eetel No solution will be given. Problem P11-2, Part (a) No solution will be given. Part (b) No difference. Part (c) No difference except on physical property data. Part (d) ‘The growing core model would have the same molar flux as the shrinking core W=- De. Cao but R(t) , the radius of the carbon a 1 iV interface will increase with time rather (o-s fe than decrease. The rate of appearance of carbon is equal to the flux of oxygen to the gas-carbon interface De.Cao wid aR: _ vet ro? Wala =~ a. dt dupe as for the shrinking model but without the minus sign, because R increases with time. sl- ¢ 4Pll-2cont’d Boundary conditions t=0 R=Ro Tp \yp — DesCaa t Ile-3 arene R-Ro® _ DeCio 3K hope f Part (e) Liquid phase ze.g. water Re = BMA _ 1000 0.1 x 0.05 _ be s4- A 10e—3 5000PLl-2cont’d sept. aes eg “'p.Das 1000 10e-9 single spheres Sh=2 +0.6Re'? Sc' =2 + 0.6(5000)'* (1000) be = Sh-Daa _ 400% 100-9 a 0,0002m? / s ip , st 3 .0: Gas phase : e.g. air iene B ae B We-S _ “p.De 1x10e-9 Sh =2+0.6Re' Sc! = 2 + 0.6(500)'" (1)'> ~ 15 _ShDss _ 15x10e~5 ke = 0.07Sm* / dp CuT wade aera ‘ 4 Problem P11-3y Mol balance on oxygen : Fo, - 0 + ro: =0 constant liquid composition. Fo:=Coz, Vo and ro: =~-k.Co2" where n is the reaction order, ‘Assuming ideal gas law applies : For = oe where vs = oxygen uptake rate mL/tt a : 4 Pp | z Assuming that Rr =constant,C by correction of v» to some reference, then Fo; =C. Ve Assuming Henry's law applies (low pressures) Co; = H.Poz where H is Henry's constant and Pop is the oxygen partial pressure I[-F