X1 Y1 P (t) KPa X2 Y2 85

0 0 55.53 1 1
0.1 0.140875 58.172 0.9 0.859125
0.2 0.26951 60.814 0.8 0.73049 80
0.3 0.387434 63.456 0.7 0.612566
0.4 0.49593 66.098 0.6 0.50407
0.5 0.596087 68.74 0.5 0.403913 75
0.6 0.688829 71.382 0.4 0.311171
0.7 0.774951 74.024 0.3 0.225049
0.8 0.855138 76.666 0.2 0.144862 70

0.9 0.929982 79.308 0.1 0.070018

1 1 81.95 0 0
65

P1(sat) 81.95
P2(sat) 55.53
60

55

50
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.
0.5 0.6 0.7 0.8 0.9 1
 Componente A B C P(sat) "inicial"/Kpa
1 14.39155 2795.817 -49.148 75
2 16.59381 3644.297 -33.385 75

Calcular T(sat) por Antoine Calcular T (chute inicial) Antoine

T1(sat) T2(sat) T 330.240771109939
326.674287957 330.2407711

Calcular P(sat) por Antoine Calcular P1(sat) com eq. Nova

P1(sat)/Kpa P2(sat)/Kpa interação valor da pressão
85.2260403385 75.0000 1 85.2260403384579

Calcular P(sat) por Antoine Calcular P1(sat) com eq. Nova

T1(sat)/K P1(sat)/Kpa P2(sat)/Kpa iteração valor da pressão
Chute inicial 84.1559207194 73.9006 1 84.2388572103742
329.911892923 84.2388572104 73.9857 2 84.2264411080022
329.9077370 84.226441108 73.9730 3 84.2282990524702
329.9083589 84.2282990525 73.9749 4 84.2280210114102

Calcular P(sat) por Antoine Calcular P1(sat) com eq. Nova

T1(sat)/K P1(sat)/Kpa P2(sat)/Kpa iteração valor da pressão
Chute inicial 83.096566539 72.8148 1 83.2395809264472
329.575833978 83.2395809264 72.9612 2 83.2208260491589
329.5694959 83.2208260492 72.9420 3 83.2232836873361
329.5703265 83.2232836873 72.9445 4 83.2229616064028
329.5702177 83.2229616064 72.9442 5 83.2230038155332
329.5702319 83.2230038155 72.9443 6 83.2229982839617
329.5702301 83.222998284 72.9442 7 83.2229990088825

Calcular P(sat) por Antoine Calcular P1(sat) com eq. Nova

T1(sat)/K P1(sat)/Kpa P2(sat)/Kpa iteração valor da pressão
Chute inicial 82.0478998824 71.7423 1 82.2298970865189
329.232983235 82.2298970865 71.9283 2 82.2093243074299
329.2259626 82.2093243074 71.9073 3 82.2116475873779
329.2267555 82.2116475874 71.9096 4 82.2113851911857
329.2266659 82.2113851912 71.9094 5 82.2114148264059

Calcular P(sat) por Antoine Calcular P1(sat) com eq. Nova

T1(sat)/K P1(sat)/Kpa P2(sat)/Kpa iteração valor da pressão
Chute inicial 81.0098431236 70.6831 1 81.2114361784107
328.883724641 81.2114361784 70.8887 2 81.1922015869777
328.8770949 81.192201587 70.8690 3 81.1940348612278
328.8777269 81.1940348612 70.8709 4 81.1938601116874
328.8776666 81.1938601117 70.8707 5 81.1938767688275
 Calcular P(sat) por Antoine Calcular P1(sat) com eq. Nova
T1(sat)/K P1(sat)/Kpa P2(sat)/Kpa iteração valor da pressão
Chute inicial 79.9823189267 69.6371 1 80.185770258285
328.528436315 80.1857702583 69.8440 2 80.1698461399823
328.5228916 80.16984614 69.8278 3 80.1710911862181
328.5233252 80.1710911862 69.8291 4 80.1709938326421
328.5232913 80.1709938326 69.8290 5 80.171001444935
328.5232939 80.1710014449 69.8290 6 80.1710008497126

Calcular P(sat) por Antoine Calcular P1(sat) com eq. Nova

T1(sat)/K P1(sat)/Kpa P2(sat)/Kpa iteração valor da pressão
Chute inicial 78.9652502462 68.6040 1 79.1544102239159
328.167489807 79.1544102239 68.7960 2 79.1427547854892
328.1633893 79.1427547855 68.7842 3 79.1434722468405
328.1636417 79.1434722468 68.7849 4 79.1434280801512

Calcular P(sat) por Antoine Calcular P1(sat) com eq. Nova

T1(sat)/K P1(sat)/Kpa P2(sat)/Kpa iteração valor da pressão
Chute inicial 77.9585603285 67.5839 1 78.1188036532554
327.801249433 78.1188036533 67.7461 2 78.1115190746256
327.7986595 78.1115190746 67.7387 3 78.1118499524716
327.7987772 78.1118499525 67.7391 4 78.111834922874

Calcular P(sat) por Antoine Calcular P1(sat) com eq. Nova

T1(sat)/K P1(sat)/Kpa P2(sat)/Kpa iteração valor da pressão
Chute inicial 76.9621727117 66.5765 1 77.0803331771709
327.430071689 77.0803331772 66.6958 2 77.0768117182579
327.4288062 77.0768117183 66.6922 3 77.0769166021535
327.4288439 77.0769166022 66.6923 4 77.0769134782122

Calcular P(sat) por Antoine Calcular P1(sat) com eq. Nova

T1(sat)/K P1(sat)/Kpa P2(sat)/Kpa iteração valor da pressão
Chute inicial 75.9760112273 65.5817 1 76.0403153525448
327.054304736 76.0403153525 65.6465 2 76.0393733887508
327.0539625 76.0393733888 65.6455 3 76.0393871826497
327.0539675 76.0393871826 65.6455 4 76.0393869806541

Calcular P(sat) por Antoine Calcular P1(sat) com eq. Nova

T1(sat)/K P1(sat)/Kpa P2(sat)/Kpa iteração valor da pressão
Chute inicial 75 64.5994 1 75
 P(t)/Kpa
75

X1 X2 SERÁ APENAS T INICIAL(CHUTE)

∑ Xi*Tisat
0 1

com eq. Nova

X1 X2
0 1

com eq. Nova Calcular T (chute inicial) Antoine X1 X2

X1 X2 T 329.884122794651 0.1 0.9
0.1 0.9

com eq. Nova Calcular T (chute inicial) Antoine X1 X2

X1 X2 T 329.527474479364 0.2 0.8
0.2 0.8

com eq. Nova Calcular T (chute inicial) Antoine X1 X2

X1 X2 T 329.170826164076 0.3 0.7
0.3 0.7

com eq. Nova Calcular T (chute inicial) Antoine X1 X2

X1 X2 T 328.814177848789 0.4 0.6
0.4 0.6
com eq. Nova Calcular T (chute inicial) Antoine X1 X2
X1 X2 T 328.457529533501 0.5 0.5
0.5 0.5

com eq. Nova Calcular T (chute inicial) Antoine X1 X2

X1 X2 T 328.100881218214 0.6 0.4
0.6 0.4

com eq. Nova Calcular T (chute inicial) Antoine X1 X2

X1 X2 T 327.744232902926 0.7 0.3
0.7 0.3

com eq. Nova Calcular T (chute inicial) Antoine X1 X2

X1 X2 T 327.387584587639 0.8 0.2
0.8 0.2

com eq. Nova Calcular T (chute inicial) Antoine X1 X2

X1 X2 T 327.030936272351 0.9 0.1
0.9 0.1

com eq. Nova Calcular T (chute inicial) Antoine X1 X2

X1 X2 T 326.674287957063 1 0
1 0
 X1 Y1 T(t) K X2 Y2 P1(sat) P2(sat) P(t)/Kpa
1 1 176.2 0 0 760 760
0.897384 0.957604 180 0.102616 0.042396 811 314
0.772812 0.896869 185 0.227188 0.103131 882 345
0.659758 0.830774 190 0.340242 0.169226 957 378
0.555377 0.757798 195 0.444623 0.242202 1037 414
0.459016 0.678257 200 0.540984 0.321743 1123 452
0.369444 0.590139 205 0.630556 0.409861 1214 494 250
0.287565 0.495671 210 0.712435 0.504329 1310 538
0.211608 0.393146 215 0.788392 0.606854 1412 585 200
0.141243 0.282486 220 0.858757 0.717514 1520 635

Temperatura
150
0.075855 0.162189 225 0.924145 0.837811 1625 689
0.012884 0.029769 230 1756 747 100
0 0 231.1 760
50

0
0 0.1
 P=75KPa=Constante
250

200
Temperatura

150

100

50

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
Composição
Componente A B C Yi
1 15.6782 2154.9 -34.52 0.5
2 15.8333 2477.07 -39.94 0.2
3 15.8366 2697.55 -48.78 0.3

Calcular T(sat) por Antoine

T1(sat) T2(sat) T3(sat)
354.12920265 399.071160494538 439.68981762

Calcular T (chute inicial) Antoine

T 388.78577871032

Calcular P(sat) por Antoine - PO

P1(sat) P2(sat) P3(sat)
14698.176161 6201.4625 2704.7486241
12604.592299 5168.31463009127 2194.5046673
15016.095703 6360.79042662618 2784.551622
17997.474667 7883.20780150069 3560.2799853
18005.041813 7887.13328667212 3562.3088454
18602.854724 8198.17649024047 3723.504125
18614.456368 8204.23075687166 3726.6501077
18642.225156 8218.72451716794 3734.1827995
P(sat) "inicial"/mmHg P(t)/mmHg
7600 7600
7600
7600

Cálculo do Ponto de Orvalho (PO) Cáculo do valor de Xi para PB

T(inicial) PO K1 2.452924 X1 0.203838
388.78577871032 1.34660083603 K2 1.081411 X2 0.184944
380.0568 1.63453599409 K3 0.49134 X3 0.610575
390.0365 1.31082907769 0.999357
400.9863 1.04435471541
401.0125 1.04380528212 Cálculo do Ponto de Bolha (PB)
403.0598 1.00200324158 T(inicial) PB
403.0991 1.00122219142 388.7857 0.762423
403.1931 0.99935722498 388.0156 1.192728
403.1931 1
 Calcular P(sat) por Antoine - PB
P1(sat) P2(sat) P3(sat)
14698.1563 6201.4526 2704.74366
14504.67025 6104.7886 2656.46557
18642.22516 8218.7245 3734.1828