Correlaes:

Capacidade Calorifica a presso constante: (J/mol*K)

Clculo da Entalpia a presso constante para gases ideais e lquidos: (J/mol)

Etilbenzeno:

TEB= 409,34 K

TFS= 178,26 K

Entalpia de vaporizao:

vapH =41,0 4,0 kJ/mol . Media de 7 valores [NIST]

Entalpia de formao padro:

fHGs= 29,8 0,84 .Media de 5 valores [NIST]

fHLquido =-12,3 kJ/mol [Prosen, Gilmont, et al., 1945]

Coeficientes de regresso de Cp a presso constante do lquido:

Range [Tmin=179,00 K; Tmx=555,00 K] [Carl L. Yaws, 1999]

A=102,111; B=5,5959e-1; C=-1,5609e-3; D=2,0149e-6

Coeficientes de regresso de Cp a presso constante do gs ideal:

Range [Tmin= 298,00 K; Tmx= 1500,00 K] [Carl L. Yaws, 1999]

A=-20,527; B=5,9578e-1; C=-3,0849e-4; D=3,5621e-8; E=1,2409e-11

Estireno:

TEB= 418,32 K

TFS= 242,51 K
Entalpia de vaporizao:

vapH =43,4 kJ/mol. Mdia de 3 valores [NIST]

Entalpia de formao padro:

fHGs = 147,36 kJ/mol [J.M. Smith, H. Van Ness, M. M. Abbott]

fHLquido = 103.4 0.92 kJ/mol [Prosen and Rossini, 1945]

Coeficientes de regresso de Cp a presso constante do liquido:

Range [Tmin=242,54 K; Tmx=518,31 K] [Carl L. Yaws, 1999]

A=66,737; B=8,4051e-1; C=-2,1615e-3; D=2,3324e-6

Coeficientes de regresso de Cp a presso constante do gs ideal:

Range [Tmin= 100,00 K; Tmx= 1500,00 K][Carl L. Yaws, 1999]

A=71,201; B=5,4767e-2; C=6,4793e-4; D=-6,9875e-7; E=2,1232e-10;

GUA:

TEB=373.13 K

TFS=273.15 k

Entalpia de vaporizao:

vapH = 39,50 kJ/mol [Carl L. Yaws, 1999]

Entalpia de formao padro:

fHGs=-241,83 kJ/mol [Chase, 1998 ]

fHLquido =-285,830 kJ/mol [Review Cox, Wagman, et al., 1984]

Coeficientes de regresso de Cp a presso constante do liquido:

Range [Tmin=273,00 K; Tmx=615,00 K] [Carl L. Yaws, 1999]

A=92,053; B=-3,9953e-2; C=-2,1103e-4; D=5,3469e-7

Coeficientes de regresso de Cp a presso constante do gas ideal:

Range [Tmin= 200,00 K; Tmx= 1500,00 K][Carl L. Yaws, 1999]

A=33,933; B=-8,4186e-3; C=2,9906e-5; D=-1,7825e-8; E=3,6934e-12;

Hidrognio

TEB=20,27 K

TFS=14,03 K

Entalpia de vaporizao:

vapH = 0,46 kJ/mol

Entalpia de formao padro:

fHGs= 0 kJ/mol

Coeficientes de regresso de Cp a presso constante do liquido:

Range [Tmin=14,00 K; Tmx=32K ] [Carl L. Yaws, 1999]

A=50,607; B=-6,1136; C=3,0930e-1; D=-4,1418e-3

Coeficientes de regresso de Cp a presso constante do gas ideal:

Range [Tmin= 250,00 K; Tmx= 1500,00 K][Carl L. Yaws, 1999]

A=25,399; B=2,017e-2; C=-3,8549e-5; D=3,1880e-8; E=-8,7585e-12;

Monxido de Carbono

TEB=81,63 K

TFS=68,60 K

Entalpia de vaporizao:

vapH = 6,0 kJ/mol Range(68. - 108. K)[A Stephenson and Malanowski, 1987]

Entalpia de formao padro:

fHGs= -110,53 0,17 kJ/mol [Review Cox, Wagman, et al., 1984 CODATA Review value]

Coeficientes de regresso de Cp a presso constante do liquido:

Range [Tmin=68,00 K; Tmx=126,00K ] [Carl L. Yaws, 1999]

A= 125,595; B -1,7022; C= 1,0707E-2; D= 4,1854E-6

Coeficientes de regresso de Cp a presso constante do gas ideal:

Range [Tmin= 60,00 K; Tmx= 1500,00 K][Carl L. Yaws, 1999]

A=29,556; B=-6,5807e-3; C=2,0130e-5; D=-1,2227e-8; E=2,2617e-12;

Dixido de Carbono

TEB= 216,6 K

TFS= 194,7 K

Entalpia de vaporizao:

vapH = 16,4 kJ/mol Range(216. - 273.K)[A Stephenson and Malanowski, 1987]

Entalpia de formao padro:

fHGs= -393.52 kJ/mol [Review Chase, 1998 Data last reviewed in September, 1965]

Coeficientes de regresso de Cp a presso constante do liquido:

Range [Tmin=220,00 K; Tmx=290,00K ] [Carl L. Yaws, 1999]

A= -3981,020; B= 5,2511E+1; C= -2,2708E-1; D 3,2866E-4

Coeficientes de regresso de Cp a presso constante do gas ideal:

Range [Tmin= 50,00 K; Tmx= 5000,00 K][Carl L. Yaws, 1999]

A=27,437; B=4,2315e-2; C=1,9555e-5; D=3,9968e-9; E=-2,9872e-13;

Nitrognio

TEB=77,34 K

TFS=63,32 K

Entalpia de vaporizao:

vapH = 6,1 kJ/mol Range(63. 126K). [Edejer and Thodos, 1967]

Entalpia de formao padro:

fHGs= 0 kJ/mol

Coeficientes de regresso de Cp a presso constante do liquido:

Range [Tmin=64,00 K; Tmx=120,00 K ] [Carl L. Yaws, 1999]

A=76,452; B= -3,5226E-1; C= -2,6690E-3; D= 5,0057E-5

Coeficientes de regresso de Cp a presso constante do gas ideal:

Range [Tmin= 50,00 K; Tmx= 1500,00 K][Carl L. Yaws, 1999]

A=29,342; B=-3,53951e-3; C=-1,0076e-5; D=-4,3116e-9; E=2,5935e-13;

Metano

TEB=111,23 K

TFS=87,70 K

Entalpia de vaporizao:

vapH = 8.6,kJ/mol- Range(92. - 110.K) [Stock, Henning, et al., 2006][ Boublik, Fried, et al.,
1984.]

Entalpia de formao padro:

fHGs= -74,6 0,3 kJ/mol [Manion, 2002]

Coeficientes de regresso de Cp a presso constante do liquido:

Range [Tmin=90,00 K; Tmx=172,00K ] [Carl L. Yaws, 1999]

A=-0,018; B=-1,1982; C=-9,8722e-3; D=3,1670e-5

Coeficientes de regresso de Cp a presso constante do gas ideal:

Range [Tmin= 250,00 K; Tmx= 1500,00 K][Carl L. Yaws, 1999]

A=34,942; B=-3,9957e-2; C=1,9184e-4; D=-1,5303e-7; E=3,9321e-11;

Oxignio
TEB=90,17 K

TFS=54,36 K

Entalpia de vaporizao:

vapH = 6,82 kJ/mol

Entalpia de formao padro:

fHGs= 0 kJ/mol

Coeficientes de regresso de Cp a presso constante do liquido:

Range [Tmin=54,00 K; Tmx=147,00K ] [Carl L. Yaws, 1999]

A=46,432; B=3,9506e-1; C=-7,0522e-3; D=3,9897e-5

Coeficientes de regresso de Cp a presso constante do gas ideal:

Range [Tmin= 250,00 K; Tmx= 1500,00 K][Carl L. Yaws, 1999]

A=29,526; B=-8,8999e-3; C=3,8083e-5; D=-3,2629e-8; E=8,8607e-12;

REFERNCIAS

YAWS, Carl L. Chemical Properties Handbook: Physical, Thermodynamic, Environmental,

Transport,Safety end Health Related Properties of Organic and Inorganic Chemical. New
York: McGraw-Hill, 1999. 770 p.

GREEN, Don W.; PERRY, Robert H. Perry's Chemical Engineer's Handbook. 8th. ed. New
York: McGraw-Hill, 2008. 2735 p.

REFERNCIAS WEBBOOK NATIONAL INSTITUTE OF STANDARS AND TECHNOLOGY:

NIST Livro de Qumica na Web, SRD 69. Disponvel em:<http://webbook.nist.gov/>

acessado em 05/08/2017.

Etilbenzeno:
Disponvelem:<http://webbook.nist.gov/cgi/cbook.cgi?ID=C100414&Units=SI&Mask=4#Th
ermo-Phase> acessado em 05/08/2017.

Majer, V.; Svoboda, V., Enthalpies of Vaporization of Organic Compounds: A Critical

Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300.
Prosen, E.J.; Gilmont, R.; Rossini, F.D., Heats of combustion of benzene, toluene, ethyl-
benzene, o-xylene, m-xylene, p-xylene, n-propylbenzene, and styrene, J. Res. NBS, 1945,
34, 65-70.

Estireno: Disponvel em:

<http://webbook.nist.gov/cgi/cbook.cgi?ID=C100425&Units=SI&Mask=4#Thermo-Phase>
acessado em 05/08/2017.

Thermodynamics Research Center, Selected Values of Properties of Chemical

Compounds., Thermodynamics Research Center, Texas A&M University, College Station,
Texas, 1997.

Prosen, E.J.; Rossini, F.D., Heats of formation and combustion of 1,3-butadiene and
styrene, J. Res. NBS, 1945, 34, 59-63.

Pitzer, K.S.; Guttman, L.; Westrum, E.F., The Heat Capacity, Heats of Fusion and
Vaporization, Vapor Pressure Entropy, Vib. Frequencies, and Barrier to Internal Rotation
of Styrene, J. Am. Chem. Soc., 1946, 68, 2209.

gua: Disponvel em:

<http://webbook.nist.gov/cgi/cbook.cgi?ID=C7732185&Units=SI&Mask=4#Thermo-
Phase>05/08/2017.

Cox, J.D.; Wagman, D.D.; Medvedev, V.A., CODATA Key Values for Thermodynamics,
Hemisphere Publishing Corp., New York, 1984, 1.

Chase, M.W., Jr., NIST-JANAF Themochemical Tables, 4th Edition, J. Phys. Chem. Ref. Data,
Monograph 9, 1998, 1951.