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5. A linearidade faz parte das Figuras de Mérito de um procedimento analítico. Descreva sobre
faixa linear.
8. Como se obtém uma Curva Analítica e qual a sua utilidade nos métodos instrumentais?
9. Num procedimento analítico obteve-se a seguinte equação da reta: y = 123,4X – 0,089. Nas
determinações obteve os seguintes valores (em absorbância) 0,45 / 0,47 / 0,44 / 0,46 / 0,47.
Qual a concentração na amostra (mg/L)? Qual o valor do coeficiente angular? Qual o valor
do coeficiente linear?
10. Por que o coeficiente de correlação (R) deve ser muito próximo de 1?
Abstract
In this work, an on-line automated system for the preconcentration and evaluation of manganese in
food samples is proposed. The preconcentration of manganese ions is carried out using two
mini-columns packed with 4-(5′-bromo-2′-thiazolylazo)orcinol (Br-TAO) loaded polyurethane foam.
After a preconcentration step, a stream of hydrochloric acid is passed through the mini-column
in order to transport the manganese directly to the flame atomic absorption spectrometer.
The sample frequency was 60 h−1 for a 60 s preconcentration time.
The limit of detection and enrichment factor were 0.70 μg L−1 and 17, respectively.
The accuracy of the procedure was evaluated by analysis of biological reference materials
(spinach leaves, tomato leaves and pine needles).
The procedure was successfully applied for the evaluation of manganese
in several food samples, such as corn, rice and cassava flour.