Grupo 1 Muestra 1 Absorbancia Tiempo In(Ai)-In(Af)

Temperatura 40 ºC 1 0.8198 60
[KMnO4]: 3,33*10-4 M 2 0.8066 180 0.01623
[CV]: constante 3 0.7586 300 0.07759
4 0.7408 420 0.10133
5 0.7391 540 0.10363
6 0.7156 660 0.13594
7 0.7058 780 0.14973

Grupo 1 Muestra 2 Absorbancia Tiempo In(Ai)-In(Af)

Temperatura 40 ºC 1 1.1787 120
[KMnO4]: 3,66*10-4 M 2 1.0438 240 0.121544
[CV]: Constante 3 1.0028 360 0.162037
4 0.9780 480 0.183109
5 0.9650 600 0.194190
6 0.9256 720 0.227943
7 0.8988 840 0.251066
In(Ai) - In(Af)
0.16000
0.14000
0.12000
0.10000
0.08000
0.06000
0.04000
0.02000
0.00000
100 200 300 400 500 600 700 800 900
Tiempo (segundos)

0.300000
0.250000
0.200000
In(Ai)-In(Af)

0.150000
0.100000
0.050000
0.000000
200 300 400 500 600 700 800 900
Tiempo (segundos)
Grupo 2 Muestra 1 Absorbancia Tiempo In(Ai) - In(Af) 1.20000
Temperatura 25 ºC 1 1.5420 60 1.00000
[CV]:2,66 *10-5 M 2 1.2238 120 0.23112 f(x) = 0
0.80000 R² = 0.9

In(Ai) - In(Af)
[KMnO4]: constante 3 1.2940 180 0.17534
0.60000
4 1.1485 240 0.29462
5 1.0771 300 0.35881 0.40000
6 1.0140 360 0.41918 0.20000
7 0.9489 420 0.48553 0.00000
8 0.8785 480 0.56262 0 100 200 30
9 0.8132 540 0.63986 Ti
10 0.7495 600 0.72143
11 0.7044 660 0.78349
12 0.6638 720 0.84285
13 0.6261 780 0.90133
14 0.6100 840 0.92738
15 0.5905 900 0.95987

Grupo 2 Muestra 2 Absorbancia Tiempo In(Ai) - In(Af) 0.45000

0.40000 f(x) =
Temperatura 25 ºC 1 1.0746 60 R² = 0
0.35000
[CV]:2,83 *10-5 M 2 0.8477 120 0.23718 0.30000

In(Ai) - In(Af)
[KMnO4]: constante 3 0.7604 180 0.34586 0.25000
4 0.7214 240 0.39851 0.20000
0.15000
5 0.712 300 0.41163 0.10000
6 0.7111 360 0.41289 0.05000
7 0.7122 420 0.41135 0.00000
0 100 200 3
8 0.7137 480 0.40924
Tie
9 0.7132 540 0.40994
10 0.7104 600 0.41388
11 0.7116 660 0.41219
12 0.7089 720 0.41599
13 0.7072 780 0.41839
14 0.7044 840 0.42236
15 0.7029 900 0.42449
 1.20000 Temperatura Muestra 1 Absorbancia
1.00000 40ºC 1 1.2936
f(x) = 0.0010696416x + 0.0475843372 2 1.2291
0.80000 R² = 0.9855098246
In(Ai) - In(Af)

3 1.1519
0.60000
4 1.1569
0.40000 5 1.0771
0.20000 6 1.0240
0.00000 7 0.9847
0 100 200 300 400 500 600 700 800 9001000
Tiempo (segundos)

0.45000 Temperatura Muestra 2 Absorbancia

0.40000 f(x) = 0.0001278675x + 0.3307790115
R² = 0.4201856484
40ºC 1 0.6323
0.35000
0.30000 2 0.5811
In(Ai) - In(Af)

0.25000 3 0.5725
0.20000 4 0.5311
0.15000
0.10000 5 0.495
0.05000 6 0.4598
0.00000 7 0.4557
0 100 200 300 400 500 600 700 800 9001000
Tiempo (segundos)
 In(Ai) - In(Af)
Tiempo In(Ai) - In(Af)
60 0.30000

180 0.05115 0.25000 f(x) = 0.0003650149x - 0.0137797145

R² = 0.9645353116
300 0.11602 0.20000
420 0.11169 0.15000
540 0.18316 0.10000
660 0.23371 0.05000
780 0.27285 0.00000
100 200 300 400 500 600 700 800 900
Tiempo (segundos)

Tiempo In(Ai) - In(Af) 0.35000

f(x) = 0.0004627373x - 0.0416925195
120 0.30000
R² = 0.9624082352
240 0.08444 0.25000
In(Ai) - In(Af)

360 0.09935 0.20000

480 0.17441 0.15000
600 0.24481 0.10000
720 0.31857 0.05000
840 0.32753 0.00000
200 300 400 500 600 700 800 900
Tiempo (segundos)
In k 1/temperatura Ea (m*R) *10-3 kj/mol ∆H *10-3 Kj/mol ∆S *10-3 J/mol*k
-6.97571 0.00335 48005.036 45734.0669 -217.4519325788
-7.90336 0.00319

-6.40000
0.00315
-6.60000 0.00320 0.00325 0.00330 0.00335 0.00340

In K
-6.80000
-7.00000
f(x) = 5774.0247709513x - 26.3418869482
-7.20000 R² = 1
-7.40000
-7.60000
-7.80000
-8.00000
1/T

In k 1/Temperatura Ea (m*R) *10-3 kj/mol ∆H *10-3 Kj/mol ∆S *10-3 J/mol*k

-8.33446 0.00335 27078.698 24807.7289 -243.6961061243
-7.81113 0.00319

-7.50000
0.00315
-7.60000 0.00320 0.00325 0.00330 0.00335 0.00340

-7.70000
-7.80000
f(x) = - 3257.3743793456x + 2.5908321475
-7.90000 R² = 1
In K

-8.00000
-8.10000
-8.20000
-8.30000
-8.40000
1/T
 ∆G *10-3 Kj/mol
105131.06228391

0 0.00335 0.00340

26.3418869482

∆G *10-3 Kj/mol
91373.32028785

0.00335 0.00340

x + 2.5908321475
Grupo 3 Muestra 1 Absorbancia Tiempo In(Ai) - In(Af) 0.25000
Temperatura 25 ºC 1 1.5595 60
0.20000 f(x) = 0.000190441
[KMnO4]: 4*10-4 M 2 1.4922 120 0.04411
R² = 0.9783838298

In(Ai) - In(Af)
[CV]: constante 3 1.4570 180 0.06799 0.15000
4 1.4361 240 0.08243
0.10000
5 1.4124 300 0.09907
6 1.3960 360 0.11075 0.05000
7 1.3742 420 0.12649
0.00000
8 1.3593 480 0.13740 0 100 200 300 400 50
9 1.3519 540 0.14285 Tiempo (segun
10 1.3312 600 0.15828
11 1.3224 660 0.16492
12 1.3070 720 0.17663
13 1.3000 780 0.18200
14 1.2877 840 0.19151
15 1.2765 900 0.20024

Grupo 3 Muestra 2 Absorbancia Tiempo In(Ai) - In(Af) 0.14000

Temperatura 25 ºC 1 1.7005 60 0.12000 f(x) = 0.0001697482
R² = 0.9895724318
[KMnO4]: 4,33*10-4 M 2 1.6858 120 0.00868 0.10000
[CV]: constante 3 1.68 180 0.01213

In(Ai) - In(Af)
0.08000
4 1.6748 240 0.01523
5 1.6547 300 0.02730 0.06000
6 1.6313 360 0.04155 0.04000
7 1.6106 420 0.05432 0.02000
8 1.5997 480 0.06111 0.00000
9 1.5723 540 0.07838 0 100 200 300 400 500
10 1.5604 600 0.08598 Tiempo (segun
11 1.5414 660 0.09823
12 1.5259 720 0.10834
13 1.5191 780 0.11280
14 1.5004 840 0.12519
15 1.4964 900 0.12786
.25000 Temperatura muestra 1 Absorbanca Tiempo
40ºC 1 1.5936 60
.20000 f(x) = 0.0001904419x + 0.0374953537 2 1.5150 180
R² = 0.9783838298
.15000 3 1.4625 300
4 1.4559 420
.10000
5 1.3358 540
.05000 6 1.2587 660
7 1.2552 780
.00000
0 100 200 300 400 500 600 700 800 900 1000
Tiempo (segundos)

4000 Temperatura Muestra 2 Absorbancia Tiempo

2000 f(x) = 0.0001697482x - 0.0182076123 40ºC 1 1.6967 120
R² = 0.9895724318
0000
2 1.4914 240
3 1.4403 360
8000
4 1.3931 480
6000 5 1.3500 600
4000 6 1.3092 720
2000 7 1.2178 840
0000
0 100 200 300 400 500 600 700 800 900 1000
Tiempo (segundos)
In(Ai) - In(Af) 0.30000 In k
0.25000 -8.51221
0.05058 f(x) = 0.0003516429x - 0.0224749258 -8.06771
0.20000 R² = 0.9322900435

In(Ai) - In(Af)
0.08585
0.15000 -7.80000
0.09037
0.17647 0.10000 0.00315
-7.90000
0.23592 0.05000 -8.00000
0.23870
0.00000 -8.10000
100 200 300 400 500 600 700 800 900

In K
-8.20000
Tiempo (segundo)
-8.30000
-8.40000
-8.50000
-8.60000
In(Ai) - In(Af)

In(Ai) - In(Af) 0.35000 In k

-8.78638
0.30000 f(x) = 0.0003169236x + 0.0471022957
0.12897 R² = 0.9726213722 -7.99365
0.16383 0.25000
0.19715 0.20000
-7.40000
0.22858 0.15000 0.00315
0.25927 -7.60000
0.10000
0.33164 -7.80000
0.05000
-8.00000
0.00000

In K
200 300 400 500 600 700 800 900 -8.20000

Tiempo (segundos) -8.40000

-8.60000
-8.80000
-9.00000
 1/temperaturEa (m*R) *10-3 kj/mol ∆H *10-3 Kj/mol ∆S *10-3 J/mol*k ∆G *10-3 Kj/mol
0.00335 22996.524 20725.5549 -246.8532061229 88153.508152468
0.00319

-7.80000
0.00315 0.00320 0.00325 0.00330 0.00335 0.00340
-7.90000
-8.00000
-8.10000 f(x) = - 2766.7015623198x + 0.76735686
R² = 1
In K

-8.20000
-8.30000
-8.40000
-8.50000
-8.60000

1/T

1/temperaturEa (m*R) *10-3 kj/mol ∆H *10-3 Kj/mol ∆S *10-3 J/mol*k ∆G *10-3 Kj/mol
0.00335 41021.276 38750.3069 -227.6093113194 100921.79028689
0.00319

-7.40000
0.00315 0.00320 0.00325 0.00330 0.00335 0.00340
-7.60000
-7.80000
-8.00000
f(x) = - 4934.2630431728x + 7.7632186586
In K

-8.20000 R² = 1
-8.40000
-8.60000
-8.80000
-9.00000
1/T
Grupo 4 Muestra 1 Absorbancia Tiempo In(Ai) - In(Af) 0.20000
Temperatura 25 ºC 1 2.31 60 0.18000
0.16000
[CV]:,3*10-5 M 2 2.191 120 0.05289
0.14000
[KMnO4]: constante 3 2.1464 180 0.07346
0.12000
4 2.125 240 0.08348

In(Ai) - In(Af)
0.10000
5 2.0924 300 0.09894 0.08000
6 2.0874 360 0.10133 0.06000
7 2.0587 420 0.11517 0.04000
8 2.039 480 0.12479 0.02000
9 2.0175 540 0.13539 0.00000
10 2.0041 600 0.14205 0 100 200 300 400 500 600 700

11 1.9762 660 0.15607 Tiempo (segundos )

12 1.9635 720 0.16252
13 1.9537 780 0.16752
14 1.9444 840 0.17229
15 1.9422 900 0.17343

Grupo 4 Muestra 2 Absorbancia Tiempo In(Ai) - In(Af)

Temperatura 25 ºC 1 2.48 60
[CV]:3,16 *10-5 M 2 2.2034 120 0.11826

In(Ai) - In(Af)
[KMnO4]: constante 3 2.134 180 0.15026 0.30000
4 2.1187 240 0.15746 0.25000 f(x) = 0.0001916022x +
5 2.0932 300 0.16956 R² = 0.9777650499
0.20000
6 2.0585 360 0.18628
0.15000
7 2.0532 420 0.18886
8 2.0189 480 0.20571 0.10000
9 1.9699 540 0.23028 0.05000
10 1.9687 600 0.23089 0.00000
11 1.9636 660 0.23348 0 100 200 300 400 500
12 1.9448 720 0.24310 Tiempo (segundos
13 1.9099 780 0.26121
14 1.8992 840 0.26683
15 1.8728 900 0.28082
0 Temperatura Muestra 1 Absorbancia Tiempo
0 40ºC 1 1.9571 60
0
2 1.8648 180
0
3 1.4787 300
0
4 1.3932 420
0
0 5 1.3732 540
0 6 1.4263 660
0 7 1.3637 780
0
0
0 100 200 300 400 500 600 700 800 900 1000

Tiempo (segundos )
K=1,5461*10-4

Temperatura Muestra 2 Absorbancia Tiempo

40ºC 1 2.3852 120
2 2.0442 240
3 1.7520 360
f(x) = 0.0001916022x + 0.1110672038 4 1.6936 480
R² = 0.9777650499 5 1.7164 600
6 1.6563 720
7 1.5566 840

0 100 200 300 400 500 600 700 800 900 1000
Tiempo (segundos )
In(Ai) - In(Af)

In(Ai) - In(Af)
0.40000 In k
0.35000 f(x) = 0.0004017761x + 0.090553032
0.04831 0.30000 R² = 0.5758241434 -8.77856
0.28030 0.25000 -7.55861
0.33986 0.20000
0.15000
0.35432 0.10000 -6.50000
0.31638 0.05000 0.00315 0.00320
0.36126 0.00000 -7.00000
100 200 300 400 500 600 700 800 900
-7.50000
Tiempo (segundos )
f(x) =

In k
-8.00000 R² =

-8.50000

-9.00000
In(Ai) - In(Af)

0.45000
0.40000 f(x) = 0.0003613466x + 0.1258324741
In(Ai) - In(Af) R² = 0.7914380054
In k
0.35000
0.30000 -8.47605
0.15428 0.25000 -7.69741
0.30852 0.20000
0.34243 0.15000
0.10000
0.32905
0.05000
0.36470 0.00000
-7.20000
0.42678 0.00315 0.00320 0.0
200 300 400 500 600 700 800 900
-7.40000
Tiempo(segundos)
-7.60000

-7.80000 f(x) = - 484

R² = 1
In K

-8.00000

-8.20000

-8.40000

-8.60000
 1/temperaturEa (m*R) *10-3 kj/mol ∆H *10-3 Kj/mol ∆S *10-3 J/mol*k ∆G *10-3 Kj/mol
0.00335 63128.202 60857.2329 -221.245435841 121290.423699964
0.00319

-6.50000
0.00315 0.00320 0.00325 0.00330 0.00335 0.00340
-7.00000

-7.50000
f(x) = - 7593.4202364525x + 16.6898983129
In k

-8.00000 R² = 1

-8.50000

-9.00000
1/T

1/temperaturEa (m*R) *10-3 kj/mol ∆H *10-3 Kj/mol ∆S *10-3 J/mol*k ∆G *10-3 Kj/mol
0.00335 40289.644 38018.6749 -227.5921933105 100185.482502764
0.00319

-7.20000
0.00315 0.00320 0.00325 0.00330 0.00335 0.00340
-7.40000

-7.60000

-7.80000 f(x) = - 4846.5366708159x + 7.7793123971

R² = 1
-8.00000

-8.20000

-8.40000

-8.60000
1/T
Grupo 5 Muesta 1 Absorbancia Tiempo In(Ai) - In(Af)
Temperatura 25 ºC 1 1.6271 60
[KMnO4]: 4,66*10-4 M 2 0.9989 120 0.48789989

In(Ai) - In(Af
[CV]: constante 3 0.8399 180 0.66127173 0.9
4 0.8381 240 0.66341714 0.8
0.7 f(x) = 0.000256327x + 0
5 0.8327 300 0.66988113 R² = 0.7529189395
0.6
6 0.8239 360 0.6805054
0.5
7 0.8125 420 0.69443865 0.4
8 0.8059 480 0.7025949 0.3
9 0.7929 540 0.71885746 0.2
10 0.7836 600 0.73065588 0.1
11 0.7742 660 0.74272433 0
0 100 200 300 400 500 600
12 0.7657 720 0.75376412
Tiempo(segundos
13 0.7582 780 0.76360737
14 0.7516 840 0.7723503
15 0.7428 900 0.78412774

Grupo 5 Muestra 2 Absorbancia Tiempo In(Ai) - In(Af)

In(Ai) - In(Af
Temperatura 25 ºC 1 1.9726 60 0.39
[KMnO4]: 5*10-4 M 2 1.4105 120 0.33540822 f(x) = 5.68567858290331
0.38
R² = 0.9022353057
[CV]: constante 3 1.4031 180 0.3406684 0.37
4 1.3921 240 0.34853907
0.36
5 1.3754 300 0.36060787
0.35
6 1.37 360 0.36454173
7 1.3679 420 0.36607575 0.34
8 1.3656 480 0.36775858 0.33
9 1.3629 540 0.36973769 0.32
10 1.3583 600 0.37311855 0.31
11 1.3566 660 0.3743709 0 100 200 300 400 500
12 1.3551 720 0.37547722 Tiempo(segundo
13 1.3508 780 0.37865546
14 1.3464 840 0.38191811
15 1.3416 900 0.38548954
 Temperatura Muestra 1 Absorbancia Tiempo
40ºC 1 1.5116 60
2 1.353 180
0.9 3 1.3228 300
0.8 4 1.2646 420
0.7 f(x) = 0.000256327x + 0.5711372175
R² = 0.7529189395 5 1.2688 540
0.6
6 1.224 660
0.5
0.4
7 1.1823 780
0.3
0.2
0.1
0
0 100 200 300 400 500 600 700 800 9001000
Tiempo(segundos)

Temperatura Muestra 1 Absorbancia Tiempo

In(Ai) - In(Af

0.39 40ºC 1 1.5076 120

f(x) = 5.68567858290331E-05x + 0.3368864017 2 1.2918 240
0.38
R² = 0.9022353057
0.37 3 1.2494 360
4 1.2233 480
0.36
5 1.2196 600
0.35
6 1.1382 720
0.34 7 1.1204 840
0.33
0.32
0.31
0 100 200 300 400 500 600 700 800 9001000
Tiempo(segundos)
In(Ai) - In(Af) 0.3

0.25 In k
0.1108443433 f(x) = 0.0002152088x + 0.0724537216 -7.87587

In(Ai) - In(Af
0.1334179904 0.2 R² = 0.9604505042 -8.40030
0.1784128259 0.15 -7.60000
0.1750971206 0.00315
-7.70000 0.0
0.2110445084 0.1
-7.80000
0.2457069986 0.05 -7.90000
-8.00000
0

In K
100 200 300 400 500 600 700 800 900 -8.10000
Tiempo(segundos) -8.20000
-8.30000
-8.40000
-8.50000

In(Ai) - In(Af) 0.35

0.3 In k
f(x) = 0.0002367689x + 0.0956789473
In(Ai) - In(Af

0.1544823878 0.25 -9.65507

R² = 0.9374454813
0.1878555463 0.2 -8.34619
0.2089668573 0.15
0.2119960463 -7.50000
0.1 0.00315 0
0.2810709152
0.05
0.296833218 -8.00000
0
200 300 400 500 600 700 800 900
-8.50000
Tiempo(segundos)
InK
-9.00000

-9.50000

-10.00000
 1/temperatura Ea (m*R) *10-3 kj/mol ∆H *10-3 Kj/mol ∆S *10-3 J/mol*k ∆G *10-3 Kj/mol
0.00335 27136.896 24865.9269 -220.2468380046 85026.3507009611
0.00319
-7.60000
0.00315
-7.70000 0.00320 0.00325 0.00330 0.00335 0.00340
-7.80000
-7.90000
f(x) = 3264.273549889x - 18.8242928932
-8.00000 R² = 1
In K

-8.10000
-8.20000
-8.30000
-8.40000
-8.50000

1/T

1/temperatura Ea (m*R) *10-3 kj/mol ∆H *10-3 Kj/mol ∆S *10-3 J/mol*k ∆G *10-3 Kj/mol
0.00335 67734.158 65463.1889 -220.7710510674 125766.801499071
0.00319

-7.50000
0.00315 0.00320 0.00325 0.00330 0.00335 0.00340
-8.00000

-8.50000 f(x) = - 8146.969071271x + 17.6700019638

R² = 1
InK

-9.00000

-9.50000

-10.00000

1/T
Grupo 6 Muestra 1 Absorbancia Tiempo In(Ai) - In(Af)

In (A i) - In (A f )
Temperatura 25 ºC 1 2.3035 60
[CV]:3,33 *10-5 M 2 2.135 120 0.07596
[KMnO4]: constante 3 1.8947 180 0.19537
4 1.8896 240 0.19806 0.25000
5 1.8852 300 0.20040 f(x) = 8.20914178321459E-05x
0.20000 + 0.15
R² = 0.34444032
6 1.8825 360 0.20183 0.15000
7 1.8895 420 0.19812 0.10000
8 1.8766 480 0.20497 0.05000
9 1.8759 540 0.20534 0.00000
10 1.8658 600 0.21074 0 200 400 600

11 1.8713 660 0.20780 Tiempo(segundos

12 1.8694 720 0.20881
13 1.868 780 0.20956
14 1.8594 840 0.21418
15 1.8584 900 0.21471
0.08000
f(x) = 3.535412663
Grupo 6 Muestra 2 Absorbancia Tiempo In(Ai) - In(Af) 0.07000 R² = 0.2963012957
Temperatura 25 ºC 1 3.0598 60 0.06000
[CV]:3,50*10-5 M 2 3.0319 120 0.00916

In(Ai) - In(Af
0.05000
[KMnO4]: constante 3 2.8639 180 0.06617
4 2.8595 240 0.06770 0.04000
5 2.8491 300 0.07135
0.03000
6 2.8861 360 0.05844
7 2.8608 420 0.06725 0.02000
8 2.8728 480 0.06306
0.01000
9 2.8678 540 0.06480
10 2.8705 600 0.06386 0.00000
11 2.866 660 0.06543 0 100 200 300 400
12 2.8578 720 0.06830 Tíempo(segundos)
13 2.8354 780 0.07617
14 2.8354 840 0.07617
15 2.8567 900 0.06868
 Temperatura Muestra 1 Absorbancia Tiempo
40ºC 1 1.978 60
2 1.6275 180
3 1.6003 300
0.25000
4 1.5503 420
) = 8.20914178321459E-05x
0.20000 + 0.1542653498 5 1.5156 540
= 0.34444032
0.15000
6 1.4923 660
0.10000 7 1.4352 780
0.05000

0.00000
0 200 400 600 800 1000

Tiempo(segundos)

0.08000
f(x) = 3.53541266369553E-05x + 0.045293783
0.07000 R² = 0.2963012957 Temperatura Muestra 2 Absorbancia Tiempo
0.06000 40ºC 1 2.0884 120
2 1.5949 240
0.05000 3 1.5043 360
0.04000 4 1.4421 480
5 1.3815 600
0.03000 6 1.3583 720
0.02000 7 1.3504 840

0.01000

0.00000
0 100 200 300 400 500 600 700 800 9001000
Tíempo(segundos)
 In (A i) - In (A f)
In(Ai) - In(Af) In k
-8.63936
0.19504 -8.47079
0.35000
0.21190
0.30000 f(x) = 0.0002049903x + 0.1548377631
0.24364 0.25000 R² = 0.9864851044 -8.35000
0.26627 0.20000 0.00315
-8.40000
0.28177 0.15000
0.32078 0.10000 -8.45000

In K
0.05000
0.00000 -8.50000
100 200 300 400 500 600 700 800 900
Tiempo(segundos) -8.55000

-8.60000

-8.65000

-8.70000

In(Ai) - In(Af) 0.50000

0.45000 In k
f(x) = 0.000281253x + 0.2226809619
0.40000
In(Ai) - In(Af)

0.26959 R² = 0.9245682862 -9.48110

0.35000
0.32807 0.30000 -8.19041
0.37030 0.25000
0.41323 0.20000 -7.50000
0.15000 0.00318 0.00320
0.43016
0.10000 -8.00000
0.43600 0.05000
0.00000 f(x) =
200 300 400 500 600 700 800 900 In K -8.50000 R² = 1
Tiempo(segundos)
-9.00000

-9.50000

-10.00000
 1/temperatura Ea (m*R) *10-3 kj/mol ∆H *10-3 Kj/mol ∆S *10-3 J/mol*k ∆G *10-3 Kj/mol
0.00335 8721.386 6450.4169 -231.0697179937 69567.110369986
0.00319

-8.35000
0.00315 0.00320 0.00325 0.00330 0.00335 0.00340
-8.40000

-8.45000
In K

-8.50000 f(x) = - 1049.268367321x - 5.120097477

R² = 1
-8.55000

-8.60000

-8.65000

-8.70000
1/T

1/temperatura Ea (m*R) *10-3 kj/mol ∆H *10-3 Kj/mol ∆S *10-3 J/mol*k ∆G *10-3 Kj/mol
0.00335 66786.362 64515.3929 -220.8704510559 124846.15660591
0.00319

-7.50000
0.00318 0.00320 0.00322 0.00324 0.00326 0.00328 0.00330 0.00332 0.00334 0.00336 0.00338
-8.00000

f(x) = - 8033.7375014622x + 17.4641878346

-8.50000 R² = 1
In K

-9.00000

-9.50000

-10.00000

1/T
 Constantes de velocidad (k) EA
[KMnO4]*10-4 M Temperatura 25 ºC Temperatura 40 ºC *10-3 kj/mol
3.33 1,854*10-4
3.66 2,158*10-4
4.00 2,001*10-4 3,135*10-4 22996.52
4.33 1,528*10-4 3,376*10-4 41021.28
4.66 3,978*10-4 2,248*10-4 27136.90
5.00 6,410*10-5 2,373*10-4 67734.16

Constantes de velocidad EA
[CV]*10-5 M Temperatura 25 ºC Temperatura 40 ºC *10-3 kj/mol
2.66 9,343*10-4 3,695*10-4 48005.04
2.83 2,401*10-4 4,052*10-4 27078.70
3.00 1,5461*10-4 5,216*10-4 63128.20
3.16 2,084*10-4 4,54*10-4 40289.64
3.33 1,77*10-4 2,095*10-4 8721.39
3.50 7,628*10-5 2,773*10-4 66786.36
 ∆H ∆S ∆G
*10-3 kj/mol *10-3 J/mol*K *10-3 kj/mol

20725.55 -246.85 88153.51

38750.31 -227.61 100921.79
24865.93 -220.25 85026.35
65463.19 -220.77 125766.80

∆H ∆S ∆G
*10-3 kj/mol *10-3 J/mol*K *10-3 kj/mol
45734.07 -217.45 105131.06
24807.73 -243.70 91373.32
60857.23 -221.25 121290.42
38018.67 -227.59 100185.48
6450.42 -231.07 69567.11
64515.39 -220.87 124846.16