Cálculo da Fugacidade da água na fase vapor, na condição de vapor saturado, usando Peng-Robinson

R 83.14 bar.cm3/mol.k
H2O
Tc (K) 647.3 50
45
Pc (bar) 220.48
40
omega 0.344 35

PRESSÃO (bar)
kij 0 30
25
SOLVER 20
15
T(K) P(bar) y Lnphil Lnphiv delta_lnphi phi f (bar)
10
283.1883 0.01 1 -0.000175 -0.000173839 2.0953E-12 0.999826 0.009998 5
308.6946 0.05 1 -0.0007 -0.0006988214 2.62155E-12 0.999301 0.049965 0
250
321.4114 0.1 1 -0.001263 -0.0012605739 4.01913E-12 0.99874 0.099874
344.2957 0.3 1 -0.003167 -0.0031668951 1.30043E-14 0.996838 0.299051
356.3007 0.5 1 -0.004833 -0.0048281641 1.95067E-11 0.995183 0.497592
374.2661 1 1 -0.008491 -0.0084909111 5.38692E-14 0.991545 0.991545
453.2691 10 1 -0.051196 -0.0511974736 1.07102E-12 0.950091 9.50091
471.4425 15 1 -0.069207 -0.0691995913 5.33442E-11 0.93314 13.99711
485.3681 20 1 -0.085423 -0.0854225444 4.72632E-13 0.918124 18.36249 45
496.8154 25 1 -0.1004 -0.1003940905 3.23596E-11 0.904481 22.61202 40
506.6183 30 1 -0.114418 -0.114411686 4.45827E-11 0.891891 26.75672 35

FUGACIDADE (bar)
515.24 35 1 -0.127673 -0.127665725 5.9471E-11 0.880148 30.80516 30
522.9679 40 1 -0.140286 -0.1402869937 3.22986E-13 0.869109 34.76435 25
529.9914 45 1 -0.152373 -0.1523723093 1.06309E-12 0.858669 38.64008 20
soma = 2.20997E-10 15
10
5
0
0
o Peng-Robinson

PRESSÃO DE VAPOR
50
45
40
35
PRESSÃO (bar)

30
25
20
15
10
5
0
250 300 350 400 450 500 550 VARIAÇÃO DO COEFICIE
TEMPERATURA (K) FUGACIDADE
1.05

COEFICIENTE DE FUGACIDADE
1
VARIAÇÃO DA FUGACIDADE 0.95
45
0.9
40
35 0.85
FUGACIDADE (bar)

30
0.8
25 0 5 10 15 20 25 30
20 PRESSÃO (bar)
15
10
5
0
0 5 10 15 20 25 30 35 40 45
PRESSÃO (bar)
ÃO DO COEFICIENTE DE
FUGACIDADE

15 20 25 30 35 40 45 50
PRESSÃO (bar)
 Cálculo da Fugacidade da 1,4-dioxano na fase vapor, na condição de vapor saturado, usando Peng-Rob
Para baixar o XSEOS: https://www.youtube.com/redirect?event=video_description&redir_token=QUFFLUhqblV3dk8xSzBZRH

R 83.14 bar.cm3/mol.k
1,4-Dioxano
Tc (K) 523.2
Pc (bar) 38.3
omega 0.363
kij 0

SOLVER
T(K) P(bar) y Lnphil Lnphiv delta_lnphi phi f (bar)
253.5037 0.01 1 -0.000799 -0.0007826837 2.68423E-10 0.999218 0.009992
279.4514 0.05 1 -0.003056 -0.0030412247 2.11396E-10 0.996963 0.049848
292.682 0.1 1 -0.005403 -0.0053888877 1.9969E-10 0.994626 0.099463
317.0094 0.3 1 -0.01311 -0.0130950358 2.21974E-10 0.98699 0.296097
330.0435 0.5 1 -0.019622 -0.0196104805 1.24131E-10 0.980581 0.49029
349.8975 1 1 -0.033583 -0.0335686308 1.98781E-10 0.966989 0.966989
441.6511 10 1 -0.180551 -0.1805441214 4.97737E-11 0.834816 8.348158
463.5467 15 1 -0.238284 -0.2382790653 2.73728E-11 0.787983 11.81974
480.4421 20 1 -0.289067 -0.2890619303 2.24287E-11 0.748966 14.97932
494.383 25 1 -0.335091 -0.3350873632 1.47916E-11 0.715276 17.88189
506.3427 30 1 -0.377563 -0.3775653512 5.94736E-12 0.685528 20.56585
515.24 35 1 -0.429973 -0.4299733901 0 0.650526 22.76842
522.9679 40 1 -0.476469 -0.4764685161 0 0.620972 24.8389
529.9914 45 1 -0.515424 -0.515424116 0 0.597247 26.87613
soma = 1.34471E-09
turado, usando Peng-Robinson
UFFLUhqblV3dk8xSzBZRHpNRWppM0dMRmtiQjFIdlZCZ3xBQ3Jtc0ttUENZeWprSVJfczVJZUJ2aTQxWnAwREJxYkpndDk3VEtVMTJ1TXhiQ

PRESSÃO DE VAPOR
50
45 VARIAÇÃO
40 FU
35
PRESSÃO (bar)

30 1.05

COEFICIENTE DE FUGACIDADE
25
1
20
15 0.95
10
5 0.9
0
250 300 350 400 450 500 550 0.85
TEMPERATURA (K)
0.8
0 5 10 1

VARIAÇÃO DA FUGACIDADE
45
40
35
FUGACIDADE (bar)

30
25
20
15
10
5
0
0 5 10 15 20 25 30 35 40 45
PRESSÃO (bar)
YkpndDk3VEtVMTJ1TXhiQVhfdnFiQ29zcElfdThIbW43NjRVbm9NUVA3NjdKeDhadjhyZ21JU3pLUHV6ZWt0MWptcXdqRzRkS2hQczJFb09

VARIAÇÃO DO COEFICIENTE DE
FUGACIDADE
1.05

0.95

0.9

0.85

0.8
0 5 10 15 20 25 30 35 40 45 50
PRESSÃO (bar)
WptcXdqRzRkS2hQczJFb092Q1FfeWNtOA&q=https%3A%2F%2Fpeople.qatar.tamu.edu%2Fmarcelo.castier%2Findex.htm&v=y_EdOVSI
2Findex.htm&v=y_EdOVSI2hs
Para baixar o XSEOS: https://www.youtube.com/redirect?event=video_description&redir_token=QUFFLUhqblV3dk8xSzBZRH

Iniciamos o desenvolvimento da questão coletando os parâmetros

1- Temperatura Crítica
2- Pressão Crítica
3- Ômega (fator acêntrico)
4- kij (parâmetro de interação entre distintos)
Estas propriedades são fundamentais pois fazem parte da equação Peng-Robinson

No enunciado, temos que a variação da pressão será de 0.01 bar até 700 bar. Para a coluna "lnphi_(1)", obtemos os valores c
na fase liquida, com a função "prlnphil"; na coluna seguinte "lnphi_(2)" calculamos o valor de ln de phi para o vapor, com a fu
coluna phi_(1) utilizamos a função exponencial dos valores obtidos em lnphi_(1). Para a coluna f_(1) utilizamos a função phi_(
vapor (y_1) x Pressão em bar, em seguida obtivemos a coluna p_(1) através da função composição y_(1) x Pressão em bar (co

R 83.14 bar.cm3/mol.k

1,4-Dioxano Água
Tc (K) 523.2 647.3
Pc (bar) 38.3 220.48
omega 0.363 0.344
kij 0 0

T(K) P(bar) y_(1) y_(2) v (cm3/mol) Lnphi_(1)

573.15 0.001 0.001 0.999 47651570.47298 -5.560215E-06
573.15 0.01 0.001 0.999 4765048.571314 -5.560241E-05
573.15 0.1 0.001 0.999 476396.3646056 -0.0005560509
573.15 10 0.001 0.999 4642.708109158 -0.0559097585
573.15 30 0.001 0.999 1461.504298795 -0.1697801335
573.15 50 0.001 0.999 820.7159743656 -0.28697458
573.15 70 0.001 0.999 541.4273848465 -0.408566001
573.15 90 0.001 0.999 32.65698967756 2.618989295
573.15 110 0.001 0.999 32.40477957234 2.5179884864
573.15 130 0.001 0.999 32.16976782139 2.4477599671
573.15 150 0.001 0.999 31.949771566 2.3989520444
573.15 170 0.001 0.999 31.74300592889 2.3658078648
573.15 190 0.001 0.999 31.54799154058 2.3445447581
573.15 200 0.001 0.999 31.45449546487 2.3375204577
573.15 300 0.001 0.999 30.63835495631 2.3529327775
573.15 400 0.001 0.999 29.98193182515 2.4553307154
573.15 500 0.001 0.999 29.43449693632 2.5997917151
573.15 600 0.001 0.999 28.96626846495 2.7677543605
573.15 700 0.001 0.999 28.5582177302 2.9500232315
 T(K) P(bar) y_(1) y_(2) v (cm3/mol) Lnphi_(1)
573.15 0.001 0.2 0.8 47651538.45694 -6.176093E-06
573.15 0.01 0.2 0.8 4765016.555052 -6.176125E-05
573.15 0.1 0.2 0.8 476364.3461512 -0.0006176443
573.15 10 0.2 0.8 4610.434587715 -0.0621253594
573.15 30 0.2 0.8 1428.614293274 -0.1887824374
573.15 50 0.2 0.8 787.0189979149 -0.3192488788
573.15 70 0.2 0.8 506.6163353362 -0.4545048247
573.15 90 0.2 0.8 343.9137017795 -0.5959207016
573.15 110 0.2 0.8 228.5855404022 -0.7443905894
573.15 130 0.2 0.8 121.0092821203 -0.8425951739
573.15 150 0.2 0.8 90.63508154603 -0.8094720833
573.15 170 0.2 0.8 81.69966273287 -0.8019121625
573.15 190 0.2 0.8 76.61113681057 -0.7995645541
573.15 200 0.2 0.8 74.72081426161 -0.7984656511
573.15 300 0.2 0.8 64.45116351047 -0.7607386236
573.15 400 0.2 0.8 59.58452177096 -0.6768265645
573.15 500 0.2 0.8 56.48883594434 -0.5632862231
573.15 600 0.2 0.8 54.26456087693 -0.430811205
573.15 700 0.2 0.8 52.55347009944 -0.2855701284

T(K) P(bar) y_(1) y_(2) v (cm3/mol) Lnphi_(1)

573.15 0.001 0.3 0.7 47651519.91738 -6.434142E-06
573.15 0.01 0.3 0.7 4764998.01532 -6.434178E-05
573.15 0.1 0.3 0.7 476345.8047272 -0.000643454
573.15 10 0.3 0.7 4591.697987532 -0.0647557601
573.15 30 0.3 0.7 1409.422182627 -0.1969947476
573.15 50 0.3 0.7 767.2786050862 -0.3334960059
573.15 70 0.3 0.7 486.2616797084 -0.4751115265
573.15 90 0.3 0.7 323.2220334991 -0.6221574508
573.15 110 0.3 0.7 211.5162445825 -0.7679521566
573.15 130 0.3 0.7 141.9840242192 -0.8657556031
573.15 150 0.3 0.7 115.3603054566 -0.9073314841
573.15 170 0.3 0.7 103.2526599417 -0.9338953262
573.15 190 0.3 0.7 95.99621363408 -0.9531574084
573.15 200 0.3 0.7 93.28618953071 -0.9605840698
573.15 300 0.3 0.7 78.78063347601 -0.9763535636
573.15 400 0.3 0.7 72.15014356351 -0.924470091
573.15 500 0.3 0.7 68.03453167391 -0.8349136592
573.15 600 0.3 0.7 65.12858834362 -0.7219953658
573.15 700 0.3 0.7 62.92276007271 -0.5934400773

T(K) P(bar) y_(1) y_(2) v (cm3/mol) Lnphi_(1)

573.15 0.001 0.4 0.6 47651499.73828 -6.657784E-06
573.15 0.01 0.4 0.6 4764977.835987 -6.657826E-05
573.15 0.1 0.4 0.6 476325.6230302 -0.0006658242
573.15 10 0.4 0.6 4571.243767965 -0.0670538705
573.15 30 0.4 0.6 1388.33710146 -0.2042966568
573.15 50 0.4 0.6 745.4696267331 -0.3463967264
573.15 70 0.4 0.6 463.8313622442 -0.493979131
573.15 90 0.4 0.6 301.6897595641 -0.6451594511
573.15 110 0.4 0.6 200.8304514004 -0.7821425835
573.15 130 0.4 0.6 151.7636387684 -0.8721685732
573.15 150 0.4 0.6 130.1518513685 -0.9293086564
573.15 170 0.4 0.6 118.2815095017 -0.9703981249
573.15 190 0.4 0.6 110.5558093477 -1.0010538474
573.15 200 0.4 0.6 107.5727451526 -1.0133110885
573.15 300 0.4 0.6 90.99545372696 -1.0615645251
573.15 400 0.4 0.6 83.24103956852 -1.0296794284
573.15 500 0.4 0.6 78.42208358078 -0.9550323404
573.15 600 0.4 0.6 75.02753782488 -0.8541835024
573.15 700 0.4 0.6 72.45891403702 -0.7358540373

T(K) P(bar) y_(1) y_(2) v (cm3/mol) Lnphi_(1)

573.15 0.001 0.5 0.5 47651477.91965 -6.847021E-06
573.15 0.01 0.5 0.5 4764956.017025 -6.847068E-05
573.15 0.1 0.5 0.5 476303.8007865 -0.0006847545
573.15 10 0.5 0.5 4549.041788488 -0.0690164053
573.15 30 0.5 0.5 1365.250578443 -0.2106628098
573.15 50 0.5 0.5 721.3989199674 -0.3578947817
573.15 70 0.5 0.5 439.2500931717 -0.5109419781
573.15 90 0.5 0.5 280.8708742121 -0.6638217113
573.15 110 0.5 0.5 196.3561047725 -0.7898673651
573.15 130 0.5 0.5 159.4457112276 -0.8760460659
573.15 150 0.5 0.5 141.0966604862 -0.9379435495
573.15 170 0.5 0.5 129.9724377963 -0.9846770851
573.15 190 0.5 0.5 122.3219429113 -1.0204468843
573.15 200 0.5 0.5 119.2879383908 -1.0350243453
573.15 300 0.5 0.5 101.7698875041 -1.1005118488
573.15 400 0.5 0.5 93.30485391942 -1.0800771589
573.15 500 0.5 0.5 87.99858091344 -1.0141593887
573.15 600 0.5 0.5 84.25018844746 -0.9204415222
573.15 700 0.5 0.5 81.41189186514 -0.8081782555

T(K) P(bar) y_(1) y_(2) v (cm3/mol) Lnphi_(1)

573.15 0.001 0.6 0.4 47651454.46147 -7.001851E-06
573.15 0.01 0.6 0.4 4764932.558404 -7.001905E-05
573.15 0.1 0.6 0.4 476280.3376885 -0.0007002444
573.15 10 0.6 0.4 4525.057121274 -0.0706388815
573.15 30 0.6 0.4 1340.028345687 -0.2160551255
573.15 50 0.6 0.4 694.8209232064 -0.3678955301
573.15 70 0.6 0.4 412.6082585045 -0.5257008372
573.15 90 0.6 0.4 263.1860992719 -0.6771292422
573.15 110 0.6 0.4 195.8476767389 -0.7941917722
573.15 130 0.6 0.4 166.3957737729 -0.878627774
573.15 150 0.6 0.4 150.3104559722 -0.9423187761
573.15 170 0.6 0.4 139.9233563148 -0.9914721341
573.15 190 0.6 0.4 132.5001731324 -1.0296258032
573.15 200 0.6 0.4 129.4966439032 -1.0453335118
573.15 300 0.6 0.4 111.5853821106 -1.119884833
573.15 400 0.6 0.4 102.6599884377 -1.1058854567
573.15 500 0.6 0.4 97.00700483265 -1.0449935519
573.15 600 0.6 0.4 92.99563828278 -0.9554291567
573.15 700 0.6 0.4 89.95178246668 -0.8467214465

T(K) P(bar) y_(1) y_(2) v (cm3/mol) Lnphi_(1)

573.15 0.001 0.7 0.3 47651429.36376 -7.122274E-06
573.15 0.01 0.7 0.3 4764907.460089 -7.122334E-05
573.15 0.1 0.7 0.3 476255.2333945 -0.0007122934
573.15 10 0.7 0.3 4499.249618353 -0.0719155325
573.15 30 0.7 0.3 1312.503578355 -0.2204198832
573.15 50 0.7 0.3 665.4245419333 -0.3762514067
573.15 70 0.7 0.3 384.4395899234 -0.5377727978
573.15 90 0.7 0.3 250.5585220717 -0.6852031511
573.15 110 0.7 0.3 197.6122177867 -0.7967048242
573.15 130 0.7 0.3 173.0356737637 -0.8803289202
573.15 150 0.7 0.3 158.6172093374 -0.9447537318
573.15 170 0.7 0.3 148.8782024357 -0.9949987203
573.15 190 0.7 0.3 141.7164538761 -1.0342912312
573.15 200 0.7 0.3 138.7733352797 -1.0505558262
573.15 300 0.7 0.3 120.7454550514 -1.1298408988
573.15 400 0.7 0.3 111.5145566409 -1.119386137
573.15 500 0.7 0.3 105.6080076971 -1.0613224454
573.15 600 0.7 0.3 101.3960075849 -0.9741210717
573.15 700 0.7 0.3 98.19151976915 -0.8674489281

T(K) P(bar) y_(1) y_(2) v (cm3/mol) Lnphi_(1)

573.15 0.001 0.8 0.2 47651402.62649 -7.208291E-06
573.15 0.01 0.8 0.2 4764880.722043 -7.208356E-05
573.15 0.1 0.8 0.2 476228.4875291 -0.0007209009
573.15 10 0.8 0.2 4471.573391474 -0.0728391985
573.15 30 0.8 0.2 1282.467336479 -0.223683453
573.15 50 0.8 0.2 632.821530706 -0.382738538
573.15 70 0.8 0.2 356.2124187254 -0.546517612
573.15 90 0.8 0.2 243.0507836097 -0.6894014414
573.15 110 0.8 0.2 200.7233185461 -0.7981342457
573.15 130 0.8 0.2 179.5361616686 -0.8813777146
573.15 150 0.8 0.2 166.3997541344 -0.9461009904
573.15 170 0.8 0.2 157.218132727 -0.9968320098
573.15 190 0.8 0.2 150.3137371073 -1.036654997
573.15 200 0.8 0.2 147.4408344909 -1.0531852635
573.15 300 0.8 0.2 129.4423041607 -1.1348361503
573.15 400 0.8 0.2 120.005273408 -1.1262312307
573.15 500 0.8 0.2 113.9087793447 -1.0696709366
573.15 600 0.8 0.2 109.5401218191 -0.9837379579
573.15 700 0.8 0.2 106.2073297234 -0.8781646974

T(K) P(bar) y_(1) y_(2) v (cm3/mol) Lnphi_(1)

573.15 0.001 0.9 0.1 47651374.24968 -7.259901E-06
573.15 0.01 0.9 0.1 4764852.344225 -7.25997E-05
573.15 0.1 0.9 0.1 476200.0996823 -0.000726066
573.15 10 0.9 0.1 4441.976187633 -0.0734011934
573.15 30 0.9 0.1 1249.654722463 -0.2257459411
573.15 50 0.9 0.1 596.5519389056 -0.3870198768
573.15 70 0.9 0.1 330.6187930816 -0.5514579377
573.15 90 0.9 0.1 239.5003098962 -0.6912257335
573.15 110 0.9 0.1 204.6859642007 -0.7988461024
573.15 130 0.9 0.1 185.976812217 -0.8819275851
573.15 150 0.9 0.1 173.859031149 -0.9467582943
573.15 170 0.9 0.1 165.1566084594 -0.9976813571
573.15 190 0.9 0.1 158.4930468473 -1.0377222937
573.15 200 0.9 0.1 155.6917577082 -1.0543639049
573.15 300 0.9 0.1 137.8014467294 -1.1370455779
573.15 400 0.9 0.1 128.2242907566 -1.1292762414
573.15 500 0.9 0.1 121.9826445827 -1.0734058631
573.15 600 0.9 0.1 117.4892267651 -0.9880599316
573.15 700 0.9 0.1 114.0520114852 -0.8829978419
QUFFLUhqblV3dk8xSzBZRHpNRWppM0dMRmtiQjFIdlZCZ3xBQ3Jtc0ttUENZeWprSVJfczVJZUJ2aTQxWnAwREJxYkpndDk3VEtVMTJ1TXh

16

Fugacidade do 1,4-Dioxano na mistura

14
12
10
8

(bar)
6
4
_(1)", obtemos os valores calculando o ln de phi
e phi para o vapor, com a função "prlnphiv"; já na 2
1) utilizamos a função phi_(1)x composição do
y_(1) x Pressão em bar (coluna C). 0
0 100 200 300 400 500
Pressão (bar)

Coeficiente de Fugacidade do 1,4-Dioxanona mistura 21

19

17

15

13

11

Lnphi_(2) phi_(1) f_(1) (bar) p_(1) (bar) 9

-5.560215E-06 0.99999444 1E-06 0.000001
7
-5.560241E-05 0.999944399 9.9994E-06 0.00001
-0.0005560509 0.999444104 9.9944E-05 0.0001 5
-0.0559097585 0.945624467 0.0094562 0.01
3
-0.1697801335 0.843850331 0.0253155 0.03
-0.28697458 0.750530807 0.0375265 0.05 1
0 100 200 300 400
-0.408566001 0.664602607 0.0465222 0.07
2.618989295 13.72184783 1.2349663 0.09 Pressão (bar)
2.5179884864 12.4036215 1.3643984 0.11
2.4477599671 11.56241749 1.5031143 0.13
2.3989520444 11.01163063 1.6517446 0.15
2.3658078648 10.65264124 1.810949 0.17
2.3445447581 10.42852415 1.9814196 0.19
2.3375204577 10.35552773 2.0711055 0.2
2.3529327775 10.51636671 3.15491 0.3
2.4553307154 11.65028584 4.6601143 0.4 No gráfico ao lado, na faixa de P
2.5997917151 13.46093403 6.730467 0.5 uma elevação rápida no coefici
2.7677543605 15.92283688 9.5537021 0.6 acontece devido as interações d
forçadas .
2.9500232315 19.10639759 13.374478 0.7
 Lnphi_(2) phi_(1) f_(1) (bar) p_(1) (bar)
-6.176093E-06 0.999993824 0.0002 0.0002
-6.176125E-05 0.999938241 0.0019999 0.002
-0.0006176443 0.999382546 0.0199877 0.02
-0.0621253594 0.939765071 1.8795301 2
-0.1887824374 0.827966622 4.9677997 6
-0.3192488788 0.726694668 7.2669467 10
-0.4545048247 0.634762209 8.8866709 14
-0.5959207016 0.551054975 9.9189896 18
-0.7443905894 0.475023696 10.450521 22
-0.8425951739 0.430591612 11.195382 26
-0.8094720833 0.445092976 13.352789 30
-0.8019121625 0.448470595 15.248 34
-0.7995645541 0.449524665 17.081937 38
-0.7984656511 0.450018921 18.000757 40
-0.7607386236 0.467321125 28.039268 60
-0.6768265645 0.508227262 40.658181 80
-0.5632862231 0.569335024 56.933502 100
-0.430811205 0.649981612 77.997793 120
-0.2855701284 0.751585632 105.22199 140

Lnphi_(2) phi_(1) f_(1) (bar) p_(1) (bar)

-6.434142E-06 0.999993566 0.0003 0.0003
-6.434178E-05 0.99993566 0.0029998 0.003
-0.000643454 0.999356753 0.0299807 0.03
-0.0647557601 0.937296361 2.8118891 3
-0.1969947476 0.821194947 7.3907545 9
-0.3334960059 0.71641476 10.746221 15
-0.4751115265 0.621815704 13.05813 21
-0.6221574508 0.5367851 14.493198 27
-0.7679521566 0.463962218 15.310753 33
-0.8657556031 0.420733525 16.408607 39
-0.9073314841 0.403599801 18.161991 45
-0.9338953262 0.393019784 20.044009 51
-0.9531574084 0.38552185 21.974745 57
-0.9605840698 0.382669315 22.960159 60
-0.9763535636 0.376682145 33.901393 90
-0.924470091 0.3967416 47.608992 120
-0.8349136592 0.433911944 65.086792 150
-0.7219953658 0.485781975 87.440756 180
-0.5934400773 0.552423632 116.00896 210

Lnphi_(2) phi_(1) f_(1) (bar) p_(1) (bar)

 -6.657784E-06 0.999993342 0.0004 0.0004
-6.657826E-05 0.999933424 0.0039997 0.004
-0.0006658242 0.999334397 0.0399734 0.04
-0.0670538705 0.935144823 3.7405793 4
-0.2042966568 0.815220495 9.7826459 12
-0.3463967264 0.707231854 14.144637 20
-0.493979131 0.610193517 17.085418 28
-0.6451594511 0.524578891 18.88484 36
-0.7821425835 0.45742489 20.126695 44
-0.8721685732 0.418044007 21.738288 52
-0.9293086564 0.394826577 23.689595 60
-0.9703981249 0.378932146 25.767386 68
-1.0010538474 0.367491957 27.929389 76
-1.0133110885 0.363015013 29.041201 80
-1.0615645251 0.345914195 41.509703 120
-1.0296794284 0.357121425 57.139428 160
-0.9550323404 0.3847997 76.95994 200
-0.8541835024 0.425630576 102.15134 240
-0.7358540373 0.479096118 134.14691 280

Lnphi_(2) phi_(1) f_(1) (bar) p_(1) (bar)

-6.847021E-06 0.999993153 0.0005 0.0005
-6.847068E-05 0.999931532 0.0049997 0.005
-0.0006847545 0.99931548 0.0499658 0.05
-0.0690164053 0.933311369 4.6665568 5
-0.2106628098 0.810047161 12.150707 15
-0.3578947817 0.699146634 17.478666 25
-0.5109419781 0.599930191 20.997557 35
-0.6638217113 0.514879848 23.169593 45
-0.7898673651 0.453904995 24.964775 55
-0.8760460659 0.416426183 27.067702 65
-0.9379435495 0.391431969 29.357398 75
-0.9846770851 0.373559835 31.752586 85
-1.0204468843 0.360433832 34.241214 95
-1.0350243453 0.355217733 35.521773 100
-1.1005118488 0.332700748 49.905112 150
-1.0800771589 0.339569324 67.913865 200
-1.0141593887 0.362707197 90.676799 250
-0.9204415222 0.398343125 119.50294 300
-0.8081782555 0.445669223 155.98423 350

Lnphi_(2) phi_(1) f_(1) (bar) p_(1) (bar)

-7.001851E-06 0.999992998 0.0006 0.0006
-7.001905E-05 0.999929983 0.0059996 0.006
-0.0007002444 0.999300001 0.059958 0.06
-0.0706388815 0.931798321 5.5907899 6
-0.2160551255 0.805690887 14.502436 18
-0.3678955301 0.692189491 20.765685 30
-0.5257008372 0.591140926 24.827919 42
-0.6771292422 0.508073457 27.435967 54
-0.7941917722 0.451946363 29.82846 66
-0.878627774 0.415352478 32.397493 78
-0.9423187761 0.389723106 35.07508 90
-0.9914721341 0.371030083 37.845068 102
-1.0296258032 0.357140576 40.714026 114
-1.0453335118 0.351574546 42.188945 120
-1.119884833 0.326317373 58.737127 180
-1.1058854567 0.330917739 79.420257 240
-1.0449935519 0.351694087 105.50823 300
-0.9554291567 0.384647035 138.47293 360
-0.8467214465 0.428818534 180.10378 420

Lnphi_(2) phi_(1) f_(1) (bar) p_(1) (bar)

-7.122274E-06 0.999992878 0.0007 0.0007
-7.122334E-05 0.999928779 0.0069995 0.007
-0.0007122934 0.99928796 0.0699502 0.07
-0.0719155325 0.930609499 6.5142665 7
-0.2204198832 0.802181905 16.84582 21
-0.3762514067 0.686429738 24.025041 35
-0.5377727978 0.584047597 28.618332 49
-0.6852031511 0.503987834 31.751234 63
-0.7967048242 0.450812024 34.712526 77
-0.8803289202 0.414646504 37.732832 91
-0.9447537318 0.388775302 40.821407 105
-0.9949987203 0.369723918 43.997146 119
-1.0342912312 0.355478244 47.278606 133
-1.0505558262 0.349743299 48.964062 140
-1.1298408988 0.323084655 67.847778 210
-1.119386137 0.326480147 91.414441 280
-1.0613224454 0.345997944 121.09928 350
-0.9741210717 0.377524024 158.56009 420
-0.8674489281 0.420021689 205.81063 490

Lnphi_(2) phi_(1) f_(1) (bar) p_(1) (bar)

-7.208291E-06 0.999992792 0.0008 0.0008
-7.208356E-05 0.999927919 0.0079994 0.008
-0.0007209009 0.999279359 0.0799423 0.08
-0.0728391985 0.929750323 7.4380026 8
-0.223683453 0.799568195 19.189637 24
-0.382738538 0.681991191 27.279648 40
-0.546517612 0.578962476 32.421899 56
-0.6894014414 0.501876382 36.135099 72
-0.7981342457 0.450168084 39.614791 88
-0.8813777146 0.414211853 43.078033 104
-0.9461009904 0.388251874 46.590225 120
-0.9968320098 0.369046728 50.190355 136
-1.036654997 0.354638969 53.905123 152
-1.0531852635 0.348824879 55.811981 160
-1.1348361503 0.321474791 77.15395 240
-1.1262312307 0.324252991 103.76096 320
-1.0696709366 0.343121408 137.24856 400
-0.9837379579 0.37391082 179.47719 480
-0.8781646974 0.415544863 232.70512 560

Lnphi_(2) phi_(1) f_(1) (bar) p_(1) (bar)

-7.259901E-06 0.99999274 0.0009 0.0009
-7.25997E-05 0.999927403 0.0089993 0.009
-0.000726066 0.999274198 0.0899347 0.09
-0.0734011934 0.929227955 8.3630516 9
-0.2257459411 0.797920795 21.543861 27
-0.3870198768 0.679077597 30.558492 45
-0.5514579377 0.576109266 36.294884 63
-0.6912257335 0.500961647 40.577893 81
-0.7988461024 0.449847743 44.534927 99
-0.8819275851 0.413984152 48.436146 117
-0.9467582943 0.387996758 52.379562 135
-0.9976813571 0.368733412 56.416212 153
-1.0377222937 0.354260665 60.578574 171
-1.0543639049 0.348413981 62.714517 180
-1.1370455779 0.320765299 86.606631 270
-1.1292762414 0.323267139 116.37617 360
-1.0734058631 0.341842265 153.82902 450
-0.9880599316 0.372298275 201.04107 540
-0.8829978419 0.41354132 260.53103 630
EJxYkpndDk3VEtVMTJ1TXhiQVhfdnFiQ29zcElfdThIbW43NjRVbm9NUVA3NjdKeDhadjhyZ21JU3pLUHV6ZWt0MWptcXdqRzRkS2hQczJFb

260

240

Fugacidade do 1,4-Dioxano na mistura (bar)

220

200

180

300 400 500 600 700 160

Pressão (bar)
140

120

100

80

60

40

20

0
0 100 200 300 400

300 400 500 600 700 Pressão (bar)

Pressão (bar)

20

18

gráfico ao lado, na faixa de Pressão entre 70 e 90 bar, ocorre

a elevação rápida no coeficiente de fugacidade; esse aumento 16
do 1,4-Dioxanona mistura

ntece devido as interações de repulsão da mistura que são

adas .
14

12

10
 0
Coeficiente de Fugacidade do 1,4-Dioxanona mist
2
4
6
8
10
12
14

0
100
200
300

Pressão (ba
40
MWptcXdqRzRkS2hQczJFb092Q1FfeWNtOA&q=https%3A%2F%2Fpeople.qatar.tamu.edu%2Fmarcelo.castier%2Findex.htm&v=y_EdO

y1 = 0,001
y1 = 0,2
y1 = 0,3
y1 = 0,4
y1 = 0,5
y1 = 0,6
y1 = 0,7
y1 = 0,8
y1 = 0,9

300 400 500 600 700

Pressão (bar)

y1 = 0,001
y1 = 0,2
y1 = 0,3
 y1 = 0,001
y1 = 0,2
y1 = 0,3
y1 = 0,4
y1 = 0,5
y1 = 0,6
y1 = 0,7
y1 = 0,8
y1 = 0,9

300 400 500 600 700

Pressão (bar)
r%2Findex.htm&v=y_EdOVSI2hs