Questão 7

T (°F) T (K) Psat isopentanoPsat pentano alfa teórico

125 324.8166667 1613.401769 1258.987952 1.281506916
150 338.7055556 2367.659015 1886.133046 1.255297987
175 352.5944444 3358.080311 2726.002634 1.231869797
200 366.4833333 4623.256615 3818.330837 1.210805667
225 380.3722222 6201.134377 5203.30809 1.191767673
250 394.2611111 8128.187721 6920.675351 1.174478979

isopentano pentano
A 15.6338 15.8333
1.3
B 2348.67 2477.07
C -40.05 -39.94 f(x) = − 0.0213369930544097 x + 1.298967312289
R² = 0.994232957832133
Dados de Antoine retirados da referência http://paginapessoal.utfpr.edu.br/lisandra/fisico-quimica-alimentos/anexos/
1.25 f(x) = − 0.024 x + 1.28066666666667
R² = 0.994736842105263

1.2

1.15

1.1

1.05
67 56 44 33 22 11
666 555 444 333 222 111
6 5 4 3 2 1
666 555 444 333 222 111
16 05 94 83 72 61
4.8 8 .7 2 .5 6 .4 0 .3 4 .2
32 33 35 36 38 39
 alfa experimental diferença
1.26 1.71%
1.23 2.06%
1.21 1.81%
1.18 2.61%
1.16 2.74%
1.14 3.02%
média 2.33%

0544097 x + 1.29896731228935
133
quimica-alimentos/anexos/C8-6_-_Pv_Antoine.pdf/view
8066666666667
263

alfa teórico
Linear (alfa teórico)
alfa experimental
Linear (alfa experimental)

33 22 11
333 222 111
33 22
2
11
1
33 2 1
72 61
0 .3 4 .2
38 39
 Questão 1a
T ebulicao n-heptano
T ebulicao tolueno
°C 98.42 110.6 intervalo
K 371.57 383.75 1.218

Lei de Raoult + Dalton 1

0.9
yi = Pvap,i * xi / P
0.8
0.7
Pt de bolha
0.6
P = (Pvap,NH - Pvap,T) * xNH + Pvap,T
0.5
0.4
Pt de orvalho

yNH
0.3
P = 1 / (yNH / Pvap,NH + yT / Pvap,T)
0.2
0.1
A 760 torr: Pt de bolha Raoult + Dalton
0
T Pvap,NH Pvap,T xNH yNH 2
31 5
371.57 759.890531823 530.1461154 1.00 1.00
80 7
337
372.788 787.418632943 550.2265413 0.88 0.92 47 58
76 0 32 4
374.006 815.721229526 570.9061292 0.77 0.83 004
4 4 2 39
0 88 77
1. 0. 0. 0
375.224 844.813073498 592.1973895 0.66 0.74
376.442 874.709027146 614.1129548 0.56 0.64
377.66 905.42406098 636.6655784 0.46 0.55
378.878 936.973251583 659.8681328 0.36 0.45
380.096 969.371779425 683.7336086 0.27 0.34
381.314 1002.63492666 708.2751125 0.18 0.23
382.532 1036.77807492 733.505866 0.09 0.12
383.75 1071.81670303 759.439204 0.00 0.00
Dados de Antoine retirados da referência http://paginapessoal.utfpr.edu.br/lisandra/fisico-quimica-alimentos/an

1b
Questão 1a

1
0.9
0.8
0.7
0.6
0.5
0.4
yNH

0.3
0.2 yNH
x=y
0.1
0
2 4 4 6 4 3 7 3 9 7 6
731 756 811 924 693 200 245 858 241 030 446
0 3 1 1 6 0 6 1 2 5 2
4 78 5 83 3 80 6 01 8 31 9 37 5 65 0 03 3 54 2 81 0 90
76 32 46 04 05 42 97 35 99 90 25
004 4 40 2 39 4 26 9 82 8 90 1 34 7 00 5 71 3 60 7 95
0 88 77 66 55 45 36 26 17 7 1
1. 0. 0. 0. 0. 0. 0. 0. 0. 08 00
0. 0.
xNH

fisico-quimica-alimentos/anexos/C8-6_-_Pv_Antoine.pdf/view

1b