RESPOSTA DAS QUESTÕES DE CÁLCULO DA 4ª LISTA DE EXERCÍCIOS FQ I – A 2ª Lei

da Termodinâmica: Conceitos

1) (a) 92 J/K, (b) 67 J/K

2) 152,67 J K–1 mol–1

3) – 22,1 J/K

4) q = 0, S = 0, U = w = + 4,1 kJ, H = + 5,4 kJ

5) H = 0, Htot = 0, Stot = + 93,4 J/K

6) (a) 0, (b) – 20 J, (c) – 20 J, (d) – 0,347 K, (e) + 0,60 J/K

7) (a) + 87,8 J K–1 mol–1, (b) − 87,8 J K–1 mol–1

8) (a) − 386,1 J K–1 mol–1, (b) + 92,6 J K–1 mol–1, (c) – 153,1 J K–1 mol–1

9) (a) S = + 2,9 J/K, Sviz = − 2,9 J/K, Stot = 0

(b) S = + 2,9 J/K, Sviz = 0, Stot = + 2,9 J/K

(c) S = 0, Sviz = 0, Stot = 0

10) (a) 0,500, (b) 0,50 kJ, (c) 0,50 kJ

11) 10,7 J K–1 mol–1

12) (a) q = 2,74 kJ, w = – 2,74 kJ, U = 0, H = 0, S = 9,13 J/K, Sviz = − 9,13
J/K, Stot = 0

(b) q = 1,66 kJ, w = – 1,66 kJ, U = 0, H = 0, S = 9,13 J/K, Sviz = − 5,53

J/K, Stot = 3,60 J/K

13) 232,0 J K–1 mol–1

𝑇 𝑇
14) ∆𝑆 = 𝑛𝐶𝑝,𝑚 ln 𝑇𝑓 + 𝑛𝐶𝑝,𝑚 ln 𝑇𝑓 , S = + 22,6 J/K
ℎ 𝑐