C3H6

C3H8

Arus 11 Arus 2

P=XX atm C3H6 C3H8O

Arus 1 T =XX oC C3H8 H2O P=XX atm
H2O
T =XX oC
C 3H 6 Arus 4
C 3H 8 Arus 8
C-01
C3H6
C3H8 P=XX atm
R-01 C6H14O T =XX oC
C3H6
C3H8O
C3H8
H2O
P=78,9 atm C6H14O
T =148,02 oC Arus 3 C3H8O P=XX atm
SP-01 H2O T =XX oC
C3H6
C3H8 P=XX atm
C6H14O T =XX oC
Arus 5
C3H8O C6H14O
H2O C3H8O
H2O
C-02
C6H14O C-03
C3H8O
H2O

C3H8O
P=1 atm
T =99,99 oC H2O
 P=XX atm
T =XX oC
T-01
C6H14O P=XX atm
C3H8O T =XX oC
C6H14O T-02
C3H8O
H2O

C-04
C-03
P=1 atm
T =98,57oC
P=XX atm
T =XX oC C3H8O
C6H14O H2O
C3H8O
H 2O
Basis 6500 kg/jam masuk R-01 Selektivitas
Data C6H14O
Koversi Propilen
BM Massa(kg) mol (kmol)
C3H6 42 0.94 6110 145.47619
C3H8 44 0.06 390 8.86363636
C6H14O 102
C3H8O 60 C3H6
H2O 18 C3H8

1 12
C3H6 + H2O <=> C3H8O
m 145.4762 1745.7143
r 110.5619 110.5619 110.5619047619
s 34.9143 1635.1524 110.5619047619

2C3H8O <=> H2O + C6H14O

m 110.5619 0.0000
r 13.9308 6.9654 6.9654
s 96.6311 6.9654 6.9654

Masuk Keluar
mol Kg mol Kg
C3H6 145.47619 6110 34.9142857 1466.4
C3H8 8.8636364 390 8.86363636 390
C6H14O 0 0 6.9654 710.4708
C3H8O 0 0 96.6311048 5797.866285714
H2O 1745.714 31422.8571429 1642.11778 29558.12005714
Total 37922.8571429 1789.49221 37922.85714
 0.93 Kapasitas Produksi
0.063 45000 ton/tahun
0.76 Asumsi karena diketahui >0.75 134.3284 ton/hari
5.597015 ton/jam
5597.015 kg/jam
93.28358 kmol/jam

6110 kg/jam H2O

390 kg/jam 31422.86 Kg/jam

Selektivtas C3H8O
Terhadap

R-01
H2O 0.932764
C3H6 0.874

C3H6 1466.4 Kg/jam

C3H8 390 Kg/jam
C6H14O 710.4708 Kg/jam
C3H8O 5797.866 Kg/jam
H2O 29558.12 Kg/jam
 SEPARATOR (SP-01)

Antoine Suhu
Komponen
A B C Separator
Propilene 6.8196 785 247 88.98
Propane 6.80398 803.81 246.99 88.98
Diisopropil Ether 7.0971 1257.6 230.01 88.98
Isopropil Alkohol 8.1182 1580.92 219.62 88.98
Air 8.07131 1730.63 233.426 88.98

Recovery LK 0.998 Komponen Feed Top Bottom BM

Recovery HK 0.002 Propilene 34.91429 34.91429 0 42
Propane 8.863636 8.863636 0 44
Diisopropil Ether 6.9654 0.013931 6.951469 102
Isopropil Alkohol 96.6311 0.193262 96.43784 60
Air 1642.118 3.284236 1638.834 18
Total 1789.492 47.26935 1742.223
1,1,1-tribromododecane
PARATOR (SP-01)

Titik Didih Pi (mmHg) Pi (atm)

47.75 30419.453107038 40.025596193
-42.2 25791.38810998 33.936036987
69 1427.7647754269 1.8786378624
80.4 989.2874248557 1.3016939801
100 505.1854584166 0.6647177084

Top( kmol/jam) Bottom(kmol/jam) Xd Xw

1466.4 0 0.7603707404 0
390 0 0.2022262608 0
1.4209416 709.0498584 0.0007367992 0.0196989351
11.5957325714 5786.2705531429 0.0060127222 0.1607550823
59.1162401143 29499.003817029 0.0306534774 0.8195459826
1928.5329142857 35994.324228572 1 1
Diketahui D
Feed Distillate
Recovery LK 0.8 Component
(Kmol/jam) (Kmol/jam)
Recovery HK 0.2 1173.1200 Propilene 34.91429 27.931429
Purity 94 78.0000 Propane 8.86364 1.772727
0.0006 Diisopropil Ether 0.01393 0.000006
0.0046 Isopropil Alkohol 0.19326 0.000077
0.0236 Air 3.28424 0.001310
1251.1488 Total 47.26935 29.705548801

Diketahui Dis
Feed Distillate
Recovery LK 0.99 Component
(Kmol/jam) (Kmol/jam)
Recovery HK 0.01 Propilene 0 0
Purity 99 Propane 0 0
Diisopropil Ether 6.9514692 6.9476213301
Isopropil Alkohol 96.437842552 95.473464127
Air 1638.8335454 16.388335454
Total 1742.2228571 118.80942091

Diketahui Distillatio
Feed Distillate
Recovery LK 0.999 Component
(Kmol/jam) (Kmol/jam)
Recovery HK 0.001 Propilene 0 0
Purity 78 Propane 0 0
Diisopropil Ether 6.9476213301 6.9406737088
Isopropil Alkohol 95.473464127 0.0954734641
Air 16.388335454 0
Total 118.80942091 7.0361471729

Diketahui Distilla
Feed Distillate
Recovery LK 0.99 Component
(Kmol/jam) (Kmol/jam)
Recovery HK 0.01 Propilene 0 0
Purity 99 Propane 0 0
Diisopropil Ether 0.0069476213 0.0068883361
Isopropil Alkohol 95.377990663 94.424210756
Air 16.388335454 0.1638833545
Total 111.77327374 94.594982447
 Tee-01
Component Recycle C-01
Feed (Kg/jam)
(Kg/jam)
0.9405587478 Propilene 4936.88 1173.12
Propane 312 78
Diisopropil Ether 0 0.000567
Isopropil Alkohol 0 0.004626
Air 0 0.023585
Total 5248.88 1251.1487785
6500.0287785

Kapasitas 135970.86349 Kg/hari

49629365.173 Kg/tahun
45550239.269 Kg/tahun
49629.365173 Ton/tahun
45550.239269 Ton/tahun
 Distillation Column 1 (Propilene-Propane)
Bottom (Kmol/jam) Xd Xw BM Distillate
(Kg/jam)
6.982857 0.94027647 0.397571 42 1173.12
7.090909 0.05967664 0.403723 44 78
0.013925 0.00000019 0.000793 102 0.000567
0.193185 0.00000260 0.010999 60 0.004626
3.282925 0.00004411 0.186914 18 0.023585
17.563802 1.00000000 1251.1487785
1928.5329143

Distillation Column 2 (Isopropil Alkohol-Air)

Bottom (Kmol/jam) Xd Xw BM Distillate
(Kg/jam)
0 0 0 42 0
0 0 0 44 0
0.0038478699 0.0584770238 2.370234120257E-06 102 708.65737567
0.9643784255 0.8035849632 0.0005940436 60 5728.4078476
1622.4452099366 0.1379380131 0.9994035861 18 294.99003817
1623.413436232 6732.0552615

Distillation Column 3 (Diisopropil Eter-Isopropil Alkohol)

Bottom (Kmol/jam) Xd Xw BM Distillate
(Kg/jam)
0 0 0 42 0
0 0 0 44 0
0.0069476213 0.9864310024 6.215816266033E-05 102 707.94871829
95.3779906627 0.0135689976 0.8533166067 60 5.7284078476
16.3883354539 0 0.1466212352 18 0
111.773273738 713.67712614

Distillation Column 4 (Isopropil Alkohol-Impurities)

Bottom (Kmol/jam) Xd Xw BM Distillate
(Kg/jam)
0 0 0 42 0
0 0 0 44 0
5.92852065783E-05 7.281925474E-05 3.451170175969E-06 102 0.7026102846
0.9537799066 0.9981947067 0.0555223969 60 5665.4526454
16.2244520994 0.0017324741 0.944474152 18 2.9499003817
17.1782912912 5669.105156
Tee-01 Tee-02
Feed R-01 Recycle C-02 Feed R-01 (Air)
Feed (Kg/jam)
(Propilene) (Kg/jam) (Kg/jam) (Kg/jam)
6110 0 0 0
390 0 0 0
0.0005669055 0 0.392483 0.392483
0.0046262876 0 57.862706 57.862706
0.0235852911 2218.8433611417 29204.013779 31422.857140
6500.0287784842 2218.8433611417 29262.268967 31481.112328

(Tanpa Shutdown)
(Dengan Shutdown)
 Xf
Bottom (Kg/jam)
293.28 0.7386241874
312 0.1875133938
1.420375 0.0002947111
11.591106 0.0040885311
59.092655 0.0694791766
677.384136 1

Bottom (Kg/jam)
0
0
0.3924827316
57.8627055314
29204.013778858
29262.268967121

Bottom (Kg/jam)
0
0
0.7086573757
5722.6794397638
294.9900381703
6018.3781353098

Bottom (Kg/jam)
0
0
0.0060470911
57.2267943976
292.0401377886
349.2729792773
 Neraca Massa Overall
Input Output
Component
Feed TEE-01 Feed TEE-02 Bottom C-01 Top C-03 Bottom C-04
Propilene 4936.88 0 293.28 0 0
Propane 312 0 312 0 0
Diisopropil Ether 0 0 1.420375 707.94871829 0.0060470911
Isopropil Alkohol 0 0 11.591106 5.7284078476 57.226794398
Air 0 2218.84336114 59.092655 0 292.04013779
5248.88 2218.84336114 677.3841358 713.67712614 349.27297928
Total
7467.7234 7467.7234
 Output
Top C-04 Recycle TEE-02 Recycle TEE-01
0 0 0
0 0 0
0.7026102846 0.3924827316 0.000567
5665.4526454 57.8627055314 0.004626
2.9499003817 0 0.023585
5669.105156 58.255188263 0.028778
7467.7234
 12 atm Distillation Colu
P 12.156 Bar Feed Distillate Bottom
Temp ( c ) αav
9119.2793 mmHg 32.27346 28.63396917 41.0638276
Propilene 0.738624 0.94027647 0.39757094 1.209182
Propane 0.187513 0.059676638 0.4037229 1
Diisopropil Ether 0.000295 1.871E-07 0.00079284 0.024873
Isopropil Alkohol 0.004089 2.59564E-06 0.01099905 0.008939
Air 0.069479 4.41094E-05 0.18691427 0.004638
Total 1 1 1

Distillation Colu
P 1.01325 Bar Feed Distillate Bottom
Temp ( c ) αav
760.12748 mmHg 84.93468937 99.9855893
Propilene 0 0 0 55.9792
Propane 0 0 0 47.52237
Diisopropil Ether 0.019699 0.058477024 2.3702E-06 2.736139
Isopropil Alkohol 0.160755 0.803584963 0.00059404 1.956869
Air 0.819546 0.137938013 0.99940359 1
Total 1 1 1

Distillation Colu
P 1.01325 Bar Distillate Bottom Antoine
Temp ( c ) αav
760.12748 mmHg 68.59452 84.11225257 A
Propilene 0 0 41.4396784 6.8196
Propane 0 0 34.955394 6.80398
Diisopropil Ether 0.986431 6.21582E-05 1.64602227 7.0971
Isopropil Alkohol 0.013569 0.853316607 1 8.1182
Air 0 0.146621235 0.51056305 8.07131
Total

Distillation Colu
P 1.01325 Bar Distillate Bottom Antoine
Temp ( c ) αav
760.12748 mmHg 82.27798 98.56571745 A
Propilene 0 0 58.5883248 6.8196
Propane 0 0 49.6983099 6.80398
Diisopropil Ether 7.28E-05 3.45117E-06 2.79184608 7.0971
Isopropil Alkohol 0.998195 0.055522397 1.95730086 8.1182
 Air 0.001732 0.944474152 1 8.07131
Total

P
 Operating Conditions

Distillation Column 1
Antoine
Po (f) Po (d) Po (w) Ki (f) Ki (d) Ki (w)
A B C
6.8196 785 247 10203.16709 9367.422621 12431.09829 1.118857 1.027211 1.36317
6.80398 803.81 246.99 8426.720628 7720.610314 10315.60256 0.924056 0.846625 1.13119
7.0971 1257.6 230.01 200.5799802 171.7187325 286.9283563 0.021995 0.01883 0.03146
8.1182 1580.92 219.62 69.5111656 56.23983181 113.1589139 0.007622 0.006167 0.01241
8.07131 1730.63 233.426 36.12625708 29.33347817 58.40006502 0.003962 0.003217 0.00640
1.90205

Distillation Column 2
Antoine
Po (d) Po (w) Ki (d) Ki (w) αd αb
A B C
6.8196 785 247 28488.98286 36079.30871 37.4792169 47.46481 65.98327 47.49191
6.80398 803.81 246.99 24116.60742 30715.7907 31.7270562 40.40874 55.85642 40.4318
7.0971 1257.6 230.01 1270.62649 1932.59109 1.671596562 2.542457 2.942895 2.543908
8.1182 1580.92 219.62 845.8177775 1485.006342 1.112731476 1.953628 1.958997 1.954743
8.07131 1730.63 233.426 431.7607088 759.6938371 0.568010916 0.99943 1 1

Distillation Column 3
Antoine
Po (d) Po (w) Ki (d) Ki (w) αd αb x
B C
785 247 21489.74 28106.24346 28.27122497 36.97569689 50.03235 34.32273 0
803.81 246.99 18068.77 23784.87952 23.77070839 31.29064534 42.06767 29.04557 0
1257.6 230.01 768.262 1240.4041 1.010701466 1.63183693 1.788666 1.514754 0.975987
1580.92 219.62 429.5168 818.8813642 0.565058862 1.077294771 1 1 0.024013
1730.63 233.426 219.3494 417.9876855 0.288569185 0.549891556 0.510689 0.510437 0
1

Distillation Column 4
Antoine
Po (d) Po (w) Ki (d) Ki (w) αd αb x
B C
785 247 27264.41 35315.27748 35.86820165 46.4596771 70.16145 48.92419 0
803.81 246.99 23055.63 30049.88582 30.33126183 39.53269213 59.33069 41.62975 0
1257.6 230.01 1175.027 1860.680041 1.545828489 2.447852602 3.02378 2.577702 4.71E-05
1580.92 219.62 761.3713 1411.416449 1.001636317 1.856815439 1.959291 1.955313 0.996564
1730.63 233.426 388.5953 721.836749 0.511223814 0.949625903 1 1 0.003389
1
 αd αb x y y
1.213301 1.205077 0.915369 0.541955 0.82641465
1 1.000000 0.070488 0.456686 0.17327279
0.022242 0.027815 0.00001 0.000025 0.0000065
0.007284 0.010970 0.000421 0.000136 0.0000312
0.003799 0.005661 0.013713 0.001197 0.00027524
2.246626 1 1 1.00000034

x y
0 0
0 0
0.034983 6.02622E-06
0.722173 0.00116054
0.242844 0.998833434
1 1

y
0
0
0.000101
0.919274
0.080626
1.000001

y
0
0
8.45E-06
0.103095
0.896897
1
 Minimum Reflux Ratio

Distillation Column 1
ɵ 1.036299 Component Xf αav αav x Xf αav - ɵ
q 1 Propilene 0.738624 1.209182 0.893131 0.1728827
Propane 0.187513 1 0.187513 -0.0362993
Diisopropil Ether 0.000295 0.024873 7.33E-06 -1.0114267
Isopropil Alkohol 0.004089 0.008939 3.65E-05 -1.0273603
Air 0.069479 0.004638 0.000322 -1.0316615

Distillation Column 2
ɵ 1.683017 Component Xf αav αav x Xf αav - ɵ
q 1 Propilene 0 55.9792 0 54.2961866
Propane 0 47.52237 0 45.8393536
Diisopropil Ether 0.019699 2.736139 0.053899 1.05312159
Isopropil Alkohol 0.160755 1.956869 0.314577 0.27385183
Air 0.819546 1 0.819546 -0.6830169

Distillation Column 3 (n-Butane - i-Pentane)

ɵ 1.579731 Component Xf αav αav x Xf αav - ɵ
q 1 Propilene 0 41.43968 0 39.8599469
Propane 0 34.95539 0 33.3756625
Diisopropil Ether 0.058477 1.646022 0.096254 0.0662908
Isopropil Alkohol 0.803585 1 0.803585 -0.5797315
Air 0.137938 0.510563 0.070426 -1.0691684

Distillation Column 4 (i-Pentane - n-Pentane)

ɵ 1.077253 Component Xf αav αav x Xf αav - ɵ
q 1 Propilene 0 58.58832 0 57.5110717
Propane 0 49.69831 0 48.6210568
Diisopropil Ether 6.22E-05 2.791846 0.000174 1.71459294
Isopropil Alkohol 0.853317 1.957301 1.670197 0.88004772
Air 0.146621 1 0.146621 -0.0772531
 (αav x Xf)/(αav - ɵ) Component Xd αav αav x Xd αav - ɵ
5.1661102405 Propilene 0.94027647 1.209182 1.136965 0.172882704
-5.1657518005 Propane 0.05967664 1 0.059677 -0.03629934
-7.24743743579E-06 Diisopropil Ether 1.871E-07 0.024873 4.65E-09 -1.01142667
-3.55744192761E-05 Isopropil Alkohol 2.5956E-06 0.008939 2.32E-08 -1.02736025
-0.0003123437 Air 4.4109E-05 0.004638 2.05E-07 -1.03166151
3.274428746035E-06 Rm+1
Rm
1.25 *Rm
Reflux ratio
4.91562367

(αav x Xf)/(αav - ɵ) Component Xd αav αav x Xd αav - ɵ

0 Propilene 0 55.9792 0 54.29618663
0 Propane 0 47.52237 0 45.83935359
0.0511802394 Diisopropil Ether 0.05847702 2.736139 0.160001 1.053121588
1.1487109533 Isopropil Alkohol 0.80358496 1.956869 1.57251 0.27385183
-1.1998911857 Air 0.13793801 1 0.137938 -0.68301692
0.000000007 Rm+1
Rm
1.25 *Rm
Reflux ratio
5.86521288

(αav x Xf)/(αav - ɵ) Component Xd αav αav x Xd αav - ɵ

0 Propilene 0 41.43968 0 39.85994693
0 Propane 0 34.95539 0 33.3756625
1.4520035812 Diisopropil Ether 0.986431 1.646022 1.623687 0.066290803
-1.3861330899 Isopropil Alkohol 0.013569 1 0.013569 -0.57973146
-0.0658699339 Air 0 0.510563 0 -1.06916841
5.5741669934E-07 Rm+1
Rm
1.25 *Rm
Reflux ratio
29.3374975
 (αav x Xf)/(αav - ɵ) Component Xd αav αav x Xd αav - ɵ
0 Propilene 0 58.58832 0 57.51107167
0 Propane 0 49.69831 0 48.62105676
0.0001012112 Diisopropil Ether 7.2819E-05 2.791846 0.000203 1.714592943
1.8978485855 Isopropil Alkohol 0.99819471 1.957301 1.953767 0.880047723
-1.8979325081 Air 0.00173247 1 0.001732 -0.07725313
1.728858391892E-05 Rm+1
Rm
1.25 *Rm
Reflux ratio
1.61697926
(αav x Xd)/(αav - ɵ)
6.5765134477
-1.6440142874
-4.60109253116E-09
-2.25846992515E-08
-1.98293855894E-07
4.9324989348
3.9324989348

(αav x Xd)/(αav - ɵ)
0
0
0.1519304499
5.7421938763
-0.2019540204
5.6921703058
4.6921703058

(αav x Xd)/(αav - ɵ)
0
0
24.4934036639
-0.0234056602
0
24.4699980037
23.4699980037
(αav x Xd)/(αav - ɵ)
0
0
0.0001185705
2.220069781
-0.0224259389
2.1977624126
1.1977624126
Distillation Column 1 Distillation Column 2

Minimum Number of Stage Minimum Number of Stage

feed X.lk 0.738624 feed X.lk 0.160755

X.hk 0.187513 X.hk 0.819546
distillat D 140.8657 Kmol/hr distillat D 10.20626 Kmol/hr
X.lk 0.940276 X.lk 0.803585
X.hk 0.059677 X.hk 0.137938
bottom B 1601.357 Kmol/hr bottom B 1601.357 Kmol/hr
X.lk 0.397571 X.lk 0.000594
X.hk 0.403723 X.hk 0.999404
alpha.lk 1.209182 alpha.lk 1.956869

Nm 14.59686 Nm 13.6892823

Rm 3.932499 Rm 4.69217031
Rop 4.915624 Rop 5.86521288

Actual Number of Stage Actual Number of Stage

R/(R+1) 0.830956 R/(R+1) 0.85433809
Rm/(Rm+1) 0.797263 Rm/(Rm+1) 0.82432008
Nm/N 0.3 Fig. 11.11 Nm/N 0.3 Fig. 11.11
N 48.65621 N 45.630941

Feed Stage Location Feed Stage Location

Log(Nr/Ns) 0.434148 Log(Nr/Ns) -0.3767124
Nr/Ns 2.717362 Nr/Ns 0.42003704
Nr 2.717362 Ns Nr 0.42003704 Ns
Nr+Ns 48.65621 Nr+Ns 45.630941
Ns 13.08891 Ns 32.1336272
Nr 35.56731 Nr 13.4973137
Distillation Column 3 Distillation Column 4

Minimum Number of Stage Minimum Number of Stage

feed X.lk 0.05847702 feed X.lk 0.853317

X.hk 0.80358496 X.hk 0.146621
distillat D 10.2062596 Kmol/hr distillat D 113.5142
X.lk 0.986431 X.lk 0.998195
X.hk 0.013569 X.hk 0.001732
bottom B 130.659397 Kmol/hr bottom B 17.14521
X.lk 6.2158E-05 X.lk 0.055522
X.hk 0.85331661 X.hk 0.944474
alpha.lk 1.64602227 alpha.lk 1.957301

Nm 27.71784 Nm 13.68478

Rm 23.47 Rm 1.197762
Rop 29.3375 Rop 1.616979

Actual Number of Stage Actual Number of Stage

R/(R+1) 0.967037 R/(R+1) 0.61788
Rm/(Rm+1) 0.959134 Rm/(Rm+1) 0.544992
Nm/N 0.2 Fig. 11.11 Nm/N 0.4 Fig. 11.11
N 138.5892 N 34.21195

Feed Stage Location Feed Stage Location

Log(Nr/Ns) -0.50115 Log(Nr/Ns) 0.293711
Nr/Ns 0.31539 Nr/Ns 1.966578
Nr 0.31539 Ns Nr 1.966578 Ns
Nr+Ns 138.5892 Nr+Ns 34.21195
Ns 105.3598 Ns 11.53246
Nr 33.22941 Nr 22.67949
mber of Stage

Kmol/hr

Kmol/hr

ber of Stage

e Location