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“Contaminação de Solos e
Águas Subterrâneas em Ambientes Urbanos"
1
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“A água é o elixir da
vida.
Sem ela,
a vida não é possível”
(Fetter, 1973)
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10
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O Ciclo Hidrológico
13
Oceanos 97.2%
Calotas Polares e Glaciers 2.14%
Águas Subterrâneas 0.65%
Rios e Lagos 0.009%
Água no Solo (umidade) 0.005%
Água na Atmosfera 0.001%
(Fetter, 1973)
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19
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Área de Exclusão
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14
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Fantástico, 10/Fev/2008
https://www.youtube.com/watch?v=V7w3POam35o&t=22s
44
Benzeno:
5 µg/l = 5 ppb
49
20
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Hexaclorobenzeno:
1 µg/l = 1 ppb
50
Tricloroetileno:
20 µg/l = 20 ppb
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21
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1µg/l equivale
a
3 segundos
em 1 século
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22
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23
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https://www.youtube.com/watch?v=HQv9Lv_GoOQ
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65
7000
6285
6110
5942
5662
5250 5376
5200
4771
4572
4131
3675
3500
2904
2514
2272
1750 1822
1596
1336
727
255
0
2002 2003 2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018 2019
Cadastro Áreas Contaminadas CETESB Fonte: CETESB, 2020
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Comercial
Postos
5%
Combustíveis
71%
68
(CETESB, 2019)
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71
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75
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• Etc
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Substâncias Orgânicas
Hidrocarbonetos Aromáticos
Voláteis, Etanos e Etenos
Mais comuns:
Clorados, Pesticidas Clorados,
Metanos Clorados, etc
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LNAPL
Light Non-Aqueous Phase Liquid (Fase Líquida Leve Não-Aquosa)
Exemplos de LNAPL:
Gasolina
Diesel
Benzeno
Óleos lubrificantes
80
EPA/540/S-95/500
81
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Fase Retida
no Solo
Fase
Vapor Text
Fase Livre
Fase
Dissolvida
84
DNAPL
Dense Non-Aqueous Phase Liquid (Fase Líquida Densa Não-Aquosa)
• Solventes clorados
• Creosoto
• Oléos PCB
• Alguns pesticidas em estado não diluído
85
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• Baixa solubilidade
• Baixa viscosidade
• Baixa tensão superficial
• Extremamente voláteis
• Baixa afinidade a sorção
• Extremamente persistentes em água subterrânea
• Normalmente, passam por biotransformações
complexas
86
"Astronautas"Ambientais
87
37
04/11/2020
Liberação de
DNAPL
Zona
Não-
Saturada
Camadas de
Baixa Condutividade
Hidráulica
ZonaSaturada
Camada Impermeável
Cortesia: Dr. John Cherry
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90
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Lixões
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100
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103
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EXTRAÇÃO DE METANO
EXTRAÇÃO DE CHORUME
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Aprox
10m!!!
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https://www.youtube.com
/watch?v=NJFbsWX4MJ
M&list=PLuCLmOWZYh9
wY5YOKnTEmc2BtVrEee
Wpi
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04/11/2020
heet –
al Fact S
Technic nate (PFOS)
octane S
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and Perf L FACT
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tograph ectrometry. docume on and he is alth- se Un ited Sta
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and microt technologies.
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dioxane 2012).an Us 4-godioriz xaed neint
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to four rchloric acid tassium
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and filtra carbon filters. increas an Em4- ergxa ency previou umer us Enes ginwe ap shee using the d from no
the m s (NPs arely pa an 10 geestna iontuof ral or ae ac
Manuf ammonium RRO 2005; propel signal flares
d teLa on ofd1,P)
ctind and co
ns riety ofthis fac t tal t can be obtaine urce ofnoparticle imat y 1inclsudtheatinar king rocket d
activate Officde e of
nt (51 06atment advanced wide va paenredvironmormati
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logies inc d mer: Th oniation,en d to bel on, to create names or co
refers
to . ntam lume ra is com for vehi so used ).
tech1no processes an Disclai scientific inform reeemted is not aic int s,de medica relied y. of trade co
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s (UFP water.ce area to vo term rfeinerins orate ag initiators 2005). It is al ITRC 2005
oltnor ca n it bedeliv erntion for use. particle d by t de inte Perchls are airb 08;
n rcent is stries,
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States on Agen oxidatio iation. availab is fact sh otovd, States. omme
Me surfa oidngglem anen
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United Protecti nts. Th ph
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drug nd onon
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mental biorem
ed docume on and is not imwit aging the an depend istry NMs ha oms an Af d ct thseirthar upta d .others tsercont indu
Environ ax im um s orm ati ati on h do rse
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pr ng od Wucat (E PA g op er pe rchlorat aerospace 2005; ITRC
ral m ) ha inf
party in
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No fede nt level (MCL by any does not consThe
titutemob surface surfa5-F e ith
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terim electro produc defense an orate (GAO
such as on EPA 50 erties20of17 issu 1,ed ). tically e hl
ina
contam blished for 1, r.
4- products factors cle size, and ocesses in prop vember , morEP e thAan ry.rs 2015
he e domes for use in th onium perc ch as
ta rti pr No 14 lth anAd dvi so
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en th
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d tured amm ons su
been es in drinking wa
te and pa l anerg d ab cy ic
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ob anufac form of id regi
-003
5-F-17
EPA 50 mber 2017
Nove
er gency
and Em
of Land (5106P)
Office
ement
Manag
1
Agency
States ection
United mental Prot
Environ
119
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120
É possível
remediar?
121
47
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CETESB, 2018
123
48
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125
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Extração de Vapores
126
Extração Multifásica
127
50
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129
51
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131
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133
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135
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139
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142
Temos o
dever ético, moral e
profissional de
gerenciar nossas áreas
contaminadas.
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Muito obrigado!
Paulo Negrão, Ph.D.
p.negrao@clean.com.br
Tel +55 19 3794-2911
Cel +55 19 98944-2626
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