Fe(+3a) + H3AsO4(a) = FeAsO4 + 3H(+a)

1/T T deltaH deltaS deltaG K Log(K)

K kJ J/K kJ
0.0035951825 278.150 84.721 247.843 15.784 1.086E-003 -2.964
0.003531697 283.150 85.302 249.914 14.539 2.078E-003 -2.682
0.0034704147 288.150 85.820 251.728 13.285 3.905E-003 -2.408
0.0034112229 293.150 86.293 253.354 12.022 7.206E-003 -2.142
0.0033540164 298.150 86.734 254.847 10.752 1.307E-002 -1.884
0.003298697 303.150 87.157 256.252 9.474 2.331E-002 -1.633
0.0032451728 308.150 87.569 257.602 8.189 4.090E-002 -1.388
0.0031933578 313.150 87.979 258.920 6.898 7.069E-002 -1.151
0.0031431715 318.150 88.390 260.224 5.600 1.204E-001 -0.919
0.0030945381 323.150 88.806 261.522 4.296 2.021E-001 -0.694
0.0030473869 328.150 89.228 262.817 2.985 3.349E-001 -0.475
0.0030016509 333.150 89.655 264.108 1.667 5.477E-001 -0.261
0.0029572675 338.150 90.090 265.404 0.344 8.850E-001 -0.053
0.0029141775 343.150 90.539 266.722 -0.987 1.413E+000 0.150
0.0028723251 348.150 91.002 268.063 -2.324 2.232E+000 0.349
0.0028316579 353.150 91.482 269.431 -3.667 3.487E+000 0.542
0.0027921262 358.150 91.980 270.831 -5.018 5.394E+000 0.732
0.0027536831 363.150 92.497 272.265 -6.376 8.263E+000 0.917
0.0027162841 368.150 93.036 273.738 -7.741 1.254E+001 1.098
0.0026798874 373.150 93.598 275.255 -9.113 1.887E+001 1.276

ESTIMACION LINEAL
B' A'
-4634.229 13.664
13.766 0.043
1.000 0.017
113329.952 18.000
32.869 0.005

A' B'
logk1 = A' + B'(1/T) 13.664 -4634.229
logk2 = A' + B'(1/T) 8.516 -2452.804
logk3 = A' + B'(1/T) 12.432 -2945.219
logk4 = A' + B'(1/T) 6.936 624.457
logk5 = A' + B'(1/T) 13.873 578.681
logk6 = A' + B'(1/T) 16.172 2745.957
logk7 = A' + B'(1/T) 25.637 3388.474
T (°C) T(K) 1/T logk1 logk2 logk3 logk4
5 278.15 0.00359518 -2.9966282 -0.3023346 1.84331193 9.18136678
25 298.15 0.00335402 -1.8790096 0.28919837 2.55359865 9.03076885
95 368.15 0.00271628 1.07638817 1.85343067 4.43185989 8.63253215
 FeOH(+2a) + H3AsO4(a) = FeAsO4 + H2O + 2H(+a)
1/T T deltaH deltaS deltaG K Log(K)
K kJ J/K kJ
0.00359518 278.150 41.689 144.931 1.376 5.516E-001 -0.258
0.0035317 283.150 42.358 147.316 0.645 7.603E-001 -0.119
0.00347041 288.150 42.994 149.544 -0.097 1.041E+000 0.018
0.00341122 293.150 43.607 151.653 -0.850 1.417E+000 0.151
0.00335402 298.150 44.204 153.672 -1.613 1.917E+000 0.283
0.0032987 303.150 44.791 155.624 -2.387 2.578E+000 0.411
0.00324517 308.150 45.373 157.528 -3.170 3.446E+000 0.537
0.00319336 313.150 45.953 159.396 -3.962 4.580E+000 0.661
0.00314317 318.150 46.534 161.238 -4.763 6.055E+000 0.782
0.00309454 323.150 47.118 163.059 -5.574 7.963E+000 0.901
0.00304739 328.150 47.705 164.862 -6.394 1.042E+001 1.018
0.00300165 333.150 48.295 166.645 -7.223 1.357E+001 1.133
0.00295727 338.150 48.889 168.415 -8.060 1.759E+001 1.245
0.00291418 343.150 49.491 170.181 -8.907 2.270E+001 1.356
0.00287233 348.150 50.100 171.944 -9.762 2.916E+001 1.465
0.00283166 353.150 50.718 173.706 -10.626 3.732E+001 1.572
0.00279213 358.150 51.345 175.470 -11.499 4.756E+001 1.677
0.00275368 363.150 51.983 177.238 -12.381 6.040E+001 1.781
0.00271628 368.150 52.632 179.014 -13.272 7.642E+001 1.883
0.00267989 373.150 53.294 180.799 -14.171 9.636E+001 1.984

B' A'
-2452.804 8.516
18.744 0.058
0.999 0.023
17124.399 18.000
9.208 0.010
logk5 logk6 logk7 k1 k2 k3 k4 k5
15.9532704 26.0442802 37.8193802 0.00100779 0.49850029 69.7127046 1518332109 8.97988E+15
15.8137123 25.3820486 37.0021955 0.01321266 1.94624885 357.765657 1073417952 6.51197E+15
15.4446689 23.630863 34.8412563 11.9230721 71.356028 27030.8618 429073954 2.784E+15
 FeOH(+2a) + H2AsO4(-a) = FeAsO4 + H2O + H(+a)
1/T T deltaH deltaS deltaG K Log(K)
K kJ J/K kJ
0.003595182 278.150 46.203 202.980 -10.256 8.438E+001 1.926
0.003531697 283.150 47.603 207.971 -11.284 1.207E+002 2.082
0.003470415 288.150 48.898 212.504 -12.335 1.723E+002 2.236
0.003411223 293.150 50.114 216.690 -13.408 2.451E+002 2.389
0.003354016 298.150 51.275 220.616 -14.502 3.474E+002 2.541
0.003298697 303.150 52.398 224.351 -15.614 4.905E+002 2.691
0.003245173 308.150 53.497 227.948 -16.745 6.898E+002 2.839
0.003193358 313.150 54.584 231.446 -17.894 9.660E+002 2.985
0.003143171 318.150 55.665 234.871 -19.059 1.347E+003 3.129
0.003094538 323.150 56.745 238.240 -20.242 1.872E+003 3.272
0.003047387 328.150 57.826 241.559 -21.442 2.590E+003 3.413
0.003001651 333.150 58.906 244.826 -22.658 3.571E+003 3.553
0.002957267 338.150 59.991 248.060 -23.890 4.905E+003 3.691
0.002914177 343.150 61.089 251.282 -25.138 6.713E+003 3.827
0.002872325 348.150 62.201 254.499 -26.403 9.155E+003 3.962
0.002831658 353.150 63.329 257.717 -27.683 1.244E+004 4.095
0.002792126 358.150 64.476 260.940 -28.980 1.686E+004 4.227
0.002753683 363.150 65.643 264.176 -30.293 2.278E+004 4.358
0.002716284 368.150 66.833 267.432 -31.622 3.069E+004 4.487
0.002679887 373.150 68.050 270.713 -32.967 4.123E+004 4.615

B' A'
-2945.219 12.432
34.914 0.108
0.997 0.043
7116.094 18.000
13.276 0.034
k6 k7
1.10734E+26 6.59751E+37
2.41018E+25 1.00507E+37
4.27428E+23 6.93835E+34
 Fe(OH)O(a) + H2AsO4(-a) + H(+a) = FeAsO4 + 2H2O
1/T T deltaH deltaS deltaG K Log(K)
K kJ J/K kJ
0.00359518 278.150 -37.181 45.923 -49.954 2.409E+009 9.382
0.0035317 283.150 -33.553 58.850 -50.217 1.839E+009 9.265
0.00347041 288.150 -30.202 70.583 -50.541 1.454E+009 9.163
0.00341122 293.150 -27.067 81.369 -50.921 1.186E+009 9.074
0.00335402 298.150 -24.100 91.407 -51.353 9.945E+008 8.998
0.0032987 303.150 -21.259 100.856 -51.834 8.552E+008 8.932
0.00324517 308.150 -18.514 109.838 -52.361 7.524E+008 8.876
0.00319336 313.150 -15.841 118.443 -52.932 6.760E+008 8.830
0.00314317 318.150 -13.224 126.734 -53.545 6.192E+008 8.792
0.00309454 323.150 -10.654 134.751 -54.199 5.774E+008 8.762
0.00304739 328.150 -8.127 142.512 -54.892 5.475E+008 8.738
0.00300165 333.150 -5.646 150.015 -55.623 5.271E+008 8.722
0.00295727 338.150 -3.193 157.322 -56.392 5.148E+008 8.712
0.00291418 343.150 -0.761 164.463 -57.196 5.096E+008 8.707
0.00287233 348.150 1.656 171.454 -58.036 5.107E+008 8.708
0.00283166 353.150 4.059 178.309 -58.911 5.179E+008 8.714
0.00279213 358.150 6.453 185.039 -59.819 5.310E+008 8.725
0.00275368 363.150 8.839 191.656 -60.761 5.501E+008 8.740
0.00271628 368.150 11.221 198.171 -61.735 5.754E+008 8.760
0.00267989 373.150 13.602 204.595 -62.742 6.076E+008 8.784

B' A'
624.457 6.936
82.248 0.256
0.762 0.102
57.645 18.000
0.597 0.186
 Fe(OH)O(a) + HAsO4(-2a) + 2H(+a) = FeAsO4 + 2H2O
1/T T deltaH deltaS deltaG K Log(K)
K kJ J/K kJ
0.00359518 278.150 -44.955 148.912 -86.374 1.667E+016 16.222
0.0035317 283.150 -40.027 166.474 -87.164 1.205E+016 16.081
0.00347041 288.150 -35.503 182.314 -88.036 9.124E+015 15.960
0.00341122 293.150 -31.292 196.801 -88.985 7.194E+015 15.857
0.00335402 298.150 -27.322 210.233 -90.003 5.880E+015 15.769
0.0032987 303.150 -23.530 222.846 -91.086 4.965E+015 15.696
0.00324517 308.150 -19.870 234.822 -92.230 4.318E+015 15.635
0.00319336 313.150 -16.306 246.295 -93.433 3.857E+015 15.586
0.00314317 318.150 -12.814 257.358 -94.692 3.533E+015 15.548
0.00309454 323.150 -9.380 268.069 -96.006 3.311E+015 15.520
0.00304739 328.150 -5.998 278.452 -97.372 3.169E+015 15.501
0.00300165 333.150 -2.674 288.507 -98.790 3.094E+015 15.491
0.00295727 338.150 0.618 298.316 -100.257 3.077E+015 15.488
0.00291418 343.150 3.894 307.932 -101.773 3.114E+015 15.493
0.00287233 348.150 7.159 317.377 -103.336 3.201E+015 15.505
0.00283166 353.150 10.417 326.670 -104.946 3.342E+015 15.524
0.00279213 358.150 13.675 335.830 -106.603 3.539E+015 15.549
0.00275368 363.150 16.936 344.873 -108.304 3.798E+015 15.580
0.00271628 368.150 20.207 353.818 -110.051 4.129E+015 15.616
0.00267989 373.150 23.492 362.682 -111.842 4.543E+015 15.657

B' A'
578.681 13.873
110.283 0.343
0.605 0.136
27.533 18.000
0.513 0.335
 FeO2(-a) + HAsO4(-2a) + 3H(+a) = FeAsO4 + 2H2O
1/T T deltaH deltaS deltaG K Log(K)
K kJ J/K kJ
0.00359518 278.150 -83.312 203.739 -139.982 1.949E+026 26.290
0.0035317 283.150 -78.897 219.472 -141.041 1.049E+026 26.021
0.00347041 288.150 -74.842 233.672 -142.174 5.956E+025 25.775
0.00341122 293.150 -71.062 246.679 -143.376 3.543E+025 25.549
0.00335402 298.150 -67.488 258.767 -144.640 2.200E+025 25.342
0.0032987 303.150 -64.065 270.155 -145.962 1.420E+025 25.152
0.00324517 308.150 -60.748 281.008 -147.340 9.501E+024 24.978
0.00319336 313.150 -57.504 291.449 -148.772 6.573E+024 24.818
0.00314317 318.150 -54.312 301.564 -150.254 4.690E+024 24.671
0.00309454 323.150 -51.156 311.404 -151.787 3.445E+024 24.537
0.00304739 328.150 -48.034 320.991 -153.368 2.600E+024 24.415
0.00300165 333.150 -44.949 330.323 -154.996 2.013E+024 24.304
0.00295727 338.150 -41.879 339.470 -156.671 1.597E+024 24.203
0.00291418 343.150 -38.807 348.488 -158.391 1.295E+024 24.112
0.00287233 348.150 -35.729 357.394 -160.155 1.074E+024 24.031
0.00283166 353.150 -32.638 366.208 -161.964 9.084E+023 23.958
0.00279213 358.150 -29.530 374.946 -163.817 7.835E+023 23.894
0.00275368 363.150 -26.400 383.627 -165.714 6.885E+023 23.838
0.00271628 368.150 -23.240 392.267 -167.654 6.157E+023 23.789
0.00267989 373.150 -20.047 400.884 -169.636 5.600E+023 23.748

B' A'
2745.957 16.172
101.577 0.316
0.976 0.126
730.795 18.000
11.540 0.284
 FeO2(-a) + AsO4(-3a) + 4H(+a) = FeAsO4 + 2H2O
1/T T deltaH deltaS deltaG K Log(K)
K kJ J/K kJ
0.00359518 278.150 -108.182 341.621 -203.204 1.457E+038 38.163
0.0035317 283.150 -101.863 364.140 -204.969 6.535E+037 37.815
0.00347041 288.150 -96.088 384.360 -206.841 3.151E+037 37.498
0.00341122 293.150 -90.731 402.792 -208.810 1.621E+037 37.210
0.00335402 298.150 -85.688 419.851 -210.867 8.833E+036 36.946
0.0032987 303.150 -80.875 435.864 -213.007 5.075E+036 36.705
0.00324517 308.150 -76.224 451.081 -215.224 3.061E+036 36.486
0.00319336 313.150 -71.686 465.688 -217.517 1.930E+036 36.286
0.00314317 318.150 -67.228 479.813 -219.881 1.269E+036 36.104
0.00309454 323.150 -62.829 493.532 -222.314 8.676E+035 35.938
0.00304739 328.150 -58.483 506.880 -224.815 6.150E+035 35.789
0.00300165 333.150 -54.194 519.851 -227.382 4.511E+035 35.654
0.00295727 338.150 -49.931 532.553 -230.013 3.416E+035 35.534
0.00291418 343.150 -45.667 545.068 -232.707 2.666E+035 35.426
0.00287233 348.150 -41.397 557.423 -235.464 2.141E+035 35.331
0.00283166 353.150 -37.112 569.644 -238.281 1.767E+035 35.247
0.00279213 358.150 -32.803 581.759 -241.160 1.497E+035 35.175
0.00275368 363.150 -28.463 593.793 -244.099 1.299E+035 35.114
0.00271628 368.150 -24.083 605.772 -247.098 1.154E+035 35.062
0.00267989 373.150 -19.655 617.719 -250.157 1.049E+035 35.021

B' A'
3388.474 25.637
141.834 0.441
0.969 0.175
570.751 18.000
17.573 0.554
T (°C) T(K) 1/T logk1 logk2 logk3 logk4
5 278.15 0.00359518 -2.9966282 -0.302334586 1.8433119321 9.1813667763
25 298.15 0.00335402 -1.8790096 0.2891983695 2.5535986494 9.0307688544
95 368.15 0.00271628 1.07638817 1.8534306675 4.4318598919 8.6325321522

∑[As(5+)] (1/[Fe]T)*([H+]^3/k1+[H+]^2/k2+[H+]/k3+1/k4[H+]+1/k5[H+]^2+1/k6[H+]^3+1/k7[H+]^4)

pH [H+] [H3AsO4] I [H3AsO4] II [H2AsO4(-)] I [H2AsO4(-)] II [HAsO4(2-)] I

0 1 992266.274 2006.01689 14.344587629 6.5861744E-07 1.113601E-13
0.5 0.31622777 31378.2147 200.601689 4.5361569002 2.0827312E-06 1.113601E-12
1 0.1 992.266274 20.0601689 1.4344587629 6.5861744E-06 1.113601E-11
1.5 0.03162278 31.3782147 2.00601689 0.45361569 2.0827312E-05 1.113601E-10
2 0.01 0.99226627 0.20060169 0.1434458763 6.5861744E-05 1.113601E-09
2.5 0.00316228 0.03137821 0.02006017 0.045361569 0.0002082731 1.113601E-08
3 0.001 0.00099227 0.00200602 0.0143445876 0.0006586174 1.113601E-07
3.5 0.00031623 3.1378E-05 0.0002006 0.0045361569 0.0020827312 1.113601E-06
4 0.0001 9.9227E-07 2.006E-05 0.0014344588 0.0065861744 0.000011136
4.5 3.1623E-05 3.1378E-08 2.006E-06 0.0004536157 0.020827312 0.0001113601
5 0.00001 9.9227E-10 2.006E-07 0.0001434459 0.0658617436 0.0011136008
5.5 3.1623E-06 3.1378E-11 2.006E-08 4.536157E-05 0.2082731204 0.0111360084
6 0.000001 9.9227E-13 2.006E-09 1.434459E-05 0.6586174357 0.1113600844
6.5 3.1623E-07 3.1378E-14 2.006E-10 4.536157E-06 2.0827312036 1.113600844
7 0.0000001 9.9227E-16 2.006E-11 1.434459E-06 6.5861743574 11.13600844
7.5 3.1623E-08 3.1378E-17 2.006E-12 4.536157E-07 20.827312036 111.3600844
8 0.00000001 9.9227E-19 2.006E-13 1.434459E-07 65.861743574 1113.600844
8.5 3.1623E-09 3.1378E-20 2.006E-14 4.536157E-08 208.27312036 11136.00844
9 1E-09 9.9227E-22 2.006E-15 1.434459E-08 658.61743574 111360.0844
9.5 3.1623E-10 3.1378E-23 2.006E-16 4.536157E-09 2082.7312036 1113600.844
10 1E-10 9.9227E-25 2.006E-17 1.434459E-09 6586.1743574 11136008.44
10.5 3.1623E-11 3.1378E-26 2.006E-18 4.536157E-10 20827.312036 111360084.4
11 1E-11 9.9227E-28 2.006E-19 1.434459E-10 65861.743574 1113600844
11.5 3.1623E-12 3.1378E-29 2.006E-20 4.536157E-11 208273.12036 11136008440
12 1E-12 9.9227E-31 2.006E-21 1.434459E-11 658617.43574 111360084395
12.5 3.1623E-13 3.1378E-32 2.006E-22 4.536157E-12 2082731.2036 1.113601E+12
13 1E-13 9.9227E-34 2.006E-23 1.434459E-12 6586174.3574 1.113601E+13
13.5 3.1623E-14 3.1378E-35 2.006E-24 4.536157E-13 20827312.036 1.113601E+14
14 1E-14 9.9227E-37 2.006E-25 1.434459E-13 65861743.574 1.113601E+15
 logk5 logk6 logk7 k1 k2 k3 k4 k5
15.953270449 26.04428017 37.8193802 0.00100779 0.49850029 69.7127046 1518332108.7 8.979878E+15
15.813712313 25.3820486 37.0021955 0.01321266 1.94624885 357.765657 1073417952.4 6.511969E+15
15.444668895 23.630863 34.8412563 11.9230721 71.356028 27030.8618 429073953.75 2.783998E+15

3+1/k7[H+]^4) [Fe]T 0.001 ∑[As(5+)] 0.01

PREDOMINANCIA
[HAsO4(2-)] II [AsO4(3-)] ∑[As(5+)] [H3AsO4] I [H3AsO4] II [H2AsO4(-)] I[H2AsO4(-)] II [HAsO4(2-)] I
9.0306671E-24 1.515723E-35 994286.636 99.79680% 0.20175% 0.00144% 0.00000% 0.00000%
2.8557477E-22 1.515723E-33 31583.3526 99.35049% 0.63515% 0.01436% 0.00000% 0.00000%
9.0306671E-21 1.515723E-31 1013.76091 97.87971% 1.97879% 0.14150% 0.00000% 0.00000%
2.8557477E-19 1.515723E-29 33.8378681 92.73106% 5.92832% 1.34056% 0.00006% 0.00000%
9.0306671E-18 1.515723E-27 1.3363797 74.25033% 15.01083% 10.73392% 0.00493% 0.00000%
2.8557477E-16 1.515723E-25 0.09700824 32.34593% 20.67883% 46.76053% 0.21470% 0.00001%
9.0306671E-15 1.515723E-23 0.0180016 5.51210% 11.14355% 79.68507% 3.65866% 0.00062%
2.8557477E-13 1.515723E-21 0.00685198 0.45794% 2.92764% 66.20212% 30.39604% 0.01625%
9.0306671E-12 1.515723E-19 0.00805282 0.01232% 0.24911% 17.81312% 81.78716% 0.13829%
2.8557477E-10 1.515723E-17 0.02139433 0.00015% 0.00938% 2.12026% 97.34970% 0.52051%
0.000000009 1.515723E-15 0.067119 0.00000% 0.00030% 0.21372% 98.12682% 1.65914%
2.8557477E-07 1.515723E-13 0.2194548 0.00000% 0.00001% 0.02067% 94.90479% 5.07440%
9.0306671E-06 1.515723E-11 0.7700009 0.00000% 0.00000% 0.00186% 85.53463% 14.46233%
0.0002855748 1.515723E-09 3.19662216 0.00000% 0.00000% 0.00014% 65.15413% 34.83680%
0.0090306671 1.515723E-07 17.7312151 0.00000% 0.00000% 0.00001% 37.14452% 62.80454%
0.2855747684 1.515723E-05 132.472987 0.00000% 0.00000% 0.00000% 15.72193% 84.06248%
9.030667104 0.001515723 1188.49477 0.00000% 0.00000% 0.00000% 5.54161% 93.69842%
285.57476839 0.151572274 11630.0079 0.00000% 0.00000% 0.00000% 1.79083% 95.75237%
9030.667104 15.15722736 121064.526 0.00000% 0.00000% 0.00000% 0.54402% 91.98407%
285574.76839 1515.722736 1402774.07 0.00000% 0.00000% 0.00000% 0.14847% 79.38562%
9030667.104 151572.2736 20324834 0.00000% 0.00000% 0.00000% 0.03240% 54.79016%
285574768.39 15157227.36 412112907 0.00000% 0.00000% 0.00000% 0.00505% 27.02174%
9030667104 1515722736 1.166E+10 0.00000% 0.00000% 0.00000% 0.00056% 9.55056%
285574768393 1.51572E+11 4.4828E+11 0.00000% 0.00000% 0.00000% 0.00005% 2.48415%
9.030667E+12 1.51572E+13 2.4299E+13 0.00000% 0.00000% 0.00000% 0.00000% 0.45829%
2.855748E+14 1.51572E+15 1.8024E+15 0.00000% 0.00000% 0.00000% 0.00000% 0.06178%
9.030667E+15 1.51572E+17 1.6061E+17 0.00000% 0.00000% 0.00000% 0.00000% 0.00693%
2.855748E+17 1.51572E+19 1.5443E+19 0.00000% 0.00000% 0.00000% 0.00000% 0.00072%
9.030667E+18 1.51572E+21 1.5248E+21 0.00000% 0.00000% 0.00000% 0.00000% 0.00007%

Diagrama de Predominancia a 5°C

120.00000%
 Diagrama de Predominancia a 5°C
120.00000%

100.00000%

80.00000% [
[
[
[
60.00000% [
[
[

40.00000%

20.00000%

0.00000%
0 2 4 6 8 10 12 14
 k6 k7
1.107338E+26 6.59751E+37
2.410175E+25 1.00507E+37
4.27428E+23 6.93835E+34

A BJERRUM
[HAsO4(2-)] II [AsO4(3-)] log[H3AsO4] log[H3AsO4] II log[H2AsO4(-)] I log[H2AsO4(-)] II
0.00000% 0.00000% -2.00088 -4.69518 -6.84082 -14.17888
0.00000% 0.00000% -2.00283 -4.19712 -5.84277 -12.18083
0.00000% 0.00000% -2.00931 -3.70360 -4.84925 -10.18730
0.00000% 0.00000% -2.03277 -3.22707 -3.87271 -8.21077
0.00000% 0.00000% -2.12930 -2.82360 -2.96924 -6.30730
0.00000% 0.00000% -2.49018 -2.68447 -2.33012 -4.66818
0.00000% 0.00000% -3.25868 -2.95298 -2.09862 -3.43668
0.00000% 0.00000% -4.33919 -3.53348 -2.17913 -2.51718
0.00000% 0.00000% -5.90932 -4.60361 -2.74926 -2.08731
0.00000% 0.00000% -7.83367 -6.02796 -3.67361 -2.01167
0.00001% 0.00000% -9.83022 -7.52451 -4.67016 -2.00821
0.00013% 0.00000% -11.84472 -9.03901 -5.68466 -2.02271
0.00117% 0.00000% -13.88986 -10.58416 -6.72980 -2.06786
0.00893% 0.00000% -16.00806 -12.20236 -7.84800 -2.18606
0.05093% 0.00000% -18.25211 -13.94640 -9.09205 -2.43011
0.21557% 0.00001% -20.62550 -15.81979 -10.46544 -2.80349
0.75984% 0.00013% -23.07837 -17.77266 -11.91831 -3.25636
2.45550% 0.00130% -25.56895 -19.76325 -13.40889 -3.74695
7.45938% 0.01252% -28.08639 -21.78068 -14.92633 -4.26438
20.35786% 0.10805% -30.65036 -23.84465 -16.49030 -4.82835
44.43169% 0.74575% -33.31140 -26.00569 -18.15134 -5.48939
69.29527% 3.67793% -36.11839 -28.31268 -19.95833 -6.29638
77.44960% 12.99927% -39.07007 -30.76437 -21.91001 -7.24807
63.70409% 33.81172% -42.15492 -33.34922 -23.99486 -8.33292
37.16438% 62.37733% -45.38896 -36.08326 -26.22890 -9.56696
15.84404% 84.09417% -48.75923 -38.95352 -28.59917 -10.93722
5.62259% 94.37048% -52.20916 -41.90345 -31.04910 -12.38715
1.84923% 98.15005% -55.69210 -44.88639 -33.53204 -13.87010
0.59227% 99.40766% -59.18657 -47.88087 -36.02651 -15.36457

Diagrama de Bjerrum a 5°C

0.00000
0 2 4 6 8 10 12 14

-10.00000
 Diagrama de Bjerrum a 5°C
0.00000
0 2 4 6 8 10 12 14

-10.00000

-20.00000
[H3As O4] I
[H3As O4] II
[H2As O4(-)] I
[H2As O4(-)] II -30.00000
[HAs O4(2-)] I
[HAs O4(2-)] II
[As O4(3-)] -40.00000

-50.00000

-60.00000

12 14 -70.00000
 M(As) ECA (mg/L)
74.92 A-1
A-3

BJERRUM SOLUBILID
log[HAsO4(2-)] I log[HAsO4(2-)] II log[AsO4(3-)] log[H3AsO4] I log[H3AsO4] II log[H2AsO4(-)] I
-20.95078 -31.04179 -42.81689 5.9966282306 3.302334586 1.1566880679
-18.45273 -28.04374 -39.31884 4.4966282306 2.302334586 0.6566880679
-15.95921 -25.05022 -35.82532 2.9966282306 1.302334586 0.1566880679
-13.48267 -22.07368 -32.34878 1.4966282306 0.302334586 -0.3433119321
-11.07920 -19.17021 -28.94531 -0.0033717694 -0.697665414 -0.8433119321
-8.94008 -16.53109 -25.80619 -1.5033717694 -1.697665414 -1.3433119321
-7.20858 -14.29959 -23.07469 -3.0033717694 -2.697665414 -1.8433119321
-5.78909 -12.38010 -20.65520 -4.5033717694 -3.697665414 -2.3433119321
-4.85922 -10.95023 -18.72533 -6.0033717694 -4.697665414 -2.8433119321
-4.28357 -9.87458 -17.14968 -7.5033717694 -5.697665414 -3.3433119321
-3.78012 -8.87113 -15.64623 -9.0033717694 -6.697665414 -3.8433119321
-3.29462 -7.88563 -14.16073 -10.503371769 -7.697665414 -4.3433119321
-2.83976 -6.93077 -12.70587 -12.003371769 -8.697665414 -4.8433119321
-2.45796 -6.04897 -11.32407 -13.503371769 -9.697665414 -5.3433119321
-2.20201 -5.29302 -10.06812 -15.003371769 -10.697665414 -5.8433119321
-2.07540 -4.66641 -8.94151 -16.503371769 -11.697665414 -6.3433119321
-2.02827 -4.11928 -7.89438 -18.003371769 -12.697665414 -6.8433119321
-2.01885 -3.60986 -6.88496 -19.503371769 -13.697665414 -7.3433119321
-2.03629 -3.12730 -5.90240 -21.003371769 -14.697665414 -7.8433119321
-2.10026 -2.69127 -4.96637 -22.503371769 -15.697665414 -8.3433119321
-2.26130 -2.35231 -4.12741 -24.003371769 -16.697665414 -8.8433119321
-2.56829 -2.15930 -3.43440 -25.503371769 -17.697665414 -9.3433119321
-3.01997 -2.11098 -2.88608 -27.003371769 -18.697665414 -9.8433119321
-3.60482 -2.19583 -2.47093 -28.503371769 -19.697665414 -10.3433119321
-4.33886 -2.42987 -2.20497 -30.003371769 -20.697665414 -10.8433119321
-5.20912 -2.80013 -2.07523 -31.503371769 -21.697665414 -11.3433119321
-6.15905 -3.25006 -2.02516 -33.003371769 -22.697665414 -11.8433119321
-7.14200 -3.73301 -2.00811 -34.503371769 -23.697665414 -12.3433119321
-8.13647 -4.22748 -2.00258 -36.003371769 -24.697665414 -12.8433119321
MINIMO DATOS

de Bjerrum a 5°C Diagrama d

0.000
8 10 12 14 0 1 2 3 4 5

-1.000
de Bjerrum a 5°C Diagrama d
0.000
8 10 12 14 0 1 2 3 4 5

-1.000

-2.000
l og[H3As O4] I
l og[H3As O4] II
l og[H2As O4(-)] I -3.000
l og[H2As O4(-)] II
l og[HAsO4(2-)] I
l og[HAsO4(2-)] II
l og[As O4(3-)] -4.000

-5.000

-6.000

-7.000
 ECA (mg/L) concentracion log
0.01 1.334757074E-07 -6.87460
0.05 6.673785371E-07 -6.17563

SOLUBILIDAD ECA
log[H2AsO4(-)] II log[HAsO4(2-)] I log[HAsO4(2-)] II log[AsO4(3-)] log∑[As(5+)] A-1
-6.1813667763 -12.9532704486 -23.0442801668 -34.819380235 5.9975116022 -6.87460
-5.6813667763 -11.9532704486 -21.5442801668 -32.819380235 4.4994582285 -6.87460
-5.1813667763 -10.9532704486 -20.0442801668 -30.819380235 3.0059355405 -6.87460
-4.6813667763 -9.9532704486 -18.5442801668 -28.819380235 1.5294029937 -6.87460
-4.1813667763 -8.9532704486 -17.0442801668 -26.819380235 0.1259298709 -6.87460
-3.6813667763 -7.9532704486 -15.5442801668 -24.819380235 -1.013191388 -6.87460
-3.1813667763 -6.9532704486 -14.0442801668 -22.819380235 -1.744688902 -6.87460
-2.6813667763 -5.9532704486 -12.5442801668 -20.819380235 -2.164183811 -6.87460
-2.1813667763 -4.9532704486 -11.0442801668 -18.819380235 -2.094051924 -6.87460
-1.6813667763 -3.9532704486 -9.5442801668 -16.819380235 -1.669701401 -6.87460
-1.1813667763 -2.9532704486 -8.0442801668 -14.819380235 -1.173154517 -6.87460
-0.6813667763 -1.9532704486 -6.5442801668 -12.819380235 -0.658654923 -6.87460
-0.1813667763 -0.9532704486 -5.0442801668 -10.819380235 -0.113508769 -6.87460
0.3186332237 0.0467295514 -3.5442801668 -8.8193802348 0.5046913058 -6.87460
0.8186332237 1.0467295514 -2.0442801668 -6.8193802348 1.2487384971 -6.87460
1.3186332237 2.0467295514 -0.5442801668 -4.8193802348 2.1221273283 -6.87460
1.8186332237 3.0467295514 0.9557198332 -2.8193802348 3.0749972751 -6.87460
2.3186332237 4.0467295514 2.4557198332 -0.8193802348 4.0655800098 -6.87460
2.8186332237 5.0467295514 3.9557198332 1.1806197652 5.0830169066 -6.87460
3.3186332237 6.0467295514 5.4557198332 3.1806197652 6.1469877283 -6.87460
3.8186332237 7.0467295514 6.9557198332 5.1806197652 7.3080270071 -6.87460
4.3186332237 8.0467295514 8.4557198332 7.1806197652 8.6150162169 -6.87460
4.8186332237 9.0467295514 9.9557198332 9.1806197652 10.066700657 -6.87460
5.3186332237 10.0467295514 11.4557198332 11.180619765 11.65155252 -6.87460
5.8186332237 11.0467295514 12.9557198332 13.180619765 13.385592962 -6.87460
6.3186332237 12.0467295514 14.4557198332 15.180619765 15.255853855 -6.87460
6.8186332237 13.0467295514 15.9557198332 17.180619765 17.205783606 -6.87460
7.3186332237 14.0467295514 17.4557198332 19.180619765 19.188729239 -6.87460
7.8186332237 15.0467295514 18.9557198332 21.180619765 21.183199929 -6.87460
-2.164 pH 3.5

Diagrama de Solubilidad a 5°C

2 3 4 5 6 7 8 9 10
 Diagrama de Solubilidad a 5°C
2 3 4 5 6 7 8 9 10

MINIMO DATOS
l og[H3As O4] I
l og[H3As O4] II
l og[H2As O4(-)] I
l og[H2As O4(-)] II
l og[HAsO4(2-)] I
l og[HAsO4(2-)] II
l og[As O4(3-)]
l og∑[As (5+)]
A-1
A-3
ECA
A-3
-6.17563
-6.17563
-6.17563
-6.17563
-6.17563
-6.17563
-6.17563
-6.17563
-6.17563
-6.17563
-6.17563
-6.17563
-6.17563
-6.17563
-6.17563
-6.17563
-6.17563
-6.17563
-6.17563
-6.17563
-6.17563
-6.17563
-6.17563
-6.17563
-6.17563
-6.17563
-6.17563
-6.17563
-6.17563
T (°C) T(K) 1/T logk1 logk2 logk3 logk4
5 278.15 0.00359518 -2.9966282 -0.3023346 1.843311932 9.181366776
25 298.15 0.00335402 -1.8790096 0.28919837 2.553598649 9.030768854
95 368.15 0.00271628 1.07638817 1.85343067 4.431859892 8.632532152

∑[As(5+)] (1/[Fe]T)*([H+]^3/k1+[H+]^2/k2+[H+]/k3+1/k4[H+]+1/k5[H+]^2+1/k6[H+]^3+1/k7[H+]^4)

pH [H+] [H3AsO4] I [H3AsO4] II [H2AsO4(-)] I[H2AsO4(-)] II [HAsO4(2-)] I

0 1 75684.961 513.808909 2.79512575 9.316036E-07 1.535634E-13
0.5 0.31622777 2393.36861 51.3808909 0.88389637 0.000002946 1.535634E-12
1 0.1 75.684961 5.13808909 0.27951257 0.000009316 1.535634E-11
1.5 0.03162278 2.39336861 0.51380891 0.08838964 2.945989E-05 1.535634E-10
2 0.01 0.07568496 0.05138089 0.02795126 9.316036E-05 1.535634E-09
2.5 0.00316228 0.00239337 0.00513809 0.00883896 0.000294599 1.535634E-08
3 0.001 7.5685E-05 0.00051381 0.00279513 0.000931604 1.535634E-07
3.5 0.00031623 2.3934E-06 5.1381E-05 0.0008839 0.002945989 1.535634E-06
4 0.0001 7.5685E-08 5.1381E-06 0.00027951 0.009316036 1.535634E-05
4.5 3.1623E-05 2.3934E-09 5.1381E-07 8.839E-05 0.029459892 0.000153563
5 0.00001 7.5685E-11 5.1381E-08 2.7951E-05 0.093160357 0.001535634
5.5 3.1623E-06 2.3934E-12 5.1381E-09 8.839E-06 0.294598917 0.015356339
6 0.000001 7.5685E-14 5.1381E-10 2.7951E-06 0.931603573 0.153563389
6.5 3.1623E-07 2.3934E-15 5.1381E-11 8.839E-07 2.945989168 1.535633888
7 0.0000001 7.5685E-17 5.1381E-12 2.7951E-07 9.316035732 15.35633888
7.5 3.1623E-08 2.3934E-18 5.1381E-13 8.839E-08 29.45989168 153.5633888
8 0.00000001 7.5685E-20 5.1381E-14 2.7951E-08 93.16035732 1535.633888
8.5 3.1623E-09 2.3934E-21 5.1381E-15 8.839E-09 294.5989168 15356.33888
9 1E-09 7.5685E-23 5.1381E-16 2.7951E-09 931.6035732 153563.3888
9.5 3.1623E-10 2.3934E-24 5.1381E-17 8.839E-10 2945.989168 1535633.888
10 1E-10 7.5685E-26 5.1381E-18 2.7951E-10 9316.035732 15356338.88
10.5 3.1623E-11 2.3934E-27 5.1381E-19 8.839E-11 29459.89168 153563388.8
11 1E-11 7.5685E-29 5.1381E-20 2.7951E-11 93160.35732 1535633888
11.5 3.1623E-12 2.3934E-30 5.1381E-21 8.839E-12 294598.9168 15356338877
12 1E-12 7.5685E-32 5.1381E-22 2.7951E-12 931603.5732 1.53563E+11
12.5 3.1623E-13 2.3934E-33 5.1381E-23 8.839E-13 2945989.168 1.53563E+12
13 1E-13 7.5685E-35 5.1381E-24 2.7951E-13 9316035.732 1.53563E+13
13.5 3.1623E-14 2.3934E-36 5.1381E-25 8.839E-14 29459891.68 1.53563E+14
14 1E-14 7.5685E-38 5.1381E-26 2.7951E-14 93160357.32 1.53563E+15
3.28 0.00052481 1.094E-05 0.00014151 0.0014669 0.001775134 5.57555E-07
 logk5 logk6 logk7 k1 k2 k3 k4 k5
15.95327045 26.04428017 37.8193802 0.00100779 0.49850029 69.7127046 1518332109 8.9799E+15
15.81371231 25.3820486 37.0021955 0.01321266 1.94624885 357.765657 1073417952 6.512E+15
15.44466889 23.630863 34.8412563 11.9230721 71.356028 27030.8618 429073954 2.784E+15

H+]^3+1/k7[H+]^4) [Fe]T 0.001 ∑[As(5+)] 0.01

PREDOMINANCIA
[HAsO4(2-)] II [AsO4(3-)] ∑[As(5+)] [H3AsO4] I [H3AsO4] II [H2AsO4(-)] I[H2AsO4(-)] I[HAsO4(2-)] I
4.149076E-23 9.949574E-35 76201.565 99.32206% 0.67428% 0.00367% 0.00000% 0.00000%
1.312053E-21 9.949574E-33 2445.6334 97.86293% 2.10092% 0.03614% 0.00000% 0.00000%
4.149076E-20 9.949574E-31 81.102572 93.32005% 6.33530% 0.34464% 0.00001% 0.00000%
1.312053E-18 9.949574E-29 2.99559662 79.89622% 17.15214% 2.95065% 0.00098% 0.00000%
4.149076E-17 9.949574E-27 0.15511027 48.79429% 33.12540% 18.02025% 0.06006% 0.00000%
1.312053E-15 9.949574E-25 0.01666504 14.36162% 30.83155% 53.03897% 1.76777% 0.00009%
4.149076E-14 9.949574E-23 0.00431638 1.75344% 11.90371% 64.75630% 21.58300% 0.00356%
1.312053E-12 9.949574E-21 0.0038852 0.06160% 1.32248% 22.75037% 75.82602% 0.03953%
4.149076E-11 9.949574E-19 0.00961612 0.00079% 0.05343% 2.90671% 96.87938% 0.15969%
1.312053E-09 9.949574E-17 0.02970236 0.00001% 0.00173% 0.29758% 99.18367% 0.51701%
4.149076E-08 9.949574E-15 0.09472404 0.00000% 0.00005% 0.02951% 98.34923% 1.62117%
1.312053E-06 9.949574E-13 0.30996541 0.00000% 0.00000% 0.00285% 95.04251% 4.95421%
4.149076E-05 9.949574E-11 1.08521125 0.00000% 0.00000% 0.00026% 85.84537% 14.15055%
0.001312053 9.949574E-09 4.482936 0.00000% 0.00000% 0.00002% 65.71562% 34.25509%
0.04149076 0.000000995 24.7138666 0.00000% 0.00000% 0.00000% 37.69558% 62.13653%
1.31205305 9.949574E-05 184.335433 0.00000% 0.00000% 0.00000% 15.98168% 83.30650%
41.4907605 0.009949574 1670.29496 0.00000% 0.00000% 0.00000% 5.57748% 91.93789%
1312.05305 0.994957426 16963.9858 0.00000% 0.00000% 0.00000% 1.73661% 90.52318%
41490.7605 99.49574261 196085.249 0.00000% 0.00000% 0.00000% 0.47510% 78.31461%
1312053.05 9949.574261 2860582.5 0.00000% 0.00000% 0.00000% 0.10299% 53.68256%
41490760.5 994957.4261 57851372.8 0.00000% 0.00000% 0.00000% 0.01610% 26.54447%
1312053050 99495742.61 1565141641 0.00000% 0.00000% 0.00000% 0.00188% 9.81147%
41490760497 9949574261 5.2976E+10 0.00000% 0.00000% 0.00000% 0.00018% 2.89873%
1.31205E+12 9.94957E+11 2.3224E+12 0.00000% 0.00000% 0.00000% 0.00001% 0.66124%
4.14908E+13 9.94957E+13 1.4114E+14 0.00000% 0.00000% 0.00000% 0.00000% 0.10880%
1.31205E+15 9.94957E+15 1.1263E+16 0.00000% 0.00000% 0.00000% 0.00000% 0.01363%
4.14908E+16 9.94957E+17 1.0365E+18 0.00000% 0.00000% 0.00000% 0.00000% 0.00148%
1.31205E+18 9.94957E+19 1.0081E+20 0.00000% 0.00000% 0.00000% 0.00000% 0.00015%
4.14908E+19 9.94957E+21 9.9911E+21 0.00000% 0.00000% 0.00000% 0.00000% 0.00002%
2.870459E-13 1.311609E-21 0.00339505 0.32223% 4.16827% 43.20712% 52.28596% 0.01642%

Diagrama de predominancia a 25°C

120.00000%
 Diagrama de predominancia a 25°C
120.00000%

100.00000%

80.00000%

60.00000%

40.00000%

20.00000%

0.00000%
0 2 4 6 8 10 12 14
 k6 k7
1.1073E+26 6.5975E+37
2.4102E+25 1.0051E+37
4.2743E+23 6.9384E+34

A BJERRUM
[HAsO4(2-)] I[AsO4(3-)] log[H3AsO4] I log[H3AsO4] II log[H2AsO4(-)] I log[H2AsO4(-)] II
0.00000% 0.00000% -2.00295 -4.17116 -6.43556 -12.91273
0.00000% 0.00000% -2.00938 -3.67759 -5.44199 -10.91916
0.00000% 0.00000% -2.03003 -3.19823 -4.46263 -8.93980
0.00000% 0.00000% -2.09747 -2.76568 -3.53008 -7.00725
0.00000% 0.00000% -2.31163 -2.47984 -2.74424 -5.22141
0.00000% 0.00000% -2.84280 -2.51100 -2.27540 -3.75258
0.00000% 0.00000% -3.75611 -2.92432 -2.18872 -2.66589
0.00000% 0.00000% -5.21040 -3.87861 -2.64301 -2.12018
0.00000% 0.00000% -7.10399 -5.27220 -3.53660 -2.01377
0.00000% 0.00000% -9.09378 -6.76199 -4.52639 -2.00356
0.00004% 0.00000% -11.09745 -8.26566 -5.53006 -2.00723
0.00042% 0.00000% -13.11230 -9.78051 -6.54491 -2.02208
0.00382% 0.00000% -15.15650 -11.32471 -7.58911 -2.06628
0.02927% 0.00000% -17.27255 -12.94076 -8.70516 -2.18233
0.16788% 0.00000% -19.51393 -14.68214 -9.94654 -2.42371
0.71177% 0.00005% -21.88660 -16.55481 -11.31921 -2.79638
2.48404% 0.00060% -24.34378 -18.51199 -12.77639 -3.25356
7.73434% 0.00587% -26.85052 -20.51873 -14.28313 -3.76030
21.15955% 0.05074% -29.41344 -22.58164 -15.84604 -4.32321
45.86664% 0.34782% -32.07744 -24.74565 -17.51005 -4.98722
71.71958% 1.71985% -34.88330 -27.05151 -19.31591 -5.79308
83.82967% 6.35698% -37.81554 -29.48375 -21.24815 -6.72532
78.31983% 18.78126% -40.84507 -32.01328 -23.27768 -7.75485
56.49637% 42.84238% -43.98692 -34.65513 -25.41953 -8.89670
29.39687% 70.49433% -47.27064 -37.43885 -27.70325 -10.18042
11.64906% 88.33730% -50.67265 -40.34086 -30.10526 -11.58243
4.00311% 95.99541% -54.13654 -43.30475 -32.56915 -13.04632
1.30154% 98.69831% -57.62449 -46.29269 -35.05709 -14.53426
0.41528% 99.58471% -61.12060 -49.28881 -37.55321 -16.03038
0.00000% 0.00000% -4.49184 -3.38004 -2.36444 -2.28161

a a 25°C Diagrama de Bjerrum a 25°C

0.00000
0 2 4 6 8 10 12
a a 25°C Diagrama de Bjerrum a 25°C
0.00000
0 2 4 6 8 10 12

-10.00000

[H3As O4] I -20.00000

[H3As O4] II
[H2As O4(-)] I
[H2As O4(-)] II -30.00000
[HAsO4(2-)] I
[HAsO4(2-)] II
[As O4(3-)] -40.00000

-50.00000

-60.00000

12 14 -70.00000
 M(As) ECA (mg/L)
74.92 A-1
A-3

JERRUM SOLUBIL
log[HAsO4(2-)] I log[HAsO4(2-)] II log[AsO4(3-)] log[H3AsO4] I log[H3AsO4] II log[H2AsO4(-)] I
-19.69568 -29.26401 -40.88416 4.8790095915 2.7108016305 0.4464013506
-17.20210 -26.27044 -37.39059 3.3790095915 1.7108016305 -0.0535986494
-14.72275 -23.29108 -33.91123 1.8790095915 0.7108016305 -0.5535986494
-12.29020 -20.35853 -30.47868 0.3790095915 -0.2891983695 -1.0535986494
-10.00435 -17.57269 -27.19284 -1.1209904085 -1.2891983695 -1.5535986494
-8.03552 -15.10385 -24.22400 -2.6209904085 -2.2891983695 -2.0535986494
-6.44883 -13.01717 -21.63731 -4.1209904085 -3.2891983695 -2.5535986494
-5.40313 -11.47146 -19.59161 -5.6209904085 -4.2891983695 -3.0535986494
-4.79671 -10.36505 -17.98520 -7.1209904085 -5.2891983695 -3.5535986494
-4.28650 -9.35484 -16.47499 -8.6209904085 -6.2891983695 -4.0535986494
-3.79017 -8.35851 -14.97866 -10.120990409 -7.2891983695 -4.5535986494
-3.30503 -7.37336 -13.49351 -11.620990409 -8.2891983695 -5.0535986494
-2.84923 -6.41756 -12.03771 -13.120990409 -9.2891983695 -5.5535986494
-2.46527 -5.53361 -10.65376 -14.620990409 -10.289198369 -6.0535986494
-2.20665 -4.77499 -9.39514 -16.120990409 -11.289198369 -6.5535986494
-2.07932 -4.14766 -8.26780 -17.620990409 -12.289198369 -7.0535986494
-2.03651 -3.60484 -7.22499 -19.120990409 -13.289198369 -7.5535986494
-2.04324 -3.11158 -6.23172 -20.620990409 -14.289198369 -8.0535986494
-2.10616 -2.67449 -5.29464 -22.120990409 -15.289198369 -8.5535986494
-2.27017 -2.33850 -4.45865 -23.620990409 -16.289198369 -9.0535986494
-2.57603 -2.14436 -3.76451 -25.120990409 -17.289198369 -9.5535986494
-3.00827 -2.07660 -3.19675 -26.620990409 -18.289198369 -10.0535986494
-3.53779 -2.10613 -2.72628 -28.120990409 -19.289198369 -10.5535986494
-4.17964 -2.24798 -2.36813 -29.620990409 -20.289198369 -11.0535986494
-4.96336 -2.53170 -2.15185 -31.120990409 -21.289198369 -11.5535986494
-5.86537 -2.93371 -2.05386 -32.620990409 -22.289198369 -12.0535986494
-6.82927 -3.39760 -2.01775 -34.120990409 -23.289198369 -12.5535986494
-7.81721 -3.88554 -2.00569 -35.620990409 -24.289198369 -13.0535986494
-8.81332 -4.38166 -2.00181 -37.120990409 -25.289198369 -13.5535986494
-5.78456 -12.07289 -20.41304 -4.9609904085 -3.8491983695 -2.8335986494
MINIMO DATOS
MINIMO REAL

rama de Bjerrum a 25°C Diagrama

0.000
8 10 12 14 0 1 2 3 4 5
rama de Bjerrum a 25°C Diagrama
0.000
8 10 12 14 0 1 2 3 4 5

-1.000

l og[H3As O4] I -2.000

1; -2.469
l og[H3As O4] II
l og[H2As O4(-)] I
l og[H2As O4(-)] II -3.000
l og[HAsO4(2-)] I
l og[HAsO4(2-)] II
l og[As O4(3-)] -4.000

-5.000

-6.000

-7.000
 ECA (mg/L) concentracion log
0.01 1.334757074E-07 -6.87460
0.05 6.673785371E-07 -6.17563

SOLUBILIDAD ECA
log[H2AsO4(-)] II log[HAsO4(2-)] I log[HAsO4(2-)] II log[AsO4(3-)] log∑[As(5+)] A-1
-6.0307688544 -12.8137123126 -22.3820486048 -34.002195502 4.88196389 -6.87460
-5.5307688544 -11.8137123126 -20.8820486048 -32.002195502 3.38839136 -6.87460
-5.0307688544 -10.8137123126 -19.3820486048 -30.002195502 1.90903463 -6.87460
-4.5307688544 -9.8137123126 -17.8820486048 -28.002195502 0.47648333 -6.87460
-4.0307688544 -8.8137123126 -16.3820486048 -26.002195502 -0.8093594 -6.87460
-3.5307688544 -7.8137123126 -14.8820486048 -24.002195502 -1.7781938 -6.87460
-3.0307688544 -6.8137123126 -13.3820486048 -22.002195502 -2.3648807 -6.87460
-2.5307688544 -5.8137123126 -11.8820486048 -20.002195502 -2.4105871 -6.87460
-2.0307688544 -4.8137123126 -10.3820486048 -18.002195502 -2.0170002 -6.87460
-1.5307688544 -3.8137123126 -8.8820486048 -16.002195502 -1.527209 -6.87460
-1.0307688544 -2.8137123126 -7.3820486048 -14.002195502 -1.0235398 -6.87460
-0.5307688544 -1.8137123126 -5.8820486048 -12.002195502 -0.5086868 -6.87460
-0.0307688544 -0.8137123126 -4.3820486048 -10.002195502 0.03551429 -6.87460
0.4692311456 0.1862876874 -2.8820486048 -8.0021955022 0.65156254 -6.87460
0.9692311456 1.1862876874 -1.3820486048 -6.0021955022 1.3929407 -6.87460
1.4692311456 2.1862876874 0.1179513952 -4.0021955022 2.26560882 -6.87460
1.9692311456 3.1862876874 1.6179513952 -2.0021955022 3.22279317 -6.87460
2.4692311456 4.1862876874 3.1179513952 -0.0021955022 4.2295279 -6.87460
2.9692311456 5.1862876874 4.6179513952 1.9978044978 5.29244492 -6.87460
3.4692311456 6.1862876874 6.1179513952 3.9978044978 6.45645448 -6.87460
3.9692311456 7.1862876874 7.6179513952 5.9978044978 7.76231367 -6.87460
4.4692311456 8.1862876874 9.1179513952 7.9978044978 9.19455365 -6.87460
4.9692311456 9.1862876874 10.6179513952 9.9978044978 10.7240797 -6.87460
5.4692311456 10.1862876874 12.1179513952 11.997804498 12.3659309 -6.87460
5.9692311456 11.1862876874 13.6179513952 13.997804498 14.1496503 -6.87460
6.4692311456 12.1862876874 15.1179513952 15.997804498 16.0516604 -6.87460
6.9692311456 13.1862876874 16.6179513952 17.997804498 18.015554 -6.87460
7.4692311456 14.1862876874 18.1179513952 19.997804498 20.0034948 -6.87460
7.9692311456 15.1862876874 19.6179513952 21.997804498 21.9996119 -6.87460
-2.7507688544 -6.2537123126 -12.5420486048 -20.882195502 -2.469154
-2.411 pH 3.5
-2.469 3.28
254.49

Diagrama de Bjerrum a 25°C

3 4 5 6 7 8 9 10
 Diagrama de Bjerrum a 25°C

3 4 5 6 7 8 9 10

MINIMO DATOS
MINIMO REAL
l og[H3As O4] I
1; -2.469 l og[H3As O4] II
l og[H2As O4(-)] I
l og[H2As O4(-)] II
l og[HAs O4(2-)] I
l og[HAs O4(2-)] II
l og[As O4(3-)]
l og∑[As (5+)]
A-1
A-3
ECA
A-3
-6.17563
-6.17563
-6.17563
-6.17563
-6.17563
-6.17563
-6.17563
-6.17563
-6.17563
-6.17563
-6.17563
-6.17563
-6.17563
-6.17563
-6.17563
-6.17563
-6.17563
-6.17563
-6.17563
-6.17563
-6.17563
-6.17563
-6.17563
-6.17563
-6.17563
-6.17563
-6.17563
-6.17563
-6.17563
T (°C) T(K) 1/T logk1 logk2 logk3 logk4
5 278.15 0.00359518 -2.9966282 -0.3023346 1.84331193 9.181366776
25 298.15 0.00335402 -1.8790096 0.28919837 2.55359865 9.030768854
95 368.15 0.00271628 1.07638817 1.85343067 4.43185989 8.632532152

∑[As(5+)] (1/[Fe]T)*([H+]^3/k1+[H+]^2/k2+[H+]/k3+1/k4[H+]+1/k5[H+]^2+1/k6[H+]^3+1/k7[H+]^4)

pH [H+] [H3AsO4] I [H3AsO4] II [H2AsO4(-)] I[H2AsO4(-)] I[HAsO4(2-)] I

0 1 83.8710018 14.014233 0.03699475 2.3306E-06 3.591957E-13
0.5 0.31622777 2.65223395 1.4014233 0.01169877 0.00000737 3.591957E-12
1 0.1 0.083871 0.14014233 0.00369948 2.3306E-05 3.591957E-11
1.5 0.03162278 0.00265223 0.01401423 0.00116988 7.37E-05 3.591957E-10
2 0.01 8.3871E-05 0.00140142 0.00036995 0.00023306 3.591957E-09
2.5 0.00316228 2.6522E-06 0.00014014 0.00011699 0.000737 3.591957E-08
3 0.001 8.3871E-08 1.4014E-05 3.6995E-05 0.0023306 3.591957E-07
3.5 0.00031623 2.6522E-09 1.4014E-06 1.1699E-05 0.00737001 0.000003592
4 0.0001 8.3871E-11 1.4014E-07 3.6995E-06 0.02330601 3.591957E-05
4.5 3.1623E-05 2.6522E-12 1.4014E-08 1.1699E-06 0.07370006 0.000359196
5 0.00001 8.3871E-14 1.4014E-09 3.6995E-07 0.23306006 0.003591957
5.5 3.1623E-06 2.6522E-15 1.4014E-10 1.1699E-07 0.73700061 0.035919568
6 0.000001 8.3871E-17 1.4014E-11 3.6995E-08 2.33060057 0.35919568
6.5 3.1623E-07 2.6522E-18 1.4014E-12 1.1699E-08 7.37000611 3.591956804
7 0.0000001 8.3871E-20 1.4014E-13 3.6995E-09 23.3060057 35.91956804
7.5 3.1623E-08 2.6522E-21 1.4014E-14 1.1699E-09 73.7000611 359.1956804
8 0.00000001 8.3871E-23 1.4014E-15 3.6995E-10 233.060057 3591.956804
8.5 3.1623E-09 2.6522E-24 1.4014E-16 1.1699E-10 737.000611 35919.56804
9 1E-09 8.3871E-26 1.4014E-17 3.6995E-11 2330.60057 359195.6804
9.5 3.1623E-10 2.6522E-27 1.4014E-18 1.1699E-11 7370.00611 3591956.804
10 1E-10 8.3871E-29 1.4014E-19 3.6995E-12 23306.0057 35919568.04
10.5 3.1623E-11 2.6522E-30 1.4014E-20 1.1699E-12 73700.0611 359195680.4
11 1E-11 8.3871E-32 1.4014E-21 3.6995E-13 233060.057 3591956804
11.5 3.1623E-12 2.6522E-33 1.4014E-22 1.1699E-13 737000.611 35919568041
12 1E-12 8.3871E-35 1.4014E-23 3.6995E-14 2330600.57 3.59196E+11
12.5 3.1623E-13 2.6522E-36 1.4014E-24 1.1699E-14 7370006.11 3.59196E+12
13 1E-13 8.3871E-38 1.4014E-25 3.6995E-15 23306005.7 3.59196E+13
13.5 3.1623E-14 2.6522E-39 1.4014E-26 1.1699E-15 73700061.1 3.59196E+14
14 1E-14 8.3871E-41 1.4014E-27 3.6995E-16 233060057 3.59196E+15
 logk5 logk6 logk7 k1 k2 k3 k4 k5
15.95327045 26.04428017 37.8193802 0.00100779 0.49850029 69.7127046 1518332109 8.9799E+15
15.81371231 25.3820486 37.0021955 0.01321266 1.94624885 357.765657 1073417952 6.512E+15
15.44466889 23.630863 34.8412563 11.9230721 71.356028 27030.8618 429073954 2.784E+15

6[H+]^3+1/k7[H+]^4) [Fe]T 0.001 ∑[As(5+)] 0.01

PREDOMINANCIA
[HAsO4(2-)] II [AsO4(3-)] ∑[As(5+)] [H3AsO4] I [H3AsO4] II [H2AsO4(-)] I[H2AsO4(-)] I[HAsO4(2-)] I
2.339575E-21 1.441265E-32 97.9222318 85.65062% 14.31159% 0.03778% 0.00000% 0.00000%
7.398386E-20 1.441265E-30 4.06536339 65.23978% 34.47228% 0.28777% 0.00018% 0.00000%
2.339575E-18 1.441265E-28 0.22773611 36.82815% 61.53716% 1.62446% 0.01023% 0.00000%
7.398386E-17 1.441265E-26 0.01791004 14.80864% 78.24790% 6.53196% 0.41150% 0.00000%
2.339575E-15 1.441265E-24 0.00208831 4.01622% 67.10816% 17.71520% 11.16025% 0.00017%
7.398386E-14 1.441265E-22 0.00099682 0.26607% 14.05896% 11.73610% 73.93527% 0.00360%
2.339575E-12 1.441265E-20 0.00238205 0.00352% 0.58833% 1.55306% 97.84001% 0.01508%
7.398386E-11 1.441265E-18 0.0073867 0.00004% 0.01897% 0.15838% 99.77399% 0.04863%
2.339575E-09 1.441265E-16 0.02334577 0.00000% 0.00060% 0.01585% 99.82968% 0.15386%
0.000000074 1.441265E-14 0.07406051 0.00000% 0.00002% 0.00158% 99.51330% 0.48500%
2.339575E-06 1.441265E-12 0.23665472 0.00000% 0.00000% 0.00016% 98.48105% 1.51780%
7.398386E-05 1.441265E-10 0.77299428 0.00000% 0.00000% 0.00002% 95.34360% 4.64681%
0.002339575 1.441265E-08 2.69213587 0.00000% 0.00000% 0.00000% 86.57069% 13.34241%
0.073983863 1.441265E-06 11.0359482 0.00000% 0.00000% 0.00000% 66.78181% 32.54779%
2.339575165 0.000144126 61.565293 0.00000% 0.00000% 0.00000% 37.85575% 58.34386%
73.98386279 0.014412645 506.894017 0.00000% 0.00000% 0.00000% 14.53954% 70.86209%
2339.575165 1.44126453 6166.03329 0.00000% 0.00000% 0.00000% 3.77974% 58.25393%
73983.86279 144.126453 110784.558 0.00000% 0.00000% 0.00000% 0.66526% 32.42290%
2339575.165 14412.6453 2715514.09 0.00000% 0.00000% 0.00000% 0.08583% 13.22754%
73983862.79 1441264.53 79024454.1 0.00000% 0.00000% 0.00000% 0.00933% 4.54537%
2339575165 144126453 2519644492 0.00000% 0.00000% 0.00000% 0.00092% 1.42558%
73983862792 14412645303 8.8756E+10 0.00000% 0.00000% 0.00000% 0.00008% 0.40470%
2.33958E+12 1.44126E+12 3.7844E+12 0.00000% 0.00000% 0.00000% 0.00001% 0.09491%
7.39839E+13 1.44126E+14 2.1815E+14 0.00000% 0.00000% 0.00000% 0.00000% 0.01647%
2.33958E+15 1.44126E+16 1.6753E+16 0.00000% 0.00000% 0.00000% 0.00000% 0.00214%
7.39839E+16 1.44126E+18 1.5153E+18 0.00000% 0.00000% 0.00000% 0.00000% 0.00024%
2.33958E+18 1.44126E+20 1.4647E+20 0.00000% 0.00000% 0.00000% 0.00000% 0.00002%
7.39839E+19 1.44126E+22 1.4487E+22 0.00000% 0.00000% 0.00000% 0.00000% 0.00000%
2.33958E+21 1.44126E+24 1.4436E+24 0.00000% 0.00000% 0.00000% 0.00000% 0.00000%

Diagrama de presominancia a 95°C

120.00000%

100.00000%
 Diagrama de presominancia a 95°C
120.00000%

100.00000%
[H3As O4]
[H3As O4]
80.00000%
[H2As O4(-
[H2As O4(-
60.00000% [HAs O4(2-
[HAs O4(2-
[As O4(3-)]
40.00000%

20.00000%

0.00000%
0 2 4 6 8 10 12 14
 k6 k7
1.1073E+26 6.5975E+37
2.4102E+25 1.0051E+37
4.2743E+23 6.9384E+34

A BJERRUM
[HAsO4(2-)] I[AsO4(3-)] log[H3AsO4] log[H3AsO4] lIog[H2AsO4(-)log[H2AsO4(-)log[HAsO4(2-)log[HAsO4(2-)
0.00000% 0.00000% -2.06727 -2.84431 -5.42274 -9.62341 -16.43555 -24.62174
0.00000% 0.00000% -2.18549 -2.46253 -4.54096 -7.74163 -14.05377 -21.73996
0.00000% 0.00000% -2.43382 -2.21086 -3.78929 -5.98996 -11.80210 -18.98829
0.00000% 0.00000% -2.82948 -2.10653 -3.18496 -4.38563 -9.69777 -16.38396
0.00000% 0.00000% -3.39618 -2.17322 -2.75165 -2.95233 -7.76446 -13.95066
0.00000% 0.00000% -4.57500 -2.85205 -2.93048 -2.13115 -6.44329 -12.12948
0.00000% 0.00000% -6.45334 -4.23038 -3.80881 -2.00948 -5.82162 -11.00781
0.00000% 0.00000% -8.44484 -5.72188 -4.80031 -2.00098 -5.31312 -9.99931
0.00001% 0.00000% -10.44460 -7.22164 -5.80007 -2.00074 -4.81288 -8.99907
0.00010% 0.00000% -12.44597 -8.72302 -6.80145 -2.00212 -4.31426 -8.00045
0.00099% 0.00000% -14.45050 -10.22755 -7.80598 -2.00665 -3.81878 -7.00498
0.00957% 0.00000% -16.46456 -11.74161 -8.82004 -2.02071 -3.33285 -6.01904
0.08690% 0.00000% -18.50649 -13.28353 -9.86196 -2.06263 -2.87477 -5.06096
0.67039% 0.00001% -20.61920 -14.89624 -10.97467 -2.17534 -2.48748 -4.17367
3.80015% 0.00023% -22.86572 -16.64277 -12.22120 -2.42187 -2.23400 -3.42020
14.59553% 0.00284% -25.28131 -18.55835 -13.63678 -2.83745 -2.14959 -2.83578
37.94295% 0.02337% -27.86639 -20.64344 -15.22187 -3.42254 -2.23467 -2.42087
66.78175% 0.13010% -30.62087 -22.89791 -16.97634 -4.17701 -2.48915 -2.17534
86.15588% 0.53075% -33.51024 -25.28728 -18.86571 -5.06638 -2.87852 -2.06472
93.62148% 1.82382% -36.47415 -27.75119 -20.82962 -6.03029 -3.34243 -2.02862
92.85338% 5.72011% -39.47773 -30.25477 -22.83320 -7.03387 -3.84601 -2.03220
83.35667% 16.23854% -42.52458 -32.80163 -24.88006 -8.08073 -4.39287 -2.07906
61.82104% 38.08404% -45.65439 -35.43143 -27.00986 -9.21053 -5.02267 -2.20886
33.91480% 66.06873% -48.91514 -38.19218 -29.27061 -10.47128 -5.78342 -2.46961
13.96546% 86.03239% -52.30047 -41.07751 -31.65594 -11.85661 -6.66875 -2.85494
4.88261% 95.11715% -55.75687 -44.03392 -34.11234 -13.31302 -7.62515 -3.31135
1.59735% 98.40263% -59.24213 -47.01917 -36.59760 -14.79827 -8.61041 -3.79660
0.51070% 99.48929% -62.73736 -50.01440 -39.09283 -16.29350 -9.60564 -4.29183
0.16206% 99.83793% -66.23584 -53.01288 -41.59131 -17.79198 -10.60412 -4.79031

ancia a 95°C Diagrama de Bjerrum a 95°C

0.00000
0 2 4 6 8 10 12 14

-10.00000
ancia a 95°C Diagrama de Bjerrum a 95°C
0.00000
0 2 4 6 8 10 12 14

-10.00000
[H3As O4] I l og[H3AsO4] I
[H3As O4] II -20.00000 l og[H3AsO4] II
[H2As O4(-)] I l og[H2AsO4(-)] I
[H2As O4(-)] II -30.00000 l og[H2AsO4(-)] II
[HAs O4(2-)] I l og[HAs O4(2-)] I
[HAs O4(2-)] II l og[HAs O4(2-)] II
-40.00000
[As O4(3-)] l og[As O4(3-)]

-50.00000

-60.00000

12 14 -70.00000
 M(As) ECA (mg/L) concentracion
74.92 A-1 0.01 1.334757074E-07
A-3 0.05 6.673785371E-07

SOLUBILIDAD
log[AsO4(3-)]log[H3AsO4] I log[H3AsO4] II log[H2AsO4(-)] I log[H2AsO4(-)] II log[HAsO4(2-)] I
-35.83214 1.9236118305 1.1465693325 -1.4318598919 -5.6325321522 -12.4446688947
-32.45036 0.4236118305 0.1465693325 -1.9318598919 -5.1325321522 -11.4446688947
-29.19869 -1.0763881695 -0.8534306675 -2.4318598919 -4.6325321522 -10.4446688947
-26.09435 -2.5763881695 -1.8534306675 -2.9318598919 -4.1325321522 -9.4446688947
-23.16105 -4.0763881695 -2.8534306675 -3.4318598919 -3.6325321522 -8.4446688947
-20.83987 -5.5763881695 -3.8534306675 -3.9318598919 -3.1325321522 -7.4446688947
-19.21821 -7.0763881695 -4.8534306675 -4.4318598919 -2.6325321522 -6.4446688947
-17.70971 -8.5763881695 -5.8534306675 -4.9318598919 -2.1325321522 -5.4446688947
-16.20946 -10.076388169 -6.8534306675 -5.4318598919 -1.6325321522 -4.4446688947
-14.71084 -11.576388169 -7.8534306675 -5.9318598919 -1.1325321522 -3.4446688947
-13.21537 -13.076388169 -8.8534306675 -6.4318598919 -0.6325321522 -2.4446688947
-11.72943 -14.576388169 -9.8534306675 -6.9318598919 -0.1325321522 -1.4446688947
-10.27135 -16.076388169 -10.853430668 -7.4318598919 0.3674678478 -0.4446688947
-8.88407 -17.576388169 -11.853430668 -7.9318598919 0.8674678478 0.5553311053
-7.63059 -19.076388169 -12.853430668 -8.4318598919 1.3674678478 1.5553311053
-6.54617 -20.576388169 -13.853430668 -8.9318598919 1.8674678478 2.5553311053
-5.63126 -22.076388169 -14.853430668 -9.4318598919 2.3674678478 3.5553311053
-4.88574 -23.576388169 -15.853430668 -9.9318598919 2.8674678478 4.5553311053
-4.27511 -25.076388169 -16.853430668 -10.4318598919 3.3674678478 5.5553311053
-3.73902 -26.576388169 -17.853430668 -10.9318598919 3.8674678478 6.5553311053
-3.24260 -28.076388169 -18.853430668 -11.4318598919 4.3674678478 7.5553311053
-2.78945 -29.576388169 -19.853430668 -11.9318598919 4.8674678478 8.5553311053
-2.41926 -31.076388169 -20.853430668 -12.4318598919 5.3674678478 9.5553311053
-2.18000 -32.576388169 -21.853430668 -12.9318598919 5.8674678478 10.5553311053
-2.06534 -34.076388169 -22.853430668 -13.4318598919 6.3674678478 11.5553311053
-2.02174 -35.576388169 -23.853430668 -13.9318598919 6.8674678478 12.5553311053
-2.00699 -37.076388169 -24.853430668 -14.4318598919 7.3674678478 13.5553311053
-2.00222 -38.576388169 -25.853430668 -14.9318598919 7.8674678478 14.5553311053
-2.00070 -40.076388169 -26.853430668 -15.4318598919 8.3674678478 15.5553311053
MINIMO DATOS -3.001 pH

Diagrama de solubilidad a 95°C

0.000
0 1 2 3 4 5 6 7 8
MINIMO DATOS
-1.000 l og[H3As O4] I
 Diagrama de solubilidad a 95°C
0.000
0 1 2 3 4 5 6 7 8
MINIMO DATOS
-1.000 l og[H3As O4] I
l og[H3AsO4] I l og[H3As O4] II
l og[H3AsO4] II -2.000 l og[H2As O4(-)] I
l og[H2AsO4(-)] I l og[H2As O4(-)] II
l og[H2AsO4(-)] II -3.000 l og[HAs O4(2-)] I
l og[HAs O4(2-)] I l og[HAs O4(2-)] II
l og[HAs O4(2-)] II l og[AsO4(3-)]
-4.000
l og[As O4(3-)] l og∑[As (5+)]
A-1
-5.000
A-3

-6.000

-7.000
 log
-6.87460
-6.17563

ECA
log[HAsO4(2-)] II log[AsO4(3-)] log∑[As(5+)] A-1 A-3
-20.6308629974 -31.841256301 1.9908813 -6.87460 -6.17563
-19.1308629974 -29.841256301 0.60909937 -6.87460 -6.17563
-17.6308629974 -27.841256301 -0.6425681 -6.87460 -6.17563
-16.1308629974 -25.841256301 -1.7469033 -6.87460 -6.17563
-14.6308629974 -23.841256301 -2.680206 -6.87460 -6.17563
-13.1308629974 -21.841256301 -3.0013838 -6.87460 -6.17563
-11.6308629974 -19.841256301 -2.6230486 -6.87460 -6.17563
-10.1308629974 -17.841256301 -2.1315495 -6.87460 -6.17563
-8.6308629974 -15.841256301 -1.6317918 -6.87460 -6.17563
-7.1308629974 -13.841256301 -1.1304133 -6.87460 -6.17563
-5.6308629974 -11.841256301 -0.6258848 -6.87460 -6.17563
-4.1308629974 -9.8412563013 -0.1118237 -6.87460 -6.17563
-2.6308629974 -7.8412563013 0.43009698 -6.87460 -6.17563
-1.1308629974 -5.8412563013 1.04280965 -6.87460 -6.17563
0.3691370026 -3.8412563013 1.78933595 -6.87460 -6.17563
1.8691370026 -1.8412563013 2.70491717 -6.87460 -6.17563
3.3691370026 0.1587436987 3.79000587 -6.87460 -6.17563
4.8691370026 2.1587436987 5.04447923 -6.87460 -6.17563
6.3691370026 4.1587436987 6.43385206 -6.87460 -6.17563
7.8691370026 6.1587436987 7.8977615 -6.87460 -6.17563
9.3691370026 8.1587436987 9.40133927 -6.87460 -6.17563
10.8691370026 10.158743699 10.9481966 -6.87460 -6.17563
12.3691370026 12.158743699 12.5780007 -6.87460 -6.17563
13.8691370026 14.158743699 14.3387477 -6.87460 -6.17563
15.3691370026 16.158743699 16.2240817 -6.87460 -6.17563
16.8691370026 18.158743699 18.1804849 -6.87460 -6.17563
18.3691370026 20.158743699 20.165737 -6.87460 -6.17563
19.8691370026 22.158743699 22.1609674 -6.87460 -6.17563
21.3691370026 24.158743699 24.1594481 -6.87460 -6.17563
2.5

MINIMO DATOS
l og[H3As O4] I
MINIMO DATOS
l og[H3As O4] I
l og[H3As O4] II
l og[H2As O4(-)] I
l og[H2As O4(-)] II
l og[HAs O4(2-)] I
l og[HAs O4(2-)] II
l og[AsO4(3-)]
l og∑[As (5+)]
A-1
A-3
Eh (Volts) As - H2O - System at 5.00 C
2.0

1.5

1.0

0.5

0.0

H3AsO4(a) H2AsO4(-a) HAsO4(-2a) AsO4(-3a)

-0.5

-1.0

-1.5

H2O Limits
-2.0
0 2 4 6 8 10 12 14

C:\HSC6\EpH\As25.iep pH

ELEMENTS Molality Pressure

As 1.000E-02 1.000E+00

Eh (Volts) As - H2O - System at 25.00 C

2.0

1.5

1.0

0.5

0.0

H3AsO4(a) H2AsO4(-a) HAsO4(-2a) AsO4(-3a)

-0.5

-1.0

-1.5

H2O Limits
-2.0
 -0.5

-1.0

-1.5

H2O Limits
-2.0
0 2 4 6 8 10 12 14

C:\HSC6\EpH\As25.iep pH

ELEMENTS Molality Pressure

As 1.000E-02 1.000E+00

Eh (Volts) As - H2O - System at 95.00 C

2.0

1.5

1.0

0.5

0.0

H3AsO4(a) H2AsO4(-a) HAsO4(-2a) AsO4(-3a)

-0.5

-1.0

-1.5

H2O Limits
-2.0
0 2 4 6 8 10 12 14

C:\HSC6\EpH\As25.iep pH

ELEMENTS Molality Pre ssure

As 1.000E-02 1.000E+00
 Eh (Volts) Fe - H2O - System at 5.00 C
2.0

1.5

1.0

0.5

0.0 Fe(OH)O(a)
4(-3a) Fe(+3a) FeO2(-a)
-0.5

FeOH(+2a)
-1.0

-1.5

H2O Limits
-2.0
14 0 2 4 6 8 10 12 14 16

pH C:\HSC6\EpH\FE25.IEP

ELEMENTS Molality Pressure

Fe 1.000E-03 1.000E+00
Eh (Volts) Fe - H2O - System at 25.00 C
2.0

1.5

1.0

0.5
Fe(OH)O(a)
Fe(+3a)
0.0 FeO2

(-3a)
-0.5

FeOH(+2a)
-1.0

-1.5

H2O Limits
-2.0
0 2 4 6 8 10
 FeOH(+2a)
-1.0

-1.5

H2O Limits
-2.0
0 2 4 6 8 10
14
C:\HSC6\EpH\FE25.IEP
pH

ELEMENTS Molality Pressure

Fe 1.000E-03 1.000E+00
Eh (Volts) Fe - H2O - System at 95.00 C
2.0

1.5

1.0

0.5
Fe(+3a)
0.0 Fe(OH)O(a)
FeO2(-a)
-3a) -0.5
FeOH(+2a)
-1.0

-1.5

H2O Limits -2.0

0 2 4 6 8 10
14
C:\HSC6\EpH\FE25.IEP
pH
ELEMENTS Molality Pressure
Fe 1.000E-03 1.000E+00
em at 5.00 C

FeO2(-a)

H2O Limits

10 12 14 16 18 20

pH

Pressure
3 1.000E+00
em at 25.00 C

H)O(a)

FeO2(-a)

H2O Limits

8 10 12 14
 H2O Limits

8 10 12 14

pH

Pressure
3 1.000E+00
em at 95.00 C

FeO2(-a)

H2O Limits

8 10 12 14

pH

Pressure
3 1.000E+00