a By = (6,8 2 w/2 Sag =(6455) 1/2 V3 oporsser| toh) 2-9 4 01968 a5" o-( | - a Ms p = Qp, + 2 Dap= Pan, Ti 141,38; yz 0 0.5, Diag- - -M Ean _{ €s Ee Fi Liia(+138' Wr, Dip Me 74.19% Ma) k \kk k T Vou A c E G 32 ), = ¢§ ot rt oe = )®* exp(DT") exp( FT") exp( HT") m A= 1,06036 B= 0,15610 C=0,19300 D=0,47635 nA =pa(¥a-¥)+P4F E = 1,03587 F=1,52996 G=1,76474 H=3,89411 Naz=Ca(vaz-Vs)# Ca¥, (l-y) 3 Di = —s* . i taiTableE.2 Collision Integrals for Use with the Lennard-Jones (6-12) Potential for the Prediction of Transport Properties of Gases at Low Densities": 0, = % 2,=% xT/e — (forviscosity Aap KT/e (for viscosity Daa or and thermal (for or and thermal (for KT/eqy conductivity) diffusivity) | KT/e4, conductivity) diffusivity) 030 2840 2649 27 10691 0.9782 035 2676 2.468 28 10383 0.9682 040 2531 2314 29 10482 0.9588, 045 2401 2182 30 10388 09500 050 2284 2066 34 10300 0.9418 055 2178 1965 32 10217 0.9340 040 2084 187 33 10139 09267 048 1999 1798 34 1.0066 09197 070 192 179 35 09996 09131 073 1853 1667 36 09931 0.9068 080 1750 1612 37 09868 0.9008 088 1734 1562 38 0.9803 0.8952 080 1682 1517 39 09753 0.8807 085 1636 a7 40 09699 08845, 1.00 1593 1440 4 09687 0879 1.05 1554 1406 0.9598 0.8748 1.0 1518 1375 09551 08703 135 1485 1347 09506 0.8659 1.20 1455 1320 0.9462 08617 125 1427 1296 09420 0.8576 130 1401 1274 0.9380 0.8537 135 137 1253 09341 0.8499 140 1355 1234 0.9004 08463 145 1334 1216 0.9268, 0.8428 1.50 1315 1198 08962 08129 135 1297 1183 oar 07808 1.60 1280 1168 08538, 07m 165 1264 1134 08380 07355 170 1249 141 omnes 0742 13 1235 1128 08018 a7 180 122 17 07836 702s 185 1208 1105 07683, 06878 190 1198 1095 180 07552 06751 195 1186 1085 200 0.7436 0.6640 2.00 1176 1073 250 07198 oat 2.10 1156 1058 300 07010 0.6235 2.20 1138 1042 350 0.5854 6088 2.30 112 1027 400 06723, 0.5964 240 1107 1013 500 06510 05763 250 10933 110006 750 06140 asais 20 1.0807 09890 1000 05887 05180 * The values inthis table, applicable for the Lennard-Jones (6-12) potential, are interpolated from the results of | Monchick and EA. Maton J. Chem: Pye, 35, 1676-1497 (1961). The Monchick-Mason table is Believed to he slightly better than the earlier table by J.O. Hirschfelder, RB. Bir, aE. Spot, J. Chem. Pits, 16, 968-881 (1948). This tale has ben extends to lower temperatures by C. F. Cuts, J. Chem. Piys, 97, 7073-786 (1992). Curis showed that at low temperatures the Bltzmann equation news to be moxie to take into account “orbiting pa ‘of molecules. Only by making this modification is # possible o geta smooth transition from quantum to classical ‘behavior. The deviations are appreciable below dimensionless temperatures of 030. “The collision integrals have been curve-ted by P.D. Neufeld, A.R. Jansen, and R.A. Aziz J. Chem. Phys, 57, 1100-1102 1972), follows: Liss, 05267 _, 216178 _ Oo Oe tet Yep 7ZDOT) @~pOATTETT) a 1.05036 , 019000 1onse7 Poo rast * aap OATARST) * expC 5996T) ay where TP = KT Ye,TableKA (cowinued) 2, =O or viscosity and thermal sTle conductivity) 170 1248 450 9464 400 9422 470 09382 480 09343 490 09305 50 09269 6 0.9963 10 as77 40 ro Dp (or mass ivi) 1140 08610 08568 08530 oso 08856 oss22 osi24 07896 om ite 440) 100 200 300 400 500 00 00 800 90.0 or viscosity and thermal conductivity) 0.9507 saa 0.7432 07005 oons 0.6508 0.6335 0.198 0.6075 0975 ‘Tile K2__Lennardones fore constnts calculated from viscosity data! ET) Bromine Butane Butane Carbon dioxide (Carbon disulfide Carbon monde Carbon tetrachloride Carbonyl suide Galore Caloroform Cyanogen Cyclobexane ‘inane hana Bihylene Pruroine Helium nlleptane nexane ‘Hydrogen “Hydrogen chloride *Caleated rom virial enfin no 27 355 357 27 20 24 250 BI 12 10.22 2et 413 333 30 Do (for mass itfcvit) 05682, ona 0.5640 08232 0.5960) 05756 05596 ote 05352 05256 5.309 2968 3.305 (© Reid and TK, Starwood, The Proprio of Gases and Lig, MeGraHil, New York, 958.Table K2_(comied) Compound Hytoges iodide Tene Keypton Methane Metnano! Methylene chide ety enlone Mercure odie Meeuy Neen Nite oxide Nitogen Nits oxide ‘rOctane Ouygen rePentane Proane Site Siton teracloride Saar dioxide Wace Xenon Formula cH, cH.OH CHC, cael Hels Catt CHa cH. sit, sic, 80; HO ean ®) ma 550 190 16s so 06 53 #1 1 357 19 ois x0 a0 113 MS 258 2016 358 232 356 =) oink 4123 49% 3.60 382 3585 4139 3375 5.625 2898 2709 340 3s 380 343 518 5.01 4.08 sos 4290 260 05s Table 244 Molecular volumes at normal boiling poin for some commonly encountered compounds Compound Hyaroges, Hy Oxygen. Os Nitrogen, Nz Air Carbon monoxide, CO Carbon dioxide, COs Carbonyl sulfide, COS Sullur dioxide, SO; ‘Molecular volume, inceigmal Compousd 143 Nitis oxi, NO 286 Nitrous oxide, NO 312 Ammonia, NH, 299 Water, HO 307 ——_Hydogen sulfide, H,S 340 Bromine, Bra SIS Chlesine, Cl 48 Iodine, Molecular volume, in em'lg mol 2s wos 258 189 329 332 484 13 Table 245 Atomic volumes for complex molecular volumes for simple substances! ‘Atomic volume, Element Bromine Carbon Chlorine Hydrogen Iodine Nitogen, double bond Nivogen. in primary amines Nitogen, in secondary amines in em'/e mol 270 us 216 37 310 136 ws no Oxyen, Oxygen, Oxygen, Oxygen, Element except as noted below in metyl esters in methyl ethers in higher eters and ether esters Oxygen, Sulfue in acids ‘Atomic volume, in em"¥g mal 74 on 99 no Ro 256 1G. Le Bix, Te Molecular Volnes of Lips Chisel Componnds, Longrans, Gree & Company, Lid, onion, 1915. Solvent Water Methanol Ethanol enrene. ether heptane. and other unassociaied solvents oe a 19 1s 10Na, Dap BA ty Nae tos) ow One =-PPap G+ Walnan top) ya. Ca, =SPa, War = earn) |oordendas eangulares: ae "tox {Coordenadas cilindricas: 18(Nae) ay, : o a \Cocrdenadas esfécicas: 1 ,A(sen0Nq.0 “ren 20 Species Diffusion Geometry Distribution, xix} orx4(r) Resistance, Roy x40) aad Ea “Assuming Cand Day ae constant Waa Cans ~ CoedlRear Nay = (Cast ~ Casa Raeays) (1-eya,)™ 1 (rim bs J nee ARRDaCa, [t-AR)coth(AR)] _saR)eot0R)-1] ‘anak Cy) mee ORE Ca__ RB seni(36e/R) an=3% oF senh(36) Mea senh(oz) cx [coin —Semne Nau =Ca (ans) <2 o=(kiPan)!? “Ca, Cale) _ sonblo(-2)) yy Dap, = PABo,, Ca, senh(S) 5 NAS nc Pas| | 7 Aahea™ Ch | ght Nac VkiDar©ao