Solução mãe 0.

14 g/L

Solução padrão F.D Absorvância

P1 40 0.031 0.031 0.032
P2 20 0.745 0.746 0.745
P3 10 1.301 1.300 1.299
P4 5 2.197 2.198 2.196

Chart Title
2.5
f(x) = 82.5374149659864 x
2 R² = 0.991254205129276

1.5

Absorvância 1

0.5

0
0.0000 0.0050 0.0100 0.0150 0.0200
Concentração (ppm)
 Concentração (ppm) Absorvância média
0.0000 0
0.0070 0.745
0.0140 1.300
0.0280 2.197

Chart Title

49659864 x
05129276

0.0100 0.0150 0.0200 0.0250 0.0300

Concentração (ppm)
 Solução F.D Absorvância Absorvância média
1 10 0.761 0.765 0.761 0.761
2 1 1.434 1.434 1.434 1.434
3 1 0.21 0.21 0.21 0.21
4 1 0.079 0.076 0.08 0.079
5 1 0.027 0.027 0.027 0.027

Vusado 0.05 L

Solução F.D Massa carvão (g) Absorvância Absorvância media

1 1 0.040 0.504 0.504 0.741 0.504
2 1 0.071 0.21 0.21 0.21 0.210
3 1 0.090 0.079 0.076 0.080 0.079
4 1 0.12 0.027 0.027 0.027 0.027
5 10 0.0139 0.809 0.81 0.811 0.810
6 10 0.0169 0.623 0.624 0.625 0.624
7 5 0.0229 0.921 0.92 0.922 0.921
8 5 0.0215 1.089 1.087 1.088 1.088
9 2 0.0340 0.9 0.9 0.9 0.900
10 1 0.0349 1.05 1.05 1.049 1.050
11 3.33 0.0251 0.891 0.89 0.891 0.891
12 10 0.0105 0.693 0.693 0.693 0.693
13 5 0.018 0.75 0.751 0.75 0.750
14 1 0.0267 1.554 1.555 1.556 1.555
15 1 0.0304 0.779 0.779 0.779 0.779
16 1 0.0345 0.543 0.543 0.544 0.543

1.80

1.60
Massa adsorvida/ Massa carvão

1.40

1.20

1.00

0.80

0.60

0.40

0.20

0.00
0.0000 0.0200 0.0400 0.0600 0.0800

Concentração (g/L)
0.00
0.0000 0.0200 0.0400 0.0600 0.0800

Concentração (g/L)
 Concentração (g/L)
0.0922
0.0174
0.0025
0.0010
0.0003

q
Concentração (g/L) Massa adsorvida Massa adsorvida/ Massa carvão
0.0061 0.02589 0.65
0.0025 0.02607 0.37
0.0010 0.02615 0.29
0.0003 0.02618 0.22
0.0981 0.02129 1.53
0.0756 0.02242 1.33
0.0558 0.02341 1.02
0.0659 0.02290 1.07
0.0218 0.02511 0.74
0.0127 0.02556 0.73
0.0359 0.02440 0.97
0.0840 0.01495 1.42
0.0454 0.01688 0.94
0.0188 0.01821 0.68
0.0094 0.01868 0.61
0.0066 0.01882 0.55

Modelo de
1.40E+00
1.20E+00
1.00E+00
8.00E-01
qmol

6.00E-01
4.00E-01
2.00E-01
0.00E+00
0.0000 0.0200 0.0400
0400 0.0600 0.0800 0.1000 0.1200 Con

Concentração (g/L)
0400 0.0600 0.0800 0.1000 0.1200

Concentração (g/L)

1.80
1.60
1.40
1.20
1.00
0.80 Experimental

q
0.60 Modelo Lang
0.40 Modelo Freun
0.20
0.00
0.0000 0.0500 0.1000 0.1500
Concentração (g/L)
 Modelo de Langmuir Modelo de Freundlich
qmol qmax C K1 residuos qmol KF C
4.54E-01 0.00611 0.0376 0.512481470397 0.0061
2.31E-01 0.00254 0.0184 0.373874572497 0.0025
9.68E-02 0.00096 0.0376 0.262898223691 0.0010
3.46E-02 0.00033 0.0337 0.178582714061 0.0003
1.27E+00 0.09814 0.0688 1.39347590485 0.0981
1.23E+00 0.07560 0.0101 1.268494547107 0.0756
1.16E+00 0.05579 0.0201 1.136994537539 0.0558
1.20E+00 0.06591 0.0180 1.207329509646 0.0659
0.02 0.1 0.2
8.95E-01 0.02181 0.0246 0.810610193382 0.0218
7.05E-01 0.01272 0.0008 0.667567520121 0.0127
1.05E+00 0.03595 0.0064 0.9704951092 0.0359
1.24E+00 0.08396 0.0322 1.317332008319 0.0840
1.12E+00 0.04543 0.0315 1.055915321509 0.0454
8.45E-01 0.01884 0.0266 0.768996152968 0.0188
5.98E-01 0.00944 0.0003 0.599507408545 0.0094
4.77E-01 0.00658 0.0047 0.526426325633 0.0066
soma 0.3714
qmáx 1.4415637
K1 75.18231
Modelo de F
Modelo de Langmuir 1.6
1.4
1.40E+00
1.2
1.20E+00
1
1.00E+00
0.8
qmol

8.00E-01
0.6
qmol

6.00E-01 0.4
4.00E-01 0.2
2.00E-01 0
0.0000 0.0200 0.0400
0.00E+00
0.0000 0.0200 0.0400 0.0600 0.0800 0.1000 0.1200 Concen
Concentração
 Experimental
Modelo Langmuir
Modelo Freundlich

0.0500 0.1000 0.1500

Concentração (g/L)
de Freundlich
n residuos
0.02
0.00
0.00
0.00
0.02
0.00
0.01
0.02
1
0.01 KF 3.21544
0.00 n 2.776232
0.00
0.01
0.01
0.01
0.00
0.00
soma 0.1194

Modelo de Freundlich

0 0.0200 0.0400 0.0600 0.0800 0.1000 0.1200

Concentração (g/L)
Vusado 0.05 L [ácido] 0.1839 g/L

pH 3.06

Solução F.D m pesada Abs Abs média

1 16.67 0.0064 0.373 0.375 0.373 0.374
2 5 0.0102 0.709 0.709 0.71 0.709
3 5 0.0206 0.254 0.253 0.254 0.254
4 1 0.0411 0.027 0.026 0.026 0.026
5 10 0.0034 0.42 0.421 0.421 0.421
6 10 0.0044 0.41 0.409 0.408 0.409
7 5 0.0056 0.707 0.707 0.706 0.707
8 5 0.0086 0.603 0.605 0.605 0.604
9 5 0.0115 0.44 0.44 0.44 0.440
10 5 0.0176 0.18 0.181 0.181 0.181
11 1 0.0231 0.256 0.256 0.257 0.256
12 1 0.0274 0.159 0.16 0.16 0.160
13 1 0.0333 0.036 0.036 0.036 0.036
14 1 0.0385 0.02 0.02 0.021 0.020

2.5000

Massa adsorvida/massa pesada

2.0000

1.5000

1.0000

0.5000

0.0000
0.0000 0.0100 0.0200 0.0300 0.0400
Concentração (g/L
 q Modelo de Langmuir
Concentração (g/L) Massa adsorvida Massa adsorvida/massa pesada qmol qmax
0.0755 0.0054 0.8471 1.3241982746
0.0430 0.0070 0.6908 1.0994362637
0.0154 0.0084 0.4091 0.6436833475
0.0003 0.0092 0.2233 0.0204764189
0.0510 0.0066 1.9549 1.1719087137
0.0496 0.0067 1.5267 1.1601859394
0.0428 0.0071 1.2597 1.0978033922
0.2
0.0366 0.0074 0.8563 1.0289688546
0.0267 0.0079 0.6837 0.8857320387
0.0109 0.0086 0.4914 0.510560026
0.0031 0.0090 0.3913 0.1814399092
0.0019 0.0091 0.3321 0.1174447172
0.0004 0.0092 0.2755 0.0278776094
0.0002 0.0092 0.2385 0.0158516589

0 Modelo de Langmuir
1.4
0
1.2
1
0
0.8
qmol

0 0.6
0.4
0 0.2
0.0000 0.0100 0.0200 0.0300 0.0400 0.0500 0.0600 0.0700 0.0800
0
Concentração (g/L)
0.0000 0.0100 0.0200 0.0300 0.0400 0.050
Concentração
 Modelo de Langmuir Modelo de Freundlich
C K1 residuos qmol KF C n residuos
0.0755 0.2276 1.3395039411 0.0755 0.2424
0.0430 0.1670 1.0653367625 0.0430 0.1403
0.0154 0.0550 0.7012927919 0.0154 0.0854
0.0003 0.0412 0.1451050268 0.0003 0.0061 QMAX
0.0510 0.6131 1.1418894424 0.0510 0.6610 K1
0.0496 0.1343 1.1289049537 0.0496 0.1582
0.0428 0.0262 1.0637064518 0.0428 0.0384 KF
1 0.1 1
0.0366 0.0298 0.998153598 0.0366 0.0201 n
0.0267 0.0408 0.8773170325 0.0267 0.0375
0.0109 0.0004 0.6109008673 0.0109 0.0143
0.0031 0.0441 0.3660467983 0.0031 0.0006
0.0019 0.0461 0.3019541151 0.0019 0.0009
0.0004 0.0613 0.1647779086 0.0004 0.0123
0.0002 0.0496 0.1306234248 0.0002 0.0116
soma 1.5364 soma 1.4292

Modelo de Langmuir Modelo de Freundlich

1.6
1.4
1.2
1
0.8
qmol

0.6
0.4
0.2
0
0.0200 0.0300 0.0400 0.0500 0.0600 0.0700 0.0800 0.0000 0.0100 0.0200 0.0300 0.0400 0.0500 0.0600 0

Concentração Concentração
 2.5000

2.0000
1.814733
35.76946 1.5000

3.8305 1.0000 Experimental

Modelo langmuir
q

2.459348
0.5000 Modelo Freundlich

0.0000
00 00 00 00 00 00 00 00 00
00 01 02 03 04 05 06 07 08
0. 0. 0. 0. 0. 0. 0. 0. 0.
Concentração (g/L)

de Freundlich

0 0.0400 0.0500 0.0600 0.0700 0.0800

Concentração
Vusado 0.05 L [básico] 0.499

pH(básico) 10

Solução F.D m pesada Abs

1 12.5 0.0038 1.361 1.362 1.362
2 12.5 0.0063 1.314 1.314 1.313
3 12.5 0.0101 1.025 1.022 1.022
4 10 0.0196 0.893 0.89 0.89
5 1 0.04 1.112 1.114 1.111
6 1 0.0712 0.289 0.286 0.289
7 1 0.0902 0.074 0.077 0.076
8 1 0.115 0.033 0.032 0.031
9 1 0.1303 0.02 0.019 0.018
10 12.5 0.1509 1.467 1.468 1.469
11
12
13
14
15
16

4.5000
4.0000
3.5000
mabsorvida/mpesada

3.0000
2.5000
2.0000
1.5000
1.0000
0.5000
0.0000
0.0000 0.0500 0.1000 0.1500 0.2000 0.25
Concentração (g/L)
 g/L

q
Abs média Concentração (g/L) Massa adsorvida Massa adsorvida/massa pesada
1.362 0.2062 0.0146 3.8524
1.314 0.1990 0.0150 2.3813
1.023 0.1549 0.0172 1.7033
0.891 0.1080 0.0196 0.9976
1.112 0.0135 0.0243 0.6069
0.288 0.0035 0.0248 0.3480
0.076 0.0009 0.0249 0.2761
0.032 0.0004 0.0249 0.2168
0.019 0.0002 0.0249 0.1914
1.468 0.2223 0.0138 0.0917

0.1000 0.1500 0.2000 0.2500

Concentração (g/L)
 Modelo de Langmuir Modelo de Freundlich
qmol qmax C K1 residuos qmol KF C n
0.0079220862 0.2062 14.7797 1.390982E-08 0.2062
0.0076535121 0.1990 5.6344 9.7155E-09 0.1990
0.0060109643 0.1549 2.8808 7.968373E-10 0.1549
0.0042268053 0.1080 0.9867 2.149266E-11 0.1080
0.0005376223 0.0135 0.3677 1.976345E-20 0.0135
0.0001394764 0.0035 0.1210 2.675704E-26 0.0035
3.66637E-05 0.2 0.0009 0.0762 4.193332E-32 0.0009
1.550699E-05 0.0004 0.2 0.0470 7.673844E-36 0.1 0.0004
0.1
9.207568E-06 0.0002 0.0366 4.178777E-38 0.0002
0.0085143898 0.2223 0.0069 2.950352E-08 0.2223
dlich
residuos
14.8407
5.6708
2.9013
0.9952
0.3683
0.1211
0.0762
0.0470
0.0366
0.0084
mpesada 3.0008 g

N1 0.1
N2 0.1
A 1269.3 0.925
B 12.693
C 0.0334
D 0.925
X/M 1092.6077
nº iodo 1010.6621
V(gasto) 16.709