yi Mi Tci,r Pci yi*Pci yi*Tci P

CO2 0.02 44.01 547.91 107.1 2.142 10.9582 2000

N2 0.01 28.01 227.49 493.1 4.931 2.2749
C1 0.85 16.04 343.33 666.4 566.44 291.8305
C2 0.04 30.1 549.92 706.5 28.26 21.9968
C3 0.03 44.1 666.06 616.4 18.492 19.9818
iC4 0.03 58.1 734.46 527.9 15.837 22.0338
nC4 0.02 58.1 765.62 550.6 11.012 15.3124

Ppc 647.114 647.114 R2

FZ  R1  r   R3 
Tpc 384.3884 384.3884
r
Ppr 3.090645543135  r  0 .27 p pr /( ZT pr )
Tpr 1.664982606135
R1  A1  A2 / T pr  A3
Z 0.86
R 2  0 . 27 p pr / T pr
R 3  A6  A7 / T pr  A8
A1 0.3265 rho_r 0.812784 R 4  A9 ( A7 / T pr  A8 /
A2 -1.07 R1 -0.433817
A3 -0.5339 R2 0.501191 R 5  A10 / T pr3
A4 0.01569 R3 0.171912
A5 -0.05165 R4 -0.039662
A6 0.5475 R5 0.132897 Hằng số A
A7 -0.7361 A1 0.3265
A8 0.1844 A2 -1.07
A9 0.1056 A3 -0.5339
A10 0.6134 A4 0.01569
A11 0.721 A5 -0.05165
A6 0.5475
A7 -0.7361
A8 0.1844
Fz 9.056041483E-07 A9 0.1056
Pr 0.526825412939 A10 0.6134
A11 0.721

Z 0.951341729664
 T
180

R2
 R1  r   R 3  r2  R 4  r5  R 5 (1  A11  r2 ) exp(  A11  r2 )  1  0
r
 0 . 27 p pr /( ZT pr )
 A1  A2 / T pr  A3 / T pr3  A4 / T pr4  A5 / T pr5
 0 . 27 p pr / T pr
 A6  A7 / T pr  A8 / T pr2
 A9 ( A7 / T pr  A8 / T pr2 )
 A10 / T pr3

Hệ số R Kết quả
R1 -0.433817 F(z) 0
R2 0.501191 ρr
R3 0.171912 z
R4 -0.039662
R5 0.132897