ACTIVIDAD : NOMENCLATURA

Acido 4-cloro 4-oxobutanoico Acido 4-bromocarbonil ciclohexano carboxílico

Cloruro de 4 hidroxi 3 metil- pentanoilo Bromuro de 2 bromo 5oxo heptanoilo

SINTESIS
 c. d.
b.
a.

f. g. h.
e.

a. Acido 2-cloro 2 butedinoico

b. Acido 4 oxo ciclohexano carboxílico
c. Acido 2 etil 3 hidroxipropanoico
d. Acido 2 ciclopentanoico
e. Acido 4 bromo benzoico
f. Acido 4 cloro 3 etil 2 hidroxi ciclopentano carboxílico
g. Acido 3 hidroxi 4 fenil butanoico
h. Acido 2 oxo propanoico

SINTESIS:
3. propino  acido 2-butinioco O
O
CH3-C≡CH Butil Litio CH3-C≡C:-Li+ CO2
CH3-C≡C-C-O-Li+ + H20 H+ CH3-C≡C-C-OH

4.
a) H2C=CH-CH3 + Br2 luz Br-CH2-CH=CH2 + NaCN Dimetilsulfóxido CN-CH2-CH=CH2 + H2O H2SO4 CH3-CH(OH)-CH2-COOH
∆

O
MgBr C-O-Mg+Br
b) CH3-CH(CH3)-CH3 + Br2 LUZ CH3-CBr(CH3)-CH3 + Mg éter CH3-C(CH3)-CH3 CO2 CH3-C(CH3)-CH3 + H2O
 HCl

CH3-C(CH3)2-COOH

COMPLETAR REAXCIONES:

∆ HCL
2.- CH3CH(CH3)CH2COOH + SOCl 2 + CH3CH(CH3)CH2 COCl + + SO 2+

+ H+

CH3CH(CH3)CH2COOCH(CH3)2

3.- CH3CH2CH=CHCH3 + KMnO4 + H2SO4 CH3CH2COOH + OH-C-CH3

O
 + NH3

+ Δ
CH3-NH-CH2CH3
CH3-N(C2H5)-CO-CH2CH3 +Δ + CH 3-NH-CO-CH2CH3

4.- CH3CH(C2H5)CH2COOH + Ag2O + Br2 +Δ 2 CH3CH(C2H5)CH2-Br + CO 2

+ 2Na
2CH3-CH(C2H5)-CH2-CO-Na-Br

CH3CH2CH(OH)-CH(OH)CH3
 5.-CH3CH2CH= CHCH3 + KMnO4 (FRÍO) + HIO4

CH3CH2-CHO +
CH3 -CHO

LiAlH4
CH3CH2CH2CH2COOH + CH3CH2CH2OH +
+ H+
CH3CH2CH2CH2COOCH2CH2CH3 + H20

CH3CH2CH(C(CH3)3)CH2COO-Na+

OH-CH2CH2C(CH3)2CH3
6.- CH3CH2CH(C(CH3)3)CH2COOCH2CH2C(CH3)2CH3 + NaOH + H2O +
+ LiAlH4 +
CH3CH2CH(C(CH3)3)CH2CH2OH + H2O H2SO4

H 2C=CHC(CH3)2CH3