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PRIMEIROS TESTES:CONCENTRAOES

Equipamento para deteo de chumbo, espectofotometro de adsoro atomica. Faixa de deteo 1


Pb+2
Relao
1:01
mg AH
50 mg
Concentrao do cido hmico:
Soluo
50 ml
Tiempo
24 hr
Agitao
175 rpm
Temperatura
25 C
pH
4a5
Diluio
C inicial (ppm)
C inicial real
C final (ppm)
% Adsoro

c1v1=C2V2
10.00
9.98
0.174
98.26

Quantidade de material
absorvido (mg)
q ( mg/g)
Cf/q
log(q)
log(Cf)

9.81

20.00
19.97
0.392
98.04

30.00
29.96
1.259
95.80

19.58

28.70

9.8061
19.5782
0.01773386 0.020012054
0.991496318 1.291772761
-0.759700418 -0.406935568

28.701
0.0438660674
1.4578970287
0.1000257301

1.- Equao de LANGMIUR linearizada

Langmiur Linealizado - Pb

Ce/qe

0.40
0.35
f(x) = 0.0129139008x + 0.0261522323
0.30 R = 0.9892076326
0.25
0.20
0.15
0.10
0.05
0.00
0.0
5.0
10.0

15.0
Ce

2.- Isoterma de Freundlich

20.0

25.0

Isoterma de Freundlich - Linealizado


2.00
1.80
1.60
log(q)

f(x) = 0.3771886245x + 1.3735885756


R = 0.9668905466

1.40
1.20
1.00
0.80
-1.00

-0.50

0.00

0.50

1.00

Log( Cf)

Comparaco das isotermas:


C
0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000
2.000
3.000
4.000
5.000
6.000
7.000
8.000
9.000
10.000
15.000
20.000
25.000

Lagmiur
0
3.637686431
6.949270327
9.976720984
12.75510204
15.31393568
17.67825575
19.86942946
21.90580504
23.80322666
25.57544757
38.46153846
46.22496148
51.41388175
55.12679162
57.91505792
60.08583691
61.82380216
63.24666198
64.43298969
68.27492035
70.37297678
71.69486665

Freundlich
0
9.917449552
12.88096839
15.00963521
16.7300419
18.19916597
19.49479406
20.66193451
21.72929035
22.71644013
23.63741608
30.70071672
35.77421702
39.87466328
43.3761983
46.46422007
49.24600226
51.78995612
54.14274552
56.33781509
65.64801864
73.17260464
79.59814948

Reldich Peterson
0
6.5554374043
11.3219461707
15.0691792685
18.1409152651
20.731172898
22.9614590866
24.9131052178
26.6432179006
28.1933897395
29.594811252
38.9226698497
44.2740869985
47.9666534614
50.7656866753
53.0119551184
54.8848442024
56.4896614426
57.8931854818
59.1402754693
63.884637608
67.2222309581
69.810560078

1.50

S:CONCENTRAOES

Teste feito o da 30 de setem

atomica. Faixa de deteo 1,00 - 8 ppm

do cido hmico:

1g/L

Eu fiz tudos estes testes com o padro da Merk, que pessoal


da quimica utilizam para a calibrao de seus equipamentos.
No h variao muito significativa entre a concentrao
preparada e a concentrao real.

50.00
49.94
4.722
90.54

80.00
79.90
15.800
80.23

100.00
99.88
25.390
74.58

45.22

64.10

74.49

45.218
64.1
0.10442744 0.24648986
1.65531135 1.80685803
0.674125983 1.198657087

Isot
80
70
60

74.49
0.340851121
1.8720979743
1.4046627009

50

q (mg/g)

40
30
20
10
0
0.0

56.3893041978

Constantes de adsoo
Metal
Pb
20.0

25.0

30.0

q max
mg/g
77.52

0.12649869

1-X
C

0.87350131
0.174

C(1-X)

0.1519892279

5.0

ado

Constantes de adsoo
n

Metal
Pb

1.00

1.50

2.65

2.00

KF

B
81.22

g
1.7444

0.8633

90.00
80.00
70.00
60.00
50.00
qe (mg/g)

40.00
30.00
20.00
10.00
0.00
0.00

5.00

10.00

15.00
Ce mg/L

20

Teste feito o da 30 de setembro

q (mg/g)

Isoterma de Adsoro Pb
80
70
60
50
40
30
20
10
0
0.0

5.0

10.0

15.0

20.0

Cf mg/L

Kads
L/mg
0.49

R2

0.0262

98.92
Cf
0.174
0.392
1.259
4.722
15.800
25.390

mg/L
0.832287207

25.0

30.0

Kf
L/mg
23.64

R2
96.69

Langmiur
Freunlich
Reldich Peterson

10.00

15.00
Ce mg/L

20.00

25.00

30.00

PRIMEIROS TESTES:CONCENTRAOES

Equipamento para deteo de chumbo, espectofotometro de adsoro atomica. Faixa de deteo 1


Pb+2
Relao
1:01
mg AH
50 mg
Concentrao do cido hmico:
Soluo
50 ml
Tiempo
24 hr
Agitao
175 rpm
Temperatura
25 C
pH
4a5
Diluio
C inicial (ppm)
C inicial real
C final (ppm)
% Adsoro

c1v1=C2V2
10.00
9.98
0.174
98.26

Quantidade de material
absorvido (mg)
q ( mg/g)
q/C
log(q)
log(Cf)

9.81

20.00
19.97
0.392
98.04

30.00
29.96
1.259
95.80

19.58

28.70

9.8061
19.5782
56.3893042 49.96988259
0.991496318 1.291772761
-0.759700418 -0.406935568

28.701
22.7966640191
1.4578970287
0.1000257301

1.- Equao de LANGMIUR linearizada

Langmiur Linealizado - Pb
60.00
50.00
40.00
Ce/qe

f(x) = - 0.8537933207x + 58.7082593369


R = 0.8549344124

30.00
20.00
10.00
0.00
0.0

10.0

20.0

30.0

40.0
Ce

2.- Isoterma de Freundlich

50.0

60.0

70.0

Isoterma de Freundlich - Linealizado


2.00
1.80
1.60
log(q)

f(x) = 0.3771886245x + 1.3735885756


R = 0.9668905466

1.40
1.20
1.00
0.80
-1.00

-0.50

0.00

0.50

1.00

Log( Cf)

Comparaco das isotermas:


C
0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000
2.000
3.000
4.000
5.000
6.000
7.000
8.000
9.000
10.000
15.000
20.000
25.000

Lagmiur
0
5.408981186
10.02904096
14.02104861
17.50491979
20.57186909
23.29251197
25.72236896
27.90569446
29.87819636
31.66900421
43.365342
49.45358567
53.18717159
55.71076106
57.53054158
58.9049107
59.97956682
60.84291011
61.55168798
63.78069095
64.95684886
65.68359812

Freundlich
0
9.917449552
12.88096839
15.00963521
16.7300419
18.19916597
19.49479406
20.66193451
21.72929035
22.71644013
23.63741608
30.70071672
35.77421702
39.87466328
43.3761983
46.46422007
49.24600226
51.78995612
54.14274552
56.33781509
65.64801864
73.17260464
79.59814948

Reldich Peterson
0
6.5554374043
11.3219461707
15.0691792685
18.1409152651
20.731172898
22.9614590866
24.9131052178
26.6432179006
28.1933897395
29.594811252
38.9226698497
44.2740869985
47.9666534614
50.7656866753
53.0119551184
54.8848442024
56.4896614426
57.8931854818
59.1402754693
63.884637608
67.2222309581
69.810560078

1.50

S:CONCENTRAOES

Teste feito o da 30 de setem

atomica. Faixa de deteo 1,00 - 8 ppm

do cido hmico:

0.0

1g/L

Eu fiz tudos estes testes com o padro da Merk, que pessoal


da quimica utilizam para a calibrao de seus equipamentos.
No h variao muito significativa entre a concentrao
preparada e a concentrao real.

50.00
49.94
4.722
90.54

80.00
79.90
15.800
80.23

100.00
99.88
25.390
74.58

45.22

64.10

74.49

45.218
64.1
9.576027107 4.056962025
1.65531135 1.80685803
0.674125983 1.198657087

Isot
80
70
60

74.49
2.9338322174
1.8720979743
1.4046627009

50

q (mg/g)

40
30
20
10
0
0.0

Constantes de adsoo
Metal
Pb
60.0

70.0

80.0

q max
mg/g
68.76

0.1426117085

1-X
C

0.8573882915
0.174

C(1-X)

0.1491855627

5.0

ado

Constantes de adsoo
n

Metal
Pb

1.00

1.50

2.65

2.00

KF

B
81.22

g
1.7444

0.8633

90.00
80.00
70.00
60.00
50.00
qe (mg/g)

40.00
30.00
20.00
10.00
0.00
0.00

5.00

10.00

15.00
Ce mg/L

20

Teste feito o da 30 de setembro

q (mg/g)

Isoterma de Adsoro Pb
80
70
60
50
40
30
20
10
0
0.0

5.0

10.0

15.0

20.0

Cf mg/L

Kads
L/mg
0.8538

R2
98.92

mg/L
0.955935051

0.017033454

25.0

30.0

Kf
L/mg
23.64

R2
96.69

Langmiur
Freunlich
Reldich Peterson

10.00

15.00
Ce mg/L

20.00

25.00

30.00

PRIMEIROS TESTES:CONCENTRAOES

Equipamento para deteo de chumbo, espectofotometro de adsoro atomica. Faixa de deteo 1


Pb+2
Relao
1:01
mg AH
50 mg
Concentrao do cido hmico:
Soluo
50 ml
Tiempo
24 hr
Agitao
175 rpm
Temperatura
25 C
pH
4a5
Diluio
C inicial (ppm)
C inicial real
C final (ppm)
% Adsoro

c1v1=C2V2
10.00
9.98
0.174
98.26

Quantidade de material
absorvido (mg)
q ( mg/g)
q/C
log(q)
log(Cf)

9.81

20.00
19.97
0.392
98.04

30.00
29.96
1.259
95.80

19.58

28.70

9.8061
19.5782
56.3893042 49.96988259
0.991496318 1.291772761
-0.759700418 -0.406935568

28.701
22.7966640191
1.4578970287
0.1000257301

1.- Equao de LANGMIUR linearizada

Langmiur Linealizado - Pb

Ce/qe

80.00
70.00
60.00
50.00
40.00
30.00
20.00
10.00
0.00
0.0

f(x) = - 1.0013364964x + 64.635121664


R = 0.8549344124

10.0

20.0

30.0
Ce

2.- Isoterma de Freundlich

40.0

50.0

Isoterma de Freundlich - Linealizado


2.00
1.80
1.60
log(q)

f(x) = 0.3771886245x + 1.3735885756


R = 0.9668905466

1.40
1.20
1.00
0.80
-1.00

-0.50

0.00

0.50

1.00

Log( Cf)

Comparaco das isotermas:


C
0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000
2.000
3.000
4.000
5.000
6.000
7.000
8.000
9.000
10.000
15.000
20.000
25.000

Lagmiur
0
5.868973032
10.76084242
14.90086836
18.4500107
21.52634384
24.21844751
26.59407512
28.7059346
30.59564508
32.29650727
43.07133575
48.46050034
51.69455941
53.85083232
55.39114165
56.5464362
57.44503572
58.16393869
58.75214747
60.59038953
61.55333241
62.14593116

Freundlich
0
9.917449552
12.88096839
15.00963521
16.7300419
18.19916597
19.49479406
20.66193451
21.72929035
22.71644013
23.63741608
30.70071672
35.77421702
39.87466328
43.3761983
46.46422007
49.24600226
51.78995612
54.14274552
56.33781509
65.64801864
73.17260464
79.59814948

Reldich Peterson
0
6.5554374043
11.3219461707
15.0691792685
18.1409152651
20.731172898
22.9614590866
24.9131052178
26.6432179006
28.1933897395
29.594811252
38.9226698497
44.2740869985
47.9666534614
50.7656866753
53.0119551184
54.8848442024
56.4896614426
57.8931854818
59.1402754693
63.884637608
67.2222309581
69.810560078

1.50

S:CONCENTRAOES

Teste feito o da 30 de setem

atomica. Faixa de deteo 1,00 - 8 ppm

do cido hmico:

1g/L

Eu fiz tudos estes testes com o padro da Merk, que pessoal


da quimica utilizam para a calibrao de seus equipamentos.
No h variao muito significativa entre a concentrao
preparada e a concentrao real.

50.00
49.94
4.722
90.54

80.00
79.90
15.800
80.23

100.00
99.88
25.390
74.58

45.22

64.10

74.49

45.218
64.1
9.576027107 4.056962025
1.65531135 1.80685803
0.674125983 1.198657087

Isot
80
70
60

74.49
2.9338322174
1.8720979743
1.4046627009

50

q (mg/g)

40
30
20
10
0
0.0

Constantes de adsoo
Metal
Pb
40.0

50.0

60.0

q max
mg/g
64.64

0.1517150151

1-X
C

0.8482849849
0.174

C(1-X)

0.1476015874

5.0

ado

Constantes de adsoo
n

Metal
Pb

1.00

1.50

2.65

2.00

KF

B
81.22

g
1.7444

0.8633

90.00
80.00
70.00
60.00
50.00
qe (mg/g)

40.00
30.00
20.00
10.00
0.00
0.00

5.00

10.00

15.00
Ce mg/L

20

Teste feito o da 30 de setembro

q (mg/g)

Isoterma de Adsoro Pb
80
70
60
50
40
30
20
10
0
0.0

5.0

10.0

15.0

20.0

Cf mg/L

0.998701688
Kads
L/mg
0.998701688

R2
98.92

mg/L
1.027868452

0.015491607

25.0

30.0

Kf
L/mg
23.64

R2
96.69

Langmiur
Freunlich
Reldich Peterson

10.00

15.00
Ce mg/L

20.00

25.00

30.00

PRIMEIROS TESTES:CONCENTRAOES

Equipamento para deteo de chumbo, espectofotometro de adsoro atomica. Faixa de deteo 1


Pb+2
Relao
1:01
mg AH
50 mg
Concentrao do cido hmico:
Soluo
50 ml
Tiempo
24 hr
Agitao
175 rpm
Temperatura
25 C
pH
4a5
Diluio
C inicial (ppm)
C inicial real
C final (ppm)
% Adsoro

c1v1=C2V2
10.00
9.98
0.174
98.26

Quantidade de material
absorvido (mg)
q ( mg/g)
1/C
1/q
log(q)
log(Cf)

9.81

20.00
19.97
0.392
98.04

30.00
29.96
1.259
95.80

19.58

28.70

9.8061
19.5782
5.750431282 2.552322614
0.101977341 0.051077219
0.991496318 1.291772761
-0.759700418 -0.406935568

28.701
0.7942811755
0.0348419916
1.4578970287
0.1000257301

1.- Equao de LANGMIUR linearizada

Langmiur Linealizado - Pb
0.12
0.10
0.08
Ce/qe

f(x) = 0.0147332625x + 0.0167291636


R = 0.9863777479

0.06
0.04
0.02

0.00
0.0

1.0

2.0

3.0

4.0
Ce

2.- Isoterma de Freundlich

5.0

6.0

Isoterma de Freundlich - Linealizado


2.00
1.80
1.60
log(q)

f(x) = 0.3771886245x + 1.3735885756


R = 0.9668905466

1.40
1.20
1.00
0.80
-1.00

-0.50

0.00

0.50

1.00

Log( Cf)

Comparaco das isotermas:


C
0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000
2.000
3.000
4.000
5.000
6.000
7.000
8.000
9.000
10.000
15.000
20.000
25.000

Lagmiur
0
6.10870902
11.0864268
15.22063505
18.70899429
21.69188207
24.27174221
26.52508735
28.51021541
30.27232542
31.84700083
41.57987054
46.29610721
49.079555
50.91629045
52.21910979
53.19127439
53.94448891
54.54523456
55.03555146
56.56085856
57.355663
57.84335883

Freundlich
0
9.917449552
12.88096839
15.00963521
16.7300419
18.19916597
19.49479406
20.66193451
21.72929035
22.71644013
23.63741608
30.70071672
35.77421702
39.87466328
43.3761983
46.46422007
49.24600226
51.78995612
54.14274552
56.33781509
65.64801864
73.17260464
79.59814948

Reldich Peterson
0
6.5554374043
11.3219461707
15.0691792685
18.1409152651
20.731172898
22.9614590866
24.9131052178
26.6432179006
28.1933897395
29.594811252
38.9226698497
44.2740869985
47.9666534614
50.7656866753
53.0119551184
54.8848442024
56.4896614426
57.8931854818
59.1402754693
63.884637608
67.2222309581
69.810560078

1.50

S:CONCENTRAOES

Teste feito o da 30 de setem

atomica. Faixa de deteo 1,00 - 8 ppm

do cido hmico:

1g/L

Eu fiz tudos estes testes com o padro da Merk, que pessoal


da quimica utilizam para a calibrao de seus equipamentos.
No h variao muito significativa entre a concentrao
preparada e a concentrao real.

50.00
49.94
4.722
90.54

80.00
79.90
15.800
80.23

100.00
99.88
25.390
74.58

45.22

64.10

74.49

45.218
0.211774672
0.022115087
1.65531135
0.674125983

64.1
0.063291139
0.015600624
1.80685803
1.198657087

Isot
80
70
60

74.49
0.0393855849
0.0134246208
1.8720979743
1.4046627009

50

q (mg/g)

40
30
20
10
0
0.0

1.136054422
59.880239521

Constantes de adsoo
Metal
Pb
5.0

6.0

7.0

q max
mg/g
59.88

0.1637625251

1-X
C

0.8362374749
0.174

C(1-X)

0.1455053206

5.0

ado

Constantes de adsoo
n

Metal
Pb

1.00

1.50

2.65

2.00

KF

B
81.22

g
1.7444

0.8633

90.00
80.00
70.00
60.00
50.00
qe (mg/g)

40.00
30.00
20.00
10.00
0.00
0.00

5.00

10.00

15.00
Ce mg/L

20

Teste feito o da 30 de setembro

q (mg/g)

Isoterma de Adsoro Pb
80
70
60
50
40
30
20
10
0
0.0

5.0

10.0

15.0

20.0

25.0

30.0

Cf mg/L

0.998701688
Kads
L/mg
1.136054

R2

0.014700064

98.92

mg/L
1.12547448

Cf
0.174
0.392
1.259
4.722
15.800
25.390

q
9.8061
19.5782
28.701
45.218
64.1
74.49

x
1-x
0.163762525 0.836237475
0.326957248 0.673042752
0.479308617 0.520691383
0.755143621 0.244856379
1.070474282 -0.070474282
1.243987976 -0.243987976

Kf
L/mg
23.64

R2
96.69

Langmiur
Freunlich
Reldich Peterson

10.00

15.00
Ce mg/L

20.00

25.00

30.00

c*(1-x)
Kads
0.145421697 1.126121676
0.26369815 1.239892079
0.655550451 0.731154431
1.156211824 0.65311875
-1.113493654 -0.961365409
-6.194854709 -0.200809871

c
0.1739
0.3918
1.259
4.722
15.8
25.39

qe
Q
B
qm
(qm-qe)^2
9.8061
76.9246228 0.44229305 5.49406433 1212.53586
19.5782
11.3614666 838.338945
28.701
27.5140992 163.877143
45.218
52.0178948 136.944875
64.1
67.2948774 727.884105
74.49
70.6347003 919.250875
40.31555
3998.83181

(qm-qe)^2 acima
abaixo
r^2
18.5936516 3998.83181 4157.65805 0.96179911
67.5147077
1.40873352
46.2385698
10.2072413
Chart
14.8633357
80
158.82624
70

Title

f(x) = 12.5948632075 ln(x) + 29.6295707709


R = 0.9829737495

60
50
40
30
20
10
0

10

15

20

25

30

20

25

30

c
0.1739
0.3918
1.259
4.722
15.8
25.39

qe
kf
n
qm
(qm-qe)^2
9.8061
25.4302422 2.96474272 14.0963126 687.448407
19.5782
18.5392512 474.20719
28.701
27.484568
164.6341
45.218
42.9270886 6.82013411
64.1
64.5140655 585.568154
74.49
75.7076156 1252.59831
40.31555
3171.27629

(qm-qe)^2 acima
abaixo
r^2
18.4059245 3171.27629 3199.14365 0.99128912
1.07941463
1.47970686
5.24827482
0.17145026
1.48258769
27.8673588

2.65111347

Chart Title
80

f(x) = 23.6367942939 x^0.3771886245


R = 0.9668905466

70
60
50
40
30
20
10
0

10

15

Chart Title

939 x^0.3771886245
6

10

15

20

25

30

Ce

lnCe
0.174
0.392
1.259
4.722
15.800
25.390

A
-1.749
-0.937
0.230
1.552
2.760
3.234

81.220

RESUMO DOS RESULTADOS


Estatstica de regresso
R mltiplo
0.9961534252
R-Quadrado
0.9923216464
R-quadrado ajusta
0.9904020581
Erro padro
0.1704865166
Observaes
6
ANOVA
gl
Regresso
Resduo
Total

Interseo
Varivel X 1

SQ
1
4
5

15.025344052
0.1162626093
15.1416066613

Coeficientes
0.5564294235
0.8633098649

Erro padro
0.0766949563
0.0379703437

RESULTADOS DE RESDUOS
Observao
1
2
3
4
5
6

Y previsto
-0.9537368175
-0.2524951776
0.7552650135
1.8964870004
2.9391732319
3.3486803431

Resduos
0.0831571402
-0.2567245066
0.1647329942
0.0987839299
-0.0096240968
-0.0803254609

ln(qe)
qe
-0.820
-0.469
0.941
2.012
2.945
3.284
7.893

B
9.8061
19.5782
28.701
45.218
64.1
74.49

G
1.7444

0.8633

ln(qm)
Qe
Acima
-0.9537383276 1.3155831 5.1498199
-0.2525047007
2.4588994
0.7552439749
0.31398
1.8964529213
0.3374097
2.9391272382
2.6358955
3.3486296701
4.1332782
15.029283

Reldich - Peterson Linealizado


4.0
3.0
2.0
ln ( KF Ce/qe - 1)

f(x) = 0.8566138052x + 0.5887981552


R = 0.9924925692

1.0
0.0
-1.0
-2.0
-2.0

-1.0

0.0

1.0

2.0

3.0

ln (Ce)

MQ
F
F de significao
15.025344 516.945013926 2.22E-005
0.0290657

Stat t
valor-P
95% inferiores
95% superioresInferior 99.0%Superior 99.0%
7.255098 0.0019163783 0.3434901 0.7693688 0.2033185684 0.9095403
22.736425 2.216575E-005 0.7578873 0.9687324 0.6884908002 1.0381289

4.0

RESULTADOS DE PROBABILIDADE
Resduos padro
0.5453364
-1.683574
1.0803029
0.6478154
-0.063114
-0.526767

Percentil
Y
8.3333333 -0.87058
25 -0.50922
41.666667 0.919998
58.333333 1.9952709
75 2.9295491
91.666667 3.2683549

1.7444327

Abaixo2
r^2
0.0178328
0.99227
0.0470424
0.0345429
0.0134544
4.04E-005
0.0041691
0.117082

n
2.65

0.99227

Kf
L/mg
23.64

0.2

Varivel X 1 Plotagem
de resduos
0.1

0
Varivel
X0.21
Plotagem
de 3.000
ajuste
-1.000
0.000
1.000
2.000
4.0

Resduos -2.000

0
-0.1
4.000
0.000
1.000
2.000
-0.2
2.000
4
Y
-0.3
-0.4
0.000
Varivel
X 1 2.000
2
-2.000 -1.000
0.000
1.000
Y -2.000
0
Varivel
0
10
20 X 130
-2

Resduos -2.000

3.000
4.0
Plotagem de probabili

-1.000

3.000
40

4.000
50

Percentil da amo

e resduos

m
de 3.000
ajuste
de linha
2.000
4.000

3.000
4.000
e probabilidade
normal

2.000

Y previsto

2.000

3.000

130

40

4.000
50

60

Percentil da amostra

70

80

90

100

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