724 4.889E+039 0.289 39.689
0.00335402 298.150 -293.926 -242.935 -221.495 6.430E+038 0.287 38.808
0.0032987 303.150 -292.220 -237.261 -220.295 9.147E+037 0.286 37.961
0.00324517 308.150 -290.552 -231.804 -219.122 1.401E+037 0.284 37.147
0.00319336 313.150 -288.914 -226.529 -217.976 2.303E+036 0.283 36.362
0.00314317 318.150 -287.297 -221.406 -216.856 4.046E+035 0.281 35.607
0.00309454 323.150 -285.696 -216.412 -215.762 7.570E+034 0.280 34.879
0.00304739 328.150 -284.107 -211.533 -214.692 1.504E+034 0.278 34.177
0.00300165 333.150 -282.528 -206.758 -213.646 3.166E+033 0.277 33.500
0.00295727 338.150 -280.955 -202.073 -212.624 7.034E+032 0.276 32.847
0.00291418 343.150 -279.384 -197.461 -211.626 1.646E+032 0.274 32.217
0.00287233 348.150 -277.813 -192.915 -210.650 4.050E+031 0.273 31.607
0.00283166 353.150 -276.239 -188.426 -209.696 1.044E+031 0.272 31.019
0.00279213 358.150 -274.660 -183.986 -208.765 2.819E+030 0.271 30.450
0.00275368 363.150 -273.074 -179.589 -207.856 7.944E+029 0.269 29.900
0.00271628 368.150 -271.479 -175.227 -206.969 2.334E+029 0.268 29.368

14994.8371 -11.462539
50.2949766 0.15734391
0.99980878 0.05841462
88886.1881 17
303.303518 0.05800856
 SO4(-2a) + 10H(+a) + 8e- = H2S(a) + 4H2O
1/T T deltaH deltaS deltaG K E vs. SHE
1/K K kJ J/K kJ V
0.00359518 278.150 -287.862 -186.454 -236.000 2.103E+044 0.306
0.0035317 283.150 -283.823 -172.059 -235.105 2.371E+043 0.305
0.00347041 288.150 -280.120 -159.093 -234.277 2.967E+042 0.304
0.00341122 293.150 -276.674 -147.236 -233.512 4.088E+041 0.303
0.00335402 298.150 -273.425 -136.243 -232.804 6.161E+040 0.302
0.0032987 303.150 -270.322 -125.924 -232.148 1.009E+040 0.301
0.00324517 308.150 -267.326 -116.121 -231.543 1.788E+039 0.300
0.00319336 313.150 -264.408 -106.726 -230.987 3.409E+038 0.299
0.00314317 318.150 -261.547 -97.663 -230.476 6.970E+037 0.299
0.00309454 323.150 -258.731 -88.879 -230.009 1.522E+037 0.298
0.00304739 328.150 -255.953 -80.349 -229.586 3.535E+036 0.298
0.00300165 333.150 -253.213 -72.062 -229.206 8.713E+035 0.297
0.00295727 338.150 -250.495 -63.963 -228.866 2.271E+035 0.297
0.00291418 343.150 -247.785 -56.008 -228.566 6.243E+034 0.296
0.00287233 348.150 -245.078 -48.177 -228.305 1.806E+034 0.296
0.00283166 353.150 -242.370 -40.454 -228.084 5.480E+033 0.296
0.00279213 358.150 -239.656 -32.821 -227.901 1.742E+033 0.295
0.00275368 363.150 -236.930 -25.263 -227.755 5.788E+032 0.295
0.00271628 368.150 -234.188 -17.764 -227.648 2.006E+032 0.295

13648.9501
89.1498674
0.99927527
23439.972
251.29997
 SO4(-2a) + 9H(+a) + 8e- = HS(-a) + 4H2O
Log(K) 1/T T deltaH deltaS deltaG K
1/K K kJ J/K kJ
44.323 0.00359518 278.150 -257.772 -221.167 -196.254 7.215E+036
43.375 0.0035317 283.150 -255.586 -213.379 -195.168 1.016E+036
42.472 0.00347041 288.150 -253.556 -206.270 -194.119 1.556E+035
41.612 0.00341122 293.150 -251.646 -199.697 -193.105 2.576E+034
40.790 0.00335402 298.150 -249.827 -193.544 -192.122 4.589E+033
40.004 0.0032987 303.150 -248.076 -187.719 -191.169 8.755E+032
39.252 0.00324517 308.150 -246.371 -182.141 -190.244 1.782E+032
38.533 0.00319336 313.150 -244.699 -176.758 -189.347 3.858E+031
37.843 0.00314317 318.150 -243.050 -171.535 -188.476 8.852E+030
37.182 0.00309454 323.150 -241.419 -166.449 -187.631 2.146E+030
36.548 0.00304739 328.150 -239.805 -161.491 -186.811 5.482E+029
35.940 0.00300165 333.150 -238.208 -156.660 -186.016 1.472E+029
35.356 0.00295727 338.150 -236.619 -151.927 -185.245 4.144E+028
34.795 0.00291418 343.150 -235.031 -147.266 -184.497 1.221E+028
34.257 0.00287233 348.150 -233.443 -142.672 -183.772 3.754E+027
33.739 0.00283166 353.150 -231.852 -138.135 -183.070 1.203E+027
33.241 0.00279213 358.150 -230.256 -133.647 -182.390 4.009E+026
32.763 0.00275368 363.150 -228.652 -129.200 -181.733 1.388E+026
32.302 0.00271628 368.150 -227.039 -124.787 -181.098 4.979E+025

-4.9483356
0.2788984
0.10354227
17
0.18225702
 SO4(-2a) + 8H(+a) + 8e- = S(-2a) + 4H2O
E vs. SHE Log(K) 1/T T deltaH deltaS deltaG
V 1/K K kJ J/K kJ
0.254 36.858 0.00359518 278.150 -208.691 -304.441 -124.011
0.253 36.007 0.0035317 283.150 -206.252 -295.750 -122.511
0.252 35.192 0.00347041 288.150 -204.135 -288.334 -121.051
0.250 34.411 0.00341122 293.150 -202.275 -281.936 -119.626
0.249 33.662 0.00335402 298.150 -200.623 -276.346 -118.231
0.248 32.942 0.0032987 303.150 -199.135 -271.394 -116.861
0.247 32.251 0.00324517 308.150 -197.773 -266.939 -115.516
0.245 31.586 0.00319336 313.150 -196.512 -262.879 -114.191
0.244 30.947 0.00314317 318.150 -195.332 -259.139 -112.886
0.243 30.332 0.00309454 323.150 -194.219 -255.670 -111.600
0.242 29.739 0.00304739 328.150 -193.169 -252.443 -110.329
0.241 29.168 0.00300165 333.150 -192.178 -249.446 -109.075
0.240 28.617 0.00295727 338.150 -191.230 -246.622 -107.835
0.239 28.087 0.00291418 343.150 -190.310 -243.922 -106.608
0.238 27.574 0.00287233 348.150 -189.413 -241.327 -105.395
0.237 27.080 0.00283166 353.150 -188.533 -238.816 -104.195
0.236 26.603 0.00279213 358.150 -187.662 -236.369 -103.007
0.236 26.142 0.00275368 363.150 -186.797 -233.969 -101.831
0.235 25.697 0.00271628 368.150 -185.930 -231.598 -100.667

12684.8592 -8.8606227
51.286704 0.16044645
0.99972218 0.05956646
61173.2739 17
217.052728 0.06031877
 K E vs. SHE Log(K)
V
1.951E+023 0.161 23.290
4.002E+022 0.159 22.602
8.821E+021 0.157 21.945
2.076E+021 0.155 21.317
5.191E+020 0.153 20.715
1.373E+020 0.152 20.138
3.826E+019 0.150 19.583
1.120E+019 0.148 19.049
3.432E+018 0.146 18.536
1.098E+018 0.145 18.041
3.661E+017 0.143 17.564
1.268E+017 0.141 17.103
4.558E+016 0.140 16.659
1.696E+016 0.138 16.229
6.520E+015 0.137 15.814
2.587E+015 0.135 15.413
1.058E+015 0.134 15.024
4.450E+014 0.132 14.648
1.924E+014 0.131 14.284

10222.7923 -13.551555
36.8120829 0.11516373
0.99977961 0.04275504
77118.4501 17
140.972052 0.0310759