Lab.

Ing de las Reacciones

Cálculos para Caso Equimolar
Integrantes Katherine Álvarez
Erika Gutiérrez
Jhonatan Criollo
Cristian Pavón
Reacción NaHCO3 + HCl

Parámetros Resultado
Intervalo de tiempo 30 seg 0:00:30
Para la reacción con concentraciones
Concentración 0,5 M Ca=Cb=0,5M el orden de reacción es
Conc. Infinito 7.06 n=2 , realizado con el método integral
Conc. Inicial 7.1
Cond. Inicial 8.24
Cond. Infinito 7.24

n=0 n=1
Tiempo video Tiempo seg Conductividad pH Concentración Cao-Caf=kt Ln(Ca/Cao)
0:00:14 0 8.24 7.10 7.1 0 0
0:00:44 30 8.00 7.10 7.0904 -0.0096 -0.0005876
0:01:14 60 7.50 7.10 7.0704 -0.0296 -0.0018144
0:01:44 90 7.15 7.10 7.0564 -0.0436 -0.0026752
0:02:14 120 7.07 7.09 7.0532 -0.0468 -0.0028721
0:02:44 150 7.05 7.07 7.0524 -0.0476 -0.0029214
0:03:14 180 6.10 7.09 7.0144 -0.0856 -0.0052678
0:03:44 210 5.89 7.07 7.006 -0.094 -0.0057882
0:04:14 240 5.43 7.07 6.9876 -0.1124 -0.0069303
0:04:44 270 5.40 7.07 6.9864 -0.1136 -0.0070049
0:05:14 300 4.65 7.06 6.9564 -0.1436 -0.0088738
0:05:44 330 4.60 7.06 6.9544 -0.1456 -0.0089987
0:06:14 360 4.20 7.06 6.9384 -0.1616 -0.009999
0:06:44 390 4.35 7.06 6.9444 -0.1556 -0.0096236

Concentracion vs tiempo
7.15

7.1
f(x) = 1.23321123321166E-07x^2 - 0.0004858681x + 7.1033085714
R² = 0.9779791611
Concententración

7.05

6.95

6.9

6.85
0 50 100 150 200 250 300 350 400 450
Tiempo (s)
Resultado

ón con concentraciones
el orden de reacción es
o con el método integral

1E-07x2 - 0,0005x + 7,1033 3E-09x3 - 1E-06x2 - 0,0002x + 7,0966

n=2 n=3 grado2 grado 3
1/ca 1/Ca^2 dCa/dt LOG(-dCa/dt) log(ca) dCa/dt LOG(-dCa/dt)log(ca)
0.14084507 0.01983733 -0.0005 -3.30 0.85125835 -0.0002 -3.69897 0.85125835
0.14103577 0.01989109 -0.000497 -3.30 0.85067074 -0.0002519 -3.5987718 0.85067074
0.14143471 0.02000378 -0.000494 -3.31 0.84944398 -0.0002876 -3.5412111 0.84944398
0.14171532 0.02008323 -0.000491 -3.31 0.84858319 -0.0003071 -3.5127202 0.84858319
0.14177962 0.02010146 -0.000488 -3.31 0.8483862 -0.0003104 -3.5080783 0.8483862
0.1417957 0.02010602 -0.000485 -3.31 0.84833694 -0.0002975 -3.526513 0.84833694
0.14256387 0.02032446 -0.000482 -3.32 0.84599053 -0.0002684 -3.5712175 0.84599053
0.1427348 0.02037322 -0.000479 -3.32 0.84547013 -0.0002231 -3.6515004 0.84547013
0.14311065 0.02048066 -0.000476 -3.32 0.84432804 -0.0001616 -3.7915586 0.84432804
0.14313523 0.0204877 -0.000473 -3.33 0.84425345 -0.0000839 -4.076238 0.84425345
0.14375252 0.02066479 -0.00047 -3.33 0.84238455 0.00001 Err:502 0.84238455
0.14379386 0.02067667 -0.000467 -3.33 0.84225967 0.0001201 Err:502 0.84225967
0.14412545 0.02077214 -0.000464 -3.33 0.84125933 0.0002464 Err:502 0.84125933
0.14400092 0.02073627 -0.000461 -3.34 0.84163473 0.0003889 Err:502 0.84163473

-3.28
0.84 0.842 0.844 0.846 0.848 0.85 0.852

-3.29

-3.30
f(x) = 3.2593818692x - 6.0759417866
R² = 0.9764078744
-3.31

-3.32

-3.33

-3.34
1E-11x4 - 9E-09x3 + 2E-06x2 - 0,0003x + 7,0995
grado4
dCa/dt Log(Ca) LOG(-dCa/dt) -3.2
0.843 0.844 0.845 0.846 0.847 0.848 0.849 0.85 0.851 0
-0.0003 0.85125835 -3.5228787 -3.3
-0.0002032 0.85067074 -3.6920336
-3.4
-0.0001486 0.84944398 -3.8280981
-0.0001295 0.84858319 -3.8875961 -3.5
f(x) = 39.7872652907x - 37.3742347787
-0.0001397 0.8483862 -3.8548658 -3.6 R² = 0.3252736034
-0.0001725 0.84833694 -3.7632109
-3.7
-0.0002215 0.84599053 -3.6545871
-0.0002803 0.84547013 -3.5524389 -3.8

-0.0003422 0.84432804 -3.4656692 -3.9

-0.000401 0.84425345 -3.3968773
-4
-0.00045 0.84238455 -3.3467875
-0.0004828 0.84225967 -3.3162147 -4.1

-0.000493 0.84125933 -3.3071883 -4.2

-0.0004739 0.84163473 -3.3242766
 Chart Title
0
0
f(x) = - 0.0004377729x
50 100
+ 0.0004228571
150 200 250 300 350 400 450

-0.02
R² = 0.9770859328

-0.04

-0.06

-0.08

-0.1

-0.12

-0.14

-0.16

-0.18
 n=1
0
0
f(x) = - 2.70983680599915E-05x
50 100 150
+ 4.43912940075366E-05
200 250 300 350 400 450

R² = 0.9771502763
-0.002

-0.004
ln (Ca/Cao)

-0.006

-0.008

-0.01

-0.012

Tíiempo (s)
 n=2
0.145

f(x) = 8.89370406097004E-06x + 0.1408245482

0.144 R² = 0.9771981716

0.143

0.142
1/Ca

0.141

0.14

0.139
0 50 100 150 200 250 300 350 400 450

Tiempo (seg)
 Método Integral para la reacción equimolar, gráfica para un orden de reacción 3
0.021

0.0208
f(x) = 2.5354228621164E-06x + 0.0198297937
0.0206 R² = 0.9772296494
0.0204

0.0202
1/Ca^2

0.02

0.0198

0.0196

0.0194

0.0192
0 50 100 150 200 250 300 350 400 450

Tiempo