Pregunta 2

1 atm * L = 101.325 J
Oxígeno = 160 gramos
# moles = masa/masa molar
# moles = 160/32
# moles = 5 moles
T1 = 30 °C + 273 = 303 K
q = ¿? J
T2 = 220 °C + 273 = 493 K
Presión constante
101.325 J
W = - 30 atm * L * 1 atm∗L = - 3039.75 J
∆U = ¿?
qp = ∆ H = n Cp. ∆ T
qp = n Cp. ∆ T
 7∗8.314 J
qp = 5 mol * mol∗K * (493 – 303) K
2

qp = 27644.05 J
∆U =q+W
∆U = 27644.05 J – 3039.75
∆U = 24604.3 J

Pregunta 3
P1 = 15 atm
P2 = 0.7 atm
T = 0°C (constante)
qt = -W = n R T ln (P2/P1)
a) ∆ U = 0
b) qt = n R T ln (P2/P1)
qt = 1 * 8.314 * 273 * ln(0.7/15)
qt = - 6956.07 J
c) W = 6956.07 J
2C(s) + H2(g) = C2H2(g) ∆ Hf0 = ¿?
2C2H2(g) + 5O2(g) = 4CO2(g) + 2H2O(l) ∆ H combustión = - 2598.8 KJ
H2(g) + 1/2O2(g) = H2O(l) ∆ Hf0 = - 285.80 KJ
C(s) + O2(g) = CO2(g) ∆ Hf0 = - 393.5 KJ
4C(s) + 4O2(g) = 4CO2(g) ∆ Hf0 = - 1574 KJ
2H2(g) + 1O2(g) = 2H2O(l) ∆ Hf0 = - 571.6 KJ
4CO2(g) + 2H2O(l) = 2C2H2(g) + 5O2(g) ∆ H combustión = 2598.8 KJ
4C(s) + 2H2(g) = 2C2H2(g) ∆ Hf0 = 453.2 KJ
2C(s) + 1H2(g) = 1C2H2(g) ∆ Hf0 = 226.6 KJ
C(s) + O2(g) = CO2(g) ∆ Hf0 = - 393.5 KJ/mol
H2(g) + 1/2O2(g) = H2O(l) ∆ Hf0 = - 285.80 KJ/mol
C2H4O(l) + 5/2O2(g) = 2CO2(g) + 2H2O(l) ∆ H combustión = - 1164 KJ/mol

4CO2(g) + 4H2O(l) = 2C2H4O(l) + 5O2(g) ∆ H combustión = 2328 KJ/mol

4C(s) + 4O2(g) = 4CO2(g) ∆ Hf0 = - 1574 KJ/mol

4H2(g) + 2O2(g) = 4H2O(l) ∆ Hf0 = - 1143.2 KJ/mol
4C(s) + 4H2(g) + O2(g) = 2C2H4O(l) ∆ Hf0 = - 389.2 KJ/mol
b) Masa = 22 gramos
# moles = 22/44
# moles = 0.5
C2H4O(l) + 5/2O2(g) = 2CO2(g) + 2H2O(l) ∆ H combustión = - 1164 KJ/mol
1 mol <> 1164 KJ
0.5 mol <> X
X = 582 KJ (calor liberado al quemar 22 gramos de C2H4O)
c) C2H4O(l) + 5/2O2(g) = 2CO2(g) + 2H2O(l) ∆ H combustión = - 1164 KJ/mol

1 mol <> 1164 KJ

X mol <> 1746 KJ
X = 1.5 moles

C2H4O(l) + 5/2O2(g) = 2CO2(g) + 2H2O(l)

 1 2
1.5 moles X moles
X * 1 = 1.5 * 2
X = 3 moles
PV = RTn
1 * V = 0.082 * 298 * 3
V = 73.308 L

V1 = V1
V2 = 10V1
W = - 5000 cal
P1 = 50 atm
a) W = - P∆ V
-5000 = - 50(9V1)
V1 = 5000/450
V1 = 11.11 L
b) -W = n R T ln (V2/V1)
5000 = 2 * 2 * T * ln(10V1/V1)
T = 542.87 K
4NH3(g) + 5O2(g) = 6H2O(g) + 4NO(g)
∆H = ∆ H productos - ∆ H reactantes
∆H = 6(-241.8) + 4(90.4) – (4(-46.2))
∆H = - 1450.8 + 361.6 + 184.8
∆H = - 904.4 KJ/mol
4 moles <> - 904.4 KJ
3.8 moles <> X
X * 4 = 3.8 * - 904.4
X = - 859.18 KJ
CH4(g) + 2O2(g) = CO2(g) + 2H2O(l) ∆ H combustión = ¿?
C(s) + O2(g) = CO2(g) ∆ Hf0 = - 393.5 KJ/mol
H2(g) + 1/2O2(g) = H2O(l) ∆ Hf0 = - 285.80 KJ/mol
C(s) + 2H2(g) = CH4(g) ∆ Hf0 = - 748 KJ/mol
CH4(g) = C(s) + 2H2(g) ∆ Hf0 = 748 KJ/mol
C(s) + O2(g) = CO2(g) ∆ Hf0 = - 393.5 KJ/mol
2H2(g) + 1O2(g) = 2H2O(l) ∆ Hf0 = - 571.6 KJ/mol
CH4(g) + 2O2(g) = CO2(g) + 2H2O(l) ∆ H combustión = - 217.1 KJ/mol
P = 8 atm
T = 345 °C + 273 = (constante)
V1 = V1
V2 = 5V1
W = ¿? J
a) -W = n R T ln (V2/V1)
-W = 5 * 8.314 * 618 * ln(5V1/V1)
-W = 41346.88
W = - 41346.88 J
b) W = - P∆ V
-41346.88 = - 8(4V1)
V1 = 1292.09 L