Report - CAMEO Chemicals - NOAA

18/06/2020 Report | CAMEO Chemicals | NOAA
Impressão
Substâncias contidas neste relatório
1. ALFA-CICLODEXTRINA
2. BENZENO
3. ÁCIDO PERCLÓRICO, COM MAIS DE 50%, MAS NÃO MAIS DE 72% DE ÁCIDO
4. GLICERINA
5. ANILINA
6. BENZALDEÍDO
7. TOLUENO
8. SOLUÇÃO DE GLUTARALDEÍDO
9. ÁCIDO TRICLOROACÉTICO
10. N, N-DIMETILFORMAMIDA
11. M-XYLENE
12. CLOROFÓRMIO
13. METANOL
14. DIOXANE
15. ACETONITRILE
16. FORMALDEÍDO
17. TRIETILAMINA
18. ACETONA
19. N-OCTANE
20. ÁCIDO ACÉTICO, GLACIAL
21. ETANOL
22. ACETATO DE ETILO
23. ANIDRIDE ACÉTICO
24. CYCLOHEXANONE
25. MATERIAL RADIOATIVO, HEXAFLUORETO DE URÂNIO FÍSICO
26. CIANETO DE POTÁSSIO
27. ÁCIDO FOSFÓRICO
28. ÁCIDO LÁTICO
Ó
https://cameochemicals.noaa.gov/report Ô 1/319
29. HIDRÓXIDO DE AMÔNIO
30. PENTANE-2,4-DIONE
31. 1,4-BUTANEDIOL
32. Fósforo, branco, seco ou debaixo de água ou em solução
33. NITRATO DE POTÁSSIO
34. METIL-ETIL-CETONA
35. TETRACLORETO DE CARBONO
36. PERÓXIDO DE HIDROGÊNIO, SOLUÇÃO AQUOSA, COM NÃO MENOS DE 20%, MAS NÃO MAIS DE
60% DE PERÓXIDO DE HIDROGÊNIO (ESTABILIZADO COMO NECESSÁRIO)
37. ÁCIDO FÓRMICO
38. DICLOROMETANO
39. CLORETO DE POTÁSSIO
40. ÁCIDO SULFÚRICO
41. ÁCIDO PÍCRICO, [SECO]
42. ÁCIDO HIDROCLÓRICO, SOLUÇÃO
43. HIDRATO DE ALUMÍNIO E LÍTIO
Conteúdo
Este relatório contém:
Previsões de risco de reação associadas à mistura dessas substâncias.
Informações detalhadas da folha de dados de cada substância.
https://cameochemicals.noaa.gov/report 2/319
Reatividade Química
Substâncias na mistura
1. ALFA-CICLODEXTRINA
2. BENZENO
3. ÁCIDO PERCLÓRICO, COM MAIS DE 50%, MAS NÃO MAIS DE 72% DE ÁCIDO
4. GLICERINA
5. ANILINA
6. BENZALDEÍDO
7. TOLUENO
8. SOLUÇÃO DE GLUTARALDEÍDO
9. ÁCIDO TRICLOROACÉTICO
10. N, N-DIMETILFORMAMIDA
11. M-XYLENE
12. CLOROFÓRMIO
13. METANOL
14. DIOXANE
15. ACETONITRILE
16. FORMALDEÍDO
17. TRIETILAMINA
18. ACETONA
19. N-OCTANE
20. ÁCIDO ACÉTICO, GLACIAL
21. ETANOL
22. ACETATO DE ETILO
23. ANIDRIDE ACÉTICO
24. CYCLOHEXANONE
25. MATERIAL RADIOATIVO, HEXAFLUORETO DE URÂNIO FÍSICO
26. CIANETO DE POTÁSSIO
27. ÁCIDO FOSFÓRICO
28. ÁCIDO LÁTICO
29. HIDRÓXIDO DE AMÔNIO
30. PENTANE-2,4-DIONE
31. 1,4-BUTANEDIOL
32. Fósforo, branco, seco ou debaixo de água ou em solução
33. NITRATO DE POTÁSSIO
34. METIL-ETIL-CETONA
35. TETRACLORETO DE CARBONO
36. PERÓXIDO DE HIDROGÊNIO, SOLUÇÃO AQUOSA, COM NÃO MENOS DE 20%, MAS NÃO MAIS DE
60% DE PERÓXIDO DE HIDROGÊNIO (ESTABILIZADO COMO NECESSÁRIO)
37. ÁCIDO FÓRMICO
38. DICLOROMETANO
39. CLORETO DE POTÁSSIO
40. ÁCIDO SULFÚRICO
41. ÁCIDO PÍCRICO, [SECO]
42. ÁCIDO HIDROCLÓRICO, SOLUÇÃO
43. HIDRATO DE ALUMÍNIO E LÍTIO
Resumo das previsões de perigo (para todos os pares de substâncias)
Corrosivo: Os produtos da reação podem ser corrosivos

Explosivo: Os produtos da reação podem ser explosivos ou sensíveis a choques ou fricção
Inflamável: Os produtos da reação podem ser inflamáveis
Gera gás: a reação libera produtos gasosos e pode causar pressurização
Gera calor: reação exotérmica à temperatura ambiente (libera calor)
Instável quando aquecido: Os produtos da reação podem ser instáveis acima da temperatura ambiente
Reação intensa ou explosiva: A reação pode ser particularmente intensa, violenta ou explosiva
Perigo de polimerização: A reação de polimerização pode se tornar intensa e causar pressurização
Tóxico: Os produtos da reação podem ser tóxicos
Potencialmente perigoso: Pode ser perigoso, mas desconhecido
Resumo das previsões de gases (para todos os pares de substâncias)
Pode produzir os seguintes gases:
Fumos ácidos
Óxido de Alumínio (Al2O3)
Álcoois
Aldeídos
Bromo (BR2)
Fumos de Base
Monóxido de carbono (CO)
Dióxido de Carbono (CO2)
Fosgênio (COCl2)
Aminas cloradas
Cloro (Cl2)
Dióxido de Cloro (ClO2)
Difluorodiazeno
Éteres
Perclorato de flúor (FClO4)
Alemães
Hidrogênio (H2)
Sulfeto de hidrogênio (H2S)
Sulfato de hidrogênio (H2SO4)
Brometo de hidrogênio (HBr)
Cianeto de hidrogênio (HCN)
Cloreto de Hidrogênio (HCl)
Fluoreto de hidrogênio (HF)
Iodeto de hidrogênio (HI)
Ácido isociânico (HNCO)
Halogeneto de hidrogênio (HX)
Halocarbonetos
Aminas Halogenadas
Organismos halogenados
Hidrocarbonetos
Metilisotiocianato
Nitrogênio (N2)
Amônia (NH3)
Óxidos de nitrogênio (NOx)
Oxigênio (O2)
Fosfina (PH3)
Dióxido de enxofre (SO2)
Óxidos de enxofre (SOx)
Gás halogênio (X2)
Halogeneto de ácido (X2CO)
Óxidos de halogênio (X2O)
Óxidos de halogênio (XO2)
Alertas de reatividade
BENZENO
Altamente inflamável
Á Ó
https://cameochemicals.noaa.gov/report Á 4/319
ÁCIDO PERCLÓRICO, COM MAIS DE 50%, MAS NÃO MAIS DE 72% DE ÁCIDO
Agente Oxidante Forte

Atividade catalítica conhecida
Reativo à água
TOLUENO
SOLUÇÃO DE GLUTARALDEÍDO
Polimerizável
Reativo à água
M-XYLENE
METANOL
DIOXANE
Composto peroxidável
ACETONITRILE
FORMALDEÍDO
Polimerizável
TRIETILAMINA
ACETONA
N-OCTANE
ETANOL
ACETATO DE ETILO
ANIDRIDE ACÉTICO
Reativo à água
CYCLOHEXANONE
MATERIAL RADIOATIVO, HEXAFLUORETO DE URÂNIO FÍSICO
Reativo à água
Material radioativo
CIANETO DE POTÁSSIO
Reativo à água
PENTANE-2,4-DIONE
Fósforo, branco, seco ou debaixo de água ou em solução
Agente de redução forte
Pirofórico
NITRATO DE POTÁSSIO
METIL-ETIL-CETONA
PERÓXIDO DE HIDROGÊNIO, SOLUÇÃO AQUOSA, COM NÃO MENOS DE 20%, MAS NÃO MAIS DE 60%
DE PERÓXIDO DE HIDROGÊNIO (ESTABILIZADO COMO NECESSÁRIO)
Explosivo
ÁCIDO SULFÚRICO

Reativo à água
ÁCIDO PÍCRICO, [SECO]
Explosivo
ÁCIDO HIDROCLÓRICO, SOLUÇÃO
HIDRATO DE ALUMÍNIO E LÍTIO
Agente de redução forte

Reativo à água
Reativo ao Ar
Previsões de perigo (para cada par de substâncias)
BENZENO misturado com

ALFA-CICLODEXTRINA
Nenhuma reação perigosa conhecida
ÁCIDO PERCLÓRICO, COM MAIS DE 50%, MAS NÃO MAIS DE 72% DE ÁCIDO, misturado com
ALFA-CICLODEXTRINA
Aldeídos
Dióxido de cloro
Hidrocarbonetos
Óxidos de nitrogênio
Óxidos de halogênio
ÁCIDO PERCLÓRICO, COM MAIS DE 50%, MAS NÃO MAIS DE 72% DE ÁCIDO misturado com
BENZENO

GLICERINA misturada com

ALFA-CICLODEXTRINA

BENZENO


Aldeídos
Dióxido de cloro
Hidrocarbonetos
ANILINA misturada com

ALFA-CICLODEXTRINA

BENZENO

ÁCIDO PERCLÓRICO , COM MAIS DE 50%, MAS NÃO MAIS DE 72% DE ÁCIDO

GLICERINA
BENZALDEÍDO misturado com

ALFA-CICLODEXTRINA


BENZENO

ÁCIDO PERCLORÓRICO , COM MAIS DE 50%, MAS NÃO MAIS DE 72% DE ÁCIDO

Álcoois
Dióxido de carbono

GLICERINA


ANILINA
TOLUENO misturado com

ALFA-CICLODEXTRINA

BENZENO


GLICERINA

ANILINA

BENZALDEÍDO
SOLUÇÃO DE GLUTARALDEÍDO misturada com

ALFA-CICLODEXTRINA


BENZENO
Solução de glutaraldeído misturada com

ácido perclórico, com mais de 50%, mas não mais de 72% de ácido

Fumos ácidos
Álcoois
Dióxido de carbono

GLICERINA


ANILINA

BENZALDEÍDO


TOLUENO
ÁCIDO TRICLOROÁTICO misturado com

ALFA-CICLODEXTRINA

Monóxido de carbono
Dióxido de carbono
Hidrocarbonetos

BENZENO

Halogeneto de hidrogênio

ÁCIDO PERCLORÓICO, COM MAIS DE 50%, MAS NÃO MAIS DE 72% DE ÁCIDO

Fumos ácidos
Dióxido de carbono
Fosgênio
Cloro
Dióxido de cloro
Óxidos de enxofre
Gás halogênio
Halogeneto de ácido
Á Á
GLICERINA

Dióxido de carbono
Hidrocarbonetos

ANILINA


BENZALDEÍDO

Dióxido de carbono

TOLUENO



Fumos ácidos
Dióxido de carbono
N, N-DIMETILFORMAMIDA misturada com

ALFA-CICLODEXTRINA

BENZENO


Dióxido de carbono
Azoto
Amônia

GLICERINA
N, N- DIMETILFORMAMIDA misturada com

ANILINA

Sulfato de hidrogênio

BENZALDEÍDO

TOLUENO


Amônia

ÁCIDO TRICLOROACETICO
M-XILENO misturado com

ALFA-CICLODEXTRINA
M-XYLENE misturado com

BENZENO



GLICERINA
M- XYLENE misturado com

ANILINA

BENZALDEÍDO

TOLUENE
M-XYLENE misturado com




N, N-DIMETILFORMAMIDA
CLOROFORM misturado com

ALFA-CICLODEXTRINA

BENZENO


Fumos ácidos
Dióxido de carbono
Fosgênio
Cloro
Gás halogênio
Halogeneto de ácido

GLICERINA
CLOROFÓRMIO misturado com

ANILINA

benzaldeído

TOLUENO



Fumos ácidos



M-XILENO

METANOL misturado com

ALFA-CICLODEXTRINA

BENZENO
Metanol misturado com

ácido perclórico, com mais de 50%, mas não mais de 72% de ácido

Aldeídos
Dióxido de cloro
Hidrocarbonetos

GLICERINA

ANILINA

BENZALDEÍDO


TOLUENO


ÁCIDO TRICLOROACETIC

Dióxido de carbono
Hidrocarbonetos


M-XILENO

CLOROFORM
DIOXANO misturado com

ALFA-CICLODEXTRINA

BENZENO



GLICERINA

ANILINA

BENZALDEÍDO

TOLUENO

DIOXANE mixed with

TRICHLOROACETIC ACID
No known hazardous reaction
DIOXANE mixed with

N,N-DIMETHYLFORMAMIDE
DIOXANE mixed with

M-XYLENE
DIOXANE mixed with

CHLOROFORM
DIOXANE mixed with

METHANOL
ACETONITRILE mixed with

ALPHA-CYCLODEXTRIN

BENZENE

PERCHLORIC ACID, WITH MORE THAN 50% BUT NOT MORE THAN 72% ACID
Flammable: Reaction products may be flammable

Generates gas: Reaction liberates gaseous products and may cause pressurization
Intense or explosive reaction: Reaction may be particularly intense, violent, or explosive
Polymerization hazard: Polymerization reaction may become intense and may cause pressurization
Toxic: Reaction products may be toxic
May produce the following gases:
Carbon Dioxide
Hydrogen Cyanide
Ammonia
Nitrogen Oxides

GLYCERINE

ANILINE

BENZALDEHYDE

TOLUENE

GLUTARALDEHYDE SOLUTION

Potentially hazardous: May be hazardous but unknown
Hydrogen Cyanide
Ammonia

Generates heat: Exothermic reaction at ambient temperatures (releases heat)


M-XYLENE

CHLOROFORM

METHANOL

DIOXANE
FORMALDEHYDE mixed with

ALPHA-CYCLODEXTRIN


BENZENE


Alcohols
Carbon Dioxide

GLYCERINE


ANILINE


BENZALDEHYDE


TOLUENE



Carbon Dioxide
FORMALDEÍDO misturado com


M-XILENO

CLOROFORM

METANOL


DIOXANO

ACETONITRILO
TRIETILAMINA misturada com

ALFA-CICLODEXTRINA
BENZENO


Fumos ácidos
Aldeídos
Fumos de Base
Hidrocarbonetos
Azoto
Amônia

GLICERINA

ANILINA

BENZALDEÍDO


TOLUENO



Fumos ácidos
Fumos de Base
Halocarbonetos


Amônia

M-XILENO
TRIETHYLAMINE misturado com

clorofórmio

Halocarbonetos

METANOL

DIOXANO
TRIETHYLAMINE misturado com

ACETONITRILE

FORMALDEÍDO

ACETONA misturada com
ALFA-CICLODEXTRINA


BENZENO


Dióxido de carbono
Dióxido de cloro
Óxidos de enxofre

GLICERINA

Unstable when heated: Reaction products may be unstable above ambient temperatures
ACETONE mixed with

ANILINE
ACETONE mixed with

BENZALDEHYDE
ACETONE mixed with

TOLUENE
ACETONE mixed with

ACETONE mixed with

ACETONE mixed with


ACETONE mixed with
M-XYLENE
ACETONE mixed with

CHLOROFORM
ACETONE mixed with

METHANOL
Explosive: Reaction products may be explosive or sensitive to shock or friction

ACETONE mixed with

DIOXANE
ACETONE mixed with

ACETONITRILE
ACETONE mixed with

FORMALDEHYDE
ACETONE mixed with

TRIETHYLAMINE
N-OCTANE mixed with

ALPHA-CYCLODEXTRIN
N-OCTANE mixed with

BENZENE
N-OCTANE mixed with

Carbon Monoxide
Carbon Dioxide
Hydrogen Halide
N-OCTANE mixed with
GLYCERINE
N-OCTANE mixed with

ANILINE
N-OCTANE mixed with

BENZALDEHYDE
N-OCTANE mixed with

TOLUENE
N-OCTANE mixed with

N-OCTANE mixed with

N-OCTANE mixed with

N-OCTANE mixed with

M-XYLENE
N-OCTANE mixed with

CHLOROFORM
N-OCTANE mixed with

METHANOL
N-OCTANE mixed with

DIOXANE
N-OCTANE mixed with

ACETONITRILE
N-OCTANE mixed with
FORMALDEHYDE
N-OCTANE mixed with

TRIETHYLAMINE
N-OCTANE mixed with

ACETONE
ACETIC ACID, GLACIAL mixed with

ALPHA-CYCLODEXTRIN

Carbon Monoxide
Carbon Dioxide
Hydrocarbons

BENZENE


Carbon Monoxide
Carbon Dioxide
Chlorine Dioxide
Nitrogen Oxides
Sulfur Oxides
Halogen Oxides

GLYCERINE

Carbon Monoxide
Carbon Dioxide
Hydrocarbons

ANILINE

BENZALDEHYDE
Carbon Dioxide

TOLUENE

Carbon Dioxide


ÁCIDO ACÉTICO GLACIAL misturado com

M-XILENO
Ácido acético glacial misturado com

clorofórmio

METANOL

Dióxido de carbono
Hidrocarbonetos

DIOXANO
ÁCIDO ACÉTICO, GLACIAL misturado com

ACETONITRILO

FORMALDEÍDO

Dióxido de carbono

TRIETILAMINA

Fumos ácidos
Fumos de Base

ACETONA

N-OCTANO
ETANOL misturado com

ALFA-CICLODEXTRINA

BENZENO

Aldeídos
Dióxido de cloro
Hidrocarbonetos

GLICERINA

ANILINA

BENZALDEÍDO


TOLUENO




Dióxido de carbono
Hidrocarbonetos

M-XILENO

CLOROFORM

METANOL

DIOXANO

ACETONITRILO

FORMALDEÍDO


TRIETILAMINA

ACETONA


N-OCTANO

ÁCIDO ACÉTICO, GLACIAL

Dióxido de carbono
Hidrocarbonetos
ACETATO DE ETIL misturado com

ALFA-CICLODEXTRINA
ACETATO ETílico misturado com

BENZENO


Fumos ácidos
Álcoois
Dióxido de carbono
Hidrocarbonetos

GLICERINA

ANILINA

BENZALDEÍDO

TOLUENO

Fumos ácidos

ETHYL ACETATE mixed with


M-XYLENE

CHLOROFORM

METHANOL

DIOXANE

ACETONITRILE

FORMALDEHYDE

TRIETHYLAMINE

Alcohols

ACETONE
N-OCTANE

ACETIC ACID, GLACIAL

ETHANOL
ACETIC ANHYDRIDE mixed with

ALPHA-CYCLODEXTRIN

BENZENE


Carbon Dioxide
Nitrogen Oxides
Sulfur Oxides
Halogen Oxides

GLYCERINE

ANILINE

BENZALDEHYDE


TOLUENE






M-XYLENE

CHLOROFORM

METHANOL

DIOXANE

ACETONITRILE

FORMALDEHYDE


TRIETHYLAMINE
Carbon Dioxide

ACETONE

N-OCTANE



ETHANOL

ETHYL ACETATE
CYCLOHEXANONE mixed with

ALPHA-CYCLODEXTRIN


BENZENE

Carbon Dioxide
Chlorine Dioxide
Nitrogen Oxides
Sulfur Oxides

GLYCERINE

ANILINE

BENZALDEHYDE

TOLUENE




M-XYLENE

CHLOROFORM

METHANOL


DIOXANE

ACETONITRILE
FORMALDEHYDE

TRIETHYLAMINE

ACETONE

N-OCTANE


ETHANOL


ETHYL ACETATE

ACETIC ANHYDRIDE
RADIOACTIVE MATERIAL, URANIUM HEXAFLUORIDE, FISSILE mixed with

ALPHA-CYCLODEXTRIN
Corrosive: Reaction products may be corrosive

Acid Fumes
Hydrogen Halide

BENZENE
Hydrogen Halide


Acid Fumes
Chlorine
Chlorine Dioxide
Hydrogen Sulfide
Hydrogen Bromide
Hydrogen Cyanide
Hydrogen Chloride
Hydrogen Fluoride
Hydrogen Halide
Oxygen
Sulfur Dioxide
Halogen Gas
Halogen Oxides

GLYCERINE

Acid Fumes
Hydrogen Halide

ANILINE

BENZALDEHYDE
Phosgene
Acid Halide

TOLUENE

Hydrogen Halide


Acid Fumes
Phosgene
Chlorine
Chlorine Dioxide
Hydrogen Sulfide
Hydrogen Bromide
Hydrogen Cyanide
Hydrogen Chloride
Hydrogen Fluoride
Hydrogen Halide
Oxygen
Sulfur Dioxide
Acid Halide


Acid Fumes
Hydrogen Fluoride
Hydrogen Halide
Phosphine

Acid Fumes
Carbon Monoxide
Carbon Dioxide
Hydrogen Cyanide
Hydrogen Halide
Halogenated Amines
Halogenated Organics
Sulfur Dioxide

M-XYLENE

Hydrogen Halide

CHLOROFORM


METHANOL

Acid Fumes
Hydrogen Halide
DIOXANE
Acid Fumes
Hydrogen Halide

ACETONITRILE
Acid Fumes
Difluorodiazene
Hydrogen Bromide
Hydrogen Chloride
Hydrogen Fluoride
Hydrogen Iodide
Hydrogen Halide

FORMALDEHYDE

Phosgene
Acid Halide

TRIETHYLAMINE


ACETONE


N-OCTANE
Hydrogen Halide
Halocarbons


Acid Fumes
Hydrogen Fluoride
Hydrogen Halide
Phosphine

ETHANOL

Acid Fumes
Hydrogen Halide

ETHYL ACETATE
Carbon Dioxide
Sulfur Dioxide

ACETIC ANHYDRIDE
CYCLOHEXANONE

POTASSIUM CYANIDE mixed with

ALPHA-CYCLODEXTRIN

BENZENE

Acid Fumes
Hydrogen Halide


Hydrogen Cyanide

GLYCERINE

ANILINE

BENZALDEHYDE


TOLUENE

Acid Fumes
Hydrogen Halide


Hydrogen Cyanide


Hydrogen Cyanide


M-XYLENE

Acid Fumes
Hydrogen Halide

CHLOROFORM

METHANOL

DIOXANE
ACETONITRILE

FORMALDEHYDE


TRIETHYLAMINE

ACETONE

N-OCTANE


Hydrogen Cyanide

ETHANOL

ETHYL ACETATE

ACETIC ANHYDRIDE

CYCLOHEXANONE
RADIOACTIVE MATERIAL, URANIUM HEXAFLUORIDE, FISSILE

PHOSPHORIC ACID mixed with

ALPHA-CYCLODEXTRIN

BENZENE


Halogen Oxides

GLYCERINE

ANILINE

BENZALDEHYDE

TOLUENE





M-XYLENE

CHLOROFORM

METHANOL

DIOXANE

ACETONITRILE

FORMALDEHYDE

TRIETHYLAMINE

ACETONE

N-OCTANE


ETHANOL

ETHYL ACETATE

ACETIC ANHYDRIDE

CYCLOHEXANONE


Hydrogen Fluoride

POTASSIUM CYANIDE
Hydrogen Cyanide
LACTIC ACID mixed with

ALPHA-CYCLODEXTRIN

Carbon Monoxide
Carbon Dioxide
Hydrocarbons

BENZENE

Aldehydes
Carbon Monoxide
Carbon Dioxide
Chlorine Dioxide
Hydrocarbons
Nitrogen Oxides
Sulfur Oxides
Halogen Oxides
Halogen Oxides

GLYCERINE

Carbon Monoxide
Carbon Dioxide
Hydrocarbons

ANILINE

BENZALDEHYDE
Carbon Dioxide

TOLUENE

Carbon Dioxide


Carbon Monoxide
Carbon Dioxide
Hydrocarbons


M-XYLENE

CHLOROFORM

METHANOL

Carbon Monoxide
Carbon Dioxide
Hydrocarbons

DIOXANE

ACETONITRILE

FORMALDEHYDE
Carbon Dioxide

TRIETHYLAMINE

Acid Fumes
Base Fumes

ACETONE


N-OCTANE


Carbon Monoxide
Carbon Dioxide
Hydrocarbons

ETHANOL

Carbon Monoxide
Carbon Dioxide
Hydrocarbons
ETHYL ACETATE

ACETIC ANHYDRIDE


CYCLOHEXANONE



Acid Fumes
Hydrogen Fluoride
Hydrogen Halide
Phosphine

POTASSIUM CYANIDE

Hydrogen Cyanide

PHOSPHORIC ACID
AMMONIUM HYDROXIDE mixed with

ALPHA-CYCLODEXTRIN

BENZENE


Acid Fumes
Base Fumes
Nitrogen Oxides

GLYCERINE

ANILINE

BENZALDEHYDE
Carbon Dioxide

TOLUENE

Carbon Dioxide


Acid Fumes
Carbon Dioxide
Hydrogen Halide
Ammonia

M-XYLENE

CHLOROFORM

Acid Fumes
Hydrogen Halide

METHANOL

DIOXANE

ACETONITRILE

Hydrogen Cyanide
Ammonia

FORMALDEHYDE
Carbon Dioxide

TRIETHYLAMINE

ACETONE

N-OCTANE

Carbon Dioxide

ETHANOL

ETHYL ACETATE

Acid Fumes
Alcohols
Hydrogen Sulfate

ACETIC ANHYDRIDE


CYCLOHEXANONE


Acid Fumes
Chlorine
Chlorine Dioxide
Hydrogen Sulfide
Hydrogen Bromide
Hydrogen Cyanide
Hydrogen Chloride
Hydrogen Fluoride
Hydrogen Halide
Oxygen
Sulfur Dioxide

POTASSIUM CYANIDE

Hydrogen Cyanide

PHOSPHORIC ACID


LACTIC ACID
Carbon Dioxide
PENTANE-2,4-DIONE mixed with

ALPHA-CYCLODEXTRIN


BENZENE

Carbon Dioxide
Chlorine Dioxide
Nitrogen Oxides
Sulfur Oxides
GLYCERINE


ANILINE

BENZALDEHYDE

TOLUENE




M-XYLENE

CHLOROFORM

METHANOL


DIOXANE

ACETONITRILE

FORMALDEHYDE

TRIETHYLAMINE

ACETONE

N-OCTANE


ETHANOL


ETHYL ACETATE

ACETIC ANHYDRIDE

CYCLOHEXANONE



POTASSIUM CYANIDE

PHOSPHORIC ACID

LACTIC ACID


AMMONIUM HYDROXIDE
1,4-BUTANEDIOL mixed with

ALPHA-CYCLODEXTRIN

BENZENE


Aldehydes
Chlorine Dioxide
Hydrocarbons
Nitrogen Oxides
Halogen Oxides

GLYCERINE

ANILINE

BENZALDEHYDE

TOLUENE




Carbon Monoxide
Carbon Dioxide
Hydrocarbons


M-XYLENE

CHLOROFORM

METHANOL

DIOXANE

ACETONITRILE
FORMALDEHYDE


TRIETHYLAMINE

ACETONE


N-OCTANE


Carbon Monoxide
Carbon Dioxide
Hydrocarbons

ETHANOL

ETHYL ACETATE

ACETIC ANHYDRIDE

CYCLOHEXANONE


Acid Fumes
Hydrogen Halide

POTASSIUM CYANIDE

PHOSPHORIC ACID

LACTIC ACID

Carbon Monoxide
Carbon Dioxide
Hydrocarbons

AMMONIUM HYDROXIDE

PENTANE-2,4-DIONE

PHOSPHORUS, WHITE, DRY OR UNDER WATER OR IN SOLUTION mixed with

ALPHA-CYCLODEXTRIN

Hydrogen
Hydrocarbons

BENZENE


Acid Fumes
Hydrogen
Hydrogen Halide
Nitrogen Oxides
Sulfur Oxides

GLYCERINE

Hydrogen
Hydrocarbons

ANILINE

BENZALDEHYDE

Hydrogen
Hydrocarbons

TOLUENE

Acid Fumes
Hydrogen
Hydrogen Halide
Hydrocarbons


Acid Fumes
Alcohols
Aldehydes
Carbon Dioxide
Hydrogen Halide
Hydrocarbons


Hydrogen
Ammonia

M-XYLENE

CHLOROFORM

Acid Fumes
Hydrogen Halide

METHANOL

Hydrogen
Hydrocarbons

DIOXANE

Hydrogen
Hydrocarbons

ACETONITRILE

Hydrogen
Hydrogen Cyanide
Ammonia

FORMALDEHYDE

Hydrogen
Hydrocarbons

TRIETHYLAMINE

ACETONE
Hydrocarbons

N-OCTANE


Alcohols
Aldehydes
Carbon Dioxide
Hydrocarbons

ETHANOL

Hydrogen
Hydrocarbons

ETHYL ACETATE

Acid Fumes
Hydrogen
Hydrogen Sulfate

ACETIC ANHYDRIDE

Alcohols
Aldehydes
Hydrocarbons

CYCLOHEXANONE

Hydrocarbons


Acid Fumes
Chlorine
Chlorine Dioxide
Hydrogen Sulfide
Hydrogen Bromide
Hydrogen Cyanide
Hydrogen Chloride
Hydrogen Fluoride
Hydrogen Halide
Oxygen
Sulfur Dioxide
Acid Halide

POTASSIUM CYANIDE

Hydrogen Cyanide

PHOSPHORIC ACID

LACTIC ACID

Alcohols
Aldehydes
Carbon Dioxide
Hydrogen
Hydrocarbons

AMMONIUM HYDROXIDE

Acid Fumes
Hydrogen
Hydrogen Halide

PENTANE-2,4-DIONE

Hydrocarbons

1,4-BUTANEDIOL

Hydrogen
Hydrocarbons
POTASSIUM NITRATE mixed with

ALPHA-CYCLODEXTRIN

BENZENE


Nitrogen Oxides

GLYCERINE


ANILINE


BENZALDEHYDE


TOLUENE




Nitrogen Oxides



M-XYLENE

CHLOROFORM

METHANOL


DIOXANE

ACETONITRILE


FORMALDEHYDE


TRIETHYLAMINE

ACETONE
N-OCTANE


Nitrogen Oxides

ETHANOL


ETHYL ACETATE


ACETIC ANHYDRIDE
Carbon Dioxide

CYCLOHEXANONE


POTASSIUM CYANIDE
Nitrogen Oxides

PHOSPHORIC ACID

Nitrogen Oxides

LACTIC ACID

Nitrogen Oxides

AMMONIUM HYDROXIDE

PENTANE-2,4-DIONE

1,4-BUTANEDIOL


PHOSPHORUS, WHITE, DRY OR UNDER WATER OR IN SOLUTION

METHYL ETHYL KETONE mixed with

ALPHA-CYCLODEXTRIN

BENZENE

Carbon Dioxide
Chlorine Dioxide
Nitrogen Oxides
Sulfur Oxides

GLYCERINE


ANILINE

BENZALDEHYDE

TOLUENE




M-XYLENE

CHLOROFORM

METHANOL


DIOXANE

ACETONITRILE

FORMALDEHYDE

TRIETHYLAMINE

ACETONE

N-OCTANE


ETHANOL


ETHYL ACETATE
ACETIC ANHYDRIDE

CYCLOHEXANONE



POTASSIUM CYANIDE

PHOSPHORIC ACID

LACTIC ACID


AMMONIUM HYDROXIDE

PENTANE-2,4-DIONE

1,4-BUTANEDIOL



Hydrocarbons
POTASSIUM NITRATE
CARBON TETRACHLORIDE mixed with

ALPHA-CYCLODEXTRIN

BENZENE
Hydrogen Halide


Acid Fumes
Carbon Dioxide
Phosgene
Chlorine
Hydrogen Halide
Halogen Gas
Acid Halide

GLYCERINE

ANILINE

BENZALDEHYDE

TOLUENE
Hydrogen Halide

Acid Fumes
Hydrogen Halide



M-XYLENE
Hydrogen Halide

CHLOROFORM

METHANOL

DIOXANE

ACETONITRILE

FORMALDEHYDE

TRIETHYLAMINE
Halocarbons

ACETONE

N-OCTANE


ETHANOL

ETHYL ACETATE

ACETIC ANHYDRIDE

CYCLOHEXANONE



POTASSIUM CYANIDE

PHOSPHORIC ACID
LACTIC ACID

AMMONIUM HYDROXIDE

Acid Fumes
Hydrogen Halide

PENTANE-2,4-DIONE

1,4-BUTANEDIOL


Acid Fumes
Hydrogen Halide

POTASSIUM NITRATE

METHYL ETHYL KETONE
HYDROGEN PEROXIDE, AQUEOUS SOLUTION, WITH NOT LESS THAN 20% BUT NOT MORE THAN 60%
HYDROGEN PEROXIDE (STABILIZED AS NECESSARY) mixed with
ALPHA-CYCLODEXTRIN

Carbon Monoxide
Carbon Dioxide
Hydrogen
Hydrogen Halide
Halogen Gas
Halogen Oxides
BENZENE

Carbon Dioxide

Acid Fumes
Chlorine
Chlorine Dioxide
Fluorine Perchlorate
Hydrogen Halide
Nitrogen Oxides
Oxygen
Halogen Oxides
GLYCERINE

Carbon Monoxide
Carbon Dioxide
Hydrogen
Hydrogen Halide
Halogen Gas
Halogen Oxides
ANILINE

BENZALDEHYDE

Aldehydes
Carbon Monoxide
Carbon Dioxide
Hydrogen
Halocarbons
Nitrogen Oxides
TOLUENE

Carbon Dioxide

Acid Fumes
Aldehydes
Carbon Monoxide
Carbon Dioxide
Chlorine
Hydrogen
Hydrogen Halide
Halocarbons
Nitrogen Oxides
Oxygen

Acid Fumes
Carbon Monoxide
Carbon Dioxide
Phosgene
Chlorine Dioxide
Hydrogen Halide
Oxygen
Halogen Gas

Acid Fumes
Carbon Monoxide
Carbon Dioxide
Hydrogen Cyanide
Hydrogen Halide
Halogenated Amines
Ammonia
M-XYLENE
Carbon Dioxide
CHLOROFORM

Acid Fumes
Phosgene
Hydrogen Halide
Halogen Gas
METHANOL

Carbon Monoxide
Carbon Dioxide
Hydrogen
Hydrogen Halide
Halogen Gas
Halogen Oxides
DIOXANE

Halogen Oxides
ACETONITRILE

Chlorinated Amines
Hydrogen Cyanide
Ammonia
Nitrogen Oxides
FORMALDEHYDE

Aldehydes
Carbon Monoxide
Carbon Dioxide
Hydrogen
Halocarbons
Nitrogen Oxides
TRIETHYLAMINE

Nitrogen
Nitrogen Oxides
ACETONE
Halocarbons
N-OCTANE

Carbon Monoxide
Carbon Dioxide

Carbon Monoxide
Carbon Dioxide
Chlorine Dioxide
Oxygen
ETHANOL

Carbon Monoxide
Carbon Dioxide
Hydrogen
Hydrogen Halide
Halogen Gas
Halogen Oxides
ETHYL ACETATE

Acid Fumes
Carbon Dioxide
Hydrogen Sulfate
Sulfur Dioxide
ACETIC ANHYDRIDE

Carbon Dioxide
CYCLOHEXANONE

Halocarbons

Acid Fumes
Chlorine
Chlorine Dioxide
Hydrogen Sulfide
Hydrogen Bromide
Hydrogen Cyanide
Hydrogen Chloride
Hydrogen Fluoride
Hydrogen Halide
Oxygen
Sulfur Dioxide
Halogen Gas
Halogen Oxides
POTASSIUM CYANIDE

Carbon Dioxide
Hydrogen Cyanide
Halogenated Amines
Nitrogen
PHOSPHORIC ACID

LACTIC ACID

Carbon Monoxide
Carbon Dioxide
Chlorine Dioxide
Hydrogen
Hydrogen Halide
Oxygen
Halogen Gas
Halogen Oxides
AMMONIUM HYDROXIDE

Acid Fumes
Chlorine
Hydrogen Halide
Ammonia
Nitrogen Oxides
Oxygen
PENTANE-2,4-DIONE

Halocarbons
1,4-BUTANEDIOL

Carbon Monoxide
Carbon Dioxide
Hydrogen
Hydrogen Halide
Halogen Gas
Halogen Oxides

Acid Fumes
Carbon Dioxide
Chlorine
Chlorine Dioxide
Hydrogen
Hydrogen Halide
Nitrogen Oxides
Oxygen
Halogen Gas
POTASSIUM NITRATE
METHYL ETHYL KETONE

Halocarbons
CARBON TETRACHLORIDE

Acid Fumes
Phosgene
Hydrogen Halide
Halogen Gas
FORMIC ACID mixed with
ALPHA-CYCLODEXTRIN

Carbon Monoxide
Carbon Dioxide
Hydrocarbons

BENZENE


Carbon Monoxide
Carbon Dioxide
Chlorine Dioxide
Nitrogen Oxides
Sulfur Oxides
Halogen Oxides

GLYCERINE

Carbon Monoxide
Carbon Dioxide
Hydrocarbons

ANILINE

BENZALDEHYDE
Carbon Dioxide

TOLUENE

Carbon Dioxide



M-XYLENE

CHLOROFORM

METHANOL

Carbon Monoxide
Carbon Dioxide
Hydrocarbons

DIOXANE

ACETONITRILE

FORMALDEHYDE
Carbon Dioxide

TRIETHYLAMINE

Acid Fumes
Base Fumes

ACETONE

N-OCTANE


ETHANOL

Carbon Monoxide
Carbon Dioxide
Hydrocarbons

ETHYL ACETATE

ACETIC ANHYDRIDE

CYCLOHEXANONE


Acid Fumes
Hydrogen Fluoride
Hydrogen Halide
Phosphine

POTASSIUM CYANIDE

Hydrogen Cyanide

PHOSPHORIC ACID

LACTIC ACID

Carbon Monoxide
Carbon Dioxide
Hydrocarbons

AMMONIUM HYDROXIDE
Carbon Dioxide

PENTANE-2,4-DIONE

1,4-BUTANEDIOL

Carbon Monoxide
Carbon Dioxide
Hydrocarbons


Alcohols
Aldehydes
Carbon Dioxide
Hydrocarbons

POTASSIUM NITRATE

Nitrogen Oxides

METHYL ETHYL KETONE


HYDROGEN PEROXIDE (STABILIZED AS NECESSARY)

Carbon Monoxide
Carbon Dioxide
Chlorine Dioxide
Oxygen
DICHLOROMETHANE mixed with

ALPHA-CYCLODEXTRIN

BENZENE
Hydrogen Halide


Acid Fumes
Carbon Dioxide
Phosgene
Chlorine
Hydrogen Halide
Halogen Gas
Acid Halide

GLYCERINE

ANILINE
BENZALDEHYDE

TOLUENE
Hydrogen Halide


Acid Fumes
Hydrogen Halide



M-XYLENE
Hydrogen Halide

CHLOROFORM

METHANOL

DIOXANE
ACETONITRILE

FORMALDEHYDE

TRIETHYLAMINE
Halocarbons

ACETONE

N-OCTANE


ETHANOL

ETHYL ACETATE

ACETIC ANHYDRIDE

CYCLOHEXANONE


POTASSIUM CYANIDE

PHOSPHORIC ACID

LACTIC ACID

AMMONIUM HYDROXIDE

Acid Fumes
Hydrogen Halide

PENTANE-2,4-DIONE

1,4-BUTANEDIOL


Acid Fumes
Hydrogen Halide

POTASSIUM NITRATE

METHYL ETHYL KETONE



Acid Fumes
Phosgene
Hydrogen Halide
Halogen Gas

FORMIC ACID
POTASSIUM CHLORIDE mixed with

ALPHA-CYCLODEXTRIN

BENZENE


Acid Fumes
Hydrogen Halide
Halogen Gas

GLYCERINE

ANILINE

BENZALDEHYDE


TOLUENE





M-XYLENE

CHLOROFORM

METHANOL

DIOXANE

ACETONITRILE

FORMALDEHYDE

TRIETHYLAMINE

ACETONE

N-OCTANE


ETHANOL

ETHYL ACETATE

ACETIC ANHYDRIDE
Carbon Dioxide

CYCLOHEXANONE



POTASSIUM CYANIDE

Isocyanic Acid

PHOSPHORIC ACID

LACTIC ACID

AMMONIUM HYDROXIDE

PENTANE-2,4-DIONE

1,4-BUTANEDIOL

Acid Halide

POTASSIUM NITRATE

METHYL ETHYL KETONE



FORMIC ACID

DICHLOROMETHANE
SULFURIC ACID mixed with

ALPHA-CYCLODEXTRIN

Aldehydes
Chlorine Dioxide
Hydrocarbons
Nitrogen Oxides
Halogen Oxides

BENZENE



Acid Fumes
Nitrogen Oxides

GLYCERINE

Aldehydes
Chlorine Dioxide
Hydrocarbons
Nitrogen Oxides
Halogen Oxides

ANILINE


BENZALDEHYDE

Alcohols
Carbon Dioxide

TOLUENE



Acid Fumes
Alcohols
Carbon Dioxide
Nitrogen Oxides


Acid Fumes
Carbon Monoxide
Carbon Dioxide
Phosgene
Chlorine
Chlorine Dioxide
Hydrogen Halide
Nitrogen Oxides
Sulfur Oxides
Halogen Gas
Acid Halide
Halogen Oxides

Carbon Dioxide
Nitrogen

M-XYLENE


CHLOROFORM

Acid Fumes
Carbon Dioxide
Phosgene
Chlorine
Hydrogen Halide
Halogen Gas
Acid Halide

METHANOL

Aldehydes
Chlorine Dioxide
Hydrocarbons
Nitrogen Oxides
Halogen Oxides

DIOXANE


ACETONITRILE

Carbon Dioxide
Hydrogen Cyanide
Nitrogen Oxides

FORMALDEHYDE

Alcohols
Carbon Dioxide

TRIETHYLAMINE

Acid Fumes
Aldehydes
Base Fumes
Hydrocarbons
Nitrogen
Ammonia
Nitrogen Oxides

ACETONE
Carbon Dioxide
Chlorine Dioxide
Nitrogen Oxides
Sulfur Oxides

N-OCTANE
Carbon Monoxide
Carbon Dioxide
Hydrogen Halide


Carbon Monoxide
Carbon Dioxide
Chlorine Dioxide
Nitrogen Oxides
Sulfur Oxides
Halogen Oxides

ETHANOL

Aldehydes
Chlorine Dioxide
Hydrocarbons
Nitrogen Oxides
Halogen Oxides

ETHYL ACETATE

Alcohols
Carbon Monoxide
Carbon Dioxide
Hydrocarbons

ACETIC ANHYDRIDE

Carbon Dioxide
Nitrogen Oxides
Sulfur Oxides
Halogen Oxides

CYCLOHEXANONE
Carbon Dioxide
Chlorine Dioxide
Nitrogen Oxides
Sulfur Oxides


Acid Fumes
Chlorine
Hydrogen Fluoride
Hydrogen Halide
Halogen Gas
Halogen Oxides

POTASSIUM CYANIDE

Hydrogen Cyanide

PHOSPHORIC ACID

Halogen Oxides

LACTIC ACID

Aldehydes
Carbon Monoxide
Carbon Dioxide
Chlorine Dioxide
Hydrocarbons
Nitrogen Oxides
Sulfur Oxides
Halogen Oxides
Halogen Oxides

AMMONIUM HYDROXIDE

Acid Fumes
Base Fumes
Nitrogen Oxides

PENTANE-2,4-DIONE
Carbon Dioxide
Chlorine Dioxide
Nitrogen Oxides
Sulfur Oxides

1,4-BUTANEDIOL

Aldehydes
Chlorine Dioxide
Hydrocarbons
Nitrogen Oxides
Halogen Oxides


Acid Fumes
Hydrogen Halide
Nitrogen Oxides
Sulfur Oxides

POTASSIUM NITRATE

Nitrogen Oxides

METHYL ETHYL KETONE
Carbon Dioxide
Chlorine Dioxide
Nitrogen Oxides
Sulfur Oxides


Acid Fumes
Carbon Dioxide
Phosgene
Chlorine
Hydrogen Halide
Halogen Gas
Acid Halide


Acid Fumes
Chlorine
Chlorine Dioxide
Fluorine Perchlorate
Hydrogen Halide
Nitrogen Oxides
Oxygen
Halogen Oxides

FORMIC ACID

Carbon Monoxide
Carbon Dioxide
Chlorine Dioxide
Nitrogen Oxides
Sulfur Oxides
Halogen Oxides
DICHLOROMETHANE

Acid Fumes
Carbon Dioxide
Phosgene
Chlorine
Hydrogen Halide
Halogen Gas
Acid Halide

POTASSIUM CHLORIDE

Acid Fumes
Hydrogen Halide
Halogen Gas
PICRIC ACID, [DRY] mixed with

ALPHA-CYCLODEXTRIN

BENZENE


Carbon Monoxide
Carbon Dioxide
Methylisothiocyanate
Nitrogen Oxides
Sulfur Oxides
Halogen Oxides
GLYCERINE

ANILINE


BENZALDEHYDE


TOLUENE


Nitrogen Oxides



M-XYLENE

CHLOROFORM

METHANOL

DIOXANE

ACETONITRILE

FORMALDEHYDE


TRIETHYLAMINE


ACETONE


N-OCTANE


ETHANOL

ETHYL ACETATE

ACETIC ANHYDRIDE
Carbon Dioxide

CYCLOHEXANONE



Acid Fumes
Hydrogen Chloride
Hydrogen Fluoride
Hydrogen Halide
Nitrogen Oxides

POTASSIUM CYANIDE
Hydrogen Cyanide

PHOSPHORIC ACID

LACTIC ACID

AMMONIUM HYDROXIDE

Nitrogen Oxides

PENTANE-2,4-DIONE

1,4-BUTANEDIOL


Hydrogen
Hydrocarbons
Nitrogen Oxides

POTASSIUM NITRATE


METHYL ETHYL KETONE




Acid Fumes
Aldehydes
Carbon Dioxide
Chlorine Dioxide
Hydrogen
Hydrogen Chloride
Halogenated Organics
Nitrogen Oxides

FORMIC ACID

DICHLOROMETHANE

POTASSIUM CHLORIDE

SULFURIC ACID

Carbon Monoxide
Carbon Dioxide
Methylisothiocyanate
Nitrogen Oxides
Sulfur Oxides
Halogen Oxides
HYDROCHLORIC ACID, SOLUTION mixed with

ALPHA-CYCLODEXTRIN

BENZENE


Acid Fumes
Chlorine
Hydrogen Chloride
Hydrogen Halide
Nitrogen
Nitrogen Oxides
Halogen Gas
Halogen Oxides

GLYCERINE

ANILINE

BENZALDEHYDE


TOLUENE


Acid Fumes


Acid Fumes
Carbon Monoxide
Carbon Dioxide
Hydrogen Halide

Carbon Monoxide
Ammonia

M-XYLENE

CHLOROFORM

Acid Fumes
Hydrogen Halide

METHANOL

DIOXANE

Hydrocarbons

ACETONITRILE

Carbon Dioxide
Hydrogen Cyanide
Ammonia

FORMALDEHYDE

TRIETHYLAMINE

Acid Fumes
Base Fumes

ACETONE

N-OCTANE


Carbon Monoxide
Carbon Dioxide

ETHANOL

ETHYL ACETATE

Acid Fumes
Alcohols
Hydrogen Sulfate

ACETIC ANHYDRIDE

Carbon Dioxide

CYCLOHEXANONE


Acid Fumes
Bromine
Chlorine
Chlorine Dioxide
Hydrogen Sulfide
Hydrogen Bromide
Hydrogen Cyanide
Hydrogen Chloride
Hydrogen Fluoride
Hydrogen Halide
Oxygen
Sulfur Dioxide
Halogen Gas

POTASSIUM CYANIDE

Hydrogen Cyanide

PHOSPHORIC ACID


LACTIC ACID

Carbon Monoxide
Carbon Dioxide

AMMONIUM HYDROXIDE

Acid Fumes

PENTANE-2,4-DIONE

1,4-BUTANEDIOL


Acid Fumes
Bromine
Chlorine
Hydrogen
Hydrogen Halide
Halogen Gas

POTASSIUM NITRATE

Nitrogen Oxides

METHYL ETHYL KETONE


Acid Fumes
Hydrogen Halide


Acid Fumes
Bromine
Chlorine
Chlorine Dioxide
Hydrogen Halide
Nitrogen Oxides
Oxygen
Halogen Gas
Halogen Oxides

FORMIC ACID

Carbon Monoxide
Carbon Dioxide

DICHLOROMETHANE

Acid Fumes
Hydrogen Halide

POTASSIUM CHLORIDE
Acid Fumes
Hydrogen Halide

SULFURIC ACID

Acid Fumes
Chlorine
Hydrogen Chloride
Hydrogen Halide
Nitrogen
Nitrogen Oxides
Halogen Gas
Halogen Oxides

PICRIC ACID, [DRY]

Carbon Dioxide
Nitrogen Oxides
LITHIUM ALUMINUM HYDRIDE mixed with

ALPHA-CYCLODEXTRIN

Hydrogen

BENZENE


Aluminum Oxide
Base Fumes
Hydrogen
Hydrocarbons

GLYCERINE

Hydrogen

ANILINE

Hydrogen
Hydrocarbons

BENZALDEHYDE

Alcohols
TOLUENE


Aluminum Oxide
Alcohols
Base Fumes
Hydrogen
Hydrocarbons


Alcohols
Aldehydes
Hydrogen
Hydrogen Halide


Aldehydes
Hydrogen
Ammonia

M-XYLENE

CHLOROFORM

Hydrogen Halide

METHANOL

Hydrogen

DIOXANE

Hydrogen
Hydrocarbons

ACETONITRILE

Aldehydes
Hydrogen
Ammonia

FORMALDEHYDE

Alcohols

TRIETHYLAMINE

Hydrogen
Hydrocarbons

ACETONE

Hydrogen

N-OCTANE


Alcohols
Aldehydes
Hydrogen

ETHANOL

Hydrogen
ETHYL ACETATE

Alcohols
Aldehydes
Phosphine

ACETIC ANHYDRIDE

Alcohols
Aldehydes
Ethers
Hydrocarbons

CYCLOHEXANONE

Hydrogen


Hydrogen
Hydrogen Fluoride

POTASSIUM CYANIDE

Hydrogen

PHOSPHORIC ACID

Hydrogen
Hydrocarbons
Phosphine

LACTIC ACID

Alcohols
Aldehydes
Hydrogen

AMMONIUM HYDROXIDE

Aluminum Oxide
Base Fumes
Hydrogen
Hydrocarbons

PENTANE-2,4-DIONE

Hydrogen

1,4-BUTANEDIOL
Hydrogen


Aluminum Oxide
Base Fumes
Hydrogen
Hydrocarbons

POTASSIUM NITRATE


METHYL ETHYL KETONE

Hydrogen


Hydrogen Halide

Aluminum Oxide
Base Fumes
Hydrogen
Hydrocarbons

FORMIC ACID

Alcohols
Aldehydes
Hydrogen

DICHLOROMETHANE

Hydrogen Halide

POTASSIUM CHLORIDE

Germanes
Hydrogen

SULFURIC ACID
Hydrogen

PICRIC ACID, [DRY]

Hydrogen
Hydrocarbons
Ammonia

HYDROCHLORIC ACID, SOLUTION

Aluminum Oxide
Base Fumes
Hydrogen
Hydrocarbons
Chemical Datasheet
ALPHA-CYCLODEXTRIN
Chemical Identifiers
CAS Number UN/NA Number DOT Hazard Label USCG CHRIS Code
10016-20-3 none data unavailable none
NIOSH Pocket Guide International Chem Safety Card

none none
NFPA 704
data unavailable
General Description
PHYSICAL DESCRIPTION: Hexagonal plates or blade-shaped needles. (NTP, 1992)
Hazards
Reactivity Alerts
none
Air & Water Reactions

No rapid reaction with air. No rapid reaction with water.
Fire Hazard
Flash point data for this chemical are not available; however, it is probably combustible. (NTP, 1992)
Health Hazard
SYMPTOMS: A symptom of exposure to this chemical is irritation.
ACUTE/CHRONIC HAZARDS: This compound may be harmful by inhalation, ingestion, or skin absorption. It may
cause irritation. When heated to decomposition this compound emits toxic fumes of carbon monoxide and carbon
dioxide. (NTP, 1992)
Reactivity Profile
ALPHA-CYCLODEXTRIN has hydrophobic cavities. It forms inclusion compounds with organic substances, salts,
and halogens in the solid state or in aqueous solutions. It is incompatible with strong oxidizing agents. (NTP, 1992)
Belongs to the Following Reactive Group(s)
Alcohols and Polyols
Potentially Incompatible Absorbents

Use caution: Liquids with this reactive group classification have been known to react with the absorbent listed below.
Cellulose-Based Absorbents
Response Recommendations
Isolation and Evacuation

No information available.
Firefighting
Fires involving this material can be controlled with a dry chemical, carbon dioxide or Halon extinguisher. (NTP, 1992)
Non-Fire Response
SMALL SPILLS AND LEAKAGE: If you should spill this chemical, FIRST REMOVE ALL SOURCES OF
IGNITION. You should then use absorbent paper to pick up liquid spill material. Your contaminated clothing and
absorbent paper should be sealed in a vapor-tight plastic bag for eventual disposal. Solvent-wash contaminated
surfaces with 60-70% methanol followed by washing with a soap and water solution. Do not reenter the contaminated
area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.
STORAGE PRECAUTIONS: You should store this chemical under ambient temperatures, and keep it away from
oxidizing materials. (NTP, 1992)
Protective Clothing
RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half
face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2)
with a dust/mist filter. (NTP, 1992)
DuPont Tychem® Suit Fabrics

First Aid
EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline
solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any
ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY
transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.
SKIN: IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently
wash all affected skin areas thoroughly with soap and water. If symptoms such as redness or irritation develop,
IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment.
INHALATION: IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. If symptoms (such as
wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be
prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown
atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a
level of protection greater than or equal to that advised under Protective Clothing.
INGESTION: DO NOT INDUCE VOMITING. If the victim is conscious and not convulsing, give 1 or 2 glasses of
water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. Be prepared to transport the
victim to a hospital if advised by a physician. If the victim is convulsing or unconscious, do not give anything by
mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body. DO
NOT INDUCE VOMITING. IMMEDIATELY transport the victim to a hospital. (NTP, 1992)
Physical Properties
Chemical Formula: C36H60O30

Flash Point: data unavailable
Lower Explosive Limit (LEL): data unavailable
Upper Explosive Limit (UEL): data unavailable
Autoignition Temperature: data unavailable
Melting Point: 532 ° F (decomposes) (NTP, 1992)
Vapor Pressure: data unavailable
Vapor Density (Relative to Air): data unavailable
Specific Gravity: data unavailable
Boiling Point: data unavailable
Molecular Weight: 972.86 (NTP, 1992)
Water Solubility: data unavailable
Ionization Potential: data unavailable
IDLH: data unavailable
AEGLs (Acute Exposure Guideline Levels)
No AEGL information available.
ERPGs (Emergency Response Planning Guidelines)
No ERPG information available.
PACs (Protective Action Criteria)
No PAC information available.
Regulatory Information
EPA Consolidated List of Lists

No regulatory information available.
DHS Chemical Facility Anti-Terrorism Standards (CFATS)
OSHA Process Safety Management (PSM) Standard List

Chemical Datasheet
BENZENE
71-43-2 1114 Flammable Liquid BNZ

Benzene BENZENE
NFPA 704
Diamond Hazard Value Description
3 Health 2 Can cause temporary incapacitation or residual injury.

2 0
Flammability 3 Can be ignited under almost all ambient temperature conditions.
Instability 0 Normally stable, even under fire conditions.
Special
(NFPA, 2010)
General Description
A clear colorless liquid with a petroleum-like odor. Flash point less than 0°F. Less dense than water and slightly
soluble in water. Hence floats on water. Vapors are heavier than air.
Hazards
Reactivity Alerts
Highly Flammable

Highly flammable. Slightly soluble in water.
Fire Hazard
Behavior in Fire: Vapor is heavier than air and may travel considerable distance to a source of ignition and flash back.
(USCG, 1999)
Health Hazard
Dizziness, excitation, pallor, followed by flushing, weakness, headache, breathlessness, chest constriction, nausea, and
vomiting. Coma and possible death. (USCG, 1999)
Reactivity Profile
BENZENE reacts vigorously with allyl chloride or other alkyl halides even at -70° C in the presence of ethyl
aluminum dichloride or ethyl aluminum sesquichloride. Explosions have been reported [NFPA 491M 1991]. Ignites in
contact with powdered chromic anhydride [Mellor 11:235 1946-47]. Incompatible with oxidizing agents such as nitric
acid. Mixtures with bromine trifluoride, bromine pentafluoride, iodine pentafluoride, iodine heptafluoride and other
interhalogens can ignite upon heating [Bretherick 5th ed. 1995]. Benzene and cyanogen halides yield HCl as a
byproduct (Hagedorn, F. H. Gelbke, and Federal Republic of Germany. 2002. Nitriles. In Ullmann's Encyclopedia of
Industrial Chemistry. Wiley-VCH Verlag GmbH & Co. KGaA.). The reaction of benzene and trichloroacetonitrile
evolves toxic chloroform and HCl gases. (Hagedorn, F., H.-P. Gelbke, and Federal Republic of Germany. 2002.
Nitriles. In Ullmann's Encyclopedia of Industrial Chemistry. Wiley-VCH Verlag GmbH & Co. KGaA.).
Hydrocarbons, Aromatic


Excerpt from ERG Guide 130 [Flammable Liquids (Water-Immiscible / Noxious)]:
As an immediate precautionary measure, isolate spill or leak area for at least 50 meters (150 feet) in all directions.
LARGE SPILL: Consider initial downwind evacuation for at least 300 meters (1000 feet).
FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also,
consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2016)
Firefighting
CAUTION: All these products have a very low flash point: Use of water spray when fighting fire may be inefficient.
SMALL FIRE: Dry chemical, CO2, water spray or regular foam.
LARGE FIRE: Water spray, fog or regular foam. Do not use straight streams. Move containers from fire area if you
can do it without risk.
FIRE INVOLVING TANKS OR CAR/TRAILER LOADS: Fight fire from maximum distance or use unmanned hose
holders or monitor nozzles. Cool containers with flooding quantities of water until well after fire is out. Withdraw
immediately in case of rising sound from venting safety devices or discoloration of tank. ALWAYS stay away from
tanks engulfed in fire. For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw
from area and let fire burn. (ERG, 2016)
Non-Fire Response
ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). All equipment used when
handling the product must be grounded. Do not touch or walk through spilled material. Stop leak if you can do it
without risk. Prevent entry into waterways, sewers, basements or confined areas. A vapor-suppressing foam may be
used to reduce vapors. Absorb or cover with dry earth, sand or other non-combustible material and transfer to
containers. Use clean, non-sparking tools to collect absorbed material.
LARGE SPILL: Dike far ahead of liquid spill for later disposal. Water spray may reduce vapor, but may not prevent
ignition in closed spaces. (ERG, 2016)
Protective Clothing
Skin: Wear appropriate personal protective clothing to prevent skin contact.
Eyes: Wear appropriate eye protection to prevent eye contact.
Wash skin: The worker should immediately wash the skin when it becomes contaminated.
Remove: Work clothing that becomes wet should be immediately removed due to its flammability hazard(i.e. for
liquids with flash point < 100°F)
Change: No recommendation is made specifying the need for the worker to change clothing after the work shift.
Provide: Eyewash fountains should be provided in areas where there is any possibility that workers could be exposed
to the substance; this is irrespective of the recommendation involving the wearing of eye protection. Facilities for
quickly drenching the body should be provided within the immediate work area for emergency use where there is a
possibility of exposure. [Note: It is intended that these facilities provide a sufficient quantity or flow of water to
quickly remove the substance from any body areas likely to be exposed. The actual determination of what constitutes
an adequate quick drench facility depends on the specific circumstances. In certain instances, a deluge shower should
be readily available, whereas in others, the availability of water from a sink or hose could be considered adequate.]
(NIOSH, 2016)

Normalized Breakthrough Times (in Minutes)
Chemical CAS Number State QS QC SL C3 TF TP BR RC TK RF
Benzene (>95%) 71-43-2 Liquid imm. >480 >480 >480 >480 >480 >480 >480
> indicates greater than.
"imm." indicates immediate; having a normalized breakthrough time of 10 minutes or less.
A blank cell indicates the fabric has not been tested. The fabric may or may not offer barrier.
Special Warnings from DuPont
1. Serged and bound seams are degraded by some hazardous liquid chemicals, such as strong acids, and should not
be worn when these chemicals are present.
2. CAUTION: This information is based upon technical data that DuPont believes to be reliable. It is subject to
revision as additional knowledge and experience are gained. DuPont makes no guarantee of results and assumes
no obligation or liability...
(DuPont, 2018)
First Aid
wash all affected skin areas thoroughly with soap and water. IMMEDIATELY call a hospital or poison control center
even if no symptoms (such as redness or irritation) develop. IMMEDIATELY transport the victim to a hospital for
treatment after washing the affected areas.
INHALATION: IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. IMMEDIATELY call a
physician and be prepared to transport the victim to a hospital even if no symptoms (such as wheezing, coughing,
shortness of breath, or burning in the mouth, throat, or chest) develop. Provide proper respiratory protection to rescuers
entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if
not available, use a level of protection greater than or equal to that advised under Protective Clothing.
INGESTION: DO NOT INDUCE VOMITING. Volatile chemicals have a high risk of being aspirated into the victim's
lungs during vomiting which increases the medical problems. If the victim is conscious and not convulsing, give 1 or 2
glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. IMMEDIATELY
transport the victim to a hospital. If the victim is convulsing or unconscious, do not give anything by mouth, ensure
that the victim's airway is open and lay the victim on his/her side with the head lower than the body. DO NOT
INDUCE VOMITING. IMMEDIATELY transport the victim to a hospital.
OTHER: Since this chemical is a known or suspected carcinogen you should contact a physician for advice regarding
the possible long term health effects and potential recommendation for medical monitoring. Recommendations from
the physician will depend upon the specific compound, its chemical, physical and toxicity properties, the exposure
level, length of exposure, and the route of exposure. (NTP, 1992)
Physical Properties
Chemical Formula: C6H6

Flash Point: 12 ° F (NTP, 1992)
Lower Explosive Limit (LEL): 1.4 % (NTP, 1992)
Upper Explosive Limit (UEL): 8 % (NTP, 1992)
Autoignition Temperature: 1097 ° F (USCG, 1999)
Melting Point: 41.9 ° F (NTP, 1992)
Vapor Pressure: 60 mm Hg at 59 ° F ; 76 mm Hg at 68° F (NTP, 1992)
Vapor Density (Relative to Air): 2.77 (NTP, 1992)
Specific Gravity: 0.879 at 68 ° F (USCG, 1999)
Boiling Point: 176.2 ° F at 760 mm Hg (NTP, 1992)
Water Solubility: 1 to 5 mg/mL at 64° F (NTP, 1992)
Ionization Potential: 9.24 eV (NIOSH, 2016)
IDLH: 500 ppm ; A potential occupational carcinogen. (NIOSH, 2016)
Interim AEGLs for Benzene (71-43-2)

Exposure Period AEGL-1 AEGL-2 AEGL-3
10 minutes 130 ppm 2000 ppm 9700 ppm
4 hours 18 ppm 400 ppm 2000 ppm

Lower Explosive Limit (LEL) = 14000 ppm
indicates value is 10-49% of LEL. Safety consideration against explosions must be taken into account.
indicates value is 50-99% of LEL. Extreme safety consideration against explosions must be taken into account.
(NAC/NRC, 2017)

Chemical ERPG-1 ERPG-2 ERPG-3
Benzene (71-43-2) 50 ppm 150 ppm 1000 ppm
indicates that odor should be detectable near ERPG-1.
(AIHA, 2016)
Chemical PAC-1 PAC-2 PAC-3
Benzene (71-43-2) 52 ppm 800 ppm 4000 ppm LEL = 14000 ppm
indicates value is 10-49% of LEL.

(DOE, 2016)

CAS Number/ EPCRA EPCRA EPCRA CAA
Regulatory 313 Category 302 304 CERCLA 313 RCRA 112(r)
Name Code EHS TPQ EHS RQ RQ TRI Code RMP TQ
Benzene 71-43-2 10 pounds 313 U019
(EPA List of Lists, 2015)

Chemical Datasheet
PERCHLORIC ACID, WITH MORE THAN 50% BUT

NOT MORE THAN 72% ACID
7601-90-3 1873 Oxidizer PCL
Corrosive

none PERCHLORIC ACID (72% SOLUTION)
NFPA 704
0 Health 3 Can cause serious or permanent injury.

3 3
ox Flammability 0 Will not burn under typical fire conditions.
Capable of detonation or explosive decomposition or explosive reaction but
requires a strong initiating source or must be heated under confinement before
Instability 3 initiation.
Special OX Possesses oxidizing properties.

(NFPA, 2010)
General Description
A clear colorless odorless aqueous solution. Corrosive to metals and tissue. Closed containers may rupture violently
under prolonged exposure to heat.
Hazards
Reactivity Alerts
Strong Oxidizing Agent

Known Catalytic Activity
Water-Reactive

Water soluble with some evolution of heat.
Fire Hazard
Behavior in Fire: Above 160°C (320°F) will react with combustible material and increase intensity of fire. Containers
may explode. (USCG, 1999)
Health Hazard
Inhalation of vapors or mist causes burning sensation of nose and throat, and lung irritation with coughing; prolonged
or excessive exposure could cause vomiting and severe coughing. Ingestion causes blistering and burns of mouth and
stomach. Contact with eyes or skin causes blistering and burns. (USCG, 1999)
Reactivity Profile
PERCHLORIC ACID, [> 50% BUT <= 72% STRENGTH] is a solution of a strong oxidizing acid. May react
vigorously or deflagrate when mixed with oxidizable material [Merck]. This includes (but is not limited to) alcohols,
amines, boranes, dicyanogen, hydrazines, hydrocarbons, hydrogen, nitroalkanes, powdered metals, silanes, or thiols
[Bretherick 1979. p.174]. Perchloric acid ignites on contact with sulfinyl chloride. (Bailar, 1973, Vol. 2, 1442).
Acids, Strong Oxidizing

Water and Aqueous Solutions

Use caution: Liquids with this reactive group classification have been known to react with the absorbents listed below.
Expanded Polymeric Absorbents

Excerpt from ERG Guide 143 [Oxidizers (Unstable)]:
As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters (150 feet) for
liquids and at least 25 meters (75 feet) for solids.
SPILL: Increase, in the downwind direction, as necessary, the isolation distance shown above.
Firefighting
SMALL FIRE: Use water. Do not use dry chemicals or foams. CO2 or Halon® may provide limited control.
LARGE FIRE: Flood fire area with water from a distance. Do not move cargo or vehicle if cargo has been exposed to
heat. Move containers from fire area if you can do it without risk. Do not get water inside containers: a violent reaction
may occur.
FIRE INVOLVING TANKS OR CAR/TRAILER LOADS: Cool containers with flooding quantities of water until well
after fire is out. Dike fire-control water for later disposal. ALWAYS stay away from tanks engulfed in fire. For massive
fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from area and let fire burn. (ERG,
2016)
Non-Fire Response
Keep combustibles (wood, paper, oil, etc.) away from spilled material. Do not touch damaged containers or spilled
material unless wearing appropriate protective clothing. Use water spray to reduce vapors or divert vapor cloud drift.
Prevent entry into waterways, sewers, basements or confined areas.
SMALL SPILL: Flush area with flooding quantities of water.
LARGE SPILL: DO NOT CLEAN-UP OR DISPOSE OF, EXCEPT UNDER SUPERVISION OF A SPECIALIST.
(ERG, 2016)
Protective Clothing
Rubber gloves; face shield or vapor-tight chemical-type safety goggles; rubber apron; rubber boots or shoes (USCG,
1999)

Perchloric acid (70%) 7601-90-3 Liquid >480 >480 >480 >480
(DuPont, 2018)
First Aid
Get medical attention following all exposures to this compound.
INHALATION: move to fresh air; give oxygen if necessary.
INGESTION: give large amounts of water.
EYES: flush with water for at least 15 min.
SKIN: flush with water. (USCG, 1999)
Physical Properties
Chemical Formula: HClO4 (aqueous)

Melting Point: -170 ° F (USCG, 1999)
Specific Gravity: 1.6 to 1.7 at 77 ° F (USCG, 1999)
Molecular Weight: 100.46 (solute only) (USCG, 1999)

Perchloric acid (7601-90-3) 0.61 ppm 6.7 ppm 40 ppm
(DOE, 2016)

Chemical Name CAS Number Threshold Quantity (TQ)

Perchloric Acid (concentration >60% by weight) 7601-90-3 5000 pounds
(OSHA, 2011)

Chemical Datasheet
GLYCERINE
56-81-5 none data unavailable GCR

Glycerin (mist) GLYCEROL
NFPA 704
1 Health 1 Can cause significant irritation.

1 0
Flammability 1 Must be preheated before ignition can occur.
Special
(NFPA, 2010)
General Description
A colorless to brown colored liquid. Combustible but may require some effort to ignite.
Hazards
Reactivity Alerts
none

Hygroscopic. Water soluble.
Fire Hazard
This chemical is combustible. (NTP, 1992)
Health Hazard
No hazard (USCG, 1999)
Reactivity Profile
GLYCERINE is incompatible with strong oxidizers. It is also incompatible with hydrogen peroxide, potassium
permanganate, nitric acid + sulfuric acid, perchloric acid + lead oxide, acetic anhydride, aniline + nitrobenzene,
Ca(OCl)2, CrO3, F2 + PbO, KMnO4, K2O2, AgClO4 and NaH. A mixture with chlorine explodes if heated to 158-
176° F. It reacts with acetic acid, potassium peroxide, sodium peroxide, hydrochloric acid, (HClO4 + PbO) and
Na2O2. Contact with potassium chlorate may be explosive. It also reacts with ethylene oxide, perchloric acid, nitric
acid + hydrofluoric acid and phosphorus triiodide. (NTP, 1992)


Firefighting
Non-Fire Response
Protective Clothing
Skin: No recommendation is made specifying the need for personal protective equipment for the body.
Eyes: No recommendation is made specifying the need for eye protection.
Wash skin: No recommendation is made specifying the need for washing the substance from the skin (either
immediately or at the end of the work shift).
Remove: No recommendation is made specifying the need for removing clothing that becomes wet or contaminated.
(NIOSH, 2016)

First Aid
Physical Properties

Melting Point: 64 ° F (NTP, 1992)
Vapor Pressure: 0.0025 mm Hg at 122 ° F ; 40 mm Hg at 388° F (NTP, 1992)
Boiling Point: 554 ° F at 760 mm Hg (decomposes) (NTP, 1992)
Water Solubility: greater than or equal to 100 mg/mL at 64° F (NTP, 1992)

Glycerine (mist); (Glycerol; Glycerin) (56-81-5) 45 mg/m3 180 mg/m3 1100 mg/m3
(DOE, 2016)


Chemical Datasheet
ANILINE
62-53-3 1547 Poison ANL

Aniline (and homologs) ANILINE
NFPA 704

3 0
Must be moderately heated or exposed to relatively high ambient temperatures
Flammability 2 before ignition can occur.
Special
(NFPA, 2010)
General Description
A yellowish to brownish oily liquid with a musty fishy odor. Melting point -6°C; boiling point 184°C; flash point
158°F. Denser than water (8.5 lb / gal) and slightly soluble in water. Vapors heavier than air. Toxic by skin absorption
and inhalation. Produces toxic oxides of nitrogen during combustion. Used to manufacture other chemicals, especially
dyes, photographic chemicals, agricultural chemicals and others.
Hazards
Reactivity Alerts
none

Darkens on exposure to air and light. Polymerizes slowly to a resinous mass on exposure to air and light. Slightly
soluble in water.
Fire Hazard
Combustion can produce toxic fumes including nitrogen oxides and carbon monoxide. Aniline vapor forms explosive
mixtures with air. It is incompatible with strong oxidizers and strong acids and a number of other materials. Avoid
heating. Hazardous polymerization may occur. Polymerizes to a resinous mass. (EPA, 1998)
Health Hazard
It is classified as very toxic. Probable oral lethal dose in humans is 50-500 mg/kg for a 150 lb. person. Aniline
poisoning is characterized by methemoglobin formation in the blood and resulting cyanosis or blue skin. The
formation of methemoglobin interferes with the oxygen-carrying capacity of the blood. The approximate minimum
lethal dose for a 150 lb. human is 10 grams. Serious poisoning may result from ingestion of 0.25 mL. People at special
risk include individuals with glucose-6-phosphate-dehydrogenase deficiency and those with liver and kidney disorders,
blood diseases, or a history of alcoholism. (EPA, 1998)
Reactivity Profile
ANILINE is a heat sensitive base. Combines with acids to form salts. Dissolves alkali metals or alkaline earth metals
with evolution of hydrogen. Incompatible with albumin, solutions of iron, zinc and aluminum, and acids. Couples
readily with phenols and aromatic amines. Easily acylated and alkylated. Corrosive to copper and copper alloys. Can
react vigorously with oxidizing materials (including perchloric acid, fuming nitric acid, sodium peroxide and ozone).
Reacts violently with BCl3. Mixtures with toluene diisocyanate may ignite. Undergoes explosive reactions with
benzenediazonium-2-carboxylate, dibenzoyl peroxide, fluorine nitrate, nitrosyl perchlorate, peroxodisulfuric acid and
tetranitromethane. Violent reactions may occur with peroxyformic acid, diisopropyl peroxydicarbonate, fluorine,
trichloronitromethane (293° F), acetic anhydride, chlorosulfonic acid, hexachloromelamine, (HNO3 + N2O4 +
H2SO4), (nitrobenzene + glycerin), oleum, (HCHO + HClO4), perchromates, K2O2, beta-propiolactone, AgClO4,
Na2O2, H2SO4, trichloromelamine, acids, FO3Cl, diisopropyl peroxy-dicarbonate, n-haloimides and
trichloronitromethane. Ignites on contact with sodium peroxide + water. Forms heat or shock sensitive explosive
mixtures with anilinium chloride (detonates at 464 F/7.6 bar), nitromethane, hydrogen peroxide, 1-chloro-2,3-
epoxypropane and peroxomonosulfuric acid. Reacts with perchloryl fluoride form explosive products. (NTP, 1992).
Amines, Aromatic


Excerpt from ERG Guide 153 [Substances - Toxic and/or Corrosive (Combustible)]:
Firefighting
Fight fire from maximum distance. Dike fire control water for later disposal and do not scatter material. If a leak or
spill has not ignited, use water spray to control vapors. Wear self-contained breathing apparatus with a full face piece
operated in pressure-demand or other positive pressure mode and special protective clothing.
Use water spray, dry chemical, foam or carbon dioxide. Use water to keep fire-exposed containers cool. (EPA, 1998)
Non-Fire Response
ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Do not touch damaged
containers or spilled material unless wearing appropriate protective clothing. Stop leak if you can do it without risk.
Prevent entry into waterways, sewers, basements or confined areas. Absorb or cover with dry earth, sand or other non-
combustible material and transfer to containers. DO NOT GET WATER INSIDE CONTAINERS. (ERG, 2016)
Protective Clothing
Remove: Work clothing that becomes wet or significantly contaminated should be removed and replaced.
Provide: Facilities for quickly drenching the body should be provided within the immediate work area for emergency
use where there is a possibility of exposure. [Note: It is intended that these facilities provide a sufficient quantity or
flow of water to quickly remove the substance from any body areas likely to be exposed. The actual determination of
what constitutes an adequate quick drench facility depends on the specific circumstances. In certain instances, a deluge
shower should be readily available, whereas in others, the availability of water from a sink or hose could be considered
adequate.] (NIOSH, 2016)

Aniline (>95%) 62-53-3 Liquid imm. >480 320 >480 >480 >480 >480 >480 >480
(DuPont, 2018)
First Aid
Signs and Symptoms of Acute Aniline Exposure: Signs and symptoms of acute exposure to aniline may be severe and
include dyspnea (shortness of breath), respiratory paralysis, cardiac arrhythmias, and cardiovascular collapse. Victims
may experience headache, irritability, disorientation, lethargy, weakness, incoordination, dizziness, and drowsiness.
Delerium, shock, convulsions, and coma may also be observed. Gastrointestinal effects include dryness of throat,
nausea, and vomiting. Painful urination, oliguria (scanty urination), and hematuria (bloody urine) may occur. Aniline
may irritate the skin, eyes, and mucous membranes; cyanosis (blue tint to skin and mucous membranes) is a common
finding.
Note: Victims at special risk include individuals with glucose-6-phosphate-dehydrogenase deficiency, those with liver
and kidney disorders, blood diseases, or a history of alcoholism.
Emergency Life-Support Procedures: Acute exposure to aniline may require decontamination and life support for the
victims. Emergency personnel should wear protective clothing appropriate to the type and degree of contamination.
Air-purifying or supplied-air respiratory equipment should also be worn, as necessary. Rescue vehicles should carry
supplies such as plastic sheeting and disposable plastic bags to assist in preventing spread of contamination.
Inhalation Exposure:
1. Move victims to fresh air. Emergency personnel should avoid self-exposure to aniline.
2. Evaluate vital signs including pulse and respiratory rate, and note any trauma. If no pulse is detected, provide CPR.
If not breathing, provide artificial respiration. If breathing is labored, administer oxygen or other respiratory support.
3. Obtain authorization and/or further instructions from the local hospital for administration of an antidote or
performance of other invasive procedures.
4. RUSH to a health care facility.
Dermal/Eye Exposure:
1. Remove victims from exposure. Emergency personnel should avoid self- exposure to aniline.
3. Remove contaminated clothing as soon as possible.
4. If eye exposure has occurred, eyes must be flushed with lukewarm water for at least 15 minutes.
5. Wash exposed skin areas twice with soap and water.
Ingestion Exposure:
3. Vomiting may be induced with syrup of Ipecac. If elapsed time since ingestion of aniline is unknown or suspected to
be greater than 30 minutes, do not induce vomiting and proceed to Step
4.Ipecac should not be administered to children under 6 months of age.Warning: Ingestion of aniline may result in
sudden onset of seizures or loss of consciousness. Syrup of Ipecac should be administered only if victims are alert,
have an active gag-reflex, and show no signs of impending seizure or coma. If ANY uncertainty exists, proceed to Step
4.The following dosages of Ipecac are recommended: children up to 1 year old, 10 mL (1/3 oz); children 1 to 12 years
old, 15 mL (1/2 oz); adults, 30 mL (1 oz). Ambulate (walk) the victims and give large quantities of water. If vomiting
has not occurred after 15 minutes, Ipecac may be readministered. Continue to ambulate and give water to the victims.
If vomiting has not occurred within 15 minutes after second administration of Ipecac, administer activated charcoal.
4. Activated charcoal may be administered if victims are conscious and alert. Use 15 to 30 g (1/2 to 1 oz) for children,
50 to 100 g (1-3/4 to 3-1/2 oz) for adults, with 125 to 250 mL (1/2 to 1 cup) of water.
5. Promote excretion by administering a saline cathartic or sorbitol to conscious and alert victims. Children require 15
to 30 g (1/2 to 1 oz) of cathartic; 50 to 100 g (1-3/4 to 3-1/2 oz) is recommended for adults.
6. RUSH to a health care facility. (EPA, 1998)
Physical Properties
Chemical Formula: C6H7N

Flash Point: 158 ° F (EPA, 1998)
Lower Explosive Limit (LEL): 1.3 % (EPA, 1998)
Upper Explosive Limit (UEL): 20 to 25 % (EPA, 1998)
Melting Point: 21 ° F (EPA, 1998)
Vapor Pressure: 0.67 mm Hg at 77 ° F (EPA, 1998)
Vapor Density (Relative to Air): 3.22 (EPA, 1998)
Specific Gravity: 1.022 at 68 ° F (EPA, 1998)
Boiling Point: 363 to 367 ° F at 760 mm Hg (EPA, 1998)
Molecular Weight: 93.12 (EPA, 1998)
Final AEGLs for Aniline (62-53-3)


8 hours 1 ppm 1.5 ppm 2.5 ppm
(NAC/NRC, 2017)


Aniline (62-53-3) 8 ppm 12 ppm 20 ppm LEL = 13000 ppm
(DOE, 2016)

1000 5000
Aniline 62-53-3 pounds pounds 5000 pounds 313 U012


Chemical Datasheet
BENZALDEHYDE
100-52-7 1990 Class 9 BZD

none BENZALDEHYDE
NFPA 704

2 0
Special
(NFPA, 2010)
General Description
A clear colorless to yellow liquid with a bitter almond odor. Flash point near 145°F. More denser than water and
insoluble in water. Hence sinks in water. Vapors are heavier than air. The primary hazard is to the environment.
Immediate steps should be taken to limit spread to the environment. Easily penetrates the soil to contaminate
groundwater and nearby waterways. Used in flavoring and perfume making.
Hazards
Reactivity Alerts
none

Oxidizes in air to form benzoic acid, which is moderately toxic by ingestion. Insoluble in water.
Fire Hazard
Excerpt from ERG Guide 129 [Flammable Liquids (Water-Miscible / Noxious)]:
HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with
air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along
ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in
sewers. Those substances designated with a (P) may polymerize explosively when heated or involved in a fire. Runoff
to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than
water. (ERG, 2016)
Health Hazard
Inhalation of concentrated vapor may irritate eyes, nose and throat. Liquid is irritating to the eyes. Prolonged contact
with the skin may cause irritation. (USCG, 1999)
Reactivity Profile
A nontoxic, combustible liquid, reacts with oxidizing reagents. BENZALDEHYDE must be blanketed with an inert
gas at all times since it is oxidized readily by air to benzoic acid [Kirk-Othmer, 3rd ed., Vol. 3, 1978, p. 736]. In
contact with strong acids or bases it will undergo an exothermic condensation reaction [Sax, 9th ed., 1996, p. 327]. A
violent reaction was observed on contact with peroxyacids (peroxyformic acid) [D'Ans, J. et al., Ber., 1915, 48, p.
1136]. An explosion occurred when pyrrolidine, benzaldehyde, and propionic acid were heated to form porphyrins.
Aldehydes


Firefighting
SMALL FIRE: Dry chemical, CO2, water spray or alcohol-resistant foam. Do not use dry chemical extinguishers to
control fires involving nitromethane (UN1261) or nitroethane (UN2842).
LARGE FIRE: Water spray, fog or alcohol-resistant foam. Do not use straight streams. Move containers from fire area
if you can do it without risk.
Non-Fire Response
Protective Clothing
Chemical goggles and protective clothing. (USCG, 1999)

First Aid
NOT INDUCE VOMITING. IMMEDIATELY transport the victim to a hospital.
Physical Properties
Chemical Formula: C7H6O

Melting Point: -15 ° F (NTP, 1992)
Vapor Pressure: 1 mm Hg at 79.2 ° F ; 5 mm Hg at 122.2° F; 10 mm Hg at 144° F (NTP, 1992)
Boiling Point: 354 ° F at 760 mm Hg (NTP, 1992)
Water Solubility: less than 0.1 mg/mL at 67.1° F (NTP, 1992)
Benzaldehyde (100-52-7) 4 ppm 9.9 ppm 59 ppm LEL = 14000 ppm
(DOE, 2016)


Chemical Datasheet
TOLUENE
108-88-3 1294 Flammable Liquid TOL

Toluene TOLUENE
NFPA 704

2 0
Special
(NFPA, 2010)
General Description
A clear colorless liquid with a characteristic aromatic odor. Flash point 40°F. Less dense than water (7.2 lb / gal) and
insoluble in water. Hence floats on water. Vapors heavier than air. May be toxic by inhalation, ingestion or skin
contact. Used in aviation and automotive fuels, as a solvent, and to make other chemicals.
Hazards
Reactivity Alerts
Highly Flammable

Highly flammable. Insoluble in water.
Fire Hazard
Behavior in Fire: Vapor is heavier than air and may travel a considerable distance to a source of ignition and flash
back. (USCG, 1999)
Health Hazard
Vapors irritate eyes and upper respiratory tract; cause dizziness, headache, anesthesia, respiratory arrest. Liquid
irritates eyes and causes drying of skin. If aspirated, causes coughing, gagging, distress, and rapidly developing
pulmonary edema. If ingested causes vomiting, griping, diarrhea, depressed respiration. (USCG, 1999)
Reactivity Profile
TOLUENE reacts vigorously with allyl chloride or other alkyl halides even at -70° C in the presence of ethyl
aluminum dichloride or ethyl aluminum sesquichloride. Explosions have been reported [NFPA 491M 1991].
Incompatible with strong oxidizing agents. When added to a tank of sulfur dichloride, the tank over pressurized and
ruptured in a reaction thought to be catalyzed by iron or iron(III) chloride [Chem. Eng. News, 1988, 66(32), 2].


Firefighting
LARGE FIRE: Water spray, fog or regular foam. Do not use straight streams. Move containers from fire area if you
can do it without risk.
Non-Fire Response
Protective Clothing
(NIOSH, 2016)

Toluene (>95%) 108-88-3 Liquid imm. imm. >480 >480 >480 >480 >480 >480 >480
(DuPont, 2018)
First Aid
Physical Properties

Upper Explosive Limit (UEL): 7.1 % (NTP, 1992)
Vapor Pressure: 10 mm Hg at 43.5 ° F ; 20 mm Hg at 65.1° F; 40 mm Hg at 89.2° F (NTP, 1992)
Water Solubility: less than 1 mg/mL at 64° F (NTP, 1992)
IDLH: 500 ppm (NIOSH, 2016)
Final AEGLs for Toluene (108-88-3)


(NAC/NRC, 2017)

Toluene (108-88-3) 50 ppm 300 ppm 1000 ppm
(AIHA, 2016)
Toluene (108-88-3) 67 ppm 560 ppm 3700 ppm LEL = 14000 ppm

(DOE, 2016)

Toluene 108-88-3 1000 pounds 313 U220

Chemical Datasheet
111-30-8 2810 Poison GTA

Glutaraldehyde GLUTARALDEHYDE
GLUTARALDEHYDE (50% SOLUTION)
NFPA 704
data unavailable
General Description
Light yellow liquid. Mixes with water. (USCG, 1999)
Hazards
Reactivity Alerts
Polymerizable
Water-Reactive

Polymerizes in the presence of water. (NTP, 1992)
Fire Hazard
Literature sources indicate that this chemical is nonflammable. (NTP, 1992)
Health Hazard
Contact with liquid causes severe irritation of eyes and irritation of skin. Chemical readily penetrates skin in harmful
amounts. Ingestion causes irritation of mouth and stomach. (USCG, 1999)
Reactivity Profile
GLUTARALDEHYDE may discolor on exposure to air. It polymerizes on heating. This chemical is incompatible with
strong oxidizing agents. It polymerizes in the presence of water. (NTP, 1992)
Aldehydes
Polymerizable Compounds

Mineral-Based & Clay-Based Absorbents
Dirt/Earth

Firefighting
Fires involving this material can be controlled with a dry chemical, carbon dioxide or Halon extinguisher. (NTP, 1992)
Non-Fire Response
SMALL SPILLS AND LEAKAGE: If you should spill this chemical, use absorbent paper to pick up all liquid spill
material. Seal the absorbent paper, as well as any of your clothing which may be contaminated, in a vapor-tight plastic
bag for eventual disposal. Wash any surfaces you may have contaminated with a soap and water solution. Do not
reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been
properly cleaned.
STORAGE PRECAUTIONS: You should keep this material in a tightly closed container under an inert atmosphere,
and store it at refrigerated temperatures. (NTP, 1992)
Protective Clothing
(NIOSH, 2016)

CAS
Chemical Number State QS QC SL C3 TF TP BR RC TK RF
1,5-Pentanedial (5% in water) 111-30-8 Liquid >480 >480 >480 >480 >480
CAS
1,5-Pentanedial (50%) 111-30-8 Liquid >480 170 170 >480 >480 >480 >480
Glutaric acid dialdehyde (5% in
water) 111-30-8 Liquid >480 >480 >480 >480 >480
Glutaric acid dialdehyde (50%) 111-30-8 Liquid >480 170 170 >480 >480 >480 >480
Glutaric aldehyde (5% in
water) 111-30-8 Liquid >480 >480 >480 >480 >480
Glutaric aldehyde (50%) 111-30-8 Liquid >480 170 170 >480 >480 >480 >480
Gluteraldehyde (5% in water) 111-30-8 Liquid >480 >480 >480 >480 >480
Gluteraldehyde (50%) 111-30-8 Liquid >480 170 170 >480 >480 >480 >480
Pentanedial, 1,5- (5% in water) 111-30-8 Liquid >480 >480 >480 >480 >480
Pentanedial, 1,5- (50%) 111-30-8 Liquid >480 170 170 >480 >480 >480 >480
(DuPont, 2018)
First Aid
Physical Properties

Melting Point: less than 20 ° F (USCG, 1999)
Vapor Pressure: 17 mm Hg at 68 ° F (NTP, 1992)
Specific Gravity: 1.062 to 1.124 at 68 ° F (USCG, 1999)
Boiling Point: 369 to 372 ° F at 760 mm Hg (decomposes) (NTP, 1992)

Glutaraldehyde (111-30-8) 0.2 ppm 1 ppm 5 ppm
(AIHA, 2016)
Gluteraldehyde (111-30-8) 0.2 ppm 1 ppm 5 ppm
(DOE, 2016)


Chemical Datasheet
76-03-9 1839 Corrosive none

Trichloroacetic acid TRICHLOROACETIC ACID
NFPA 704
data unavailable
General Description
Trichloroacetic acid, solid is a colorless crystalline solid. It absorbs moisture from air and forms a syrup. It is soluble
in water with release of heat. It is corrosive to metals and tissue.
Hazards
Reactivity Alerts
none

It is soluble in water with release of heat.
Fire Hazard
Combustible material: may burn but does not ignite readily. When heated, vapors may form explosive mixtures with
air: indoors, outdoors and sewers explosion hazards. Those substances designated with a (P) may polymerize
explosively when heated or involved in a fire. Contact with metals may evolve flammable hydrogen gas. Containers
may explode when heated. Runoff may pollute waterways. Substance may be transported in a molten form. (ERG,
2016)
Health Hazard
TOXIC; inhalation, ingestion or skin contact with material may cause severe injury or death. Contact with molten
substance may cause severe burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be
delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be
corrosive and/or toxic and cause pollution. (ERG, 2016)
Reactivity Profile
TRICHLOROACETIC ACID is a strong acid; when heated, in the presence of water, decomposes forming phosgene
and HCl. [Handling Chemicals Safely 1980 p. 915]. The acid was added to copper wool and rinsed down with
dimethyl sulfoxide. This caused what was thought to be an extremely exothermic dehydrohalogenation reaction that
melted the neck of the flask, [Chem. Eng. News, 1981, 59(28), 4].
Acids, Carboxylic
Halogenated Organic Compounds


Firefighting
SMALL FIRE: Dry chemical, CO2 or water spray.
LARGE FIRE: Dry chemical, CO2, alcohol-resistant foam or water spray. Move containers from fire area if you can
do it without risk. Dike fire-control water for later disposal; do not scatter the material.
holders or monitor nozzles. Do not get water inside containers. Cool containers with flooding quantities of water until
well after fire is out. Withdraw immediately in case of rising sound from venting safety devices or discoloration of
tank. ALWAYS stay away from tanks engulfed in fire. (ERG, 2016)
Non-Fire Response
Protective Clothing
Change: Workers whose clothing may have become contaminated should change into uncontaminated clothing before
leaving the work premise.
(NIOSH, 2016)

Trichloroacetic acid (>95%) 76-03-9 Liquid >480 >480
(DuPont, 2018)
First Aid
INGESTION: DO NOT INDUCE VOMITING. Corrosive chemicals will destroy the membranes of the mouth, throat,
and esophagus and, in addition, have a high risk of being aspirated into the victim's lungs during vomiting which
increases the medical problems. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the
chemical and IMMEDIATELY call a hospital or poison control center. IMMEDIATELY transport the victim to a
hospital. If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is
open and lay the victim on his/her side with the head lower than the body. DO NOT INDUCE VOMITING. Transport
the victim IMMEDIATELY to a hospital. (NTP, 1992)
Physical Properties
Chemical Formula: C2HCl3O2

Flash Point: greater than 230 ° F (NTP, 1992)
Melting Point: 135 to 136 ° F (NTP, 1992)
Vapor Pressure: 1 mm Hg at 123.8 ° F ; 5 mm Hg at 168.8° F (NTP, 1992)
Specific Gravity: 1.62 at 77 ° F (NTP, 1992)
Boiling Point: 385 to 387 ° F at 760 mm Hg (NTP, 1992)
Trichloroacetic acid (76-03-9) 1.5 ppm 16 ppm 99 ppm
(DOE, 2016)


Chemical Datasheet
68-12-2 2265 Flammable Liquid DMF

Dimethylformamide N,N-DIMETHYLFORMAMIDE
NFPA 704

2 0
Special
(NFPA, 2010)
General Description
A water-white liquid with a faint fishy odor. Flash point 136°F. Slightly less dense than water. Vapors heavier than air.
Toxic by inhalation or skin absorption. May irritate eyes.
Hazards
Reactivity Alerts
none

Flammable. Water soluble.
Fire Hazard
Special Hazards of Combustion Products: Vapors are irritating (USCG, 1999)
Health Hazard
Irritation of eyes, skin and nose. May cause nausea. (USCG, 1999)
Reactivity Profile
N,N-DIMETHYLFORMAMIDE may react violently with a broad range of chemicals, e.g.: alkaline metals (sodium,
potassium), azides, hydrides (sodium borohydride, lithium aluminum hydride), bromine, chlorine, carbon tetrachloride,
hexachlorocyclohexane, phosphorus pentaoxide, triethylaluminum, magnesium nitrate, organic nitrates. Forms
explosive mixtures with lithium azide [Bretherick, 5th ed., 1995, p. 453]. Oxidation by chromium trioxide or
potassium permanganate may lead to explosion [Pal B. C. et al., Chem. Eng. News, 1981, 59, p. 47].
Amides and Imides


Firefighting
Non-Fire Response
Protective Clothing
(NIOSH, 2016)

CAS
Dimethylformamide, N,N-
(>95%) 68-12-2 Liquid imm. 90 >480 >480 >480 >480 >480 >480 >480
N,N-Dimethylformamide
(>95%) 68-12-2 Liquid imm. 90 >480 >480 >480 >480 >480 >480 >480
(DuPont, 2018)
First Aid
Physical Properties
Chemical Formula: C3H7NO

Lower Explosive Limit (LEL): 2.2 % at 212° F (NTP, 1992)
Upper Explosive Limit (UEL): 15.2 % at 212° F (NTP, 1992)
Vapor Pressure: 3.7 mm Hg at 77 ° F ; 2.7 mm Hg at 68° F (NTP, 1992)
Boiling Point: 300 to 313 ° F at 760 mm Hg (NTP, 1992)
Final AEGLs for N,N-Dimethylformamide (68-12-2)

10 minutes NR 110 ppm 970 ppm
4 hours NR 57 ppm 280 ppm
NR = Not recommended due to insufficient data
(NAC/NRC, 2017)

Dimethylformamide (68-12-2) 2 ppm 100 ppm 200 ppm
(AIHA, 2016)

Dimethylformamide, N,N- (68-12-2) 2 ppm 91 ppm 530 ppm LEL = 22000 ppm
(DOE, 2016)

313 Category 302 304 CERCLA 313 RCRA 112(r)
Regulatory Name Code EHS TPQ EHS RQ RQ TRI Code RMP TQ
Dimethylformamide 68-12-2 100 pounds X
N,N-
Dimethylformamide 68-12-2 100 pounds 313
"X" indicates that this is a second name for an EPCRA section 313 chemical already included on this consolidated list.
May also indicate that the same chemical with the same CAS number appears on another list with a different chemical
name.


Chemical Datasheet
M-XYLENE
108-38-3 1307 Flammable Liquid XLM

m-Xylene m-XYLENE
NFPA 704

2 0
Special
(NFPA, 2010)
General Description
A colorless watery liquid with a sweet odor. Less dense than water. Insoluble in water. Irritating vapor. (USCG, 1999)
Hazards
Reactivity Alerts
Highly Flammable

Fire Hazard
Behavior in Fire: Vapor is heavier than air and may travel considerable distance to a source of ignition and flash back.
(USCG, 1999)
Health Hazard
Vapors cause headache and dizziness. Liquid irritates eyes and skin. If taken into lungs, causes severe coughing,
distress, and rapidly developing pulmonary edema. If ingested, causes nausea, vomiting, cramps, headache, and coma;
can be fatal. Kidney and liver damage can occur. (USCG, 1999)
Reactivity Profile
M-XYLENE may react with oxidizing materials. (NTP, 1992).


Firefighting
Fire Extinguishing Agents Not to Be Used: Water may be ineffective.
Fire Extinguishing Agents: Foam, dry chemical, or carbon dioxide (USCG, 1999)
Non-Fire Response
material. Your contaminated clothing and absorbent paper should be sealed in a vapor-tight plastic bag for eventual
disposal. Solvent wash all contaminated surfaces with acetone followed by washing with a strong soap and water
solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that
the area has been properly cleaned.
STORAGE PRECAUTIONS: You should store this material in a refrigerator away from oxidizers. STORE AWAY
FROM SOURCES OF IGNITION. (NTP, 1992)
Protective Clothing
(NIOSH, 2016)

First Aid
Physical Properties

Lower Explosive Limit (LEL): 1.1 % (USCG, 1999)
Upper Explosive Limit (UEL): 7 % (USCG, 1999)
Melting Point: -54.2 ° F (NTP, 1992)
Vapor Pressure: 10 mm Hg at 82.9 ° F (NTP, 1992)
Water Solubility: Insoluble (NTP, 1992)

Xylene, m- (includes o- (95-47-6) and p- (106- LEL = 11000
42-3) isomers) (108-38-3) 130 ppm 920 ppm 2500 ppm ppm

(DOE, 2016)

Benzene, m-
dimethyl- 108-38-3 1000 pounds X U239
m-Xylene 108-38-3 1000 pounds 313 U239
name.


Chemical Datasheet
CHLOROFORM
67-66-3 1888 Poison CRF

Chloroform CHLOROFORM
NFPA 704

2 0
Flammability 0 Will not burn under typical fire conditions.
Special
(NFPA, 2010)
General Description
A clear colorless liquid with a characteristic odor. Denser (12.3 lb / gal) than water and slightly soluble in water. Hence
sinks in water. Nonflammable under most conditions, but burns under extreme conditions. May cause illness by
inhalation, skin absorption or ingestion. Used as a solvent, to make other chemicals, as a fumigant.
Hazards
Reactivity Alerts
none

Slightly soluble in water. Dissolves in water to form a corrosive solution of hypochlorous acid which decomposes on
standing to chlorine, oxygen, and chloric acid.
Fire Hazard
Container may explode in the heat of fire. When heated it liberates phosgene, hydrogen chloride, chlorine and toxic
and corrosive oxides of carbon and chlorine. Chloroform explodes when in contact with aluminum powder or
magnesium powder or with alkali metals (e.g., lithium, sodium, and potassium) and dinitrogen tetroxide. It reacts
vigorously with acetone in the presence of potassium hydroxide or calcium hydroxide. It is oxidized by strong
oxidizers such as chromic acid forming phosgene and chlorine. It reacts vigorously with triisopropylphosphine. It
develops acidity from prolonged exposure to air and light. (EPA, 1998)
Health Hazard
It is classified as moderately toxic. Probable oral lethal dose for humans is 0.5 to 5 g/kg (between 1 ounce and 1 pint)
for a 150 lb. person. The mean lethal dose is probably near 1 fluid ounce (44 g). It is a human suspected carcinogen.
Also, it is a central nervous system depressant and a gastrointestinal irritant. It has caused rapid death attributable to
cardiac arrest and delayed death from liver and kidney damage. (EPA, 1998)
Reactivity Profile
A mixture of acetone and CHLOROFORM in a residue bottle exploded. Since addition of acetone to chloroform in the
presence of base will result in a highly exothermic reaction, it is thought that a base was in the bottle. [MCA Case
History 1661(1970)]. Powdered aluminum and carbon tetrachloride (also methyl chloride and chloroform or mixtures
of these chemicals) exploded when heated (to 153° C) and by impact, [Chem. Eng. News 32:258(1954); UL Bull.
Research 34 (1945), ASESB Pot. Incid. 39(1968)]. An inadequately cooled addition of sodium to a chloroform-
methanol mixture (sodium methoxide) caused a violent explosion, [MCA Case History No. 693]. It is incompatible
with dinitrogen tetraoxide, fluorine, sodium metal and alcohols, nitromethane, and triisopropylphosphine.


Excerpt from ERG Guide 151 [Substances - Toxic (Non-combustible)]:
Firefighting
Wear self-contained breathing apparatus and special protective clothing. Move container from fire area. Fight fire from
maximum distance. Dike fire control water for later disposal; do not scatter the material.
Extinguish with dry chemical, carbon dioxide, water spray, fog or foam. (EPA, 1998)
Non-Fire Response
Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Stop leak if you
can do it without risk. Prevent entry into waterways, sewers, basements or confined areas. Cover with plastic sheet to
prevent spreading. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers.
DO NOT GET WATER INSIDE CONTAINERS. (ERG, 2016)
Protective Clothing
(NIOSH, 2016)

Chloroform (>95%) 67-66-3 Liquid imm. imm. imm. imm. imm. >480 >480 >480 >480
(DuPont, 2018)
First Aid
Signs and Symptoms of Chloroform Exposure: Signs and symptoms of acute exposure to chloroform vapor may
include conjunctivitis and blepharospasm (twitching of the eyelid). Burning pain and corneal epithelium injury may
occur from chloroform liquid splashed in the eye. Acute exposure may also lead to respiratory depression, chemical
pneumonitis, pulmonary edema, metabolic acidosis, central nervous system depression, headache, fatigue, and
dizziness. Gastrointestinal signs and symptoms include nausea, vomiting, salivation, anorexia, and gastrointestinal
irritation. Cardiac arrhythmias and cardiac arrest have been reported.
Emergency Life-Support Procedures: Acute exposure to chloroform may require decontamination and life support for
the victims. Emergency personnel should wear protective clothing appropriate to the type and degree of contamination.
1. Move victims to fresh air. Emergency personnel should avoid self-exposure to chloroform.
3. Obtain authorization and/or further instructions from the local hospital for performance of invasive procedures.
4. Transport to a health care facility.
1. Remove victims from exposure. Emergency personnel should avoid self-exposure to chloroform.
3. Remove and isolate contaminated clothing as soon as possible.
5. Wash exposed skin areas thoroughly with water.
6. Obtain authorization and/or further instructions from the local hospital for performance of other invasive
procedures.
7. Transport to a health care facility.
Ingestion Exposure:
2. DO NOT induce vomiting.
to 30 g (1/2 to 1 oz) of cathartic; 50 to 100 g (1-3/4 to 3-1/2 oz) is recommended for adults.
6. Transport to a health care facility. (EPA, 1998)
Physical Properties
Chemical Formula: CHCl3

Flash Point: None (EPA, 1998)
Lower Explosive Limit (LEL): None (EPA, 1998)
Upper Explosive Limit (UEL): NoneNone (EPA, 1998)
Autoignition Temperature: Not flammable (USCG, 1999)
Melting Point: -82.3 ° F (EPA, 1998)
Vapor Pressure: 100 mm Hg at 50.72 ° F (EPA, 1998)
Specific Gravity: 1.4832 at 68 ° F (EPA, 1998)
Boiling Point: 143 ° F at 760 mm Hg (EPA, 1998)
Final AEGLs for Chloroform (67-66-3)

(NAC/NRC, 2017)

Chloroform (67-66-3) NA 50 ppm 5000 ppm
NA = not appropriate.
(AIHA, 2016)

Chloroform (67-66-3) 2 ppm 64 ppm 3200 ppm
(DOE, 2016)

10000 20000
Chloroform 67-66-3 pounds 10 pounds 10 pounds 313 U044 pounds
Methane, 10000 20000
trichloro- 67-66-3 pounds 10 pounds 10 pounds X U044 pounds
name.

RELEASE THEFT SABOTAGE
CAS Min Security Min Security Min Security
Chemical of Interest Number Conc STQ Issue Conc STQ Issue Conc STQ Issue
Chloroform; 20000
[Methane, trichloro-] 67-66-3 1.00 % pounds toxic
(DHS, 2007)

Chemical Datasheet
METHANOL
67-56-1 1230 Flammable Liquid MAL
Poison (international)

Methyl alcohol METHANOL
NFPA 704

1 0
Special
(NFPA, 2010)
General Description
A colorless fairly volatile liquid with a faintly sweet pungent odor like that of ethyl alcohol. Completely mixes with
water. The vapors are slightly heavier than air and may travel some distance to a source of ignition and flash back. Any
accumulation of vapors in confined spaces, such as buildings or sewers, may explode if ignited. Used to make
chemicals, to remove water from automotive and aviation fuels, as a solvent for paints and plastics, and as an
ingredient in a wide variety of products.
Hazards
Reactivity Alerts
Highly Flammable

Highly flammable. Soluble in water in all proportions.
Fire Hazard
Behavior in Fire: Containers may explode. (USCG, 1999)
Health Hazard
Exposure to excessive vapor causes eye irritation, headache, fatigue and drowsiness. High concentrations can
produce central nervous system depression and optic nerve damage. 50,000 ppm will probably cause death in 1 to 2
hrs. Can be absorbed through skin. Swallowing may cause death or eye damage. (USCG, 1999)
Reactivity Profile
METHANOL reacts violently with acetyl bromide [Merck 11th ed. 1989]. Mixtures with concentrated sulfuric acid
and concentrated hydrogen peroxide can cause explosions. Reacts with hypochlorous acid either in water solution or
mixed water/carbon tetrachloride solution to give methyl hypochlorite, which decomposes in the cold and may explode
on exposure to sunlight or heat. Gives the same product with chlorine. Can react explosively with isocyanates under
basic conditions. The presence of an inert solvent mitigates this reaction [Wischmeyer 1969]. A violent exothermic
reaction occurred between methyl alcohol and bromine in a mixing cylinder [MCA Case History 1863. 1972]. A flask
of anhydrous lead perchlorate dissolved in methanol exploded when it was disturbed [J. Am. Chem. Soc. 52:2391.
1930]. P4O6 reacts violently with methanol. (Thorpe, T. E. et al., J. Chem. Soc., 1890, 57, 569-573). Ethanol or
methanol can ignite on contact with a platinum-black catalyst. (Urben 1794).


Excerpt from ERG Guide 131 [Flammable Liquids - Toxic]:
Firefighting
SMALL FIRE: Dry chemical, CO2, water spray or alcohol-resistant foam.
LARGE FIRE: Water spray, fog or alcohol-resistant foam. Move containers from fire area if you can do it without risk.
Dike fire-control water for later disposal; do not scatter the material. Use water spray or fog; do not use straight
streams.
Non-Fire Response
Fully encapsulating, vapor-protective clothing should be worn for spills and leaks with no fire. ELIMINATE all
ignition sources (no smoking, flares, sparks or flames in immediate area). All equipment used when handling the
product must be grounded. Do not touch or walk through spilled material. Stop leak if you can do it without risk.
Prevent entry into waterways, sewers, basements or confined areas. A vapor-suppressing foam may be used to reduce
vapors.
SMALL SPILL: Absorb with earth, sand or other non-combustible material and transfer to containers for later
disposal. Use clean, non-sparking tools to collect absorbed material.
Protective Clothing
Approved canister mask for high vapor concentrations; safety goggles; rubber gloves. (USCG, 1999)

Methanol (>95%) 67-56-1 Liquid imm. >480 imm. 117 >480 185 >480 >480 >480
(DuPont, 2018)
First Aid
INDUCE VOMITING. IMMEDIATELY transport the victim to a hospital. (NTP, 1992)
Physical Properties
Chemical Formula: CH4O

Lower Explosive Limit (LEL): 6 % (NTP, 1992)
Vapor Pressure: 100 mm Hg at 70.2 ° F ; 237.87 mm Hg at 100° F (NTP, 1992)
Interim AEGLs for Methanol (67-56-1)


Level of Distinct Odor Awareness (LOA) = 8.9 ppm
(NAC/NRC, 2017)

Methanol (67-56-1) 200 ppm 1000 ppm 5000 ppm
(AIHA, 2016)
Methanol; (Methyl alcohol) (67-56-1) 530 ppm 2100 ppm 7200 ppm LEL = 55000 ppm

(DOE, 2016)

Methanol 67-56-1 5000 pounds 313 U154

Chemical Datasheet
DIOXANE
123-91-1 1165 Flammable Liquid DOX

Dioxane 1,4-DIOXANE
NFPA 704

2 1
Normally stable but can become unstable at elevated temperatures and
Instability 1 pressures.
Special
(NFPA, 2010)
General Description
A clear colorless liquid with a faint ethereal odor. Flash point 55°F. Slightly denser than water and soluble in water.
Vapors heavier than air. Susceptible to autooxidation to form peroxides.
Hazards
Reactivity Alerts
Highly Flammable
Peroxidizable Compound

Highly flammable. When exposed to air it undergoes autooxidation with formation of peroxides. In the distillation
process peroxides will concentrate causing violent explosion. Water soluble.
Fire Hazard
Special Hazards of Combustion Products: Toxic vapors are generated when heated.
Behavior in Fire: Vapor is heavier than air and may travel to a source of ignition and flash back. (USCG, 1999)
Health Hazard
No significant irritation from brief exposure of skin; prolonged or repeated exposure may cause a rash or burn and
absorption of toxic amounts leading to serious injury of liver and kidney. Chemical has poor warning properties;
illness may be delayed. Moderately irritating to eyes; overexposure may cause corneal injury. (USCG, 1999)
Reactivity Profile
DIOXANE is a flammable liquid; when exposed to air it undergoes autooxidation with formation of peroxides. In the
distillation process peroxides will concentrate causing violent explosion. The addition complex with sulfur trioxide
(1:1) sometimes decomposes violently on storing at room temperature [Sisler, H. H. et al., Inorg. Synth., 1947, 2, p.
174]. Evaporation of boron trifluoride in aqueous dioxane with nitric acid led to an explosion upon addition of
perchloric acid [MCA Guide, 1972, p. 312]. Explosive reaction with Raney nickel catalyst above 210° C {Mozingo R.,
Org. Synth., 1955, Coll. Vol. 3, p. 182].
Ethers


Excerpt from ERG Guide 127 [Flammable Liquids (Water-Miscible)]:
Firefighting
CAUTION: For fire involving UN1170, UN1987 or UN3475, alcohol-resistant foam should be used.
Non-Fire Response
Protective Clothing
(NIOSH, 2016)

Dioxane, 1,4- (>95%) 123-91-1 Liquid >480 >480 >480 >480 >480 >480 >480
(DuPont, 2018)
First Aid
NOT INDUCE VOMITING. IMMEDIATELY transport the victim to a hospital.
Physical Properties

Interim AEGLs for 1,4-Dioxane (123-91-1)

Level of Distinct Odor Awareness = 1.7 ppm
AEGL Process).
(NAC/NRC, 2017)

Dioxane, 1,4-; (1,4-Diethyleneoxide) (123-91- LEL = 20000
1) 17 ppm 320 ppm 760 ppm ppm
(DOE, 2016)


1,4-Dioxane 123-91-1 100 pounds 313 U108

Chemical Datasheet
ACETONITRILE
75-05-8 1648 Flammable Liquid ATN

Acetonitrile ACETONITRILE
NFPA 704

2 0
Special
(NFPA, 2010)
General Description
A colorless limpid liquid with an aromatic odor. Flash point 42°F. Density 0.783 g / cm3. Toxic by skin absorption.
Less dense than water. Vapors are denser than air.
Hazards
Reactivity Alerts
Highly Flammable

Highly flammable. Water soluble.
Fire Hazard
Special Hazards of Combustion Products: Toxic vapors are generated when heated
Behavior in Fire: Vapor heavier than air and may travel a considerable distance to a source of ignition and flash back.
(USCG, 1999)
Health Hazard
Exposure to 160 ppm for 4 hours causes flushing of the face and a feeling of constriction in the chest; 500 ppm for
brief periods is irritating to the nose and throat. Severe exposures cause irritability, skin eruptions, confusion, delirium,
convulsions, paralysis, and death due to central nervous system depression. (USCG, 1999)
Reactivity Profile
ACETONITRILE decomposes when heated to produce deadly toxic hydrogen cyanide gas and oxides of nitrogen.
Strongly reactive [Hawley]. May react vigorously with strong oxidizing reagents, sulfuric acid, chlorosulfonic acid,
sulfur trioxide, perchlorates, nitrating reagents, and nitric acid. [Sax, 9th ed., 1996, p. 20]. Potentially explosive in
contact with nitrogen-fluorine compounds (e.g., tetrafluorourea) [Fraser, G. W. et al., Chem. Comm., 1966, p. 532].
Nitriles


Firefighting
Non-Fire Response
Protective Clothing

Provide: Facilities for quickly drenching the body should be provided within the immediate work area for emergency
use where there is a possibility of exposure. [Note: It is intended that these facilities provide a sufficient quantity or
flow of water to quickly remove the substance from any body areas likely to be exposed. The actual determination of
what constitutes an adequate quick drench facility depends on the specific circumstances. In certain instances, a deluge
shower should be readily available, whereas in others, the availability of water from a sink or hose could be considered
adequate.] (NIOSH, 2016)

Acetonitrile (>95%) 75-05-8 Liquid imm. 60 imm. >480 >480 >480 >480 >480 >480
(DuPont, 2018)
First Aid
Physical Properties
Chemical Formula: CH3CN
Water Solubility: greater than or equal to 100 mg/mL at 72.5° F (NTP, 1992)
Final AEGLs for Acetonitrile (75-05-8)

NR = Not recommended
(NAC/NRC, 2017)

Acetonitrile (75-05-8) 13 ppm 50 ppm 150 ppm LEL = 30000 ppm
(DOE, 2016)

Acetonitrile 75-05-8 5000 pounds 313 U003

Chemical Datasheet
FORMALDEHYDE
50-00-0 3077 Class 9 none

Formaldehyde FORMALDEHYDE
FORMALDEHYDE (37% SOLUTION, methanol free)
NFPA 704

3 0
Special
(NFPA, 2010)
General Description
Solids containing varying amounts of formaldehyde, probably as paraformaldehyde (polymers of formula
HO(CH2O)xH where x averages about 30). A hazard to the environment. Immediate steps should be taken to limit
spread to the environment.
Hazards
Reactivity Alerts
Polymerizable

No rapid reaction with air. No rapid reaction with water.
Fire Hazard
Excerpt from ERG Guide 171 [Substances (Low to Moderate Hazard)]:
Some may burn but none ignite readily. Containers may explode when heated. Some may be transported hot. For
UN3508, be aware of possible short circuiting as this product is transported in a charged state. (ERG, 2016)
Health Hazard
Exposure Routes: inhalation, skin and/or eye contact
Symptoms: Irritation eyes, nose, throat, respiratory system; lacrimation (discharge of tears); cough; wheezing;
[potential occupational carcinogen]
Target Organs: Eyes, respiratory system (NIOSH, 2016)
Reactivity Profile
FORMALDEHYDE (ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S.) may react violently
with strong oxidizing agents (hydrogen peroxide, performic acid, perchloric acid in the presence of aniline, potassium
permanganate, nitromethane). May react with bases (sodium hydroxide, potassium hydroxide, ammonia), and with
nitrogen dioxide (explosive reaction around 180°C). May react with hydrochloric acid to form highly toxic
bis(chloromethyl) ether. Polymerization reaction with phenol may develop sudden destructive pressure [Bretherick, 5th
ed., 1995, p.168]. May generate flammable and/or toxic gases in combination with azo, diazo compounds,
dithiocarbamates, nitrides, and strong reducing agents. May generate toxic formaldehyde gas when heated. Can react
with air to give first peroxo acids, and ultimately formic acid. These reactions are activated by light, catalyzed by salts
of transition metals, and are autocatalytic (catalyzed by the products of the reaction). Incompatible with liquid oxygen.
Aldehydes
Polymerizable Compounds

Dirt/Earth

Firefighting
LARGE FIRE: Water spray, fog or regular foam. Do not scatter spilled material with high-pressure water streams.
Move containers from fire area if you can do it without risk. Dike fire-control water for later disposal.
FIRE INVOLVING TANKS: Cool containers with flooding quantities of water until well after fire is out. Withdraw
tanks engulfed in fire. (ERG, 2016)
Non-Fire Response
Do not touch or walk through spilled material. Stop leak if you can do it without risk. Prevent dust cloud. Avoid
inhalation of asbestos dust.
SMALL DRY SPILL: With clean shovel, place material into clean, dry container and cover loosely; move containers
from spill area.
SMALL SPILL: Pick up with sand or other non-combustible absorbent material and place into containers for later
disposal.
LARGE SPILL: Dike far ahead of liquid spill for later disposal. Cover powder spill with plastic sheet or tarp to
minimize spreading. Prevent entry into waterways, sewers, basements or confined areas. (ERG, 2016)
Protective Clothing
Skin: No recommendation is made specifying the need for personal protective equipment for the body.
Wash skin: No recommendation is made specifying the need for washing the substance from the skin (either
immediately or at the end of the work shift).
Remove: No recommendation is made specifying the need for removing clothing that becomes wet or contaminated.
(NIOSH, 2016)

Formaldehyde (100 ppm) 50-00-0 Vapor >480 >480 >480 >480
(DuPont, 2018)
First Aid
Eye: If this chemical contacts the eyes, immediately wash the eyes with large amounts of water, occasionally lifting the
lower and upper lids. Get medical attention immediately. Contact lenses should not be worn when working with this
chemical.
Breathing: If a person breathes large amounts of this chemical, move the exposed person to fresh air at once. If
breathing has stopped, perform mouth-to-mouth resuscitation. Keep the affected person warm and at rest. Get medical
attention as soon as possible. (NIOSH, 2016)
Physical Properties
Chemical Formula: CH2O

Lower Explosive Limit (LEL): 7 % (NIOSH, 2016)
Upper Explosive Limit (UEL): 73 % (NIOSH, 2016)
Melting Point: -134 ° F (NIOSH, 2016)
Vapor Pressure: greater than 1 atm (NIOSH, 2016)
Boiling Point: -6 ° F at 760 mm Hg (NIOSH, 2016)
Molecular Weight: 30 (NIOSH, 2016)
Water Solubility: Miscible (NIOSH, 2016)
Interim AEGLs for Formaldehyde (50-00-0)

10 minutes 0.9 ppm 14 ppm 100 ppm
4 hours 0.9 ppm 14 ppm 35 ppm
(NAC/NRC, 2017)

Formaldehyde (50-00-0) 1 ppm 10 ppm 40 ppm
(AIHA, 2016)
Formaldehyde (50-00-0) 0.9 ppm 14 ppm 56 ppm
(DOE, 2016)

500 100 15000
Formaldehyde 50-00-0 pounds pounds 100 pounds 313 U122 pounds
Formaldehyde 500 100 15000
(solution) 50-00-0 pounds pounds 100 pounds X U122 pounds
name.

Chemical of CAS Min Security Min Security Min Security
Interest Number Conc STQ Issue Conc STQ Issue Conc STQ Issue
Formaldehyde 15000
(solution) 50-00-0 1.00 % pounds toxic
(DHS, 2007)

Formaldehyde (Formalin) 50-00-0 1000 pounds
(OSHA, 2011)

Chemical Datasheet
TRIETHYLAMINE
121-44-8 1296 Flammable Liquid TEN
Corrosive

Triethylamine TRIETHYLAMINE
NFPA 704

3 0
Special
(NFPA, 2010)
General Description
A clear colorless liquid with a strong ammonia to fish-like odor. Flash point 20°F. Vapors irritate the eyes and mucous
membranes. Less dense (6.1 lb / gal) than water. Vapors heavier than air. Produces toxic oxides of nitrogen when
burned.
Hazards
Reactivity Alerts
Highly Flammable

Highly flammable. Soluble in water.
Fire Hazard
Excerpt from ERG Guide 132 [Flammable Liquids - Corrosive]:
Flammable/combustible material. May be ignited by heat, sparks or flames. Vapors may form explosive mixtures with
water. (ERG, 2016)
Health Hazard
Vapors irritate nose, throat, and lungs, causing coughing, choking, and difficult breathing. Contact with eyes causes
severe burns. Clothing wet with chemical causes skin burns. (USCG, 1999)
Reactivity Profile
TRIETHYLAMINE reacts violently with oxidizing agents. Reacts with Al and Zn. Neutralizes acids in exothermic
reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols
(acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with
strong reducing agents, such as hydrides.
Amines, Phosphines, and Pyridines


Firefighting
Some of these materials may react violently with water.
Dike fire-control water for later disposal; do not scatter the material. Do not get water inside containers.
Non-Fire Response
vapors. Absorb with earth, sand or other non-combustible material and transfer to containers (except for Hydrazine).
Use clean, non-sparking tools to collect absorbed material.
Protective Clothing
Provide: Eyewash fountains should be provided (when concentration is >1%) in areas where there is any possibility
that workers could be exposed to the substance; this is irrespective of the recommendation involving the wearing of
eye protection. Facilities for quickly drenching the body should be provided (when concentration is >1%) within the
immediate work area for emergency use where there is a possibility of exposure. [Note: It is intended that these
facilities provide a sufficient quantity or flow of water to quickly remove the substance from any body areas likely to
be exposed. The actual determination of what constitutes an adequate quick drench facility depends on the specific
circumstances. In certain instances, a deluge shower should be readily available, whereas in others, the availability of
water from a sink or hose could be considered adequate.] (NIOSH, 2016)

Triethylamine (>95%) 121-44-8 Liquid 22 >480 >480 >480 >480
(DuPont, 2018)
First Aid
Physical Properties
Chemical Formula: C6H15N

Upper Explosive Limit (UEL): 8 % (USCG, 1999)
Vapor Pressure: 53.5 mm Hg (NTP, 1992)
Water Solubility: Soluble (NTP, 1992)

Triethylamine (121-44-8) 1 ppm 170 ppm 1000 ppm LEL = 12000 ppm
(DOE, 2016)

Triethylamine 121-44-8 5000 pounds 313 U404


Chemical Datasheet
ACETONE
67-64-1 1090 Flammable Liquid ACT

Acetone ACETONE
NFPA 704

1 0
Special
(NFPA, 2010)
General Description
A clear colorless liquid with a sweetish odor. Flash point 0°F. Less dense than water. Vapors are heavier than air. Used
as a solvent in paint and nail polish removers.
Hazards
Reactivity Alerts
Highly Flammable

Highly flammable. Water soluble.
Fire Hazard
water. (ERG, 2016)
Health Hazard
INHALATION: vapor irritating to eyes and mucous membranes; acts as an anesthetic in very high concentrations.
INGESTION: low order of toxicity but very irritating to mucous membranes. SKIN: prolonged excessive contact
causes defatting of the skin, possibly leading to dermatitis. (USCG, 1999)
Reactivity Profile
It was reported that a mixture of ACETONE and chloroform, in a residue bottle, exploded. Since addition of acetone to
chloroform in the presence of base will result in a highly exothermic reaction, it is thought that a base was in the bottle
[MCA Case History 1661. 1970]. Also, Nitrosyl chloride, sealed in a tube with a residue of acetone in the presence of
platinum catalyst, gave an explosive reaction [Chem. Eng. News 35(43):60. 1967]. The reaction of nitrosyl perchlorate
and acetone ignites and explodes. Explosions occur with mixtures of nitrosyl perchlorate and primary amine [Ann.
Chem. 42:2031. 1909]. Reacts violently with nitric acid. Also causes exothermic reaction when in contact with
aldehydes.
Ketones


Firefighting
Non-Fire Response
Protective Clothing
(NIOSH, 2016)

Acetone (>95%) 67-64-1 Liquid imm. imm. >480 >480 >480 >480 >480 >480 >480
(DuPont, 2018)
First Aid
Physical Properties

Vapor Density (Relative to Air): 2 (NTP, 1992)
Interim AEGLs for Acetone (67-64-1)


Level of Distinct Odor Awareness = 160 ppm
(NAC/NRC, 2017)

Acetone (67-64-1) 200 ppm 3200 ppm 5700 ppm LEL = 26000 ppm

(DOE, 2016)

Acetone 67-64-1 5000 pounds U002

Chemical Datasheet
N-OCTANE
111-65-9 1262 Flammable Liquid OAN

Octane OCTANE
NFPA 704

1 0
Special
(NFPA, 2010)
General Description
Colorless liquid with an odor of gasoline. Less dense than water and insoluble in water. Hence floats on water.
Produces irritating vapor.
Hazards
Reactivity Alerts
Highly Flammable

Fire Hazard
Behavior in Fire: Vapor is heavier than air and may travel a considerable distance to a source of ignition and flash
back. (USCG, 1999)
Health Hazard
Inhalation of concentrated vapor may cause irritation of respiratory tract, depression, and pulmonary edema. Liquid
can cause irritation of eyes and (on prolonged contact) irritation and cracking of skin. Ingestion causes irritation of
mouth and stomach. Aspiration causes severe lung irritation, rapidly developing pulmonary edema, and central
nervous system excitement, followed by depression. (USCG, 1999)
Reactivity Profile
May be incompatible with strong oxidizing agents like nitric acid. Charring may occur followed by ignition of
unreacted material and other nearby combustibles. In other settings, mostly unreactive. Not affected by aqueous
solutions of acids, alkalis, most oxidizing agents, and most reducing agents. When heated sufficiently or when ignited
in the presence of air, oxygen or strong oxidizing agents, burns exothermically to produce mostly carbon dioxide and
water.
Hydrocarbons, Aliphatic Saturated


Excerpt from ERG Guide 128 [Flammable Liquids (Water-Immiscible)]:
Firefighting
Fire Extinguishing Agents Not to Be Used: Water may be ineffective.
Fire Extinguishing Agents: Dry chemical, foam, carbon dioxide (USCG, 1999)
Non-Fire Response
Excerpt from ERG Guide 128 [Flammable Liquids (Water-Immiscible)]:
Protective Clothing
(NIOSH, 2016)
Octane, n- (>95%) 111-65-9 Liquid >480 >480 >480 >480
(DuPont, 2018)
First Aid
chemical.
Skin: If this chemical contacts the skin, promptly wash the contaminated skin with soap and water. If this chemical
penetrates the clothing, promptly remove the clothing and wash the skin with soap and water. Get medical attention
promptly.
attention as soon as possible.
Swallow: If this chemical has been swallowed, get medical attention immediately. (NIOSH, 2016)
Physical Properties

Flash Point: 56 ° F (USCG, 1999)
Lower Explosive Limit (LEL): 1 % (USCG, 1999)
Upper Explosive Limit (UEL): 6.5 % (USCG, 1999)
Melting Point: -70.2 ° F (USCG, 1999)
Vapor Pressure: 10 mm Hg (NIOSH, 2016)
Boiling Point: 258.1 ° F at 760 mm Hg (USCG, 1999)
Molecular Weight: 114.2 (USCG, 1999)
Water Solubility: 7e-05 % at 77° F (NIOSH, 2016)
IDLH: 1000 ppm Based on 10% of the lower explosive limit. (NIOSH, 2016)
Octane, n- (111-65-9) 230 ppm 385 ppm 5000 ppm LEL = 10000 ppm

(DOE, 2016)


Chemical Datasheet
64-19-7 2789 Corrosive AAC
Flammable Liquid

Acetic acid ACETIC ACID
NFPA 704

3 0
Special
(NFPA, 2010)
General Description
A clear colorless liquid with a strong odor of vinegar. Flash point 104°F. Density 8.8 lb / gal. Corrosive to metals and
tissue. Used to make other chemicals, as a food additive, and in petroleum production.
Hazards
Reactivity Alerts
none

Flammable. Water soluble. Dissolution generates some heat.
Fire Hazard
Special Hazards of Combustion Products: Irritating vapor generated when heated. (USCG, 1999)
Health Hazard
Breathing of vapors causes coughing, chest pain, and irritation of nose and throat; may cause nausea andvomiting.
Contact with skin and eye causes burns. (USCG, 1999)
Reactivity Profile
Mixing acetic acid in equal molar portions with any of the following substances in a closed container caused the
temperature and pressure to increase: 2-Aminoethanol, chlorosulfonic acid, ethylene diamine, ethyleneimine [NFPA
1991]. Acetic acid or acetic anhydride can explode with nitric acid if not kept cold. Potassium hydroxide residue in a
catalyst pot reacted violently when acetic acid was added [MCA Case History 920. 1963]. During the production of
terephthalic acid, n-xylene is oxidized in the presence of acetic acid. During these processes, detonating mixtures may
be produced. Addition of a small amount of water may largely eliminate the risk of explosion [NFPA 491M.1991.p. 7].
Acetaldehyde was put in drums previously pickled with acetic acid. The acid caused the acetaldehyde to polymerize
and the drums got hot and vented [MCA Case History 1764. 1971]. A mixture of ammonium nitrate and acetic acid
ignites when warmed, especially if concentrated [Von Schwartz 1918. p. 322 ]. Several laboratory explosions have
been reported using acetic acid and phosphorus trichloride to form acetyl chloride. Poor heat control probably caused
the formation of phosphine [J. Am. Chem. Soc. 60:488. 1938]. Acetic acid forms explosive mixtures with p-xylene and
air (Shraer, B.I. 1970. Khim. Prom. 46(10):747-750.).
Acids, Carboxylic


Firefighting
Some of these materials may react violently with water.
Dike fire-control water for later disposal; do not scatter the material. Do not get water inside containers.
Non-Fire Response
vapors. Absorb with earth, sand or other non-combustible material and transfer to containers (except for Hydrazine).
Use clean, non-sparking tools to collect absorbed material.
Protective Clothing
Skin: If concentration is >10%, wear appropriate personal protective clothing to prevent skin contact.
Wash skin: If concentration is >10%, the worker should immediately wash the skin when it becomes contaminated.
Remove: When concentration is >10% work clothing that becomes wet or significantly contaminated should be
removed and replaced.

Acetic acid (10%) 64-19-7 Liquid
Acetic acid (>95%) 64-19-7 Liquid imm. >480 84 >480 >480 339 >480 >480 >480
(DuPont, 2018)
First Aid
Physical Properties

Vapor Pressure: 11.4 mm Hg at 68 ° F ; 20 mm Hg at 86° F (NTP, 1992)
Acetic Acid (64-19-7) 5 ppm 35 ppm 250 ppm
(AIHA, 2016)
Acetic acid (64-19-7) 5 ppm 35 ppm 250 ppm LEL = 40000 ppm
(DOE, 2016)

Acetic acid 64-19-7 5000 pounds

Chemical Datasheet
ETHANOL
64-17-5 1170 Flammable Liquid EAL

Ethyl alcohol ETHANOL (ANHYDROUS)
NFPA 704

2 0
Special
(NFPA, 2010)
General Description
A clear colorless liquid with a characteristic vinous odor and pungent taste. Flash point 55°F. Density 6.5 lb / gal.
Vapors are heavier than air.
Hazards
Reactivity Alerts
Highly Flammable

Highly flammable. Soluble in water in all proportions.
Fire Hazard
FLAMMABLE. Flashback along vapor trail may occur. Vapor may explode if ignited in an enclosed area. (USCG,
1999)
Health Hazard
VAPOR: Irritating to eyes, nose and throat. LIQUID: Not harmful. (USCG, 1999)
Reactivity Profile
ETHANOL reacts violently with acetyl chloride and acetyl bromide [Rose, (1961); Merck 11th ed., 1989]. Mixtures
with concentrated sulfuric acid and strong hydrogen peroxide can cause explosions. Mixtures with concentrated
hydrogen peroxide form powerful explosives. Reacts readily with hypochlorous acid and with chlorine to give ethyl
hypochlorite, which decomposes in the cold and explodes on exposure to sunlight or heat. Base-catalysed reactions
with isocyanates should be carried out in inert solvents. Such reactions in the absence of solvents often occur with
explosive violence [Wischmeyer(1969)]. Highly oxidized potassium metal was dropped into a dish of ethyl alcohol, an
immediate explosion shattered the dish. Potassium superoxide was considered the cause of the reaction [Health and
Safety Inf. 251(1967)]. Ethanol or methanol can ignite on contact with a platinum-black catalyst. (Urben 1794).


Firefighting
Non-Fire Response
Protective Clothing
(NIOSH, 2016)

Ethanol (>95%) 64-17-5 Liquid >480 >480 >480 >480
Ethyl alcohol (>95%) 64-17-5 Liquid >480 >480 >480 >480
Ethyl hydroxide (>95%) 64-17-5 Liquid >480 >480 >480 >480
(DuPont, 2018)
First Aid
Physical Properties
Ethanol (64-17-5) 1800 ppm 3300 ppm NA LEL = 33000 ppm

NA = not appropriate.
(AIHA, 2016)
Ethanol: (Ethyl alcohol) (64-17-5) 1800 ppm 3300 ppm 15000 ppm LEL = 33000 ppm

(DOE, 2016)


Chemical Datasheet
ETHYL ACETATE
141-78-6 1173 Flammable Liquid ETA

Ethyl acetate ETHYL ACETATE
NFPA 704

1 0
Special
(NFPA, 2010)
General Description
A clear colorless liquid with a fruity odor. Flash point 24°F. Less dense than water. Vapors heavier than air.
Hazards
Reactivity Alerts
Highly Flammable

Highly flammable. Slightly soluble in water. This chemical is slowly hydrolyzed by moisture.
Fire Hazard
water. (ERG, 2016)
Health Hazard
Headache, irritation of respiratory passages and eyes, dizziness and nausea, weakness, loss of consciousness. (USCG,
1999)
Reactivity Profile
ETHYL ACETATE is also sensitive to heat. On prolonged storage, materials containing similar functional groups have
formed explosive peroxides. This chemical may ignite or explode with lithium aluminum hydride. It may also ignite
with potassium tert-butoxide. It is incompatible with nitrates, strong alkalis and strong acids. It will attack some forms
of plastics, rubber and coatings. It is incompatible with oxidizers such as hydrogen peroxide, nitric acid, perchloric
acid and chromium trioxide. Violent reactions occur with chlorosulfonic acid. (NTP, 1992). SOCl2 reacts with esters,
such as ethyl acetate, forming toxic SO2 gas and water soluble/toxic acyl chlorides, catalyzed by Fe or Zn (Spagnuolo,
C.J. et al. 1992. Chemical and Engineering News 70(22):2.).
Esters, Sulfate Esters, Phosphate Esters, Thiophosphate Esters, and Borate Esters


Firefighting
Non-Fire Response
Protective Clothing
(NIOSH, 2016)

Ethyl acetate (>95%) 141-78-6 Liquid imm. imm. >480 >480 >480 >480 >480 >480 >480
(DuPont, 2018)
First Aid
Physical Properties
Ethyl acetate (141-78-6) 1200 ppm 1700 ppm 10000 ppm LEL = 20000 ppm

(DOE, 2016)

Ethyl acetate 141-78-6 5000 pounds U112


Chemical Datasheet
ACETIC ANHYDRIDE
108-24-7 1715 Corrosive ACA
Flammable Liquid

Acetic anhydride ACETIC ANHYDRIDE
NFPA 704

3 1

Special
(NFPA, 2010)
General Description
A clear colorless liquid with a strong odor of vinegar. Flash point 129°F. Corrosive to metals and tissue. Density 9.0 lb
/gal. Used to make fibers, plastics, pharmaceuticals, dyes, and explosives.
Hazards
Reactivity Alerts
Water-Reactive

Flammable. Reacts violently with water to generate acetic acid. This reaction is heightened by the presence of mineral
acids (nitric, perchloric, sulfuric acid, etc.) [Chem. Eng. News 25, 3458].
Fire Hazard
Special Hazards of Combustion Products: Irritating vapors are generated when heated.
Behavior in Fire: Dangerous when exposed to heat or fire. (USCG, 1999)
Health Hazard
Liquid is volatile and causes little irritation on uncovered skin. However, causes severe burns when clothing is wet
with the chemical or if it enters gloves or shoes. Causes skin and eye burns and irritation of respiratory tract. Nausea
and vomiting may develop after exposure. (USCG, 1999)
Reactivity Profile
ACETIC ANHYDRIDE reacts violently on contact with water, steam, methanol, ethanol, glycerol and boric acid.
Reaction with water is particularly dangerous in presence with mineral acids (e.g., nitric, perchloric, chromic, sulfuric
acid) [Chem. Eng. News 25, 3458]. Potentially explosive reactions with oxidizing reagents such as barium peroxide,
chromium trioxide, chromic acid, hypochlorous acid, nitric acid, perchloric acid, peroxyacetic acid, potassium
permanganate, hydrogen peroxide. [Sax, 9th ed., 1996, p. 15]. Reacts violently with metal nitrates used as nitrating
agents [Davey W. et al., Chem. & Ind., 1948, p. 814].
Anhydrides

Dirt/Earth

Excerpt from ERG Guide 137 [Substances - Water-Reactive - Corrosive]:
Firefighting
When material is not involved in fire, do not use water on material itself.
SMALL FIRE: Dry chemical or CO2. Move containers from fire area if you can do it without risk.
LARGE FIRE: Flood fire area with large quantities of water, while knocking down vapors with water fog. If
insufficient water supply: knock down vapors only.
FIRE INVOLVING TANKS OR CAR/TRAILER LOADS: Cool containers with flooding quantities of water until well
after fire is out. Do not get water inside containers. Withdraw immediately in case of rising sound from venting safety
devices or discoloration of tank. ALWAYS stay away from tanks engulfed in fire. (ERG, 2016)
Non-Fire Response
Fully encapsulating, vapor-protective clothing should be worn for spills and leaks with no fire. Do not touch damaged
Use water spray to reduce vapors; do not put water directly on leak, spill area or inside container. Keep combustibles
(wood, paper, oil, etc.) away from spilled material.
SMALL SPILL: Cover with DRY earth, DRY sand or other non-combustible material followed with plastic sheet to
minimize spreading or contact with rain. Use clean, non-sparking tools to collect material and place it into loosely
covered plastic containers for later disposal. Prevent entry into waterways, sewers, basements or confined areas. (ERG,
2016)
Protective Clothing
(NIOSH, 2016)

Acetic anhydride (>95%) 108-24-7 Liquid 48 >480 >480 >480 >480 >480 >480
(DuPont, 2018)
First Aid
Physical Properties

Specific Gravity: 1.08 (USCG, 1999)
Water Solubility: Soluble in cold (greater than or equal to 10mg/ml); Decomposes in hot (NTP, 1992)
Acetic Anhydride (108-24-7) 0.5 ppm 15 ppm 100 ppm
(AIHA, 2016)
Acetic anhydride (108-24-7) 0.5 ppm 15 ppm 100 ppm LEL = 27000 ppm
(DOE, 2016)

Acetic anhydride 108-24-7 5000 pounds

Chemical Datasheet
CYCLOHEXANONE
108-94-1 1915 Flammable Liquid CCH

Cyclohexanone CYCLOHEXANONE
NFPA 704

1 0
Special
(NFPA, 2010)
General Description
A colorless to pale yellow liquid with a pleasant odor. Less dense than water . Flash point 111°F. Vapors heavier than
air. Used to make nylon, as a chemical reaction medium, and as a solvent.
Hazards
Reactivity Alerts
Highly Flammable

Flammable. Soluble in water.
Fire Hazard
water. (ERG, 2016)
Health Hazard
Inhalation of vapors from hot material can cause narcosis. The liquid may cause dermatitis. (USCG, 1999)
Reactivity Profile
CYCLOHEXANONE forms an explosive peroxide with H2O2, and reacts vigorously with oxidizing materials (nitric
acid). (NTP, 1992)
Ketones


Firefighting
Non-Fire Response
Protective Clothing
(NIOSH, 2016)

Cyclohexanone (>95%) 108-94-1 Liquid 136 >480 >480 >480 >480 >480 >480
(DuPont, 2018)
First Aid
Physical Properties

Vapor Pressure: 5.2 mm Hg at 77 ° F ; 10 mm Hg at 101.7° F (NTP, 1992)

Cyclohexanone; (Ketohexamethylene) (108-94- LEL = 11000
1) 60 ppm 830 ppm 5000 ppm ppm

(DOE, 2016)

Cyclohexanone 108-94-1 5000 pounds U057

Chemical Datasheet
RADIOACTIVE MATERIAL, URANIUM

HEXAFLUORIDE, FISSILE
7783-81-5 2977 Radioactive none
Corrosive

Uranium (soluble compounds, as U) URANIUM HEXAFLUORIDE
NFPA 704
data unavailable
General Description
A colorless volatile white crystalline solid. Highly toxic and corrosive. Radioactive. Emits high energy rays which may
be harmful and are detectable only by special instruments. Chemically irritates skin, eyes and mucous membranes.
Used to make fuel for nuclear power plants.
Hazards
Reactivity Alerts
Water-Reactive
Radioactive Material

Reacts vigorously with water to form uranyl fluoride (UO2F2) and corrosive hydrogen fluoride (hydrofluoric acid).
Based on a scenario where the chemical is spilled into an excess of water (at least 5 fold excess of water), half of the
maximum theoretical yield of Hydrogen Fluoride gas will be created in 1.2 minutes. Experimental details are in the
following: "Development of the Table of Initial Isolation and Protective Distances for the 2008 Emergency Response
Guidebook", ANL/DIS-09-2, D.F. Brown, H.M. Hartmann, W.A. Freeman, and W.D. Haney, Argonne National
Laboratory, Argonne, Illinois, June 2009.
Fire Hazard
Excerpt from ERG Guide 166 [Radioactive Materials - Corrosive (Uranium Hexafluoride / Water-Sensitive)]:
Substance does not burn. The material may react violently with fuels. Product will decompose to produce toxic and/or
corrosive fumes. Containers in protective overpacks (horizontal cylindrical shape with short legs for tie-downs), are
identified with "AF", "B(U)F" or "H(U)" on shipping papers or by markings on the overpacks. They are designed and
evaluated to withstand severe conditions including total engulfment in flames at temperatures of 800°C (1475°F) for a
period of 30 minutes. Bare filled cylinders, identified with UN2978 as part of the marking (may also be marked H(U)
or H(M)), may rupture in heat of engulfing fire; bare empty (except for residue) cylinders will not rupture in fires.
Radioactivity does not change flammability or other properties of materials. (ERG, 2016)
Health Hazard
Radiation presents minimal risk to transport workers, emergency response personnel and the public during
transportation accidents. Packaging durability increases as potential radiation and criticality hazards of the content
increase. Chemical hazard greatly exceeds radiation hazard. Substance reacts with water and water vapor in air to form
toxic and corrosive hydrogen fluoride gas and an extremely irritating and corrosive, white-colored, water-soluble
residue. If inhaled, may be fatal. Direct contact causes burns to skin, eyes, and respiratory tract. Low-level radioactive
material; very low radiation hazard to people. Runoff from control of cargo fire may cause low-level pollution. (ERG,
2016)
Reactivity Profile
URANIUM HEXAFLUORIDE [FISSILE, CONTAINING MORE THAN 1% U-235] has been enriched in the fissile
isotope of uranium. Naturally occurring uranium contains 0.7% U-235 (higher radioactivity) and 99.3% U-238 (lower
radioactivity). Emits fumes of highly toxic metallic uranium and uranium fluorides when heated to decomposition
[Lewis, 3rd ed., 1993, p. 1301]. Reacts vigorously with aromatic hydrocarbons (benzene, toluene, xylenes), undergoes
a violent reaction with water or alcohols (methanol, ethanol) [Bretherick, 5th ed., 1995, p. 1439]. Reacts with most
metals.
Fluoride Salts, Soluble

Halogenating Agents

Sand
Dirt/Earth

SPILL: See ERG Table 1 - Initial Isolation and Protective Action Distances on the UN/NA 2977 datasheet.
FIRE: When a large quantity of this material is involved in a major fire, consider an initial evacuation distance of 300
meters (1000 feet) in all directions. (ERG, 2016)
Firefighting
DO NOT USE WATER OR FOAM ON MATERIAL ITSELF. Move containers from fire area if you can do it without
risk.
SMALL FIRE: Dry chemical or CO2.
LARGE FIRE: Water spray, fog or regular foam. Cool containers with flooding quantities of water until well after fire
is out. If this is impossible, withdraw from area and let fire burn. ALWAYS stay away from tanks engulfed in fire.
(ERG, 2016)
Non-Fire Response
Do not touch damaged packages or spilled material. DO NOT GET WATER INSIDE CONTAINERS. Without fire or
smoke, leak will be evident by visible and irritating vapors and residue forming at the point of release. Use fine water
spray to reduce vapors; do not put water directly on point of material release from container. Residue buildup may self-
seal small leaks. Dike far ahead of spill to collect runoff water. (ERG, 2016)
Protective Clothing
Excerpt from GUIDE 166 [Radioactive Materials - Corrosive (Uranium Hexafluoride / Water-Sensitive)]:
Wear positive pressure self-contained breathing apparatus (SCBA). Wear chemical protective clothing that is
specifically recommended by the manufacturer. It may provide little or no thermal protection. Structural firefighters'
protective clothing provides limited protection in fire situations ONLY; it is not effective in spill situations where direct
contact with the substance is possible. (ERG, 2016)

First Aid
Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves. Call
911 or emergency medical service. Medical problems take priority over radiological concerns. Use first aid treatment
according to the nature of the injury. In case of contact with Hydrofluoric acid (UN1790), flush with large amounts of
water. For skin contact, if calcium gluconate gel is available, rinse 5 minutes, then apply gel. Otherwise, continue
rinsing until medical treatment is available. For eyes, flush with water or a saline solution for 15 minutes. Do not delay
care and transport of a seriously injured person. Give artificial respiration if victim is not breathing. Administer oxygen
if breathing is difficult. In case of contact with substance, immediately flush skin or eyes with running water for at least
20 minutes. Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed. Keep victim calm
and warm. (ERG, 2016)
Physical Properties
Chemical Formula: F6U

Melting Point: data unavailable
Molecular Weight: 352
IDLH: 10 mg/m3 As U (soluble compounds, as U); A potential occupational carcinogen. (NIOSH, 2016)
Final AEGLs for Uranium hexafluoride (7783-81-5)


10 minutes 3.6 mg/m3 28 mg/m3 216 mg/m3
60 minutes 3.6 mg/m3 9.6 mg/m3 36 mg/m3
4 hours NR 2.4 mg/m3 9 mg/m3
8 hours NR 1.2 mg/m3 4.5 mg/m3
(NAC/NRC, 2017)

Uranium Hexafluoride (7783-81-5) 5 mg/m3 15 mg/m3 30 mg/m3
(AIHA, 2016)
Uranium hexafluoride; (Uranium fluoride) (7783-
81-5) 3.6 mg/m3 9.6 mg/m3 36 mg/m3
(DOE, 2016)


Chemical Datasheet
POTASSIUM CYANIDE
151-50-8 1680 Poison PTC

Potassium cyanide (as CN) POTASSIUM CYANIDE
NFPA 704

3 0
Special
(NFPA, 2010)
General Description
White amorphous lumps or a crystalline mass with a faint odor of bitter almonds. Density 1.52 g / cm3 Toxic by skin
absorption through open wounds, by ingestion. Heating to decomposition produces toxic fumes. Used for gold and
silver extraction, in chemical analysis, to make other chemicals, and as an insecticide.
Hazards
Reactivity Alerts
Water-Reactive

Deliquescent. Soluble in water. Dissolution releases some poisonous hydrogen cyanide gas. The amount is not
hazardous except in an enclosed space. If the water is acidic, dangerous amounts of hydrogen cyanide form at once.
Based on a scenario where the chemical is spilled into an excess of water (at least 5 fold excess of water), half of the
maximum theoretical yield of Hydrogen Cyanide gas will be created in 12 minutes. Experimental details are in the
following: "Development of the Table of Initial Isolation and Protective Distances for the 2008 Emergency Response
Guidebook", ANL/DIS-09-2, D.F. Brown, H.M. Hartmann, W.A. Freeman, and W.D. Haney, Argonne National
Laboratory, Argonne, Illinois, June 2009.
Fire Hazard
Contact with acid releases highly flammable hydrogen cyanide gas. Moisture may cause this material to volatilize as
hydrogen cyanide. When heated to decomposition, it emits very toxic fumes of cyanide and nitrogen oxides. Reacts
with acids to produce hydrogen cyanide gas. Reacts with strong oxidizers such as nitrates and chlorates, nitrogen
trichloride; perchloryl fluoride; sodium nitrate; acids; alkaloids; chloral hydrate; iodine. Avoid contact with acids.
(EPA, 1998)
Health Hazard
It is classified as super toxic. Probable oral lethal dose in humans is less than 5 mg/kg or less than a taste (7 drops) for
a 150 lb. person. It is an eye and skin irritant. Poisonous in very small quantities; a taste is lethal. (EPA, 1998)
Reactivity Profile
POTASSIUM CYANIDE is a basic salt and a reducing agent. Reacts with acids of all kinds to generate poisonous
hydrogen cyanide gas. Can react violently with oxidizing agents: fusion with metal chlorates, perchlorates, nitrates, or
nitrites can cause explosions [Bretherick 1979. p. 101]. A mixture with perchloryl fluoride may explode above 100°C.
A mixture with nitrite salts may cause an explosion [Pieters 1957. p. 30]. Incompatible with iodine. Initiates the
explosive decomposition of nitrogen trichloride.
Cyanides, Inorganic


Excerpt from ERG Guide 157 [Substances - Toxic and/or Corrosive (Non-Combustible / Water-Sensitive)]:
SPILL: See ERG Table 1 - Initial Isolation and Protective Action Distances on the UN/NA 1680 datasheet.
Firefighting
Wear full protective clothing. Wear positive pressure breathing apparatus and special protective clothing. Move
container from fire area if you can do it without risk. Fight fire from maximum distance. Dike fire control water for
later disposal; do not scatter the material.
Water may be used on fire in an area containing potassium cyanide. Extinguish with dry chemical, carbon dioxide,
water spray, fog, or foam. (EPA, 1998)
Non-Fire Response
handling the product must be grounded. Do not touch damaged containers or spilled material unless wearing
appropriate protective clothing. Stop leak if you can do it without risk. A vapor-suppressing foam may be used to
reduce vapors. DO NOT GET WATER INSIDE CONTAINERS. Use water spray to reduce vapors or divert vapor
cloud drift. Avoid allowing water runoff to contact spilled material. Prevent entry into waterways, sewers, basements
or confined areas.
covered plastic containers for later disposal. (ERG, 2016)
Protective Clothing
(NIOSH, 2016)

Potassium cyanide (10%) 151-50-8 Liquid >480
(DuPont, 2018)
First Aid
Warning: Effects may be delayed. Caution is advised. Vital signs should be monitored closely. Heart palpitation may
occur within minutes after exposure.
Signs and Symptoms of Acute Potassium Cyanide Exposure: Signs and symptoms of acute exposure to potassium
cyanide may include hypertension (high blood pressure) and tachycardia (rapid heart rate), followed by hypotension
(low blood pressure) and bradycardia (slow heart rate). Cardiac arrhythmias and other cardiac abnormalities are
common. Cyanosis (blue tint to the skin and mucous membranes), and cherry-red or bloody mucous membranes may
appear. Tachypnea (rapid respiratory rate) may be followed by respiratory depression. Lung hemorrhage and
pulmonary edema may occur. Headache, vertigo (dizziness), agitation, and giddiness may precede combative behavior,
convulsions, paralysis, protruding eyeballs, dilated and unreactive pupils, and coma. Potassium cyanide is irritating to
the skin, eyes, and mucous membranes. Lacrimation (tearing) and a burning sensation of the mouth and throat are
common. Salivation, nausea, and vomiting may also occur.
Emergency Life-Support Procedures: Acute exposure to potassium cyanide may require decontamination and life
support for the victims. All exposed persons should be transported to a health care facility as quickly as possible.
Emergency personnel should wear protective clothing appropriate to the type and degree of contamination. Air-
purifying or supplied-air respiratory equipment should also be worn, as necessary. Rescue vehicles should carry
1. Move victims to fresh air. Emergency personnel should avoid self-exposure to potassium cyanide.
If not breathing, provide artificial respiration. IMMEDIATELY begin administering 100% oxygen to all victims.
Monitor victims for respiratory distress.Warning: To prevent self-poisoning, avoid mouth-to-mouth breathing; use a
forced-oxygen mask. Direct oral contact with potassium cyanide- contaminated persons or their gastric contents can
result in self- poisoning.
3. RUSH to a health care facility!
1. Remove victims from exposure. Emergency personnel should avoid self- exposure to potassium cyanide.
6. Wash exposed skin areas twice with soap and water.
Ingestion Exposure:
3. DO NOT induce vomiting. Ipecac is not recommended for ingestion of potassium cyanide.
to 30 g (1/2 to 1 oz) of cathartic; 50 to 100 g (1-3/4 to 3-1/2 oz) is recommended for adults. (EPA, 1998)
Physical Properties
Chemical Formula: KCN

Flash Point: Not flammable (EPA, 1998)
Melting Point: 1173 ° F (EPA, 1998)
Vapor Pressure: 0 mm Hg (approx) (NIOSH, 2016)
Specific Gravity: 1.52 at 60.8 ° F (EPA, 1998)
Boiling Point: Very high (USCG, 1999)
Water Solubility: 72 % at 77° F (NIOSH, 2016)
IDLH: 25 mg/m3 (as CN) (NIOSH, 2016)
Final AEGLs for Potassium cyanide (151-50-8)
4 hours 3.5 mg/m3 9.3 mg/m3 23 mg/m3
8 hours 2.7 mg/m3 6.6 mg/m3 18 mg/m3
(NAC/NRC, 2017)

Potassium cyanide (151-50-8) 5.3 mg/m3 19 mg/m3 40 mg/m3
(DOE, 2016)

Cyanide
Compounds N106 & 313
Potassium cyanide 151-50-8 100 pounds 10 pounds 10 pounds 313c P098
"c" indicates that although not listed by name and CAS number, this chemical is reportable under one or more of the
EPCRA section 313 chemical categories.
& indicates that no RQ is assigned to this generic or broad class, although the class is a CERCLA hazardous substance.
See 50 Federal Register 13456 (April 4, 1985).

Potassium sabotage/
cyanide 151-50-8 ACG APA contamination
ACG = a commercial grade.
APA = a placarded amount.
(DHS, 2007)

Chemical Datasheet
PHOSPHORIC ACID
7664-38-2 1805 (solution) Corrosive PAC
3453 (solid)

Phosphoric acid PHOSPHORIC ACID
NFPA 704

3 0
Special
(NFPA, 2010)
General Description
A clear colorless liquid or transparent crystalline solid. The pure solid melts at 42.35°C and has a density of 1.834 g /
cm3. Liquid is usually an 85% aqueous solution. Shipped as both a solid and liquid. Corrosive to metals and tissue.
Used in making fertilizers and detergents and in food processing.
Hazards
Reactivity Alerts
none

Soluble in water with small release of heat.
Fire Hazard
Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:
Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic
fumes. Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.). Contact with metals may
evolve flammable hydrogen gas. Containers may explode when heated. For electric vehicles or equipment, ERG Guide
147 (lithium ion batteries) or ERG Guide 138 (sodium batteries) should also be consulted. (ERG, 2016)
Health Hazard
Burns on mouth and lips, sour acrid taste, severe gastrointestinal irritation, nausea, vomiting, bloody diarrhea, difficult
swallowing, severe abdominal pains, thirst, acidemia, difficult breathing, convulsions, collapse, shock, death. (USCG,
1999)
Reactivity Profile
PHOSPHORIC ACID reacts exothermically with bases. May react with active metals, including such structural metals
as aluminum and iron, to release hydrogen, a flammable gas. Can initiate the polymerization of certain classes of
organic compounds. Reacts with cyanide compounds to release gaseous hydrogen cyanide. May generate flammable
and/or toxic gases in contact with dithiocarbamates, isocyanates, mercaptans, nitrides, nitriles, sulfides, and strong
reducing agents. Forms explosive mixture with nitromethane. Reacts violently with sodium tetrahydroborate. In the
presence of chlorides can corrode stainless steel to form explosive hydrogen gas. Emits toxic and irritating fumes of
oxides of phosphorus when heated to decomposition [Lewis, 3rd ed., 1993, p. 1029].
Acids, Weak


Firefighting
Non-Fire Response
Protective Clothing

Provide: Eyewash fountains should be provided (when concentration is >1.6%) in areas where there is any possibility
eye protection. Facilities for quickly drenching the body should be provided (when concentration is >1.6%) within the

Phosphoric acid (50%) 7664-38-2 Liquid
Phosphoric acid (85%) 7664-38-2 Liquid >480 >480 >480 >480 >480 >480 >480 >480
(DuPont, 2018)
First Aid
chemical.
Skin: If this chemical contacts the skin, immediately flush the contaminated skin with water. If this chemical penetrates
the clothing, immediately remove the clothing and flush the skin with water. Get medical attention promptly.
Physical Properties
Chemical Formula: H3PO4

Melting Point: 108 ° F (NIOSH, 2016)
Vapor Pressure: 0.03 mm Hg (NIOSH, 2016)
Boiling Point: greater than 266 ° F at 760 mm Hg (USCG, 1999)
Molecular Weight: 98 (USCG, 1999)
IDLH: 1000 mg/m3 (NIOSH, 2016)
Phosphoric Acid (7664-38-2) 3 mg/m3 30 mg/m3 150 mg/m3
(AIHA, 2016)
Phosphoric acid (7664-38-2) 3 mg/m3 30 mg/m3 150 mg/m3
(DOE, 2016)

Phosphoric acid 7664-38-2 5000 pounds

Chemical Datasheet
LACTIC ACID
50-21-5 3265 Corrosive LTA

none LACTIC ACID
NFPA 704
data unavailable
General Description
A colorless to yellow odorless syrupy liquid. Corrosive to metals and tissue. Used to make cultured dairy products, as
a food preservative, and to make chemicals.
Hazards
Reactivity Alerts
none

Soluble in water.
Fire Hazard
Combustible material: may burn but does not ignite readily. When heated, vapors may form explosive mixtures with
air: indoors, outdoors and sewers explosion hazards. Those substances designated with a (P) may polymerize
explosively when heated or involved in a fire. Contact with metals may evolve flammable hydrogen gas. Containers
may explode when heated. Runoff may pollute waterways. Substance may be transported in a molten form. (ERG,
2016)
Health Hazard
Inhalation of mist causes coughing and irritation of mucous membranes. Ingestion, even of diluted preparations, has a
corrosive effect on the esophagus and stomach. Contact with more concentrated solutions can cause severe burns of
skin or eye. (USCG, 1999)
Reactivity Profile
LACTIC ACID is a carboxylic acid. Carboxylic acids donate hydrogen ions if a base is present to accept them. They
react in this way with all bases, both organic (for example, the amines) and inorganic. Their reactions with bases,
called "neutralizations", are accompanied by the evolution of substantial amounts of heat. Neutralization between an
acid and a base produces water plus a salt. Carboxylic acids with six or fewer carbon atoms are freely or moderately
soluble in water; those with more than six carbons are slightly soluble in water. Soluble carboxylic acid dissociate to
an extent in water to yield hydrogen ions. The pH of solutions of carboxylic acids is therefore less than 7.0. Many
insoluble carboxylic acids react rapidly with aqueous solutions containing a chemical base and dissolve as the
neutralization generates a soluble salt. Carboxylic acids in aqueous solution and liquid or molten carboxylic acids can
react with active metals to form gaseous hydrogen and a metal salt. Such reactions occur in principle for solid
carboxylic acids as well, but are slow if the solid acid remains dry. Even "insoluble" carboxylic acids may absorb
enough water from the air and dissolve sufficiently in it to corrode or dissolve iron, steel, and aluminum parts and
containers. Carboxylic acids, like other acids, react with cyanide salts to generate gaseous hydrogen cyanide. The
reaction is slower for dry, solid carboxylic acids. Insoluble carboxylic acids react with solutions of cyanides to cause
the release of gaseous hydrogen cyanide. Flammable and/or toxic gases and heat are generated by the reaction of
carboxylic acids with diazo compounds, dithiocarbamates, isocyanates, mercaptans, nitrides, and sulfides. Carboxylic
acids, especially in aqueous solution, also react with sulfites, nitrites, thiosulfates (to give H2S and SO3), dithionites
(SO2), to generate flammable and/or toxic gases and heat. Their reaction with carbonates and bicarbonates generates a
harmless gas (carbon dioxide) but still heat. Like other organic compounds, carboxylic acids can be oxidized by strong
oxidizing agents and reduced by strong reducing agents. These reactions generate heat. A wide variety of products is
possible. Like other acids, carboxylic acids may initiate polymerization reactions; like other acids, they often catalyze
(increase the rate of) chemical reactions. Slowly corrodes most metals (USCG, 1999).
Acids, Carboxylic


Firefighting
Non-Fire Response
Protective Clothing
Rubber gloves; goggles; self-contained breathing apparatus where high concentrations of mist are present (USCG,
1999)

First Aid
INHALATION: move to fresh air.
INGESTION: give large amount of water.
EYES: flush with water for at least 15 min.
SKIN: flush with water; wash well with soap and water. (USCG, 1999)
Physical Properties

Molecular Weight: 90 (USCG, 1999)


Chemical Datasheet
AMMONIUM HYDROXIDE
1336-21-6 2672 Corrosive none

none AMMONIUM HYDROXIDE (10%-35% solution)
NFPA 704
data unavailable
General Description
A colorless aqueous solution. Concentration of ammonia ranges up to approximately 30%. Ammonia vapors (which
arise from the solution) irritate the eyes.
Hazards
Reactivity Alerts
none

Water soluble. Generates a small amount of heat when diluted with water.
Fire Hazard
Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic
fumes. Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.). Contact with metals may
evolve flammable hydrogen gas. Containers may explode when heated. For electric vehicles or equipment, ERG Guide
147 (lithium ion batteries) or ERG Guide 138 (sodium batteries) should also be consulted. (ERG, 2016)
Health Hazard
TOXIC; inhalation, ingestion or skin contact with material may cause severe injury or death. Contact with molten
substance may cause severe burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be
delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be
corrosive and/or toxic and cause pollution. (ERG, 2016)
Reactivity Profile
AMMONIUM HYDROXIDE reacts exothermically with acids. Evolves toxic gaseous ammonia with strong bases.
Reacts extremely violently with dimethyl sulfate [NFPA 491M 1991]. Reacts with aqueous silver nitrate sodium
hydroxide to give a black precipitate of silver nitride. Such a precipitate can explode on stirring [MCA Case History
1554 1968]. Aqueous ammonia and Hg react to form an explosive solid, likely a fulminate. (Thodos, G. Amer. Inst.
Chen. Engrs. J., 1964, 10, 274.).
Bases, Weak


Firefighting
Non-Fire Response
Protective Clothing
Excerpt from GUIDE 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:
protective clothing provides limited protection in fire situations ONLY; it is not effective in spill situations where direct
contact with the substance is possible. (ERG, 2016)

CAS
Ammonium hydroxide (16%) 1336-21-6 Liquid
CAS
Ammonium hydroxide (2-3%
in household cleaner) 1336-21-6 Liquid >480 >480 >480
Ammonium hydroxide
(28%-30%) 1336-21-6 Liquid imm. >480 89 >480 35 160 >480 >480 >480
(DuPont, 2018)
First Aid
Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves. Move
victim to fresh air. Call 911 or emergency medical service. Give artificial respiration if victim is not breathing. Do not
use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a
pocket mask equipped with a one-way valve or other proper respiratory medical device. Administer oxygen if
breathing is difficult. Remove and isolate contaminated clothing and shoes. In case of contact with substance,
immediately flush skin or eyes with running water for at least 20 minutes. For minor skin contact, avoid spreading
material on unaffected skin. Keep victim calm and warm. Effects of exposure (inhalation, ingestion or skin contact) to
substance may be delayed. (ERG, 2016)
Physical Properties
Chemical Formula: H5NO

Molecular Weight: data unavailable

Ammonium hydroxide (1336-21-6) 61 ppm 330 ppm 2300 ppm
(DOE, 2016)

Ammonium
hydroxide 1336-21-6 1000 pounds X
name.


Chemical Datasheet
PENTANE-2,4-DIONE
123-54-6 2310 Flammable Liquid ATA
Poison

none 2,4-PENTADIONE
NFPA 704

2 0
Special
(NFPA, 2010)
General Description
A colorless or yellow colored liquid. Less dense than water. Vapors are heavier than air. Used as a solvent in paints and
varnishes.
Hazards
Reactivity Alerts
Highly Flammable

Fire Hazard
Behavior in Fire: Vapor is heavier than air and may travel to a source of ignition and flash back. (USCG, 1999)
Health Hazard
Inhalation causes dizziness, headache, nausea, vomiting and loss of consciousness. Contact with liquid irritates eyes.
(USCG, 1999)
Reactivity Profile
Ketones, such as PENTANE-2,4-DIONE, are reactive with many acids and bases liberating heat and flammable gases
(e.g., H2). The amount of heat may be sufficient to start a fire in the unreacted portion of the ketone. Ketones react
with reducing agents such as hydrides, alkali metals, and nitrides to produce flammable gas (H2) and heat. Ketones are
incompatible with isocyanates, aldehydes, cyanides, peroxides, and anhydrides. They react violently with aldehydes,
HNO3, HNO3 + H2O2, and HClO4. May dissolve plastics (USCG, 1999).
Ketones


Firefighting
Dike fire-control water for later disposal; do not scatter the material. Use water spray or fog; do not use straight
streams.
Non-Fire Response
vapors.
SMALL SPILL: Absorb with earth, sand or other non-combustible material and transfer to containers for later
disposal. Use clean, non-sparking tools to collect absorbed material.
Protective Clothing
Safety glasses; eye bath and safety shower; air-supplied mask for concentrations above 2% (USCG, 1999)
First Aid
INHALATION: remove to fresh air; if victim is not breathing, give artificial respiration and then oxygen; call a
physician.
EYES or SKIN: flush with water. (USCG, 1999)
Physical Properties

Flash Point: 93 ° F (USCG, 1999)
Upper Explosive Limit (UEL): 11.6 % (USCG, 1999)
Melting Point: -10.3 ° F (USCG, 1999)
Pentanedione, 2,4-; (Acetylacetone) (123-54-6) 75 ppm 110 ppm 200 ppm
(DOE, 2016)


Chemical Datasheet
1,4-BUTANEDIOL
110-63-4 none data unavailable BUG

none 1,4-BUTANEDIOL
NFPA 704

1 0
Special
(NFPA, 2010)
General Description
Odorless colorless liquid or solid (depending upon temperature). (USCG, 1999)
Hazards
Reactivity Alerts
none

This chemical is hygroscopic. Water soluble.
Fire Hazard
Special Hazards of Combustion Products: Carbon dioxide and carbon monoxide may be produced in fire.
Behavior in Fire: Unstable with heat; may form flammable tetrahydrofuran at 300°F. (USCG, 1999)
Health Hazard
Ingestion of large amounts needed to produce any symptoms. (USCG, 1999)
Reactivity Profile
1,4-BUTANEDIOL is heat and light sensitive. This compound reacts with acid chlorides, acid anhydrides and
chloroformates. It also reacts with oxidizing agents and reducing agents. It is incompatible with isocyanates and acids.
It is also incompatible with peroxides, perchloric acid, sulfuric acid, hypochlorous acid, nitric acid, caustics,
acetaldehyde, nitrogen peroxide and chlorine. (NTP, 1992)


Firefighting
Fire Extinguishing Agents Not to Be Used: Water or foam may cause frothing.
Fire Extinguishing Agents: Alcohol foam, dry chemical or carbon dioxide. (USCG, 1999)
Non-Fire Response
Protective Clothing
Eye protection and rubber gloves. (USCG, 1999)

First Aid
Physical Properties

Vapor Pressure: less than 1 mm Hg at 100 ° F (NTP, 1992)

Butanediol, 1,4-; (1,4-Tetramethylene glycol) LEL = 19500
(110-63-4) 4.7 mg/m3 52 mg/m3 640 mg/m3 ppm
(DOE, 2016)


Chemical Datasheet
PHOSPHORUS, WHITE, DRY OR UNDER WATER

OR IN SOLUTION
7723-14-0 1381 Spontaneously Combustible PPW
Poison

Phosphorus (yellow) none
NFPA 704
4 Health 4 Can be lethal.

4 2
Burns readily. Rapidly or completely vaporizes at atmospheric pressure and
Flammability 4 normal ambient temperature.
Readily undergoes violent chemical changes at elevated temperatures and

Special
(NFPA, 2010)
General Description
A soft waxy solid with a sharp pungent odor similar to garlic. Insoluble in water and ethyl alcohol. Soluble in carbon
disulfide. Shipped as a solid or liquid in an atmosphere of inert gas or as a solid under water. Barely soluble in water
and denser than water. Hence, sinks in water. Uses include munitions manufacture, pyrotechnics, explosives, smoke
bombs, artificial fertilizers, and rat poisons. Density approximately 15.2 lb / gal.
Hazards
Reactivity Alerts
Highly Flammable
Strong Reducing Agent
Pyrophoric

Highly flammable. Emits a weak green light and gives off white acidic fumes of phosphorus oxides when exposed to
air. Ignites at 30°C in moist air, higher temperatures are required for ignition in dry air [Merck 11th ed. 1989]. Readily
ignites in air if warmed, finely divided, or if held under conditions in which the heat of reaction can build up. Contact
with finely divided charcoal or lampblack promotes ignition, probably by the absorbed oxygen. Contact with
amalgamated aluminum also promotes ignition [Mellor 1940 and 1971].
Fire Hazard
Special Hazards of Combustion Products: Fumes from burning phosphorus are highly irritating.
Behavior in Fire: Intense white smoke is formed. (USCG, 1999)
Health Hazard
Solid or liquid causes severe burns of skin. If ingested, causes nausea, vomiting, jaundice, low blood pressure,
depression, delirium, coma, death. Symptoms after ingestion may be delayed for from a few hours to 3 days. (USCG,
1999)
Reactivity Profile
WHITE PHOSPHORUS is reacts readily with most oxidizing agents. Often ignites on contact with air; storage under
water prevents this reaction. Submersion in water stops the white phosphorus/air reaction which however usually
resumes when the water is removed. Reacts violently with bromine trifluoride, even at 10°C [Mellor 2:113. 1946-47].
Reacts explosively on contact with bromoazide. Reacts explosively with selenium oxychloride, evolving light and heat
[Mellor 10:906. 1946-47]. Can also serve as an oxidizing agent---reacts incandescently if heated with thorium
[Svenska Akad. 1829. p. 1].
Reducing Agents, Strong



Excerpt from ERG Guide 136 [Substances - Spontaneously Combustible - Toxic and/or Corrosive (Air-Reactive)]:
SPILL: Consider initial downwind evacuation for at least 300 meters (1000 feet).
Firefighting
SMALL FIRE: Water spray, wet sand or wet earth.
LARGE FIRE: Water spray or fog. Do not scatter spilled material with high-pressure water streams. Move containers
from fire area if you can do it without risk.
Non-Fire Response
ignition sources (no smoking, flares, sparks or flames in immediate area). Do not touch or walk through spilled
material. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Stop
leak if you can do it without risk.
SMALL SPILL: Cover with water, sand or earth. Shovel into metal container and keep material under water.
LARGE SPILL: Dike for later disposal and cover with wet sand or earth. Prevent entry into waterways, sewers,
basements or confined areas. (ERG, 2016)
Protective Clothing
Skin: Wear appropriate personal protective clothing to prevent skin contact. Flame retardant personal protective
equipment should be provided.
(NIOSH, 2016)

First Aid
chemical.
Skin: If this chemical contacts the skin, immediately flush the contaminated skin with water. If this chemical penetrates
the clothing, immediately remove the clothing and flush the skin with water. Get medical attention promptly.
Physical Properties
Chemical Formula: P4
Melting Point: 111.4 ° F (USCG, 1999)
Vapor Pressure: 0.03 mm Hg (NIOSH, 2016)
Water Solubility: 0.0003 % (NIOSH, 2016)
Phosphorus (red, violet, and black) (7723-14-0) 0.27 mg/m3 3 mg/m3 18 mg/m3
(DOE, 2016)

CAA
CAS Number/ EPCRA EPCRA EPCRA 112(r)
313 Category 302 304 CERCLA 313 RCRA RMP
Regulatory Name Code EHS TPQ EHS RQ RQ TRI Code TQ
100
Phosphorus 7723-14-0 pounds 1 pound 1 pound
Phosphorus (yellow or 100
white) 7723-14-0 pounds 1 pound 1 pound 313
400
Phosphorus 7723-14-0 ACG pounds EXP/IEDP
EXP/IEDP = explosives/improvised explosive device precursors.
(DHS, 2007)

Chemical Datasheet
POTASSIUM NITRATE
7757-79-1 1486 Oxidizer PNR

none POTASSIUM NITRATE
NFPA 704
data unavailable
General Description
A white to dirty gray crystalline solid. Water soluble. Noncombustible, but accelerates the burning of combustible
materials. If large quantities are involved in fire or the combustible material is finely divided an explosion may result.
May explode under prolonged exposure to heat or fire. Toxic oxides of nitrogen are produced in fires. Used in solid
propellants, explosives, fertilizers.
Hazards
Reactivity Alerts

Soluble in water.
Fire Hazard
Special Hazards of Combustion Products: May produce toxic nitrogen oxides upon decomposition.
Behavior in Fire: Strong oxidizer which may react explosively when mixed with reducing agents. Mixture may
detonate by heat or shock. Increases the flammability of any combustible material. (USCG, 1999)
Health Hazard
Exposure can cause mild irritation of eyes, nose and throat. (USCG, 1999)
Reactivity Profile
POTASSIUM NITRATE mixed with alkyl esters may explode, owing to the formation of alkyl nitrates; mixtures with
phosphorus, tin (II) chloride, or other reducing agents may react explosively [Bretherick 1979. p. 108-109]. Powdered
antimony mixed with potassium nitrate explodes when heated [Mellor 9:282 1946-47]. A mixture of antimony
trisulfide and potassium nitrate explodes at a red heat [Mellor 9:524. 1946-47]. Arsenic disulfide forms explosive
mixtures when mixed with potassium nitrate, [Mellor 9:270.1946-47]. A mixture of sodium acetate and potassium
nitrate may cause an explosion [Pieters 1957. p. 30]. A mixture of potassium nitrate and sodium hypophosphite
constitutes a powerful explosive [Mellor 8:881. 1946-47]. A mixture of powdered zirconium and potassium nitrate
explodes when heated above the melting point [Mellor 7:116. 1946-47].
Nitrate and Nitrite Compounds, Inorganic


Excerpt from ERG Guide 140 [Oxidizers]:
Firefighting
heat. Move containers from fire area if you can do it without risk.
holders or monitor nozzles. Cool containers with flooding quantities of water until well after fire is out. ALWAYS stay
away from tanks engulfed in fire. For massive fire, use unmanned hose holders or monitor nozzles; if this is
impossible, withdraw from area and let fire burn. (ERG, 2016)
Non-Fire Response
material unless wearing appropriate protective clothing. Stop leak if you can do it without risk. Do not get water inside
containers.
from spill area.
SMALL LIQUID SPILL: Use a non-combustible material like vermiculite or sand to soak up the product and place
into a container for later disposal.
LARGE SPILL: Dike far ahead of liquid spill for later disposal. Following product recovery, flush area with water.
(ERG, 2016)
Protective Clothing
Full cover clothing and chemical goggles. Use approved respirator to protect against dust. (USCG, 1999)
First Aid
Get medical attention.
INHALATION: Remove to fresh air.
EYES: Flush with water for at least 15 min., lifting lids occasionally.
SKIN: Remove contaminated clothing and shoes. Flush with water. (USCG, 1999)
Physical Properties
Chemical Formula: KNO3

Melting Point: 633.2 ° F (USCG, 1999)
Specific Gravity: 2.109 (USCG, 1999)
Boiling Point: 752 ° F at 760 mm Hg (decomposes) (USCG, 1999)
Potassium nitrate (7757-79-1) 9 mg/m3 100 mg/m3 600 mg/m3
(DOE, 2016)


Potassium 400
nitrate 7757-79-1 ACG pounds EXP/IEDP
(DHS, 2007)

Chemical Datasheet
METHYL ETHYL KETONE
78-93-3 1193 Flammable Liquid MEK

2-Butanone METHYL ETHYL KETONE
NFPA 704

1 0
Special
(NFPA, 2010)
General Description
Colorless fairly volatile liquid with a pleasant pungent odor. Flash point 20°F. Vapors heavier than air. Does not react
with water or many common materials. Stable in normal transportation. Irritates the nose, eyes, and throat. Combustion
may produce toxic materials. Density 6.7 lb / gal. Used as a solvent, for making other chemicals, and for production of
wax from petroleum.
Hazards
Reactivity Alerts
Highly Flammable

Fire Hazard
water. (ERG, 2016)
Health Hazard
Liquid causes eye burn. Vapor irritates eyes, nose, and throat; can cause headache, dizziness, nausea, weakness, and
loss of consciousness. (USCG, 1999)
Reactivity Profile
METHYL ETHYL KETONE is explosive in the form of vapor when exposed to heat, flame or sparks. Ignition on
contact with potassium tert-butoxide. Reactive with strong oxidizing materials, and will dissolve or soften some
plastics. Mixture with 2-propanol will form explosive peroxides during storage. Vigorous reaction with chloroform in
the presence of alkali (sodium hydroxide, potassium hydroxide), chlorosulfonic acid, fuming sulfuric acid (oleum)
[Lewis, 3rd ed., 1993, p. 855]. Reaction with hydrogen peroxide in the presence of nitric acid forms heat- and shock-
sensitive explosive acetone peroxides. [Bjorklund, G. H. et al., Trans. R. Soc. Can, 1950, 44, p. 25].
Ketones


Firefighting
Non-Fire Response
Protective Clothing
to the substance; this is irrespective of the recommendation involving the wearing of eye protection. (NIOSH, 2016)

CAS
MEK (Methyl ethyl ketone)
(>95%) 78-93-3 Liquid 18 >480 71 71 >480 >480 >480 >480
Methyl ethyl ketone (>95%) 78-93-3 Liquid 18 >480 71 71 >480 >480 >480 >480
(DuPont, 2018)
First Aid
Physical Properties

Vapor Pressure: 77.5 mm Hg at 68 ° F ; 100 mm Hg at 77.0° F (NTP, 1992)
Final AEGLs for Methyl ethyl ketone (78-93-3)


(NAC/NRC, 2017)

Butanone, 2-; (Methyl ethyl ketone; MEK) (78- LEL = 18000
93-3) 200 ppm 2700 ppm 4000 ppm ppm

(DOE, 2016)
Methyl ethyl
ketone 78-93-3 5000 pounds U159


Chemical Datasheet
56-23-5 1846 Poison CBT

Carbon tetrachloride CARBON TETRACHLORIDE
NFPA 704

3 0
Special
(NFPA, 2010)
General Description
A clear colorless liquid with a characteristic odor. Denser than water (13.2 lb / gal) and insoluble in water.
Noncombustible. May cause illness by inhalation, skin absorption and/or ingestion. Used as a solvent, in the
manufacture of other chemicals, as an agricultural fumigant, and for many other uses.
Hazards
Reactivity Alerts
none

Insoluble in water.
Fire Hazard
Special Hazards of Combustion Products: Forms poisonous phosgene gas when exposed to open flames.
Behavior in Fire: Decomposes to form chlorine and phosgene (USCG, 1999)
Health Hazard
Dizziness, incoordination, anesthesia; may be accompanied by nausea and liver damage. Kidney damage also occurs,
often producing decrease or stopping of urinary output. (USCG, 1999)
Reactivity Profile
CARBON TETRACHLORIDE is a commonly used liquid in fire extinguishers to combat small fires. It has no flash
point, it is not flammable. However, when heated to decomposition, it will emit fumes of extremely toxic phosgene and
of hydrogen chloride. Forms explosive mixtures with chlorine trifluoride, calcium hypochlorite, decaborane, dinitrogen
tetraoxide, fluorine. Forms impact-sensitive explosive mixtures with particles of many metals: lithium, sodium,
potassium, beryllium, zinc, aluminum, barium. Vigorous exothermic reaction with allyl alcohol, boron trifluoride,
diborane, disilane, aluminum chloride, dibenzoyl peroxide, potassium tert-butoxide, liquid oxygen, zirconium.
[Bretherick, 5th ed., 1995, p. 666]. Potentially dangerous reaction with dimethylformamide or dimethylacetamide in
presence of iron [Cardillo, P. et al., Ann. Chim. (Rome), 1984, 74, p. 129].


Firefighting
LARGE FIRE: Water spray, fog or regular foam. Move containers from fire area if you can do it without risk. Dike
fire-control water for later disposal; do not scatter the material. Use water spray or fog; do not use straight streams.
tank. ALWAYS stay away from tanks engulfed in fire. For massive fire, use unmanned hose holders or monitor
nozzles; if this is impossible, withdraw from area and let fire burn. (ERG, 2016)
Non-Fire Response
Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Stop leak if you
can do it without risk. Prevent entry into waterways, sewers, basements or confined areas. Cover with plastic sheet to
prevent spreading. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers.
DO NOT GET WATER INSIDE CONTAINERS. (ERG, 2016)
Protective Clothing
(NIOSH, 2016)

Carbon tetrachloride (>95%) 56-23-5 Liquid >480 11 11 >480 >480 >480 >480
(DuPont, 2018)
First Aid
Physical Properties
Chemical Formula: CCl4

Final AEGLs for Carbon tetrachloride (56-23-5)

4 hours NR 7.6 ppm 200 ppm
8 hours NR 5.8 ppm 150 ppm
NR = Not recommended
(NAC/NRC, 2017)

Carbon Tetrachloride (56-23-5) 20 ppm 100 ppm 750 ppm
(AIHA, 2016)

Carbon tetrachloride (56-23-5) 1.2 ppm 13 ppm 340 ppm
(DOE, 2016)


Carbon
tetrachloride 56-23-5 10 pounds 313 U211


Chemical Datasheet
HYDROGEN PEROXIDE, AQUEOUS SOLUTION,

WITH NOT LESS THAN 20% BUT NOT MORE THAN
60% HYDROGEN PEROXIDE (STABILIZED AS
NECESSARY)
7722-84-1 2014 Oxidizer none
Corrosive

Hydrogen peroxide HYDROGEN PEROXIDE (>60% SOLUTION IN WATER)
NFPA 704

3 1
ox Flammability 0 Will not burn under typical fire conditions.
Special OX Possesses oxidizing properties.

(NFPA, 2010)
General Description
Colorless aqueous solution. Vapors may irritate the eyes and mucous membranes. Contact with most common metals
and their compounds may cause violent decomposition, especially in the higher concentrations. Contact with
combustible materials may result in spontaneous ignition. Prolonged exposure to fire or heat may cause decomposition
and rupturing of the container. Used to bleach textiles and wood pulp, in chemical manufacturing and food processing.
Hazards
Reactivity Alerts
Explosive

An aqueous solution that is readily diluted.
Fire Hazard
These substances will accelerate burning when involved in a fire. Some may decompose explosively when heated or
involved in a fire. May explode from heat or contamination. Some will react explosively with hydrocarbons (fuels).
May ignite combustibles (wood, paper, oil, clothing, etc.). Containers may explode when heated. Runoff may create
fire or explosion hazard. (ERG, 2016)
Health Hazard
Inhalation, ingestion or contact (skin, eyes) with vapors or substance may cause severe injury, burns or death. Fire may
produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may cause pollution. (ERG,
2016)
Reactivity Profile
The hazards associated with the use of HYDROGEN PEROXIDE (especially highly concentrated solutions) are well
documented. There is a release of enough energy during the catalytic decomposition of 65% peroxide to evaporate all
water and ignite nearby combustible materials. Most cellulose materials contain enough catalyst to cause spontaneous
ignition with 90% peroxide. Contamination of concentrated peroxide causes the possibility of explosion. Readily
oxidizable materials, or alkaline substances containing heavy metals may react violently. Solvents(acetone, ethanol,
glycerol) will detonate on mixture with peroxide of over 30% concentration, the violence increasing with
concentration. Concentrated peroxide may decompose violently in contact with iron, copper, chromium, and most
other metals or their salts, and dust(which frequently contain rust). During concentration under vacuum of aqueous or
of aqueous-alcoholic solutions of hydrogen peroxide, violent explosions occurred when the concentration was
sufficiently high(>90%), [Bretherick 2nd ed., 1979]. Mixtures of alcohols with concentrated sulfuric acid and strong
hydrogen peroxide can cause explosions. Example: An explosion will occur if dimethylbenzylcarbinol is added to 90%
hydrogen peroxide then acidified with concentrated sulfuric acid. Mixtures of ethyl alcohol with concentrated
hydrogen peroxide form powerful explosives. Mixtures of hydrogen peroxide and 1-phenyl-2-methyl propyl alcohol
tend to explode if acidified with 70% sulfuric acid, [Chem. Eng. News 45(43):73(1967); J, Org. Chem.
28:1893(1963)]. Hydrogen selenide and hydrogen peroxide undergo a very rapid decomposition, [Mellor 1:941(1946-
1947)].
Oxidizing Agents, Strong



Firefighting
heat. Move containers from fire area if you can do it without risk.
holders or monitor nozzles. Cool containers with flooding quantities of water until well after fire is out. ALWAYS stay
away from tanks engulfed in fire. For massive fire, use unmanned hose holders or monitor nozzles; if this is
impossible, withdraw from area and let fire burn. (ERG, 2016)
Non-Fire Response
material unless wearing appropriate protective clothing. Stop leak if you can do it without risk. Do not get water inside
containers.
from spill area.
SMALL LIQUID SPILL: Use a non-combustible material like vermiculite or sand to soak up the product and place
into a container for later disposal.
LARGE SPILL: Dike far ahead of liquid spill for later disposal. Following product recovery, flush area with water.
(ERG, 2016)
Protective Clothing
Excerpt from GUIDE 140 [Oxidizers]:
protective clothing will only provide limited protection. (ERG, 2016)

CAS
Hydrogen peroxide
(30%) 7722-84-1 Liquid >480 >480 >480 >480
Hydrogen peroxide
(50%) 7722-84-1 Liquid >480 >480 >480 >480
Hydrogen peroxide
(70%) 7722-84-1 Liquid >480 >480 >480 >480 >480 >480 >480
(DuPont, 2018)
First Aid
Physical Properties
Chemical Formula: H2O2, aqueous

Specific Gravity: 1.11 at 68 ° F (NTP, 1992)
Hydrogen Peroxide (7722-84-1) 10 ppm 50 ppm 100 ppm
(AIHA, 2016)
Hydrogen peroxide (7722-84-1) 10 ppm 50 ppm 100 ppm
(DOE, 2016)

EPCRA CAA
CAS Number/ 302 EPCRA EPCRA 112(r)
313 Category EHS 304 CERCLA 313 RCRA RMP
Regulatory Name Code TPQ EHS RQ RQ TRI Code TQ
Hydrogen peroxide (Conc.> 1000 1000
52%) 7722-84-1 pounds pounds

Hydrogen peroxide
(concentration of at least 7722-84- 35.00 400
35%) 1 % pounds EXP/IEDP
(DHS, 2007)

Hydrogen Peroxide (52% by weight or greater) 7722-84-1 7500 pounds
(OSHA, 2011)

Chemical Datasheet
FORMIC ACID
64-18-6 1779 Corrosive FMA
Flammable Liquid

Formic acid FORMIC ACID
NFPA 704

3 0
Special
(NFPA, 2010)
General Description
A colorless liquid with a pungent odor. Flash point 156°F. Density 10.2 lb / gal. Corrosive to metals and tissue.
Hazards
Reactivity Alerts
none

Fumes in air. Soluble in water with release of heat.
Fire Hazard
Special Hazards of Combustion Products: Toxic vapor generated in fires (USCG, 1999)
Health Hazard
Liquid causes skin and eye burns. Vapors are irritating and painful to breath. Vapor exposure may cause nausea and
vomiting. (USCG, 1999)
Reactivity Profile
FORMIC ACID reacts exothmerically with all bases, both organic (for example, the amines) and inorganic. Reacts
with active metals to form gaseous hydrogen and a metal salt. Reacts with cyanide salts to generate gaseous hydrogen
cyanide. Reacts with diazo compounds, dithiocarbamates, isocyanates, mercaptans, nitrides, and sulfides to generate
flammable or toxic gases. Reacts with sulfites, nitrites, thiosulfates (to give H2S and SO3), dithionites (SO2), to
generate flammable and/or toxic gases and heat. Reacts with carbonates and bicarbonates to generate carbon dioxide
but still heat. Can be oxidized by strong oxidizing agents and reduced by strong reducing agents. These reactions
generate heat. May initiate polymerization reactions or catalyze other chemical reactions. A mixture with furfuryl
alcohol exploded [Chem. Eng. News 18:72(1940)].
Acids, Carboxylic


Firefighting
Non-Fire Response
Protective Clothing
(NIOSH, 2016)

Formic acid (30%) 64-18-6 Liquid
Formic acid (>95%) 64-18-6 Liquid imm. >480 >480 260 260 >480 >480 >480 >480
(DuPont, 2018)
First Aid
Physical Properties
Chemical Formula: CH2O2

Lower Explosive Limit (LEL): 18 % (90% solution) (NTP, 1992)
Upper Explosive Limit (UEL): 57 % (90% solution) (NTP, 1992)
Vapor Pressure: 35 mm Hg at 68 ° F ; 200 mm Hg at 142.5° F (NTP, 1992)
Formic Acid (64-18-6) 3 ppm 25 ppm 250 ppm
(AIHA, 2016)

Formic acid (64-18-6) 3 ppm 25 ppm 250 ppm LEL = 180000 ppm
(DOE, 2016)

Formic acid 64-18-6 5000 pounds 313 U123


Chemical Datasheet
DICHLOROMETHANE
75-09-2 1593 Poison DCM

Methylene chloride DICHLOROMETHANE
NFPA 704

2 0
Special
(NFPA, 2010)
General Description
A colorless liquid with a sweet, penetrating, ether-like odor. Noncombustible by if exposed to high temperatures may
emit toxic chloride fumes. Vapors are narcotic in high concentrations. Used as a solvent and paint remover.
Hazards
Reactivity Alerts
none

Somewhat water soluble. Subject to slow hydrolysis which is accelerated by light.
Fire Hazard
Special Hazards of Combustion Products: Dissociation products generated in a fire may be irritating or toxic. (USCG,
1999)
Health Hazard
INHALATION: anesthetic effects, nausea and drunkenness. CONTACT WITH SKIN AND EYES: skin irritation,
irritation of eyes and nose. (USCG, 1999)
Reactivity Profile
DICHLOROMETHANE reacts vigorously with active metals such as lithium, sodium and potassium, and with strong
bases such as potassium tert-butoxide. It is incompatible with strong oxidizers, strong caustics and chemically active
metals such as aluminum or magnesium powders. The liquid will attack some forms of plastic, rubber and coatings.
This compound reacts with sodium-potassium alloy, (potassium hydrogen + N-methyl-N-nitrosurea), nitrogen
tetraoxide and liquid oxygen. It also reacts with titanium. On contact with water it corrodes iron, some stainless steels,
copper and nickel. It is incompatible with alkali metals. It is incompatible with amines, zinc and alloys of aluminum,
magnesium and zinc. This compound is liable to explode when mixed with dinitrogen pentaoxide or nitric acid.
Mixtures of this compound in air with methanol vapor are flammable. (NTP, 1992)


Excerpt from ERG Guide 160 [Halogenated Solvents]:
Firefighting
Non-Fire Response
ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop leak if you can do it
without risk.
SMALL LIQUID SPILL: Pick up with sand, earth or other non-combustible absorbent material.
LARGE SPILL: Dike far ahead of liquid spill for later disposal. Prevent entry into waterways, sewers, basements or
confined areas. (ERG, 2016)
Protective Clothing
(NIOSH, 2016)

CAS
Dichloromethane (>95%) 75-09-2 Liquid imm. imm. imm. imm. imm. >480 >480 >480 >480
Methylene chloride
(>95%) 75-09-2 Liquid imm. imm. imm. imm. imm. >480 >480 >480 >480
(DuPont, 2018)
First Aid
Physical Properties
Chemical Formula: CH2Cl2

Interim AEGLs for Methylene chloride (75-09-2)

(NAC/NRC, 2017)

Methylene Chloride (75-09-2) 300 ppm 750 ppm 4000 ppm
(AIHA, 2016)

Methylene chloride; (Dichloromethane) (75-09- LEL = 130000
2) 200 ppm 560 ppm 6900 ppm ppm
(DOE, 2016)


Dichloromethane 75-09-2 1000 pounds 313 U080
Methylene
chloride 75-09-2 1000 pounds X U080
name.


Chemical Datasheet
POTASSIUM CHLORIDE
7447-40-7 none data unavailable none

none POTASSIUM CHLORIDE
NFPA 704
data unavailable
General Description
PHYSICAL DESCRIPTION: White colorless cubic crystals. Strong saline taste. (NTP, 1992)
Hazards
Reactivity Alerts
none

Hygroscopic. Water soluble.
Fire Hazard
Flammability data is not available, but this compound is probably nonflammable. (NTP, 1992)
Health Hazard
SYMPTOMS: Large doses of this chemical usually induce vomiting, so acute intoxication by mouth is rare. If no pre-
existing kidney damage, it is rapidly excreted. Poisoning disturbs the rhythm of heart. Large doses by mouth can cause
gastrointestinal irritation, purging, weakness, and circulatory disturbances. (NTP, 1992)
Reactivity Profile
POTASSIUM CHLORIDE is not in general strongly reactive. Violent reaction with BrF3 and with a mixture of
sulfuric acid potassium permanganate mixture (NTP, 1992). Reacts with concentrated sulfuric acid to generate fumes
of hydrogen chloride.
Non-Redox-Active Inorganic Compounds

Firefighting
Non-Fire Response
material. Seal the absorbent paper, as well as any of your clothing which may be contaminated, in a vapor-tight plastic
bag for eventual disposal. Wash any surfaces you may have contaminated with a strong soap and water solution. Do
not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has
been properly cleaned.
STORAGE PRECAUTIONS: You should store this material in a refrigerator. (NTP, 1992)
Protective Clothing
RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half
face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2)
with a dust/mist filter. (NTP, 1992)

First Aid
Physical Properties
Chemical Formula: ClK

Specific Gravity: 1.984 (NTP, 1992)
Boiling Point: Sublimes at 2732° F (NTP, 1992)
Water Solubility: greater than 100 mg/mL at 68° F (NTP, 1992)


Chemical Datasheet
SULFURIC ACID
7664-93-9 1830 Corrosive SFA

Sulfuric acid SULFURIC ACID
NFPA 704

3 2
W Flammability 0 Will not burn under typical fire conditions.
Special W Reacts violently or explosively with water.

(NFPA, 2010)
General Description
Sulfuric acid is a colorless oily liquid. It is soluble in water with release of heat. It is corrosive to metals and tissue. It
will char wood and most other organic matter on contact, but is unlikely to cause a fire. Density 15 lb / gal. Long term
exposure to low concentrations or short term exposure to high concentrations can result in adverse health effects from
inhalation. It is used to make fertilizers and other chemicals, in petroleum refining, in iron and steel production, and for
many other uses.
Rate of onset: Immediate
Persistence: Hours, days
Odor threshold:
Source/use/other hazard: Battery/dyes/paper/glue/metals industries; volcanic gas; toxic fumes when heated.
Hazards
Reactivity Alerts

Water-Reactive
Reaction with water is negligible unless acid strength is above 80-90% then heat from hydrolysis is extreme, may
cause severe burns [Merck, 11th ed. 1989]. During sulfonation of mononitrobenzene by fuming sulfuric acid, a leak
from an internal cooling coil permitted water to enter the reaction tank. A violent eruption occurred due to the heat of
solution [MCA Case History 944 1963].
Fire Hazard
It is highly reactive and capable of igniting finely-divided combustible materials on contact. When heated, it emits
highly toxic fumes. Avoid heat; water and organic materials. Sulfuric acid is explosive or incompatible with an
enormous array of substances. Can undergo violent chemical change at elevated temperatures and pressure. May react
violently with water. When heated, it emits highly toxic fumes. Hazardous polymerization may not occur. (EPA, 1998)
Health Hazard
Corrosive to all body tissues. Inhalation of vapor may cause serious lung damage. Contact with eyes may result in total
loss of vision. Skin contact may produce severe necrosis. Fatal amount for adult: between 1 teaspoonful and one-half
ounce of the concentrated chemical. Even a few drops may be fatal if the acid gains access to the trachea. Chronic
exposure may cause tracheobronchitis, stomatitis, conjunctivitis, and gastritis. Gastric perforation and peritonitis may
occur and may be followed by circulatory collapse. Circulatory shock is often the immediate cause of death. Those
with chronic respiratory, gastrointestinal, or nervous diseases and any eye and skin diseases are at greater risk. (EPA,
1998)
Reactivity Profile
SULFURIC ACID is strongly acidic. Reacts violently with bromine pentafluoride [Mellor 2 Supp. 1:172 1956].
Exploded with para-nitrotoluene at 80°C [Chem. Eng. News 27:2504]. An explosion occurred when concentrated
sulfuric acid was mixed with crystalline potassium permanganate in a vessel containing moisture. Manganese
heptoxide was formed, which explodes at 70°C [Delhez 1967]. A mixture of acrylonitrile with concentrated sulfuric
acid must be kept well chilled, otherwise a vigorous exothermic reaction occurs [Chem. Safety Data Sheet SD-31:8.
1949]. Mixing sulfuric acid (96%) in equal portions with any of the following substances in a closed container caused
the temperature and pressure to increase: acetonitrile, acrolein, 2-aminoethanol, ammonium hydroxide (28%), aniline,
n-butyraldehyde, chlorosulfonic acid, ethylene diamine, ethyleneimine, epichlorohydrin, ethylene cyanohydrin,
hydrochloric acid (36%), hydrofluoric acid (48.7%), propiolactone, propylene oxide, sodium hydroxide, styrene
monomer [NFPA 1991]. Sulfuric acid (concentrated) is extremely hazardous in contact with carbides, bromates,
chlorates, fulminates, picrates, and powdered metals [Haz. Chem. Data 1966]. Allyl chloride may polymerize violently
under conditions involving an acid catalyst, such as sulfuric acid [Ventrone 1971]. React exothermically with sodium
hypochlorite to produce chlorine gas. Mixing chlorosulfuric acid and 98% sulfuric acid may evolve HCl [Subref:
Anon, Loss Prev. Bull. 1977, (013), 2-3]. Zinc iodide reacts violently with H2SO4. (Pascal, 1962, Vol. 5, 168).
Acids, Strong Oxidizing


Firefighting
Fight fire from safe distance or from protected location. Use care as water applied directly to this acid results in
evolution of heat and causes spattering. Cool containers that are exposed to flames with streams of water until fire is
out. Wear positive pressure breathing apparatus and special protective clothing.
Not flammable. For small fires use dry chemical or carbon dioxide. Use water on combustibles burning in vicinity of
this material. For large fires flood fire area with water from a distance. Do not get solid streams of water on material.
Move container from area if you can do so without risk. (EPA, 1998)
Non-Fire Response
Fully encapsulating, vapor-protective clothing should be worn for spills and leaks with no fire. Do not touch damaged
Use water spray to reduce vapors; do not put water directly on leak, spill area or inside container. Keep combustibles
(wood, paper, oil, etc.) away from spilled material.
covered plastic containers for later disposal. Prevent entry into waterways, sewers, basements or confined areas. (ERG,
2016)
Protective Clothing

Sulfuric acid (18%) 7664-93-9 Liquid
Sulfuric acid (30%) 7664-93-9 Liquid >480
Sulfuric acid (>95%) 7664-93-9 Liquid >480 >480 >480 >480 >480 50 >480 >480 >480 >480
(DuPont, 2018)
First Aid
Caution: Sulfuric acid is extremely corrosive. Caution is advised.
Signs and Symptoms of Acute Sulfuric Acid Exposure: Signs and symptoms of acute ingestion of sulfuric acid may be
severe and include salivation, intense thirst, difficulty in swallowing, pain, and shock. Oral, esophageal, and stomach
burns are common. Vomitus generally has a coffee-ground appearance. The potential for circulatory collapse is high
following ingestion of sulfuric acid. Acute inhalation exposure may result in sneezing, hoarseness, choking, laryngitis,
dyspnea (shortness of breath), respiratory tract irritation, and chest pain. Bleeding of nose and gums, ulceration of the
nasal and oral mucosa, pulmonary edema, chronic bronchitis, and pneumonia may also occur. If the eyes have come in
contact with sulfuric acid, irritation, pain, swelling, corneal erosion, and blindness may result. Dermal exposure may
result in severe burns, pain, and dermatitis (red, inflamed skin).
Emergency Life-Support Procedures: Acute exposure to sulfuric acid may require decontamination and life support for
the victims. Emergency personnel should wear protective clothing appropriate to the type and degree of contamination.
1. Move victims to fresh air. Emergency personnel should avoid self-exposure to sulfuric acid.
1. Remove victims from exposure. Emergency personnel should avoid self- exposure to sulfuric acid.
5. Wash exposed skin areas THOROUGHLY with soap and water.
Ingestion Exposure:
2. Rinse mouth with large amounts of water. Instruct victims not to swallow the water.
3. DO NOT induce vomiting or attempt to neutralize!
5. Activated charcoal is of no value.
6. Give the victims water or milk: children up to 1 year old, 125 mL (4 oz or 1/2 cup); children 1 to 12 years old, 200
mL (6 oz or 3/4 cup); adults, 250 mL (8 oz or 1 cup). Water or milk should be given only if victims are conscious and
alert.
7. RUSH to a health care facility. (EPA, 1998)
Physical Properties
Chemical Formula: H2SO4

Melting Point: 50.65 ° F (EPA, 1998)
Vapor Pressure: 1 mm Hg at 294.8 ° F (EPA, 1998)
Specific Gravity: 1.841 (EPA, 1998)
Boiling Point: 554 ° F at 760 mm Hg (EPA, 1998)
Interim AEGLs for Sulfuric acid (7664-93-9)

4 hours 0.2 mg/m3 8.7 mg/m3 110 mg/m3
8 hours 0.2 mg/m3 8.7 mg/m3 93 mg/m3
(NAC/NRC, 2017)

Sulfuric Acid (Oleum [8014-95-7], Sulfur
Trioxide [7446-11-9], and Sulfuric Acid [7664-
93-9]) 2 mg/m3 10 mg/m3 120 mg/m3
(AIHA, 2016)
Sulfuric acid (7664-93-9) 0.2 mg/m3 8.7 mg/m3 160 mg/m3
(DOE, 2016)
EPCRA CAA
EPCRA CAA
1000 1000 1000
Sulfuric acid 7664-93-9 pounds pounds pounds
Sulfuric acid (aerosol forms 1000 1000 1000
only) 7664-93-9 pounds pounds pounds 313

Chemical Datasheet
PICRIC ACID, [DRY]
88-89-1 0154 Explosive 1.1D none

Picric acid PICRIC ACID
NFPA 704

3 4
Burns readily. Rapidly or completely vaporizes at atmospheric pressure and
Flammability 4 normal ambient temperature.
Readily capable of detonation or explosive decomposition or explosive reaction

Instability 4 at normal temperatures and pressures.
Special
(NFPA, 2010)
General Description
Yellow crystals. An explosive. Specific gravity 1.767. Melting point 251.2°F (121.8°C). Explodes at 572°F. Toxic by
ingestion.
Hazards
Reactivity Alerts
Explosive

Flammable. Water soluble.
Fire Hazard
Excerpt from ERG Guide 112 [Explosives* - Division 1.1, 1.2, 1.3 or 1.5]:
MAY EXPLODE AND THROW FRAGMENTS 1600 METERS (1 MILE) OR MORE IF FIRE REACHES CARGO.
For information on "Compatibility Group" letters, refer to Glossary section. (ERG, 2016)
Health Hazard
Exposure Routes: inhalation, skin absorption, ingestion, skin and/or eye contact
Symptoms: Irritation eyes, skin; sensitization dermatitis; yellow-stained hair, skin; lassitude (weakness, exhaustion),
myalgia, anuria, polyuria; bitter taste, gastrointestinal disturbance; hepatitis, hematuria (blood in the urine),
albuminuria, nephritis
Target Organs: Eyes, skin, kidneys, liver, blood (NIOSH, 2016)
Reactivity Profile
PICRIC ACID, [DRY] undergoes vigorous reactions with both oxidizing or reducing agents. Apt to explode when
shocked or exposed to heat. Very unstable. Readily forms salts on contact with many metals (including copper, lead,
mercury, zinc, nickel, iron) that are more sensitive explosives than picric acid itself when subjected to heat, friction, or
impact. Contact with concrete floors may form the friction-sensitive calcium picrate [Urbanski, 1964, vol. 1, p. 518].
Contact with metallic zinc or lead can cause detonation. Salts with ammonia, amines and complexes with
hydrocarbons are less sensitive [Kirk-Othmer, 1965, vol. 8, p. 617]. Sufficiently pure samples of picric acid have the
same order of stability as TNT [Chem. Eng. News, 1979, 57(41), p. 51]. Impure samples are less stable. Mixtures with
aluminum and water will ignite after a delay period [Hajek, V. et al., Research, 1951, 4, p. 186].
Nitro, Nitroso, Nitrate, and Nitrite Compounds, Organic

Phenols and Cresols


Isolate spill or leak area immediately for at least 500 meters (1/3 mile) in all directions.
LARGE SPILL: Consider initial evacuation for 800 meters (1/2 mile) in all directions.
FIRE: If rail car or trailer is involved in a fire, ISOLATE for 1600 meters (1 mile) in all directions; also, initiate
evacuation including emergency responders for 1600 meters (1 mile) in all directions. (ERG, 2016)
Firefighting
CARGO FIRE: DO NOT fight fire when fire reaches cargo! Cargo may EXPLODE! Stop all traffic and clear the area
for at least 1600 meters (1 mile) in all directions and let burn. Do not move cargo or vehicle if cargo has been exposed
to heat.
TIRE OR VEHICLE FIRE: Use plenty of water - FLOOD it! If water is not available, use CO2, dry chemical or dirt. If
possible, and WITHOUT RISK, use unmanned hose holders or monitor nozzles from maximum distance to prevent
fire from spreading to cargo area. Pay special attention to tire fires as re-ignition may occur. Stand by, at a safe
distance, with extinguisher ready for possible re-ignition. (ERG, 2016)
Non-Fire Response
handling the product must be grounded. Do not touch or walk through spilled material. DO NOT OPERATE RADIO
TRANSMITTERS WITHIN 100 METERS (330 FEET) OF ELECTRIC DETONATORS. DO NOT CLEAN-UP OR
DISPOSE OF, EXCEPT UNDER SUPERVISION OF A SPECIALIST. (ERG, 2016)
Protective Clothing
Wash skin: The worker should immediately wash the skin when it becomes contaminated. The worker should wash
daily at the end of each work shift.
leaving the work premise. (NIOSH, 2016)

First Aid
chemical.
Skin: If this chemical contacts the skin, promptly wash the contaminated skin with soap and water. If this chemical
penetrates the clothing, promptly remove the clothing and wash the skin with soap and water. Get medical attention
promptly.
Physical Properties
Chemical Formula: C6H3N3O7

Flash Point: 302 ° F (NIOSH, 2016)
Melting Point: 252 ° F (NIOSH, 2016)
Vapor Pressure: 1 mm Hg at 383 ° F (NIOSH, 2016)
Specific Gravity: 1.76 (NIOSH, 2016)
Boiling Point: Explodes above 572° F (NIOSH, 2016)
Molecular Weight: 229.1 (NIOSH, 2016)
Water Solubility: 1 % (NIOSH, 2016)

Picric acid (88-89-1) 0.3 mg/m3 17 mg/m3 100 mg/m3
(DOE, 2016)

Picric acid 88-89-1 313

5000 400
Trinitrophenol 88-89-1 ACG pounds explosive ACG pounds EXP/IEDP
(DHS, 2007)

Chemical Datasheet
HYDROCHLORIC ACID, SOLUTION
7647-01-0 1789 Corrosive HCL

Hydrogen chloride HYDROGEN CHLORIDE
NFPA 704

3 1
Special
(NFPA, 2010)
General Description
Colorless watery liquid with a sharp, irritating odor. Consists of hydrogen chloride, a gas, dissolved in water. Sinks and
mixes with water. Produces irritating vapor. (USCG, 1999)
Hazards
Reactivity Alerts

An aqueous solution. Dilution may generate heat. Fumes in air.
Fire Hazard
Special Hazards of Combustion Products: Toxic and irritating vapors are generated when heated. (USCG, 1999)
Health Hazard
Inhalation of fumes results in coughing and choking sensation, and irritation of nose and lungs. Liquid causes burns.
(USCG, 1999)
Reactivity Profile
HYDROCHLORIC ACID is an aqueous solution of hydrogen chloride, an acidic gas. Reacts exothermically with
organic bases (amines, amides) and inorganic bases (oxides and hydroxides of metals). Reacts exothermically with
carbonates (including limestone and building materials containing limestone) and hydrogen carbonates to generate
carbon dioxide. Reacts with sulfides, carbides, borides, and phosphides to generate toxic or flammable gases. Reacts
with many metals (including aluminum, zinc, calcium, magnesium, iron, tin and all of the alkali metals) to generate
flammable hydrogen gas. Reacts violently with acetic anhydride, 2-aminoethanol, ammonium hydroxide, calcium
phosphide, chlorosulfonic acid, 1,1-difluoroethylene, ethylenediamine, ethyleneimine, oleum, perchloric acid, b-
propiolactone, propylene oxide, silver perchlorate/carbon tetrachloride mixture, sodium hydroxide, uranium(IV)
phosphide, vinyl acetate, calcium carbide, rubidium carbide, cesium acetylide, rubidium acetylide, magnesium boride,
mercury(II) sulfate [Lewis]. Mixtures with concentrated sulfuric acid can evolve toxic hydrogen chloride gas at a
dangerous rate. Undergoes a very energetic reaction with calcium phosphide [Mellor 8:841(1946-1947)].
Acids, Strong Non-oxidizing



Firefighting
Note: Some foams will react with the material and release corrosive/toxic gases.
SMALL FIRE: CO2 (except for Cyanides), dry chemical, dry sand, alcohol-resistant foam.
Use water spray or fog; do not use straight streams. Dike fire-control water for later disposal; do not scatter the
material.
Non-Fire Response
handling the product must be grounded. Do not touch damaged containers or spilled material unless wearing
appropriate protective clothing. Stop leak if you can do it without risk. A vapor-suppressing foam may be used to
reduce vapors. DO NOT GET WATER INSIDE CONTAINERS. Use water spray to reduce vapors or divert vapor
cloud drift. Avoid allowing water runoff to contact spilled material. Prevent entry into waterways, sewers, basements
or confined areas.
covered plastic containers for later disposal. (ERG, 2016)
Protective Clothing
Skin: If chemical is in solution, wear appropriate personal protective clothing to prevent skin contact and to prevent
skin from becoming frozen from contact with the liquid or from contact with vessels containing the liquid.
Eyes: Wear appropriate eye protection to prevent eye contact with the liquid that could result in burns or tissue damage
from frostbite.
Wash skin: If the chemical is in solution, the worker should immediately wash the skin when it becomes contaminated.
Remove: If chemical is in solution, work clothing that becomes wet or significantly contaminated should be removed
and replaced.
Provide: Eyewash fountains should be provided (when chemical is in solution) in areas where there is any possibility
eye protection. Facilities for quickly drenching the body should be provided (when chemical is in solution) within the
water from a sink or hose could be considered adequate.] Quick drench facilities and/or eyewash fountains should be
provided within the immediate work area for emergency use where there is any possibility of exposure to liquids that
are extremely cold or rapidly evaporating. (NIOSH, 2016)

CAS
Hydrochloric acid (16%) 7647-01-0 Liquid
Hydrochloric acid (32%) 7647-01-0 Liquid
Hydrochloric acid (37%) 7647-01-0 Liquid 140 >480 >480 >480 >480 >480 >480 >480 >480
Hydrogen chloride (>95%,
gas) 7647-01-0 Vapor imm. >480 >480 >480 >480 >480 >480 >480 >480
Hydrogen chloride (>95%,
liquid, -90° C) 7647-01-0 Liquid >180
Muriatic acid (16%) 7647-01-0 Liquid
Muriatic acid (32%) 7647-01-0 Liquid
Muriatic acid (37%) 7647-01-0 Liquid 140 >480 >480 >480 >480 >480 >480 >480 >480
(DuPont, 2018)
First Aid
INHALATION: remove person to fresh air; keep him warm and quiet and get medical attention immediately; start
artificial respiration if breathing stops.
INGESTION: have person drink water or milk; do NOT induce vomiting.
EYES: immediately flush with plenty of water for at least 15 min. and get medical attention; continue flushing for
another 15 min. if physician does not arrive promptly.
SKIN: immediately flush skin while removing contaminated clothing; get medical attention promptly; use soap and
wash area for at least 15 min. (USCG, 1999)
Physical Properties
Chemical Formula: HCl (aqueous)

Vapor Pressure: 413.6 mm Hg (USCG, 1999)
Boiling Point: 123 ° F at 760 mm Hg (USCG, 1999)
Final AEGLs for Hydrogen chloride (7647-01-0)

(NAC/NRC, 2017)

Hydrogen Chloride (7647-01-0) 3 ppm 20 ppm 150 ppm
(AIHA, 2016)

Hydrogen chloride; (Hydrochloric acid) (7647-
01-0) 1.8 ppm 22 ppm 100 ppm
(DOE, 2016)

EPCRA CAA
5000
Hydrochloric acid 7647-01-0 pounds
Hydrochloric acid (aerosol 5000
forms only) 7647-01-0 pounds 313
Hydrochloric acid (conc 37% 5000 15000
or greater) 7647-01-0 pounds pounds
500 5000 5000 5000
Hydrogen chloride (anhydrous) 7647-01-0 pounds pounds pounds X pounds
500 5000 5000 5000
Hydrogen chloride (gas only) 7647-01-0 pounds pounds pounds X pounds
name.

Hydrochloric acid 7647-01- 37.00 15000
(conc. 37% or greater) 0 % pounds toxic
Hydrogen chloride 7647-01- 1.00 5000 500
(anhydrous) 0 % pounds toxic ACG pounds WME
WME = weapons of mass effect.
(DHS, 2007)

Hydrochloric Acid, Anhydrous 7647-01-0 5000 pounds
Hydrogen Chloride 7647-01-0 5000 pounds
(OSHA, 2011)

Chemical Datasheet
LITHIUM ALUMINUM HYDRIDE
16853-85-3 1410 Dangerous When Wet LAH

none none
NFPA 704

3 2
W Flammability 2 before ignition can occur.

Special W Reacts violently or explosively with water.

Note: NFPA ratings shown are for lithium aluminum hydride, CAS number 1302-30-3.
(NFPA, 2010)
General Description
A white powder that turns gray on standing. If spread out over a large flat combustible surface, friction can cause
ignition. Used to make other chemicals, as a polymerization catalyst, as a hydrogen source, and as a propellant.
Hazards
Reactivity Alerts
Strong Reducing Agent

Water-Reactive
Air-Reactive

Reacts with water vigorously attaining incandescence and ignition of evolved hydrogen [Kelen, Cahiers, 1977, (86),
100]. Reactions with water or moist air (or heated air) are violent and may be explosive [Schmidt, D.L., et al. Inorg.
Synth. 1973. p. 14, 51].
Fire Hazard
Behavior in Fire: Decomposes at 257°F to form hydrogen gas. The heat generated may cause ignition and/or
explosion. (USCG, 1999)
Health Hazard
Contact of solid with eyes and skin causes severe burns similar to those caused by caustic soda. (USCG, 1999)
Reactivity Profile
LITHIUM ALUMINUM HYDRIDE is a powerful reducing agent. React violently on contact with many oxidizing
agents. Ignites by friction, especially if powdered. Reacts vigorously with hydroxy compounds such as water, alcohols,
carboxylic acids [Mellor 2 Supp. 2:142. 1961]. Caused a violent explosion when used to dry diethylene glycol
dimethyl ether: Ignition may have been caused by heat from reaction with impurity water or perhaps decomposition of
peroxides in the ether. About 75% of the ether had been removed when the explosion occurred [MCA Case History
1494. 1968]. Reduces carbon dioxide or sodium hydrogen carbonate to methane and ethane at elevated temperatures.
These flammable or explosive gases can form when CO2 extinguishers are used to fight hydride fires. Forms explosive
complexes with ether, dimethylamine and various tetrazoles. Tetrazoles include, 2-methyl, 2-ethyl, 5-ethyl, 2-methyl-
5-vinyl, 5-amino-2-ethyl [US Pat. 3 396 170, 1968].
Metal Hydrides, Metal Alkyls, Metal Aryls, and Silanes


Excerpt from ERG Guide 138 [Substances - Water-Reactive (Emitting Flammable Gases)]:
Firefighting
DO NOT USE WATER OR FOAM.
SMALL FIRE: Dry chemical, soda ash, lime or sand.
LARGE FIRE: DRY sand, dry chemical, soda ash or lime or withdraw from area and let fire burn. Move containers
from fire area if you can do it without risk.
FIRE INVOLVING METALS OR POWDERS (ALUMINUM, LITHIUM, MAGNESIUM, ETC.): Use dry chemical,
DRY sand, sodium chloride powder, graphite powder or Met-L-X® powder; in addition, for Lithium you may use
Lith-X® powder or copper powder. Also, see ERG Guide 170.
Non-Fire Response
ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Do not touch or walk
through spilled material. Stop leak if you can do it without risk. Use water spray to reduce vapors or divert vapor cloud
drift. Avoid allowing water runoff to contact spilled material. DO NOT GET WATER on spilled substance or inside
containers.
minimize spreading or contact with rain. Dike for later disposal; do not apply water unless directed to do so.
POWDER SPILL: Cover powder spill with plastic sheet or tarp to minimize spreading and keep powder dry. DO NOT
CLEAN-UP OR DISPOSE OF, EXCEPT UNDER SUPERVISION OF A SPECIALIST. (ERG, 2016)
Protective Clothing
Rubberized gloves; full face shield. (USCG, 1999)

First Aid
In case of accidental contact with the skin, wipe off excess with a dry paper towel. Wash the affected area with a large
volume of water to prevent localized heating of the skin. (USCG, 1999)
Physical Properties
Chemical Formula: LiAlH4


Lithium tetrahydroaluminate(1-); (Lithium
aluminum hydride) (16853-85-3) 8.4 mg/m3 92 mg/m3 550 mg/m3
(DOE, 2016)


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18/06/2020 Report | CAMEO Chemicals | NOAA

Substâncias contidas neste relatório

20. ÁCIDO ACÉTICO, GLACIAL

22. ACETATO DE ETILO

23. ANIDRIDE ACÉTICO

25. MATERIAL RADIOATIVO, HEXAFLUORETO DE URÂNIO FÍSICO

26. CIANETO DE POTÁSSIO

27. ÁCIDO FOSFÓRICO

28. ÁCIDO LÁTICO

32. Fósforo, branco, seco ou debaixo de água ou em solução

33. NITRATO DE POTÁSSIO

35. TETRACLORETO DE CARBONO

37. ÁCIDO FÓRMICO

39. CLORETO DE POTÁSSIO

40. ÁCIDO SULFÚRICO

41. ÁCIDO PÍCRICO, [SECO]

42. ÁCIDO HIDROCLÓRICO, SOLUÇÃO

43. HIDRATO DE ALUMÍNIO E LÍTIO

Este relatório contém:

Previsões de risco de reação associadas à mistura dessas substâncias.

Informações detalhadas da folha de dados de cada substância.

Resumo das previsões de perigo (para todos os pares de substâncias)

Corrosivo: Os produtos da reação podem ser corrosivos

Resumo das previsões de gases (para todos os pares de substâncias)

Pode produzir os seguintes gases:

Agente Oxidante Forte

Fósforo, branco, seco ou debaixo de água ou em solução

Agente Oxidante Forte

Agente Oxidante Forte

ÁCIDO PÍCRICO, [SECO]

ÁCIDO HIDROCLÓRICO, SOLUÇÃO

Atividade catalítica conhecida

HIDRATO DE ALUMÍNIO E LÍTIO

Agente de redução forte

Previsões de perigo (para cada par de substâncias)

BENZENO misturado com

Nenhuma reação perigosa conhecida

Explosivo: Os produtos da reação podem ser explosivos ou sensíveis a choques ou fricção

GLICERINA misturada com

Nenhuma reação perigosa conhecida

GLICERINA misturada com

Nenhuma reação perigosa conhecida

GLICERINA misturada com

Explosivo: Os produtos da reação podem ser explosivos ou sensíveis a choques ou fricção

ANILINA misturada com

Nenhuma reação perigosa conhecida

ANILINA misturada com

Nenhuma reação perigosa conhecida

ANILINA misturada com

ANILINA misturada com

Nenhuma reação perigosa conhecida

BENZALDEÍDO misturado com

Gera calor: reação exotérmica à temperatura ambiente (libera calor)

BENZALDEÍDO misturado com

Nenhuma reação perigosa conhecida

BENZALDEÍDO misturado com

Inﬂamável: Os produtos da reação podem ser inﬂamáveis

BENZALDEÍDO misturado com

Gera calor: reação exotérmica à temperatura ambiente (libera calor)

BENZALDEÍDO misturado com

Nenhuma reação perigosa conhecida

TOLUENO misturado com

Nenhuma reação perigosa conhecida