A.

Compresión isotérmica

Tabla 2.1 Compresión isotérmica p0=74 mm deHg T=25°C T=298 K

V [mL] P manométrica [mm de Hg] PT [mm de Hg]

V1=50 -74 P1 =512
V=48 24 P =610
V=46 50 P =636
V=44 78 P =664
V=43 106 P =692
V=40 140 P =726

Tabla 2.2 Compresión isotérmica del aire

V [mL] PT [mm de Hg]

V1=50 P1 =512 ln(V2/V1) ln(P1/P2)
V2 P2
48 610 -0.0408 -0.1751
46 636 -0.0833 -0.2168
44 664 -0.1278 -0.2599
42 692 -0.1743 -0.3012
40 726 -0.2231 -0.3492

Gráfica 1
0
-0.25 -0.2 -0.15 -0.1 -0.05 0
-0.05

-0.1

y = 0.9493x - 0.1372 -0.15

ln(P1/P2)

-0.2

-0.25

-0.3

-0.35

-0.4
ln(V2/V1)

𝛿𝑙𝑖𝑡𝑒𝑟𝑎𝑡𝑢𝑟𝑎 = 1 𝛿𝑒𝑥𝑝𝑒𝑟𝑖𝑚𝑒𝑛𝑡𝑎𝑙 = 0.9493

 |𝛿𝑙𝑖𝑡𝑒𝑟𝑎𝑡𝑢𝑟𝑎 − 𝛿𝑒𝑥𝑝𝑒𝑟𝑖𝑚𝑒𝑛𝑡𝑎𝑙 |
% 𝑒𝑟𝑟𝑜𝑟 = × 100
𝛿𝑙𝑖𝑡𝑒𝑟𝑎𝑡𝑢𝑟𝑎

|1 − 0.9493|
% 𝑒𝑟𝑟𝑜𝑟 = × 100 = 5.07 %
1

B. Expansión isobárica

C. Expansión adiabática

Tabla 2.4 Coeficiente adiabático

No. Experimento
cm Hg
1 2 3
∆h1 9.6 9.6 9.6
∆h3 1.3 1.4 1.1

P1 = ∆h1 × ρHg + 58.6 [cm Hg] P3 = ∆h3 × ρHg + 58.6 [cm Hg]

𝜌𝐻𝑔 = 13.55 g/mol 𝛾𝑙𝑖𝑡𝑒𝑟𝑎𝑡𝑢𝑟𝑎 = 1.4

Tabla 2.5 Coeficiente adiabático del aire

𝑷𝟐
No. 𝑷𝟏 𝑷𝟐 𝑷𝟑 𝒍𝒏( ⁄𝑷 ) |𝜸𝒆𝒙𝒑 − 𝜸𝒍𝒊𝒕 |
𝟏
𝜸= % 𝒆𝒓𝒓𝒐𝒓 = × 𝟏𝟎𝟎
Experimento [cm Hg] [cm Hg] [cm Hg] 𝑷𝟑 𝜸𝒍𝒊𝒕
𝒍𝒏( ⁄ ) 𝑷𝟏
1 188.68 58.6 76.21 1.28 8.57
2 188.68 58.6 77.57 1.31 6.42
3 188.68 58.6 73.50 1.24 11.42