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( s ) = log(A s )− E 2,303RT
Escrevendo a equação de Arrhenius com a dimensão correta, teremos:
log k −1 −1
a [2]
Suponha que o tempo necessário para uma reação alcançar uma certa extensão em
duas diferentes temperaturas, sejam t1 e t2, sabendo que a cinética de reação segue um
mesmo funcional para as temperaturas e que somente as constantes de velocidades
mudam, então:
t1/t2= exp[(-Ea/RT2)]/exp[(-Ea/RT1)]
Exercício: sabendo que ∆H0 = ∆U0 + ∆nRT, mostre que (dlnK0p/dt) = (∆U0/RT2) e que
(dlnK0c/dt) = (∆U0/RT2), onde K0p é a constante de equilíbrio para pressão, K0c é a
constante de equilíbrio para concentração e ∆U0 energia interna molar padrão.
kd
K =0
c ln k d − ln k r = ln K c0 Onde Kco é a constante de
kr
equilíbrio químico.
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k [ A]
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